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At least 1,099 records · Page 61

Two-color, intracavity pump–probe, cavity ringdown spectroscopy

Here, we report a proof-of-principle demonstration of intracavity pump–probe, cavity ringdown (CRD) detection in a three-mirror, traveling-wave cavity. With cavity-enhanced pump power and probe absorption path length, the technique is a generally applicable, high-sensitivity, high-selectivity detection method. In our experiments, the pump radiation is switched off during every other probe ringdown, which allows uncorrelated measurements of analyte and background cavity decay rates. The net, two-color signal from the difference between the pump-on and pump-off decay rates is immune to empty-CRD drifts and spectral overlaps from non-target molecular transitions. The immunity to the ringdown drifts allows longer signal-averaging and, thus, higher detection sensitivity. The ability to compensate for the background absorption enhances the detection selectivity in spectrally congested regions. Our technique is well-suited for trace-detection in the mid-IR region, where pump–probe schemes based on strong rovibrational transitions can be applied. In this work, two-color CRD detection is implemented on a ladder-type, three-level system based on the N 2 O, ν 3 = 1 ← 0, P(19) (pump) and ν 3 = 2 ← 1, R(18) (probe), rovibrational transitions. By frequency-locking two-quantum cascade lasers to the p-polarization (pump, Finesse = 5280) and s-polarization (probe, Finesse = 67 700) cavity modes, we achieve high intracavity pump power (36 W) and high probe ringdown rates (>2 kHz). The observed two-color spectra are simulated by a density-matrix, three-level system model that is solved under the constraints of the cavity resonance conditions. In addition to its background compensation capability, experimental flexibility in the selection of pump–probe schemes and signal insensitivity to intracavity laser power are further features that enhance the utility of our technique for mid-IR trace-detection.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Coherent spin wave excitation with radio-frequency spin–orbit torque

Spin waves, collective perturbations of magnetic moments, are both fundamental probes for magnetic physics and promising candidates for energy-efficient signal processing and computation. Traditionally, coherent propagating spin waves have been generated by radio frequency (RF) inductive Oersted fields from current-carrying electrodes. An alternative mechanism, spin–orbit torque (SOT), offers more localized excitation through interfacial spin accumulation but has been mostly limited to DC to kHz frequencies. SOT driven by RF currents, with potentially enhanced pumping efficiency and unique spin dynamics, remains largely unexplored, especially in magnetic insulators. Here, we conduct a comprehensive theoretical and computational investigation into the generation of coherent spin waves via RF-SOT in the prototypical yttrium iron garnet. We characterize the excitation of forward volume, backward volume, and surface modes in both linear and nonlinear regimes, employing single and interdigitated electrode configurations. We reveal and explain several unique and surprising features of RF-SOT compared to inductive excitation, including higher efficiency, distinct mode selectivity, and directional symmetry, a ~ $3π/4$ phase offset, reduced anharmonic distortion in the nonlinear regime, and the absence of second harmonic generation. These insights position RF-SOT as a promising new mechanism for future magnonic and spintronic applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Structural basis for divergent and convergent evolution of catalytic machineries in plant aromatic amino acid decarboxylase proteins

Radiation of the plant pyridoxal 5'-phosphate (PLP)-dependent aromatic L -amino acid decarboxylase (AAAD) family has yielded an array of paralogous enzymes exhibiting divergent substrate preferences and catalytic mechanisms. Plant AAADs catalyze either the decarboxylation or decarboxylation-dependent oxidative deamination of aromatic L -amino acids to produce aromatic monoamines or aromatic acetaldehydes, respectively. These compounds serve as key precursors for the biosynthesis of several important classes of plant natural products, including indole alkaloids, benzylisoquinoline alkaloids, hydroxycinnamic acid amides, phenylacetaldehyde-derived floral volatiles, and tyrosol derivatives. In this paper, we present the crystal structures of four functionally distinct plant AAAD paralogs. Through structural and functional analyses, we identify variable structural features of the substrate-binding pocket that underlie the divergent evolution of substrate selectivity toward indole, phenyl, or hydroxyphenyl amino acids in plant AAADs. Moreover, we describe two mechanistic classes of independently arising mutations in AAAD paralogs leading to the convergent evolution of the derived aldehyde synthase activity. Applying knowledge learned from this study, we successfully engineered a shortened benzylisoquinoline alkaloid pathway to produce (S)-norcoclaurine in yeast. This work highlights the pliability of the AAAD fold that allows change of substrate selectivity and access to alternative catalytic mechanisms with only a few mutations.

59 BASIC BIOLOGICAL SCIENCES↗

The Closure Relations in Optical Afterglow of Gamma-Ray Bursts

Gamma-ray bursts (GRBs) are extremely high-energy events that can be observed at very high redshift. In addition to γ rays, they can emit in X-ray, optical, and sometimes radio wavelengths. Here, following the approach in Srinivasaragavan et al.; Dainotti et al.; and Dainotti et al., we consider 82 GRBs from Dainotti et al. that have been observed in optical wavelengths and fitted with a broken power law. We consider the relations between the spectral and temporal indices (closure relations; CRs) according to the synchrotron forward-shock model evolving in the constant-density interstellar medium (ISM; k = 0) and the stellar wind environment (k = 2) in both slow- and fast-cooling regimes, where the density profile is defined as n ∝ r -k . We find the $ν$ > $max${$ν$ c , $ν$ m } regime is most favored, where ν c and ν m are the cooling and characteristic frequencies, respectively. Finally, we test the 2D Dainotti correlation between the rest-frame end time of the plateau and the luminosity at that time on GRBs that fulfill the most-favored CRs. When we compare the intrinsic scatter σ int of those 2D correlations to the scatter presented in Dainotti et al., we see the scatters of our correlations generally agree with the previous values within 1σ, both before and after correction for selection bias. This new information has helped us to pinpoint subsamples of GRBs with features that could drive the GRB emission mechanism, and eventually allow for GRBs to be used as standard candles.

79 ASTRONOMY AND ASTROPHYSICS↗

Boundary layer moisture variability at the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic observatory during marine conditions

Abstract. Boundary layer moisture variability at the Eastern North Atlantic (ENA) site during marine conditions is examined at monthly and daily timescales using 5 years of ground-based observations and output from the European Center for Medium range Weather Forecast (ECMWF) reanalysis model. The annual cycle of the mixed-layer total water budgets is presented to estimate the relative contribution of large-scale advection, local moisture tendency, entrainment, and precipitation to balance the moistening due to surface latent heat flux on monthly timescales. When marine conditions prevail, advection of colder and dry air from the north acts as an important moisture sink (∼ 50 % of the overall budget) during fall and winter driving the seasonality of the budget. Entrainment and precipitation contribute to the drying of the boundary layer (∼ 25 % and ∼ 15 % respectively), and the local change in moisture contributes to a small residual part. On a daily temporal scale, moist and dry mesoscale columns of vapor (∼ 10 km) are analyzed during 10 selected days of precipitating stratocumulus clouds. Adjacent moist and dry columns present distinct mesoscale features that are strongly correlated with clouds and precipitation. Dry columns adjacent to moist columns have more frequent and stronger downdrafts immediately below the cloud base. Moist columns have more frequent updrafts, stronger cloud-top cooling, and higher liquid water path and precipitation compared to the dry columns. This study highlights the complex interaction between large-scale and local processes controlling the boundary layer moisture and the importance of spatial distribution of vapor to support convection and precipitation.

54 ENVIRONMENTAL SCIENCES↗

Long-term measurements of ice nucleating particles at Atmospheric Radiation Measurement (ARM) sites worldwide

Ice nucleating particles (INPs) play a critical role in cloud microphysics and precipitation formation, yet long-term, spatially extensive observational datasets remain limited. Here, we present one of the most comprehensive publicly available datasets of immersion-mode INP concentrations using a single analytical method, generated through the U.S. Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) user facility. INP filter samples have been collected across a broad range of environments – including agricultural plains, Arctic coastlines, high-elevation mountain sites, marine regions, and urban areas – via fixed observatories, mobile facility deployments, and vertically-resolved tethered balloon system operations. We describe the standardized processing and quality assurance pipeline, from filter collection and processing using the Ice Nucleation Spectrometer to final data products archived on the ARM Data Discovery portal. The dataset includes both total INP concentrations and selectively treated samples, allowing for classification of biological, organic, and inorganic INP types. It features a continuous 5-year record of INP measurements from a central U.S. site, with data collection still ongoing. Seasonal and site-specific differences in INP concentrations are illustrated through intercomparisons at −10 and −20 °C, revealing distinct regional sources and atmospheric drivers. We also outline mechanisms for researchers to access existing data, request additional sample analyses, and propose future field campaigns involving ARM INP measurements. This dataset supports a wide range of scientific applications, from observational and mechanistic studies to model development, and provides critical constraints on aerosol-cloud interactions across diverse atmospheric regimes (Creamean et al., 2024, 2020b; https://doi.org/10.5439/1770816).

Creamean, Jessie M. [Colorado State Univ., Fort Co↗

Pattern recognition system and procedures

The ratio transformation technique is used to determine effective features as function of time in remote multiple sensing of crops and soils. The selection of quantizer parameters for a two-class recognition problem under the criteria of minimizing the probability of errors is also discussed.

Nelson, G. D.↗

The programming language HAL: A specification

HAL accomplishes three significant objectives: (1) increased readability, through the use of a natural two-dimensional mathematical format; (2) increased reliability, by providing for selective recognition of common data and subroutines, and by incorporating specific data-protect features; (3) real-time control facility, by including a comprehensive set of real-time control commands and signal conditions. Although HAL is designed primarily for programming on-board computers, it is general enough to meet nearly all the needs in the production, verification and support of aerospace, and other real-time applications.

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Editing ERTS-1 data to exclude land aids cluster analysis of water targets

The author has identified the following significant results. It has been determined that an increase in the number of spectrally distinct coastal water types is achieved when data values over the adjacent land areas are excluded from the processing routine. This finding resulted from an automatic clustering analysis of ERTS-1 system corrected MSS scene 1002-18134 of 25 July 1972 over Monterey Bay, California. When the entire study area data set was submitted to the clustering only two distinct water classes were extracted. However, when the land area data points were removed from the data set and resubmitted to the clustering routine, four distinct groupings of water features were identified. Additionally, unlike the previous separation, the four types could be correlated to features observable in the associated ERTS-1 imagery. This exercise demonstrates that by proper selection of data submitted to the processing routine, based upon the specific application of study, additional information may be extracted from the ERTS-1 MSS data.

Erb, R. B.↗

Current structural vibration problems associated with noise

As the performance of aerospace vehicles has increased, the noise generated by the propulsion system and by the passage of the vehicle through the air has also increased. Further increases in performance are now underway for space vehicles such as the space shuttle vehicle and for short distance takeoff and landing (STOL) aircraft, and are being planned for supersonic aircraft. The flight profiles and design features of these high-performance vehicles are reviewed and an estimate made of selected noise-induced structural vibration problems. Considerations for the prevention of acoustic fatigue, noise transmission, and electronic instrument malfunction are discussed.

Mixson, J. S.↗

The utilization of LANDSAT imagery in nuclear power plant siting

LANDSAT imagery was used primarily to map geologic features such as lineaments, linears, faults, and other major geologic structures which affect site selection for a nuclear power plant. Areas studied include Pakistan, the South Carolina Piedmont, and Huelva, Spain.

Eggenberger, A. J.↗

Design data brochure for the Owens-Illinois Sunpak (TM) air-cooled solar collector

Information necessary to evaluate the design and installation of the Owens-Illinois Sunpak TM Air-Cooled Solar Collector is presented. Information includes collector features, fluid flow, thermal performance, installation and system tips. The collector utilizes a highly selective wavelength coating in combination with vacuum insulation, which virtually eliminates conduction and convention losses.

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The ground segment

The LMSS ground segment consists of two types of terminals, mobile and fixed. The salient features of these two components of the LMSS ground segment are discussed. Factors surrounding selection of a modulation scheme for the LMSS are presented. The mobile vehicle antenna, which with its attendant mechanical and electrical requirements pose a challenging problem to the LMSS designers, is covered.

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Solidification of undercooled liquids

During rapid solidification processing (RSP) the amount of liquid undercooling is an important factor in determining microstructural development by controlling phase selection during nucleation and morphological evolution during crystal growth. While undercooling is an inherent feature of many techniques of RSP, the deepest undercoolings and most controlled studies have been possible in carefully prepared fine droplet samples. From past work and recent advances in studies of nucleation kinetics it has become clear that the initiation of crystallization during RSP is governed usually by heterogeneous sites located at surfaces. With known nucleant sites, it has been possible to identify specific pathways of metastable phase formation and microstructural development in alloys. These advances have allowed for a clearer assessment of the interplay between undercooling, cooling rate and particle size statistics in structure formation. New approaches to the examination of growth processes have been developed to follow the thermal behavior and morphology in small samples in the period of rapid crystallization and recalescence. Based upon the new experimental information from these studies, useful models can be developed for the overall solidification process to include nucleation behavior, thermodynamic constraints, thermal history, growth kinetics, solute redistribution and resulting structures. From the refinement of knowledge concerning the underlying factors that govern RSP a basis is emerging for an effective alloy design and processing strategy.

Perepezko, J. H.↗

Flexible aircraft flying and ride qualities

A brief analytic exposition is presented to illustrate a central principle in flexible mode control, some of the pertinent pilot centered requirements are listed and discussed. The desired features of the control methodology are exposed and the methodology to be used is selected. The example Boeing supplied characteristics are discussed and approximated with a reduced order model and a simplified treatment of unsteady aerodynamics. The closed loop flight control system design follows, along with first level assessments of resulting handling and ride quality characteristics. Some of these do not meet the postulated requirements and remain problems to be solved possibly by further analysis or future simulation.

Ashkenas, I. L.↗

On the Latitudinal Distribution of Debris in the Northern Hemisphere of Mars

Examination of Mariner 9 images showed evidence of debris mantling on Mars. The evidence included craters that appeared to be filled with debris and an apparent lack of small craters. Based on such data, it was suggested that a circumpolar debris mantle exists poleward of about 30N and 30S latitudes. The presence of a debris layer has important implications for the modulation over time of atmospheric pressure by the cap-regolith-atmosphere system. Preliminary efforts in providing constraints on the thickness and distribution of debris are discussed. The initial approach is to examine crater size-frequency data for selected regions on Mars, later expanding the study to include an inventory of aeolian features and other direct indicators of debris deposition. The crater size-frequency distributions for ten regions between latitudes 20N and 80N and covering a range of longitudes were discovered. Crater data were derived from Viking Orbiter images with resolutions of between 26 and 75 meters/pixel.

Guinness, E. A.↗

Detection and analysis of photospheric CNO features in the ultraviolet spectrum of the hot DO white dwarf PG 1034 + 001

An analysis of PG 1034 + 001 extended to include the high-dispersion IUE spectra and the high-resolution optical multiple-mirror telescope echelle spectra is discussed. The observations reveal the presence of absorption lines (C IV at 1548 and 1551 A, N V at 1238 and 1242 A, and O V at 1371 A) from highly ionized species with large redshifts (+ 40-50) km/s) relative to the interstellar lines. The results of a preliminary abundance analysis of the photospheric lines, together with the results of a search of sharp shortward-shifted features are presented. An interpretation of the observed abundances is made in terms of selective radiative forces acting in a high-temperature photosphere. Some speculations on the evolutionary status of DO stars like PG 1034 + 001 are given.

Sion, E. M.↗

Advanced X-ray Astrophysics Facility (AXAF) instrumentation

The instrumentation planned for the Advanced X-ray Astrophysics Facility (AXAF), a space-based observation platform for the 1990s, is described. The AXAF will feature a grazing incidence telescope at the end of the observatory and four independently selected instruments at the other end, including: a CCD imaging spectrometer; a Bragg crystal spectrometer; and two transmission grating spectrometers located directly behind the telescope to detect first order spectral images. The instruments are currently in the definition phase to be followed by design and development starting in the late 1980s. A detailed schematic diagram of the Bragg crystal imaging spectrometer is provided.

Winkler, C. E.↗