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DOE OSTI2024

X-ray imaging and electron temperature evolution in laser-driven magnetic reconnection experiments at the national ignition facility

We present results from x-ray imaging of high-aspect-ratio magnetic reconnection experiments driven at the National Ignition Facility. Two parallel, self-magnetized, elongated laser-driven plumes are produced by tiling 40 laser beams. A magnetic reconnection layer is formed by the collision of the plumes. A gated x-ray framing pinhole camera with micro-channel plate detector produces multiple images through various filters of the formation and evolution of both the plumes and current sheet. As the diagnostic integrates plasma self-emission along the line of sight, two-dimensional electron temperature maps ⟨Te⟩Y are constructed by taking the ratio of intensity of these images obtained with different filters. The plumes have a characteristic temperature ⟨Te⟩Y=240 ± 20 eV at 2 ns after the initial laser irradiation and exhibit a slow cooling up to 4 ns. The reconnection layer forms at 3 ns with a temperature ⟨Te⟩Y=280 ± 50 eV as the result of the collision of the plumes. The error bars of the plumes and current sheet temperatures separate at 4 ns, showing the heating of the current sheet from colder inflows. Using a semi-analytical model, we survey various heating mechanisms in the current sheet. We find that reconnection energy conversion would dominate at low density (ne≲7×1018 cm−3) and electron-ion collisional drag at high-density (≳1019 cm−3).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1972

Investigation of the Ignition and Burning of Materials in Space Cabin Atmospheres. Part 1: Ignition and Burning of Material

An analytical study of the theory of ignition and burning of a plastic material immersed in an atmosphere of a space cabin which may be subjected to gravity force changes is considered. The hazardous condition in a space cabin environment where the changes of gravity may effect the combustion process is evaluated. The model considered the analysis of the coupled gas and solid phases and is based on the premise that material heating leads to the formation of pyrolysis gases from the decomposed solid which then react with the ambient oxidizer to further the combustion process. Moreover, free convection plays a dominant role in transporting these hot gases to the virgin material. A time-dependent study of the coupled gas-solid model as required for ignition processes with emphasis on the surface energy interchange of the gas and solid phases has been made. Detailed distribution of species composition and temperature patterns provide a spatial and time map of the evolving gases from the material combustion.

Lew, H. G.↗

NASA NTRS1992

Microstructural transitions during containerless processing of undercooled Fe-Ni alloys

In order to identify the possible hierarchy of microstructural pathways and transitions, a systematic evaluation of the microstructural evolution in undercooled Fe-Ni alloys was performed on uniformly processed samples covering seven orders of magnitude in volume. At appropriate undercooling levels, alternate solidification pathways become thermodynamically possible and metastable product structures can result from the operation of competitive solidification kinetics. For thermal history evaluation, a heat flow analysis was applied and tested with large Fe-Ni alloy particles (1 to 3 mm) to assess undercooling potential. Alloy powders (10 to 150 microns), with large liquid undercoolings, were studied under the same composition and processing conditions to evaluate the solidification kinetics and microstructural evolution, including fcc/bcc phase selection and the thermal stability of a retained metastable bcc phase. The identification of microstructural transitions with controlled variations in sample size and composition during containerless solidification processing was used to develop a microstructure map which delineates regimes of structural evolutions and provides a unified analysis of experimental observations in the Fe-Ni system.

Thoma, D. J.↗

NASA NTRS2000

The Coupled Roles of Dust and Clouds in the Mars Climate

During the period October 1997 to September 1999 we obtained and analyzed over 100 millimeter-wave observations of Mars atmospheric CO line absorption for atmospheric temperature profiles. These measurements extend through one full Mars year (solar longitudes L(sub S) of 190 deg in 1997 to 180 deg in 1999) and coincide with atmospheric temperature profile and dust column measurements front the Thermal Emission Spectrometer (TES) experiment on board the Mars Global Surveyor (MGS) spacecraft. A comparison of Mars atmospheric temperatures retrieved by these distinct methods provides the first opportunity to place the long-term (1982-1999) millimeter retrievals of Mars atmospheric temperatures within the context of contemporaneous, spatially mapped spacecraft, observations. Profile comparisons of 0-30 km altitude atmospheric temperatures retrieved with the two techniques agree typically to within the 5 K calibration accuracy of the millimeter observations. At the 0.5 mbar pressure level (approximately 25 km altitude) the 30N/30S average for TES infrared temperatures and the disk-averaged millimeter temperatures are also well correlated in their seasonal and dust-storm-related variations over the 1997-1999 period. This period includes the Noachis Terra regional dust storm, which led to very abrupt heating (approximately 15 K at 0.5 mbar) of the global Mars atmosphere at L(sub S)=224 deg in 1997 [Christensen et al., 1998; Conrath et al., this issue; Smith et al., this issue]. Much colder (10-20 K) global atmospheric temperatures were observed during the 1997 versus 1977 perihelion periods (L(sub S)=200 deg-330 deg), consistent with the much (2 to 8 times) lower global dust loading of the atmosphere during the 1997 perihelion dust storm season versus the Viking period of the 1977a,b storms. The 1998-1999 Mars atmosphere revealed by both the millimeter and TES observations is also 10-15 K colder than presented by the Viking climatology during the aphelion season (L(sub S)=0 deg-180 deg, northern spring/summer) of Mars. We reassess the observational basis of the Viking dusty-warm climatology for this season to conclude that the global aphelion atmosphere of Mars is colder, less dusty, and cloudier than indicated by the established Viking climatology even for the Viking period. We also conclude that Mars atmospheric temperatures exhibit their most significant interannual variations during the perihelion dust storm season (10-20 K for L(sub S)=200 deg-340 deg) and during the post-aphelion northern summer season (5-10 K for L(sub S)=100 deg-200 deg).

Clancy, R. Todd↗

NASA NTRS1995

NASA Tech Briefs, November 1995

The contents include: 1) Mission Accomplished; 2) Resource Report: Marshall Space Flight Center; 3) NASA 1995 Software of the Year Award; 4) Microbolometers Based on Epitaxial YBa2Cu3O(sub 7-x) Thin Films; 5) Garnet Random-Access Memory; 6) Fabrication of SNS Weak Links on SOS Substrates; 7) High-Voltage MOSFET Switching Circuit; 8) Asymmetric Switching for a PWM H-Bridge Power Circuit; 9) Better Ohmic Contacts for InP Semiconductor Devices; 10) Low-Bandgap Thermovoltaic Materials and Devices; 11) Digital Frequency-Differencing Circuit; 12) Imaging Magnetometer; 13) Computer-Assisted Monitoring of a Complex System; 14) Buffered Telemetry Demodulator; 15) Compact Multifunction Inspection Head; 16) Optical Detection of Fractures in Ceramic Diaphragms; 17) Eddy-Current Detection of Cracks in Reinforced Carbon/Carbon; 18) Apparent Thermal Conductivity of Multilayer Insulation; 19) Optimizing Misch-Metal Compositions in Metal Hydride Anodes; 20) Device for Sampling Surface Contamination; 21) Probabilistic Failure Assessment for Fatigue; 22) Probabilistic Fatigue and Flaw-Propagation Analysis; 23) Windows Program for Driving the TDU-850 Printer; 24) Subband/Transform MATLAB Functions for Processing Images; 25) Computing Equilibrium Chemical Compositions; 26) Program Processes Thermocouple Readings; 27) ICAN-Second-Generation Integrated Composite Analyzer; 28) Integrated Composite Analyzer with Damping Capabilities; 29) Computing Efficiency of Transfer of Microwave Power; 30) Program Calculates Power Demands of Electronic Designs; 31) Cost-Estimation Program; 32) Program Estimates Areas Required by Electronic Designs; 33) Program to Balance Mapped Turbopump Assemblies; 34) BiblioTech; 35) Controlling Mirror Tilt With a Bimorph Actuator; 36) Burst-Disk Device Simulates Effect of Pyrotechnic Device; 37) Bearing-Mounting Concept Accommodates Thermal Expansion; 38) Parallel-Plate Acoustic Absorbers for Hot Environments; 39) Adjustable-Length Strut Withstands Large Cyclic Loads; 40) Tool Indicates Contact Angles in Bearing Raceways; 41) Gravity Slides With Magnetic Braking; 42) High-Torque, Lightweight, Pneumatically Driven Wrench for Small Spaces; 43) Device for Testing Compatibility of an O-Ring; 44) Magnetic Heat Pump Containing Flow Diverters; 45) Variable-Tilt Helicopter Rotor Mast; 46) "Beach-Ball" Robotic Rovers; 47) Apparatus Would Measure Temperatures of Ball Bearings; 48) Flexible Borescope for Inspecting Ducts; 49) Texturing Copper To Reduce Secondary Emission of Electrons; 50) Automated Laser Cutting in Three Dimensions; 51) Algorithm Helps Monitor Engine Operation; 52) Flexible Revision of Data-Processing Communications; 53) Software for Managing the Use of Land; 54) Thermal Strap Increases Cryocooling Efficiency; 55) Reversible Nut With Engagement Indication; 56) Control Algorithms for Kinematically Redundant Manipulators; 57) Computed Hydrogen-Flow Splits in a Rocket Engine; 58) Pressure and Thermal Modeling of Rocket Launches; 59) Field of View of a Spacecraft Antenna: Analysis and Software; 60) Digital Controller for Laser-Beam-Steering Subsystem; 61) More About Beam-Steering Subsystem for Laser Communication; 62) Digital Controller for Laser-Beam-Steering Subsystem: Part 2; 63) Interface Circuit Board for Space-Shuttle Communications; 64) Automated Planning of Spacecraft Telecommunications; 65) Artifacts of Spectral Analysis of Instrument Readings; 66) Neural-Network Controller for Vibration Suppression; 67) Adaptive Finite-Element Computation in Fracture Mechanics; 68) Attitude Control for the Cassini Spacecraft; 69) Analytical Model for Fluid Dynamics in a Microgravity Environment; 70) Study of Rocket-Engine Joints Bonded by NVCU/NARloy-Z; 71) Improved Silicon Nitride for Advanced Heat Engines; 72) Parameters for Welding Aluminum/Lithium Alloys; 73) Lightweight Composite Intertank Structure; 74) Foil Patches Seal Small Vacuum Leaks; 75) Data Base on Cables and Connectors; 76) Effect of Clock Mode on Radiation Hardnessf an ADC; and 77) Fault-Tolerant Control for a Robotic Inspection System.

Source record↗

NASA NTRS2024

Storm-Time Variability of Terrestrial Hydrogen Exosphere: Kinetic Simulation Results

Recent studies of TWINS Lyman-α observations have reported an increase in geocoronal column brightness during geomagnetic storms, indicating enhanced exospheric hydrogen atom density (NH). This suggests a complex role of exospheric neutrals in determining storm-time magnetosphere dynamics and their energy release through charge-exchange processes. We developed a Model for Analyzing Terrestrial Exosphere (MATE) to investigate storm-time exospheric behaviors and their physical drivers. MATE traces test hydrogen atoms backward in time from locations in the exosphere to a nominal exobase altitude of 500 km, employing Newtonian mechanics with gravitational force. The model then calculates the phase-space densities (PSDs) of test hydrogen atoms at the exobase using the Maxwellian distribution with physics-based exobase conditions from the TIMEGCM upper atmosphere model. MATE maps PSDs at the exobase to the exosphere using Liouville’s Theorem under collisionless assumptions and derives NH by integrating the PSDs across velocity space. We conducted MATE simulation before, during, and after a minor geomagnetic storm from 12 to 18 June 2008, and compared the model results with NH estimates from the TWINS geocorona data. MATE reproduces storm-time density enhancements soon after the minimum Dst is reached, matching well with a general trend of TWINS NH estimates. The results suggest that upper atmospheric heating during a geomagnetic storm increases the number of ballistic and escaping hydrogen atoms entering the exosphere from the exobase, thereby boosting NH. However, the magnitude of modeled NH mismatches the TWINS NH estimates. The potential mechanisms of this density discrepancy include the physics excluded in the MATE model — such as neutralneutral collisions, neutral-plasma charge exchange, solar radiation pressure, and photoionization — as well as the higher exobase hydrogen density of TIMEGCM compared to typical empirical values, which will be addressed in future.

Hyunju K Connor↗

DOE OSTI2023

AN OVERVIEW OF THE DESIGN AND PERFORMANCE TESTING OF A 275 BAR INTEGRALLY GEARED SUPERCRITICAL CO2 COMPRESSOR FOR POWER GENERATION

An integrally geared compressor-expander (compander) for supercritical CO2 (sCO2) was developed to convert thermal energy to electricity. With operating pressures of 275 bar, this turbomachine represents the state of the art in integrally geared machine architecture, hitting compressor inlet densities of 600 kg/m3 and discharge pressures of 275 bar. The product development was funded by the Department of Energy’s Energy Efficiency and Renewable Energy Office under EE0007114 to advance the state of the art in concentrated solar power applications; however, the technology itself is agnostic to heat source, and is predicted to achieve a thermal-to-electric conversion efficiency of 50% for any indirect heat source capable of providing turbine inlet temperatures of 700°C or greater. While the program encompassed the design and testing for the compressor and turbine elements, this paper will focus on the compressor design and operation. The paper will begin with an introduction to the cycle design and analysis of an indirectly heated integrally geared sCO2 compander, a discussion of the mechanical and aerodynamic design of the compressor that is a two stage radial compressor operating subcritically at 27,512 rpm, and will then proceed to describe the test facility and measured data to characterize the performance and robustness of the machine. The paper will conclude with a discussion on lessons learned throughout the course of commissioning and testing. Practical aspects of testing a compressor operating near the dome including complications relating to obtaining an accurate compressor flow map, efficiency calculations, flow unsteadiness, and associated measurement uncertainties will be discussed.

wilkes, jason↗

NASA NTRS1985

The 8.3 and 12.4 micron imaging of the Galactic Center source complex with the Goddard infrared array camera

A 30 x 30 arcsec field at the Galactic Center (1.5 x 1.5 parsec) was mapped at 8.3 microns and 12.41 microns with high spatial resolution and accurate relative astrometry, using the 16 x 16 Si:Bi accumulation mode charge injection device Goddard infrared array camera. The design and performance of the array camera detector electronics system and image data processing techniques are discussed. Color temperature and dust opacity distributions derived from the spatially accurate images indicate that the compact infrared sources and the large scale ridge structure are bounded by warmer, more diffuse material. None of the objects appear to be heated appreciably by internal luminosity sources. These results are consistent with the model proposing that the complex is heated externally by a strong luminosity source at the Galactic Center, which dominates the energetics of the inner few parsecs of the galaxy.

Gezari, D. Y.↗

NASA NTRS1985

8.3 and 12.4 micron imaging of the Galactic Center source complex with the Goddard infrared array camera

Gezari, D. Y.↗

NASA NTRS1995

Graphite fiber textile preform/copper matrix composites

Graphite fiber reinforced/copper matrix composites have sufficiently high thermal conduction to make them candidate materials for critical heat transmitting and rejection components. The term textile composites arises because the preform is braided from fiber tows, conferring three-dimensional reinforcement and near net shape. The principal issues investigated in the past two years have centered on developing methods to characterize the preform and fabricated composite and on braidability. It is necessary to have an analytic structural description for both processing and final property modeling. The structure of the true 3-D braids used is complex and has required considerable effort to model. A structural mapping has been developed as a foundation for analytic models for thermal conduction and mechanical properties. The conductivity has contributions both from the copper and the reinforcement. The latter is accomplished by graphitization of the fibers, the higher the amount of graphitization the greater the conduction. This is accompanied by an increase in the fiber modulus, which is desirable from a stiffness point of view but decreases the braidability; the highest conductivity fibers are simply too brittle to be braided. Considerable effort has been expended on determining the optimal braidability--conductivity region. While a number of preforms have been fabricated, one other complication intervenes; graphite and copper are immiscible, resulting in a poor mechanical bond and difficulties in infiltration by molten copper. The approach taken is to utilize a proprietary fiber coating process developed by TRA, of Salt Lake City, Utah, which forms an itermediary bond. A number of preforms have been fabricated from a variety of fiber types and two sets of these have been infiltrated with OFHC copper, one with the TRA coating and one without. Mechanical tests have been performed using a small-scale specimen method and show the coated specimens to have superior mechanical properties. Final batches of preforms, including a finned, near net shape tube, are being fabricated and will be infiltrated before summer.

Gilatovs, G. J.↗

NASA NTRS2012

Lunar Prospecting Using Thermal Wadis and Compact Rovers: Infrastructure for Surviving the Lunar Night - Part A

Recent missions have confirmed the existence of water and other volatiles on the Moon, both in permanently-shadowed craters and elsewhere. Non-volatile lunar resources may represent significant additional value as infrastructure or manufacturing feedstock. Characterization of lunar resources in terms of abundance concentrations, distribution, and recoverability is limited to in-situ Apollo samples and the expanding remote-sensing database. This paper introduces an approach to lunar resource prospecting supported by a simple lunar surface infrastructure based on the Thermal Wadi concept of thermal energy storage and using compact rovers equipped with appropriate prospecting sensors and demonstration resource extraction capabilities. Thermal Wadis are engineered sources of heat and power based on the storage and retrieval of solar-thermal energy in modified lunar regolith. Because Thermal Wadis keep compact prospecting rovers warm during periods of lunar darkness, the rovers are able to survive months to years on the lunar surface rather than just weeks without being required to carry the burdensome capability to do so. The resulting lower-cost, long-lived rovers represent a potential paradigm breakthrough in extra-terrestrial prospecting productivity and will enable the production of detailed resource maps. Integrating resource processing and other technology demonstrations that are based on the content of the resource maps will inform engineering economic studies that can define the true resource potential of the Moon. Once this resource potential is understood quantitatively, humans might return to the Moon with an economically sound objective including where to go, what to do upon arrival, and what to bring along.

Sacksteder, Kurt R.↗

NASA NTRS2018

Dynamic Power Convertor Development for Radioisotope Power Systems at NASA GRC

The Thermal Energy Conversion Branch at NASA Glenn Research Center (GRC) is supporting the development of high-efficiency power convertors in support of Radioisotope Power System (RPS) development. Significant progress was made towards such a system that utilized Stirling conversion machines during the 2001 to 2015 timeframe. Flight development of the Advanced Stirling Radioisotope Generator (ASRG) was cancelled in 2013 by the Department of Energy (DOE) and NASA Headquarters primarily due to budget constraints, and the Advanced Stirling Convertor (ASC) technology contract was subsequently concluded in 2015. A new chapter of technology development has recently been initiated by the NASA RPS Program. This new effort is considering all dynamic power convertor options, such as Stirling and Brayton cycles. Four convertor development contracts supporting this effort were awarded in 2017. The awarded contracts include two free-piston Stirling, one thermoacoustic Stirling, and one turbo-Brayton designs. The technology development contracts each consist of up to three phases: Design, Fabricate, and Test. As of May 2018, all contracts have completed the Design Phase, and each underwent a design review with an independent review board. Two of the contracts have been awarded the Phase 2 option for fabrication. Convertors manifesting from these development efforts will then undergo independent validation and verification at NASA facilities, which will consist of convertor performance and RPS viability demonstrations. Example tests include launch vibration simulation, performance mapping over the environmental temperature range, and static acceleration exposure. In parallel with this renewed development effort, NASA GRC is still demonstrating free-piston Stirling convertor technology using assets from previous projects. The Stirling Research Laboratory (SRL) is still operating 10 convertors from previous development projects. Four of which are flexure-bearing based, and the other six are gas-bearing based. One of the flexure-bearing convertors has accumulated over 110,000 hours of operation, and holds the current maintenance-free heat-engine run-time record. Another flexure-bearing convertor was recently manually shutdown after 105,620 hours of operation, then disassembled and inspected. This inspection produced a wealth of information about the effects of this amount of runtime on the technology's components. One of the engineering unit flexure-bearing convertors recently underwent launch simulation vibration test, a static acceleration exposure up to 20 g, and was then placed on extended operation. Amongst the gas-bearing convertors, the longest running unit has accumulated over 70,000 hours of operation. Four high-fidelity gas-bearing convertors from the ASRG project are still operating continuously, for which the longest runtime has reached 26,000 hours.

Oriti, Salvatore↗

DOE OSTI2024

The Evolution of Galaxies and Clusters at High Spatial Resolution with Advanced X-ray Imaging Satellite (AXIS)

Stellar and black hole feedback heat and disperse surrounding cold gas clouds, launching gas flows off circumnuclear and galactic disks, producing a dynamic interstellar medium. On large scales bordering the cosmic web, feedback drives enriched gas out of galaxies and groups, seeding the intergalactic medium with heavy elements. In this way, feedback shapes galaxy evolution by shutting down star formation and ultimately curtailing the growth of structure after the peak at redshift 2–3. To understand the complex interplay between gravity and feedback, we must resolve both the key physics within galaxies and map the impact of these processes over large scales, out into the cosmic web. The Advanced X-ray Imaging Satellite (AXIS) is a proposed X-ray probe mission for the 2030s with arcsecond spatial resolution, large effective area, and low background. AXIS will untangle the interactions of winds, radiation, jets, and supernovae with the surrounding interstellar medium across the wide range of mass scales and large volumes driving galaxy evolution and trace the establishment of feedback back to the main event at cosmic noon. This white paper is part of a series commissioned for the AXIS Probe mission concept; additional AXIS white papers can be found at the AXIS website.

47 OTHER INSTRUMENTATION↗

NASA NTRS2000

Polar Spacecraft Based Comparisons of Intense Electric Fields and Poynting Flux Near and Within the Plasma Sheet-Tail Lobe Boundary to UVI Images: An Energy Source for the Aurora

In this paper, we present measurements from two passes of the Polar spacecraft of intense electric and magnetic field structures associated with Alfven waves at and within the outer boundary of the plasma sheet at geocentric distances of 4-6 R(sub E), near local midnight. The electric field variations have maximum values exceeding 100 mV/m and are typically polarized approximately normal to the plasma sheet boundary. The electric field structures investigated vary over timescales (in the spacecraft frame.) ranging front 1 to 30 s. They are associated with strong magnetic field fluctuations with amplitudes of 10-40 nT which lie predominantly ill the plane of the plasma sheet and are perpendicular to the local magnetic field. The Poynting flux associated with the perturbation fields measured at these altitudes is about 1-2 ergs per square centimeters per second and is directed along the average magnetic field direction toward the ionosphere. If the measured Poynting flux is mapped to ionospheric altitudes along converging magnetic field lines. the resulting energy flux ranges up to 100 ergs per centimeter squared per second. These strongly enhanced Poynting fluxes appear to occur in layers which are observed when the spacecraft is magnetically conjugate (to within a 1 degree mapping accuracy) to intense auroral structures as detected by the Polar UV Imager (UVI). The electron energy flux (averaged over a spatial resolution of 0.5 degrees) deposited in the ionosphere due to auroral electron beams as estimated from the intensity in the UVI Lyman-Birge-Hopfield-long filters is 15-30 ergs per centimeter squared per second. Thus there is evidence that these electric field structures provide sufficient Poynting flux to power the acceleration of auroral electrons (as well as the energization of upflowing ions and Joule heating of the ionosphere). During some events the phasing and ratio of the transverse electric and magnetic field variations are consistent with earthward propagation of Alfven surface waves with phase velocities of 4000-10000 kilometers per second. During other events the phase shifts between electric and magnetic fields suggest interference between upward and downward propagating Alfven waves. The E/B ratios are about an order of magnitude larger than typical values of C/SIGMA(sub p), where SIGMA(sub p), is the height integrated Pedersen conductivity. The contribution to the total energy flux at these altitudes from Poynting flux associated with Alfven waves is comparable to or larger than the contribution from the particle energy flux and 1-2 orders of magnitude larger than that estimated from the large-scale steady state convection electric field and field-aligned current system.

Wygant, J. R.↗

NASA NTRS2002

Infrared Spectroscopy as a Chemical Fingerprinting Tool

Infrared (IR) spectroscopy is a powerful analytical tool in the chemical fingerprinting of materials. The technique is rapid, reproducible and usually non-invasive. With the appropriate accessories, the technique can be used to examine samples in either a solid, liquid or gas phase. Solid samples of varying sizes and shapes may be used, and with the addition of microscopic IR (microspectroscopy) capabilities, minute materials such as single fibers and threads may be examined. With the addition of appropriate software, microspectroscopy can be used for automated discrete point or compositional surface area mapping, with the latter providing a means to record changes in the chemical composition of a material surface over a defined area. Both aqueous and non-aqueous free-flowing solutions can be analyzed using appropriate IR techniques, as can viscous liquids such as heavy oils and greases. Due to the ability to characterize gaseous samples, IR spectroscopy can also be coupled with thermal processes such as thermogravimetric (TG) analyses to provide both thermal and chemical data in a single run. In this configuration, solids (or liquids) heated in a TG analyzer undergo decomposition, with the evolving gases directed into the IR spectrometer. Thus, information is provided on the thermal properties of a material and the order in which its chemical constituents are broken down during incremental heating. Specific examples of these varied applications will be cited, with data interpretation and method limitations further discussed.

Huff, Tim↗

NASA NTRS2004

On Nonlinear Combustion Instability in Liquid Propellant Rocket Motors

All liquid propellant rocket instability calculations in current use have limited value in the predictive sense and serve mainly as a correlating framework for the available data sets. The well-known n-t model first introduced by Crocco and Cheng in 1956 is still used as the primary analytical tool of this type. A multitude of attempts to establish practical analytical methods have achieved only limited success. These methods usually produce only stability boundary maps that are of little use in making critical design decisions in new motor development programs. Recent progress in understanding the mechanisms of combustion instability in solid propellant rockets"' provides a firm foundation for a new approach to prediction, diagnosis, and correction of the closely related problems in liquid motor instability. For predictive tools to be useful in the motor design process, they must have the capability to accurately determine: 1) time evolution of the pressure oscillations and limit amplitude, 2) critical triggering pulse amplitude, and 3) unsteady heat transfer rates at injector surfaces and chamber walls. The method described in this paper relates these critical motor characteristics directly to system design parameters. Inclusion of mechanisms such as wave steepening, vorticity production and transport, and unsteady detonation wave phenomena greatly enhance the representation of key features of motor chamber oscillatory behavior. The basic theoretical model is described and preliminary computations are compared to experimental data. A plan to develop the new predictive method into a comprehensive analysis tool is also described.

Sims, J. D.↗

DOE OSTI2021

Magnetic ground state of the one-dimensional ferromagnetic chain compounds M (NCS) 2 (thiourea) 2 (M=Ni,Co)

The magnetic properties of the two isostructural molecule-based magnets— Ni ( NCS ) 2 ( thiourea ) 2 , S = 1 [ thiourea = SC ( NH 2 ) 2 ] and Co ( NCS ) 2 ( thiourea ) 2 , S = 3 / 2 —are characterized using several techniques in order to rationalize their relationship with structural parameters and to ascertain magnetic changes caused by substitution of the spin. Zero-field heat capacity and muon-spin relaxation measurements reveal low-temperature long-range ordering in both compounds, in addition to Ising-like ( D < 0 ) single-ion anisotropy ( D Co ~ - 100 K, D Ni ~ - 10 K). Crystal and electronic structure, combined with dc-field magnetometry, affirm highly quasi-one-dimensional behavior, with ferromagnetic intrachain exchange interactions J Co ≈ + 4 K and J Ni ~ + 100 K and weak antiferromagnetic interchain exchange, on the order of J ' ~ - 0.1 K. Furthermore, electron charge- and spin-density mapping reveals through-space exchange as a mechanism to explain the large discrepancy in J -values despite, from a structural perspective, the highly similar exchange pathways in both materials. Both species can be compared to the similar compounds M Cl 2 ( thiourea ) 4 , M = Ni(II) (DTN) and Co(II) (DTC), where DTN is known to harbor two magnetic-field-induced quantum critical points. Direct comparison of DTN and DTC with the compounds studied here shows that substituting the halide Cl - ion for the NCS - ion results in a dramatic change in both the structural and magnetic properties.

36 MATERIALS SCIENCE↗

DOE OSTI2026

TRACE Input Modernization

This work presents a Tom’s Obvious Minimal Language (TOML)-based representation of input for the US Nuclear Regulatory Commission’s TRAC/RELAP Advanced Computational Engine (TRACE) thermal hydraulics code. Implemented using the Workbench Analysis Sequence Processor (WASP), the approach maps traditional TRACE input structures to a hierarchical format composed of named parameters, typed values, and native data collections. The resulting representation preserves TRACE’s existing modeling capabilities while providing a modern, structured interface for model development and management. WASP further extends TOML through a file import directive that supports modular model composition and reusable input organization. In addition, WASP provides extended array data entry convenience with various data repeat and interpolation capabilities. Examples of the new TOML syntax are provided for major TRACE input categories, including hydraulic components, heat structures, control systems, and trip logic. The TOML representation establishes a foundation for improved validation, tooling, automation, and model maintainability while remaining compatible with existing TRACE workflows. To facilitate migration to the TOML-based input format, the TRACE executable now supports conversion of native TRACE input into an intermediate JSON representation. A Python utility subsequently transforms the JSON data into an equivalent TOML model. Lastly, the TRACE executable now supports execution using TOML-formatted input.

Lefebvre, Robert A. [Oak Ridge National Laboratory↗