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NASA NTRS2013

Thermal and Structural Performance of Woven Carbon Cloth For Adaptive Deployable Entry and Placement Technology

Arcjet testing and analysis of a three-dimensional (3D) woven carbon fabric has shown that it can be used as a thermal protection system and as a load bearing structural component for a low ballistic coefficient hypersonic decelerator called ADEPT (Adaptive Deployable Entry and Placement Technology). Results of arcjet tests proved that the 3D woven carbon fabric can withstand flight-like heating while under flight-like biaxial mechanical loads representative of those encountered during shallow entry flight path angles into the atmosphere of Venus. Importantly, the arcjet test results have been used to extend a preliminary material thermal response model based on previous testing of the same 3D woven carbon fabric under uni-axial mechanical loading.

Carbon fabric↗

NASA NTRS2013

Photosynthesis-dependent Isoprene Emission from Leaf to Planet in a Global Carbon-chemistry-climate Model

We describe the implementation of a biochemical model of isoprene emission that depends on the electron requirement for isoprene synthesis into the FarquharBallBerry leaf model of photosynthesis and stomatal conductance that is embedded within a global chemistry-climate simulation framework. The isoprene production is calculated as a function of electron transport-limited photosynthesis, intercellular and atmospheric carbon dioxide concentration, and canopy temperature. The vegetation biophysics module computes the photosynthetic uptake of carbon dioxide coupled with the transpiration of water vapor and the isoprene emission rate at the 30 min physical integration time step of the global chemistry-climate model. In the model, the rate of carbon assimilation provides the dominant control on isoprene emission variability over canopy temperature. A control simulation representative of the present-day climatic state that uses 8 plant functional types (PFTs), prescribed phenology and generic PFT-specific isoprene emission potentials (fraction of electrons available for isoprene synthesis) reproduces 50 of the variability across different ecosystems and seasons in a global database of 28 measured campaign-average fluxes. Compared to time-varying isoprene flux measurements at 9 select sites, the model authentically captures the observed variability in the 30 min average diurnal cycle (R2 6496) and simulates the flux magnitude to within a factor of 2. The control run yields a global isoprene source strength of 451 TgC yr1 that increases by 30 in the artificial absence of plant water stress and by 55 for potential natural vegetation.

photosynthesis↗

NASA NTRS2013

Label-Free Detection of Cardiac Troponin-I Using Carbon Nanofiber Based Nanoelectrode Arrays

A sensor platform based on vertically aligned carbon nanofibers (CNFs) has been developed. Their inherent nanometer scale, high conductivity, wide potential window, good biocompatibility and well-defined surface chemistry make them ideal candidates as biosensor electrodes. A carbon nanofiber (CNF) multiplexed array has been fabricated with 9 sensing pads, each containing 40,000 carbon nanofibers as nanoelectrodes. Here, we report the use of vertically aligned CNF nanoelectrodes for the detection of cardiac Troponin-I for the early diagnosis of myocardial infarction. Antibody, antitroponin, probe immobilization and subsequent binding to human cardiac troponin-I were characterized using electrochemical impedance spectroscopy and cyclic voltammetry techniques. Each step of the modification process resulted in changes in electrical capacitance or resistance to charge transfer due to the changes at the electrode surface upon antibody immobilization and binding to the specific antigen. This sensor demonstrates high sensitivity, down to 0.2 ng/mL, and good selectivity making this platform a good candidate for early stage diagnosis of myocardial infarction.

cardiac output↗

NASA NTRS2014

A Five-year Performance Study of Low VOC Coatings over Zinc Thermal Spray for the Protection of Carbon Steel at the Kennedy Space Center

The launch facilities at the Kennedy Space Center (KSC) are located approximately 1000 feet from the Atlantic Ocean where they are exposed to salt deposits, high humidity, high UV degradation, and acidic exhaust from solid rocket boosters. These assets are constructed from carbon steel, which requires a suitable coating to provide long-term protection to reduce corrosion and its associated costs. While currently used coating systems provide excellent corrosion control performance, they are subject to occupational, safety, and environmental regulations at the Federal and State levels that limit their use. Many contain high volatile organic compounds (VOCs), hazardous air pollutants, and other hazardous materials. Hazardous waste from coating operations include vacuum filters, zinc dust, hazardous paint related material, and solid paint. There are also worker safety issues such as exposure to solvents and isocyanates. To address these issues, top-coated thermal spray zinc coating systems were investigated as a promising environmentally friendly corrosion protection for carbon steel in an acidic launch environment. Additional benefits of the combined coating system include a long service life, cathodic protection to the substrate, no volatile contaminants, and high service temperatures. This paper reports the results of a performance based study to evaluate low VOC topcoats (for thermal spray zinc coatings) on carbon steel for use in a space launch environment.

Zinc Thermal Spray↗

NASA NTRS2010

Measuring CO2 from Space: The NASA Orbiting Carbon Observatory-2

The Orbiting Carbon Observatory (OCO) was the first NASA satellite designed to measure atmospheric carbon dioxide (CO2) from space with the precision, resolution, and coverage needed to detect CO2 surface fluxes. OCO was designed to collect 0.5 to 1 million soundings each day. Typical measurements over land were expected to have precisions of 0.3% within surface footprints smaller less than 3 square km. This project suffered a major setback in February 2009 when the OCO launch vehicle failed to achieve orbit and the satellite was lost. The U.S. Congress has since authorized a restart of the OCO project, and the President's 2010 budget proposal includes funding to develop and fly a replacement for OCO that could be ready for launch no later than February 2013. This mission has been designated OCO-2. While this mission will be a near "carbon copy" of OCO, some changes were needed to replace components that were no longer available. Here, we describe the capabilities, of the OCO-2 mission, highlighting its differences from OCO.

carbon cycle↗

NASA NTRS2014

Revised (Mixed-Effects) Estimation for Forest Burning Emissions of Gases and Smoke, Fire/Emission Factor Typology, and Potential Remote Sensing Classification of Types for Ozone and Black-Carbon Simulation

We summarize recent progress (a) in correcting biomass burning emissions factors deduced from airborne sampling of forest fire plumes, (b) in understanding the variability in reactivity of the fresh plumes sampled in ARCTAS (2008), DC3 (2012), and SEAC4RS (2013) airborne missions, and (c) in a consequent search for remotely sensed quantities that help classify forest-fire plumes. Particle properties, chemical speciation, and smoke radiative properties are related and mutually informative, as pictures below suggest (slopes of lines of same color are similar). (a) Mixed-effects (random-effects) statistical modeling provides estimates of both emission factors and a reasonable description of carbon-burned simultaneously. Different fire plumes will have very different contributions to volatile organic carbon reactivity; this may help explain differences of free NOx(both gas- and particle-phase), and also of ozone production, that have been noted for forest-fire plumes in California. Our evaluations check or correct emission factors based on sequential measurements (e.g., the Normalized Ratio Enhancement and similar methods). We stress the dangers of methods relying on emission-ratios to CO. (b) This work confirms and extends many reports of great situational variability in emissions factors. VOCs vary in OH reactivity and NOx-binding. Reasons for variability are not only fuel composition, fuel condition, etc., but are confused somewhat by rapid transformation and mixing of emissions. We use "unmixing" (distinct from mixed-effects) statistics and compare briefly to approaches like neural nets. We focus on one particularly intense fire the notorious Yosemite Rim Fire of 2013. In some samples, NOx activity was not so suppressed by binding into nitrates as in other fires. While our fire-typing is evolving and subject to debate, the carbon-burned delta(CO2+CO) estimates that arise from mixed effects models, free of confusion by background-CO2 variation, should provide a solid base for discussion. (c) We report progress using promising links we find between emissions-related "fire types" and promising features deducible from remote observations of plumes, e.g., single scatter albedo, Angstrom exponent of scattering, Angstrom exponent of absorption, (CO column density)/(aerosol optical depth).

Remote sensing↗

NASA NTRS2017

Heatshield for Extreme Entry Environment Technology (HEEET) Enabling Missions Beyond Heritage Carbon Phenolic

Future NASA robotic missions utilizing an entry system into Venus and the outer planets, results in extremely high entry conditions that exceed the capabilities of state of the art low to mid density ablators such as PICA or AVCOAT. Previously, mission planners had to assume the use of fully dense carbon phenolic heatshields similar to what was flown on Pioneer Venus or Galileo. Carbon phenolic is a robust TPS material, however, its high density and relatively high thermal conductivity constrain mission planners to steep entries, with high heat fluxes and pressures and short entry durations. The high entry conditions pose challenges for certification in existing ground based test facilities and the longer-term sustainability of CP will continue to pose challenges. NASA has decided to invest in new technology development rather than invest in reviving carbon phenolic. The HEEET project, funded by STMD is maturing a game changing Woven Thermal Protection System technology. HEEET is a capability development project and is not tied to a single mission or destination, therefore, it is challenging to complete ground testing needed to demonstrate a capability that is much broader than any single mission or destination would require. This presentation will status HEEET progress. Near term infusion target for HEEET is the upcoming New Frontiers (NF-4) class of competitively selected Science Mission Directorate (SMD) missions for which it is incentivized.

thermal protection↗

NASA NTRS2018

Ecosystem Carbon Emissions from 2015 Forest Fires in Interior Alaska

In the summer of 2015, hundreds of wildfires burned across the state of Alaska, and consumed more than 1.6 million ha of boreal forest and wetlands in the Yukon-Koyukuk region. Mapping of 113 large wildfires using Landsat satellite images from before and after 2015 indicated that nearly 60% of this area was burned at moderate-to-high severity levels. Field measurements near the town of Tanana on the Yukon River were carried out in July of 2017 in both unburned and 2015 burned forested areas (nearly adjacent to one-another) to visually verify locations of different Landsat burn severity classes (low, moderate, or high). Results: Field measurements indicated that the loss of surface organic layers in boreal ecosystem fires is a major factor determining post-fire soil temperature changes, depth of thawing, and carbon losses from the mineral topsoil layer. Measurements in forest sites showed that soil temperature profiles to 30 cm depth at burned forest sites increased by an average of 8o - 10o C compared to unburned forest sites. Sampling and laboratory analysis indicated a 65% reduction in soil carbon content and a 58% reduction in soil nitrogen content in severely burned sample sites compared to soil mineral samples from nearby unburned spruce forests. Conclusions: Combined with nearly unprecedented forest areas severely burned in the Interior region of Alaska in 2015, total ecosystem fire emission of carbon to the atmosphere exceeded most previous estimates for the state.

Ecosystem↗

NASA NTRS2019

Holocene Vegetation, Climate, and Carbon History on Western Kodiak Island, Alaska

At Phalarope Pond, western Kodiak Island, a multidisciplinary study using pollen and spores, macrofossils, stable isotopes, and carbon accumulation provides the Holocene vegetation and climate history following the deglaciation that began over 16,000 cal years ago (yr BP) [years Before Present, as calibrated from 1950]. Following a cold and dry Younger Dryas, a warm and wet early Holocene was characterized by abundant ferns in a sedge tundra environment with maximum carbon accumulation, similar to high latitude peatlands globally. About 8,700 cal yr BP sedge and ferns declined and climate remained warm as drier conditions prevailed, limiting carbon sequestration. The abrupt shift in D/H (Deuterium/Hydrogen) isotopes of about 60 percent indicates a shift to cooler conditions or a more distal moisture source. Neoglaciation beginning about 3,700 cal yr BP is evident from increases in Artemisia, Empetrum and Betula, signifying cooler conditions, while Alnus declines, paralleling regional trends.

Alaska↗

NASA NTRS2019

Assimilation of Remotely Sensed Leaf Area Index into the Noah-MP Land Surface Model: Impacts on Water and Carbon Fluxes and States over the Continental U.S.

Accurate representation of vegetation states is required for the modeling of terrestrial water-energy-carbon exchanges and the characterization of the impacts of natural and anthropogenic vegetation changes on the land surface. This study presents a comprehensive evaluation of the impact of assimilating remote sensing-based Leaf Area Index (LAI) retrievals over the Continental U.S. in the Noah-MP land surface model, during a time period of 2000 to 2017. The results demonstrate that the assimilation has a beneficial impact on the simulation of key water budget terms such as soil moisture, evapotranspiration, snow depth, terrestrial water storage and streamflow, when compared with a large suite of reference datasets. In addition, the assimilation of LAI is also found to improve the carbon fluxes of Gross Primary Production (GPP) and Net Ecosystem Exchange (NEE). Most prominent improvements in the water and carbon variables are observed over the agricultural areas of the U.S., where assimilation improves the representation of vegetation seasonality impacted by cropping schedules. The systematic, added improvements from assimilation in a configuration that employs high quality boundary conditions highlight the significant utility of LAI data assimilation in capturing the impacts of vegetation changes.

anthropogenic vegetation↗

NASA NTRSDate not supplied

Structural Carbon Nanotube Development

Mechanical properties of carbon nanotubes (CNTs) at the nanoscale suggest their potential to enable significantly lighter structures of interest in aerospace applications. As different formats of the material became available over the last 20 years, understanding of how CNTs contribute to improvements in mechanical properties of structural composites has evolved.Although the material is now available in large quantities that permit the development of composite fabrication processes, the retention of properties that make these materials attractive on the nano scale remains a challenge in large assemblies of CNTs. The work to be presented will summarize lessons learned in our efforts to produce carbon nanotube composites with tensile properties that begin to rival those of carbon fiber reinforced polymer composites. Challenges that need to be overcome for practical adoption of this emerging material system will be considered.

Carbon nanotube↗

NASA NTRS2019

Land carbon models underestimate the severity and duration of drought’s impact on plant productivity

The ability to accurately predict ecosystem drought response and recovery is necessary to produce reliable forecasts of land carbon uptake and future climate. Using a suite of models from the Multi-scale Synthesis and Terrestrial Model Intercomparison Project (MsTMIP), we assessed modeled net primary productivity (NPP) response to, and recovery from, drought events against a benchmark derived from tree ring observations between 1948 and 2008 across forested regions of the US and Europe. We find short lag times (0–6 months) between climate anomalies and modeled NPP response. Although models accurately simulate the direction of drought legacy effects (i.e. NPP decreases), projected effects are approximately four times shorter and four times weaker than observations suggest. This discrepancy between observed and simulated vegetation recovery from drought reveals a potential critical model deficiency. Since productivity is a crucial component of the land carbon balance, models that underestimate drought recovery time could overestimate predictions of future land carbon sink strength and, consequently, underestimate forecasts of atmospheric CO2.

carbon cycle↗

NASA NTRS2022

Tracing the Path of Carbon Export in the Ocean though DNA Sequencing of Individual Sinking Particles

Surface phytoplankton communities were linked with the carbon they export into the deep ocean by comparing 18 S rRNA gene sequence communities from surface seawater and individually isolated sinking particles. Particles were collected in sediment traps deployed at locations in the North Pacific subtropical gyre and the California Current. DNA was isolated from individual particles, bulk-collected trap particles, and the surface seawater. The relative sequence abundance of exported phytoplankton taxa in the surface water varied across functional groups and ecosystems. Of the sequences detected in sinking particles, about half were present in large (>300 μm), individually isolated particles and primarily belonged to taxa with small cell sizes (<50 μm). Exported phytoplankton taxa detected only in bulk trap samples, and thus presumably packaged in the smaller sinking size fraction, contained taxa that typically have large cell sizes (>500 m). The effect of particle degradation on the detectable 18 S rRNA gene community differed across taxa, and differences in community composition among individual particles from the same location largely reflected differences in relative degradation state. Using these data and particle imaging, we present an approach that incorporates genetic diversity into mechanistic models of the ocean's biological carbon pump, which will lead to better quantification of the ocean’s carbon cycle.

Carbon Expert↗

NASA NTRSDate not supplied

The Ocean’s Breath: How Autonomous Robotic Vehicles at Sea and Super Computers are Helping us Understand the Carbon Cycle in the Ocean

Carbon dioxide due to human activities such as fossil fuel burning has well-known and concerning implications for global temperatures as well as terrestrial and marine ecosystems. Hence, an important objective of NASA Earth science is to observe and understand the variations in the global carbon cycle and the associated climate and ecosystem impacts in the context of past and projected anthropogenic emissions. In my presentation, I will tell the story of how some of my collaborators and I are using autonomous robotic vehicles and super computers to try to untangle the mysteries of the carbon cycle in the ocean, which depends in fascinating ways on atmospheric and ocean physics, marine ecosystem dynamics, as well as the chemistry of the seawater.

Ocean's breath↗

NASA NTRSDate not supplied

Degradation of Carbon Fiber Microstructures Due to Oxidative Etch Pitting

In order to understand the influence of etch pits on the material properties of carbon fiber microstructures, we use the Porous Microstructure Analysis (PuMA) software to create realistic pitted structures from virgin fiber structures and then analyze their degradation as the degree of pitting increases. For that purpose, we developed a pitting module within PuMA that creates pits with user-defined geometry (shape, size) and distribution (defect density) on the surface of arbitrary microstructures. In this work, we consider FiberForm microstructures, which are commonly used as the base material for ablative thermal protection systems (TPS). Using the new pitting module, we mimic the evolution of etch pits on FiberForm as it occurs from oxidation in ablative heating environments, by first importing the virgin FiberForm structure from a micrograph scan and then imposing different pitting conditions by varying pit radii and defect densities. We then leverage PuMA’s capabilities to calculate material properties for each structure. The results clearly show the degradation of thermal conductivity and structural integrity as etch pits grow, and furthermore highlight the complex evolution of the surface topology, which results in significant changes of the flowgeometry and chemical gas-surface interactions. Furthermore, a comparison of these changes with the case of shrinking fibers, which has heretofore been the standard for modelling ablation of carbon structures, yields significant differences. For example, we observe the formation of small chunks of fibers as pits grow in size, which could be released into the surrounding flow environment as spallation particles. This motivates us to continue our efforts of modelling pitting as an integral part of the structural degradation of carbon fiber structures in oxidation environments, which will ultimately improve our understanding of failure mechanisms in those materials.

PuMA↗

NASA NTRS2023

Remote Sensing of Dissolved Organic Carbon (DOC) Stocks, Fluxes and Transformations Along the Land-Ocean Aquatic Continuum: Advances, Challenges, and Opportunities

From stream headwaters to the deep ocean, dissolved organic carbon (DOC) is ubiquitous across the world’s aquatic systems, where it fulfills important biogeochemical and ecological functions. Importantly, DOC is a dynamic component of the carbon cycle and represents a global reservoir (mass of carbon) equivalent in size to the atmospheric CO 2 pool. The mobilization, transport, and transformations of DOC along the land-ocean aquatic continuum biogeochemically connect terrestrial landscapes, freshwater and marine ecosystems, and the atmosphere. As a result, DOC budgets are vulnerable to climate- and human-driven changes. Having the ability to quantify DOC stocks, fluxes, and transformations consistently and accurately in aquatic systems is therefore critical to our understanding of DOC’s functions in the environment and of their susceptibility to change. In recent years, optical techniques and synoptic earth observations have opened new doors to achieve this objective on a global scale. In this review, we explore how in situ measurements, earth observations, and the models they inform have facilitated the large-scale quantification of DOC stocks, fluxes, and transformations along the land-ocean aquatic continuum and how they have helped shape our current understanding of the global DOC cycle. The review also explores the limitations and challenges we still face today, and discusses how upcoming and future sensors are expected to provide new insights into our understanding of the global DOC cycle.

Dissolved organic carbon↗

NASA NTRSDate not supplied

Degradation of Carbon Fiber Microstructures Due to Oxidative Etch Pitting

PuMA↗

NASA NTRS2023

New York Ecological Conservation: Evaluating Agricultural Conservation Easement Impact Using Earth Observations to Examine Avoided Soil Carbon Loss to Development

Farmland provides ecosystems and communities with services ranging from habitat conservation to food security. As total U.S. farmland continues to decline, agricultural lands near urban areas are especially vulnerable. Our project partners—Finger Lakes Land Trust, Genesee Land Trust, and Saratoga Preserving Land and Nature (PLAN)—can use study results to better profile farmland vulnerability, issuing conservation easements to protect maximum acreage in Saratoga County and the Finger Lakes Region of New York. Multiple existing studies effectively use remote sensing imagery to analyze historical land cover and forecast future change. This study examined soil carbon stocks and land cover change to estimate avoided soil carbon loss. We also predicted farmland vulnerability. We completed these analyses using European Space Agency (ESA) and NASA Earth observations that include Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI), Landsat 9 OLI-2, Sentinel-2 Multispectral Instrument (MSI), and Suomi National Polar-Orbiting Partnership (NPP) Visible Infrared Imaging Radiometer Suite (VIIRS) for nighttime lights data that aided in the land change model analysis. We determined that the conversion of agriculture to development from 1990 to 2022 occurred at rates of 0.91% (Finger Lakes) and 7% (Saratoga). Urban development is predicted to increase surrounding urban centers through 2030 and 2050. We also estimate that between 26.5 and 348,101 kilotons (Finger Lakes) and 3.7 and 58,006 kilotons (Saratoga) of soil carbon losses have been avoided through agricultural easements. Findings from this study will support our partners in determining agricultural conservation easement benefits and prioritizing the acquisition of future easement sites.

Agriculture↗