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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Pilot-Scale Silicone Process for Low-Cost Carbon Dioxide Capture

GE Global Research is developing technology to remove carbon dioxide (CO 2) from the flue gas of coal-fired powerplants. A mixture of 3-aminopropyl end-capped polydimethylsiloxane (GAP-1m) and triethylene glycol (TEG) is the preferred CO2-capture solvent. GE Global Research was contracted by the Department of Energy to test a pilot-scale continuous CO2 absorption/desorption system using a GAP-1m/TEG mixture as the solvent. As part of that effort, an Environmental, Health, and Safety (EH&S) assessment for a CO2-capture system for a 550 MW coal-fired powerplant was conducted. Five components of the solvent, CAS#2469-55-8 (GAP-0), CAS#106214-84-0 (GAP-1-4), TEG, and methanol and xylene (minor contaminants from the aminosilicone) are included in this assessment. One by-product, GAP- 1m/SOX salt, and dodecylbenzenesulfonicacid (DDBSA) were also identified foranalysis. An EH&S assessment was also completed for the manufacturing process for the GAP-1m solvent. The chemicals associated with the manufacturing process include methanol, xylene, allyl chloride, potassium cyanate, sodium hydroxide (NaOH), tetramethyldisiloxane (TMDSO), tetramethyl ammonium hydroxide, Karstedt catalyst, octamethylcyclotetrasiloxane (D4), Aliquat 336, methyl carbamate, potassium chloride, trimethylamine, and (3-aminopropyl) dimethyl silanol. The toxicological effects of each component of both the CO2 capture system and the manufacturing process were defined, and control mechanisms necessary to comply with U.S. EH&S regulations are summarized. Engineering and control systems, including environmental abatement, are described for minimizing exposure and release of the chemical components. Proper handling and storage recommendations are made for each chemical to minimize risk to workers and the surrounding community.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2014

Rebuild of Capture Cavity 1 at Fermilab

The front end of the proposed Advanced Superconducting Test Accelerator at Fermilab employs two single cavity cryomodules, known as 'Capture Cavity 1' and 'Capture Cavity 2', for the first stage of acceleration. Capture Cavity 1 was previously used as the accelerating structure for the A0 Photoinjector to a peak energy of ~14 MeV. In its new location a gradient of ~25 MV/m is required. This has necessitated a major rebuild of the cryomodule including replacement of the cavity with a higher gradient one. Retrofitting the cavity and making upgrades to the module required significant redesign. The design choices and their rationale, summary of the rebuild, and early test results are presented.

43 PARTICLE ACCELERATORS↗
DOE OSTI2019

SUBTASK 2.3 – SUPPORT OF DOE CARBON CAPTURE SYSTEMS DEVELOPMENT AND MODELING

The ultimate goal of this project is to reduce uncertainty in the deployment of carbon capture and storage (CCS) technologies by overcoming key challenges through a combination of experimentation and modeling studies. The studies focused on key areas of concern for CCS systems and worked to increase overall confidence in the technology. To achieve project goals, the Energy & Environmental Research Center (EERC) identified the following objectives: Determine the potential impacts of coal combustion-derived aerosols on solvent emissions, solvent degradation, and fouling of postcombustion CO2 capture systems. Identify methods to control the formation of aerosols. Evaluate, quantify, and document the regional impacts that could result from implementation of CO2 capture technologies and enhanced oil recovery. Support U.S. Department of Energy (DOE) modeling efforts by providing key information to help reduce the uncertainty of future CCS projects and increase investor and public confidence in the technologies. Four activities were executed to support this effort, and the detailed results of these activities are presented herein. This project was cofunded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FE0024233. Nonfederal funding was provided by the North Dakota Industrial Commission, Mitsubishi Heavy Industries America, Minnkota Power Cooperative, ALLETE, and the Lignite Energy Council.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2019

Subtask 2.5 – Syngas Testing of NETL's Advanced Precombustion CO2 Capture Solvent

U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) on-site researchers have been examining and developing a novel solvent for precombustion capture that has the potential for improved performance and lower costs compared to Selexol™ and Rectisol®. In Subtask 2.5, the Energy & Environmental Research Center (EERC) conducted actual comparison tests on actual coal-derived syngas of a PEGDME (polyethylene glycol dimethyl ether) Selexol-type solvent and three other solvents provided by NETL. One was a new hybrid PEG–PDMS (poly[dimethylsiloxane]) solvent engineered by NETL. In addition, two commercially available chemicals that are projected to have good CO2 capture abilities were also selected for testing on actual coal-derived syngas. These tests were conducted in the EERC high-pressure fluid-bed gasifier (HPFBG) system utilizing an existing gas-sweetening absorption system (GSAS) to test the solvents. The four solvents tested were Solvent 1 – AGR II from Coastal Chemical Co., LLC, NETL Solvent 2 – XG-3229 Bis(methoxytriethyleneoxypropyl)hexamethyltrisiloxane, as manufactured by Gelast, Inc.; Solvent 3 – CASSH-1 (diethyl sebacate), procured from Sigma Aldrich; and Solvent 4 – TBP (tributyl phosphate), purchased from ThermoFisher Scientific. The solvents were all tested at a consistent syngas flow and composition at approximately 50 bar to make direct comparisons easier; two solvent flow rates which would bracket 90% CO2 capture; and, temperatures of 10°, 25°, 40°, and 55°C to determine the effects of temperature on CO2 uptake and CO2 to H2 selectivity. Figure E-1 shows the results for CO2 uptake and selectivity for the various solvents. These data show that the CO2 uptake for the Selexol-type solvent for the PEG-PDMS-3 and CASHH-1 solvents at higher operating temperatures around 40°C was better than the Selexol-type solvent was able to achieve at the lower operating temperature of 10°C. Selectivity of CO2 over H2 was at least as good as Selexol for the PEG-PDMS-3 solvent and even better than Selexol for the CASSH-1 solvent. The TBP solvent also displayed good CO2 uptake; however, CO2/H2 selectivity was worse than for the Selexol-type solvent. Operation of precombustion CO2 solvents at temperatures above ambient can provide a 2% process efficiency improvement along with a significant capital cost reduction since refrigeration and solvent dehydration equipment is not required. The excellent results from these tests warrant further longer-duration testing with one or both superior NETL-provided solvents to determine if longer-term exposure to any coal-derived syngas trace species may have an adverse impact on solvent performance. This project was funded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FE0024233.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2018

A Viable Path Forward to Carbon Capture and Storage in Wyoming, USA

The State of Wyoming, USA, benefits from favorable geologic, regulatory, and infrastructure attributes that promote efficient and sustainable carbon capture and storage (CCS). Two research sites in Wyoming exhibit high potential for the underground geologic storage of greater than 50 million metric tons of carbon dioxide (CO 2 ) over 25 years. Funded by the U.S. Department of Energy’s (DOE) Carbon Storage Assurance and Facility Enterprise (DOE CarbonSAFE) Phase I prefeasibility initiative, studies of both sites indicate promising capture, transport, utilization, and storage characteristics. The Dry Fork site is located near Gillette, in northeast Wyoming. Four storage reservoir/seal pairs have been identified at the Dry Fork site that provide excellent prospects for stacked storage of CO 2 . All four reservoirs lie at sufficient depths to maintain supercritical CO 2 and all four seals exhibit favorable characteristics for stratigraphic confinement. The reservoir with the highest expected significance is the Pennsylvanian/Permian Minnelusa Formation, which consists of near-shore dunes and shoreline sands, as well as shale and carbonate layers. The Minnelusa resides at a depth of ~2,900 m below the land surface and is ~45 m thick in the study area. Average porosity for samples from core within 10 km of the study area is 9%, with permeability values as high as 169 mD (n=6). The Permian Opeche Formation seals the Minnelusa and consists of redbed shales with minor fine-grained siltstones and evaporite deposits. Entry pressures as high as ~4700 psia were measured by mercury injection capillary pressure (MICP) analysis on core samples from the Opeche. A CarbonSAFE Phase II feasibility proposal at the Dry Fork site has recently been selected by DOE for negotiation leading to award. The second proposed site is located at the Rock Springs Uplift (RSU) in southwest Wyoming. Four reservoir/seal pairs have been studied at the RSU, all of which present promising geologic attributes for the stacked storage of CO 2 . The two deepest reservoirs (Mississippian Madison Limestone and Pennsylvanian/Permian Weber Formation) and their seals were studied previously under the auspices of the Wyoming Carbon Underground Storage Project (WY-CUSP), which was funded by DOE and the State of Wyoming. For the more recent CarbonSAFE initiative, two shallower reservoir/seal pairs were studied in detail. The highest priority of these reservoirs is the Triassic/Jurassic Nugget Formation, which consists of eolian sands and minor fluvial and interdune deposits. The Nugget lies at a depth of ~2,800 m and is ~140 m thick in the study area. Average measured porosity for samples from core within 40 km of the study site is 9%, with permeability values as high as 91 mD (n=10). The Nugget is sealed by the overlying Jurassic Gypsum Spring and Morrison Formations, as well as a thick (~1,700 m) regional Upper Cretaceous seal that includes shales from multiple geologic units. Entry pressures as high as 1120 psia were measured by MICP for shales within this regional confining unit. Overall, the State of Wyoming provides an advantageous climate to develop sustainable integrated CCS projects based on the following considerations: (1) well-characterized and favorable geology; (2) some of the largest deposits of economically recoverable coal in the USA; (3) an existing CO 2 -enhanced oil recovery industry, including CO 2 pipeline infrastructure; (4) supportive commercial enterprises, including utilities and the oil and gas industry; (5) supportive policymakers; (6) a favorable legal and regulatory environment; (7) proximity to carbon-constrained markets such as the State of California; (8) large CO 2 emission sources, including coal-fired power plants; and (9) backing for carbon capture, storage, and management related research and development, specifically implementation of the Integrated Test Center at Dry Fork Station, which is hosting the coal-track of the NRG/COSIA Carbon XPrize® competition.

Phillips, Erin↗
DOE OSTI2021

Polyamine phosphorus dendrimer materials for carbon dioxide capture

The present disclosure provides novel solid sorbents synthesized by the reaction of polyamines with polyaldehyde phosphorous dendrimer (P-dendrimer) compounds. The sorbents are highly stable and exhibit rapid reaction kinetics with carbon dioxide, making the sorbents applicable for carbon capture, and can be easily regenerated for further use. The material is stable to aqueous and organic media, as well as strong acid and bases. The sorbent maintains full capacity over extended use. The material can be used for CO2 capture from pure CO2 streams, mixed gas streams, simulated flue gas, and ambient air. Additionally, the material can be adhered to surfaces for reversible CO2 capture applications outside of bulk particle-based processes.

Thompson, III, Samuel John↗
DOE OSTI2021

Recent Improvements in the Beam Capture at Fermilab Booster for High Intensity Operation

The Fermilab Booster uses multi-turn beam injection with all its cavities phased such that beam sees a net zero RF voltage even when each station is at the same maxi-mum voltage. During beam capture the RF voltage is increased slowly by using its paraphase system. At the end of the capture the feedback is turned on for beam acceleration. It is vital for present operations as well as during the PIP-II era that both the HLRF and LLRF systems provide the proper intended phase and RF voltage to preserve the longitudinal emittance from injection to extraction. In this paper, we describe the original architecture of the cavity phase distribution, our recent beam-based RF phase measurements, observed significant deviation in the relative phases between cavities and correction effort. Results from the improved capture for high intensity beam are also presented.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Additional Analysis of Carbon Capture at Industrial Facilities

This poster provides summary cost details for a technoeconomic analysis of CO2 capture from flue gas generated by cement plants, conducted by U.S. Department of Energy National Energy Technology Laboratory and presented at the 2022 Carbon Management Project Review Meeting held in Pittsburgh, PA (August 15-19, 2022). A range of modern cement plant configurations was considered, along with different fuel types (coal, coke, and natural gas) and two levels of CO2 capture (95% and 99%). The sensitivity of capture cost to a range of modeling assumptions (such as fuel price, financing assumptions, utilization rate, and plant size) was also conducted, to show possible cost ranges that could be expected for decarbonization of typical cement plants in the U.S.

Hughes, Sydney↗
DOE OSTI2022

User Guide for the Public Industrial CO2 Capture Retrofit Database Models

OBSOLETE CCRD – SUPERSEDED<p>The National Energy Technology Laboratory (NETL) user manual accompanies the carbon capture retrofit database (CCRD) model that allows users to evaluate the cost of carbon capture on industrial sources (ammonia, cement, ethanol, hydrogen, and natural gas processing). The model was created by the National Energy Technology Laboratory (NETL) based on the technical report titled &quot;Cost of Capturing CO2 from Industrial Sources&quot; (NETL/DOE-2022/3319). Revised 12/21/22.</p>

Hughes, Sydney↗
DOE OSTI2022

Industrial CO2 Capture Retrofit Database (IND CCRD)

OBSOLETE CCRD - SUPERSEDED<p>This carbon capture retrofit database (CCRD) model allows users to evaluate the cost of carbon capture on industrial sources (ammonia, cement, ethanol, hydrogen, and natural gas processing). The model was created by the National Energy Technology Laboratory (NETL) based on the technical report titled Cost of Capturing CO2 from Industrial Sources (NETL/DOE-2022/3319). Revised 12/21/22.</p>

Hughes, Sydney↗
DOE OSTI2023

Demographic Microsimulator for Integrated Urban Systems: Adapting Panel Survey of Income Dynamics to Capture the Continuum of Life

Agent-based models (ABMs) simulate activity and travel decisions at the disaggregate level of households, and individuals. To do this, ABMs require detailed information pertaining to socioeconomic and demographic characteristics of individuals. Various synthetic population generators (SPGs) have been proposed to address this need. However, most of the SPGs currently in practice are cross-sectional in nature, and do not account for the interrelationships among household's or individual's life progression. This is a major shortcoming of SPGs as literature has shown that transportation decisions are impacted by lifecycle events that unfold over a span of time. While some demographic evolution simulators have been proposed to address this shortcoming, they: i) are developed using cross-sectional data, ii) do not capture the full spectrum of lifecycle events and their interdependency. Overcoming these drawbacks, this paper proposes a Demographic Microsimulator (DEMOS) which captures the 'continuum of life' by accounting for a range of household-, and individual-level lifecycle events. DEMOS is developed using the Panel Survey of Income Dynamics, which is one of the world's longest running longitudinal surveys. DEMOS sub-models consider key lifecycle events which are influenced by a host of demographic variables. The whole framework is applied to evolve the population of San Francisco Bay Area over a 9-year horizon. Results indicate that the household and individual evolution are tightly connected, and that the structural framework (i.e., model sequencing) is a key element in capturing the population trend accurately.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗
DOE OSTI2023

Comparative Economic Analysis of Capture, Transport, and Storage from a CO2 Source Perspective

This presentation provides an overview of a study that evaluated multiple carbon capture and storage (CCS) networks within the Central United States using NETL-developed resources and models to assess management options different CO2 source types face from both economic and regional geologic perspectives when capturing, transporting and storing their CO2. It was presented at the Carbon Capture, Utilization, and Storage (CCUS) 2023 conference, organized and presented by the Society of Petroleum Engineers (SPE), American Association of Petroleum Geologists (AAPG), and Society of Exploration Geophysicists (SEG) and held in Houston, Texas, April 25-27, 2023.

Guinan, Allison↗
DOE OSTI2022

Bio-Energy with Carbon Capture and Storage (BECCS): Achieving Net Zero and Beyond

This work evaluates the life cycle environmental performance of Bioenergy with Carbon Capture and Storage (BECCS) across different biomass types, processing technologies, and capture rates. Preliminary results suggest that carbon neutrality could be achieved if 35% biomass is co-fired with 90% carbon capture and sequestration.

Carlson, Derrick R.↗
DOE OSTI2020

The Use of Silver Chloride Injection in Remediation of Iodine-129 by In Situ Capture as Silver Iodide at the F-Area Seepage Basin - 20225

The Savannah River Site (SRS) produced tritium, plutonium, and special nuclear materials for national defense, medicine, and the space programs. As part of operations, the F-Area Seepage Basins operated until 1988 for the disposition of deionized acidic wastewater from the F Separations Facility. The wastewater contained dilute nitric acid and low concentrations of non-radioactive metals, and radionuclides, with the major isotopes being Cs-137, Sr-90, U-235, U-238, Pu-239, Tc-99, I-129, and tritium. The seepage basins were closed in 1988 and backfilled and capped by 1991. The groundwater emanating from beneath the closed and capped seepage basins is acidic and contains elevated levels of both chemical and radiological contaminants. Releases from the groundwater plumes sourced from the F-Area Seepage Basins have impacted the water quality of Fourmile Branch, which is a small tributary to the Savannah River, a regional water source. A large pump-and-treat system was constructed in 1997 and operated until 2003 in an attempt to capture the releases to Fourmile Branch. The system in F Area and a similar system in H Area were expensive (∼$1.3 M/month) to operate and produced large quantities of radioactive waste, with concentrations of I- 129 too high to be disposed of at the SRS. In 2004, SRS replaced pump-and-treat with a funnel and gate system that along with operation of a base injection system at the gates reduces the flux of contaminants to the wetlands adjacent to Fourmile Branch. The alkaline solution injected into the aquifer neutralizes the acidic plume and immobilizes many of the cationic constituents. However, base injection is not effective in managing the release of iodine-129, an anionic contaminant. To address iodine-129 SRS and the Savannah River National Laboratory developed an in situ technology that uses ultra-fine ground silver chloride (AgCl) as an injectable capture medium for the sequestration of iodine-129. The AgCl amendment has a very small particle size and is designed to be injected into the contaminated aquifer to capture iodine-129. Dissolved iodine-129 forms a stable and highly insoluble solid (silver iodide) upon contact with AgCl. Laboratory studies, a field scale pilot test (2009), and three deployments (2011, 2015 and 2019) of AgCl have been successfully performed at the F-Area Seepage Basins. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Simulation and Sensitivity Analysis of a Cryogenic Carbon Capture System for the Cement Industry

The talk will describe modeling and analysis of cryogenic systems for carbon capture from industrial point sources, thermodynamic and process simulation requirements to predict capture from typical flue gases, quantification of temperature and flow profiles for a range of gas feed compositions and capture levels, and impacts of process conditions and heat transfer on energy requirements for heat integration.

Paul, Brandon↗
DOE OSTI2018

Packed and fluidized bed absorber modeling for carbon capture with micro-encapsulated sodium carbonate solution

Micro-Encapsulated CO 2 Sorbents (MECS) are a promising technology for post-combustion carbon capture because they enable slow-reacting solvents like carbonate solution to compete with traditional amine solvents. Before scaling up MECS for pilot testing, modeling is needed to design a MECS absorber and quantify its size and energy penalty. To that end, a multi-scale model for MECS- that ranges from a single capsule to a 500 MWe power plant absorber- is developed and presented here in this paper. First, the individual capsule model is developed and fitted to experimental CO 2 absorption data collected on a 0.1 g sample of capsules filled with sodium carbonate solution. This capsule model is then validated against data collected on a 25 g batch of capsules exposed to flue gas conditions in a fluidized column. This model is then scaled up to represent two absorber designs: a multi-stage, counter-flow fluidized bed and a hollow, cylindrical packed bed with radial gas flow. These two absorber bed models are first optimized for a 1 MWe pilot-scale absorber, and then optimized for a 500 MWe coal plant. This model predicts absorbers of similar dimensions and smaller energy penalties than previously modeled absorbers filled with amine solvent capsules. Furthermore, it is demonstrated here that a few reasonable improvements to capsule design would result in absorber sizes and energy penalties lower than those of a benchmark amine solvent tower. These results demonstrate that micro-encapsulated carbonate solution can compete with faster-acting amine solvents for post-combustion carbon capture.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2023

Techno-economic and environmental life cycle assessment of next-generation fiber-encapsulated nanoscale hybrid materials for direct air carbon capture

A techno-economic and environmental life cycle assessment was conducted for manufacturing two novel types of solid sorbents used for direct air CO 2 capture (DAC). One type of solid sorbent comprised Polyacrylonitrile (PAN)/Organopolysilizane (OPSZ)/nanoscale organic hybrid materials (NOHM)(, and the other comprised polymers of intrinsic microporosity (PIM)/NOHM. These solid sorbents were assumed to be manufactured via an unconventional route: electrospinning as fibers. Economic analyses revealed that manufacturing costs for a 0.73 MT/year capacity plant was $\$$831 and $\$$1398/kg of electrospun fiber in the case ofPAN/OPSZ/NOHM and PIM/NOHM, respectively. The costs were higher for PIM/NOHM owing to high raw material prices (Spirobisindane and tetrafluoroterephthalonitrile), that are used only in manufacturing PIM. Scaling up the plant capacity from 0.73 to 30 MT/year plant decreased the manufacturing cost by nearly half from $\$$831 to $\$$379 in the case of PAN/OPSZ/NOHM, depicting the economies of scale of effect. An LCA of both types of solid sorbent was performed using OpenLCA software, the Ecoinvent v 3.5 database, and the TRACI LCI assessment method. The Global Warming Potential (GWP) ofPAN/OPSZ/NOHM and PIM/NOHM was observed to be 151 × 10 -3 and 166 × 10 -3 kg CO 2 per kg CO 2 captured in the DAC plant, respectively. In conclusion, these GWP values were nearly five times as high as those observed for other solid sorbents existing in the literature such as PEI on silica gel, carbonate on silica, and carbonate on activated carbon owing to large amounts of electricity used in electrospinning unit operation.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Molecular Understanding of Nitrogen Oxide Fixation of Water-Lean Carbon Capture Solvents by Atomistic Modeling

Nitrogen oxides, present in flue gas, can cause negative impacts on amine carbon capture solvents by the formation of heat-stable salts and suspected carcinogens. Thus, to maximize the performance of water-lean solvents, a better understanding of this process in these systems is necessary. Here, a computational study for the fixation of the CO 2 capture solvent N-(2-ethoxyethyl)-3-morpholinopropan-1-amine (EEMPA) to nitramine/nitrosamine was conducted. The first step involves the dissociation of the NH bond of EEMPA, in which the homolytic mechanism is energetically more favorable than the heterolytic mechanism. The second step involves radical recombination to form N–N bonds. While NO 2 directly reacts with EEMPA, NO has almost no effect. However, in the presence of O 2 , fixation of EEMPA by NO is enhanced via the formation of N 2 O 4 species. Finally, low reaction energies indicate that the formation of nitramine/nitrosamine may be a reversible process, suggesting that EEMPA could be recovered under thermal stripping conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗