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NASA NTRS1981

Observing chemical abundances in comets

The atomic resonance lines of the major elements were observed in the atmospheres of a few comets, by using vacuum ultraviolet spectrographs on board rockets or orbiting observatories. Dust-to-gas ratios were also deduced for two comets through a Finson-Probstein's analysis of their dust-tail isophotes. The geometric albedo of the dust for the phase angle alpha of the observations is not accurately known but, the dust-to-gas ratio is not overly sensitive to the actual value of this albedo. Infrared observations of the dust head of some comets show that the bulk of cometary dust must be silicates, although a minor component (5-10 percent) of carbon compounds is rather likely, because of poor dielectric properties of the grains. This interpretation is confirmed by the fact that interplanetary dust probably of cometary origin, that was collected in the stratosphere by NASA-U2 Spacecraft, is chondritic in nature. Metal abundances in the head of a sungrazing comet support the chondritic hypothesis.

Delsemme, A. H.↗

NASA NTRS1982

CNO abundances in H II regions of the Magellanic clouds and the galaxy with implications regarding the nucleosynthesis of the CNO element group

Final abundance results of IUE observations of the UV spectra of three H II regions in the Small Magellanic Cloud and four H II regions in the Large Magellanic Cloud are presented. Calculated yields of carbon and oxygen derived are y(C)=.00063 and y(O)=.0016. The nucleosynthetic origin of nitrogen was evaluated as being predominantly a secondary element produced from carbon as its seed. Plotting log N/C versus log C/H yielded the rather unexpected result that log N/C decreases with lo C/H over the SMC-LMC-Orion range. The cause of this relationship is discussed.

Dufour, R. J.↗

NASA NTRS1981

The helium abundance of Jupiter from Voyager

The helium abundance in the Jovian atmosphere is derived from Voyager 1 data by two methods. The first method uses only infrared spectra from selected locations on the planet while the second method uses a thermal profile independently derived from radio occultation measurements and infrared spectra recorded near the occultation point. A hydrogen mole fraction of 0.897 plus or minus 0.030 is obtained from the first method, while the second method gives 0.880 plus or minus 0.036, corresponding to helium mass fractions of 0.19 plus or minus 0.05 and 0.21 plus or minus 0.06, respectively. The estimated errors for the first method are primarily due to systematic uncertainties in the H2 and He absorption coefficients, while those for the second method result mainly from errors in the radio occultation profile and are less well known. Random errors in the measured infrared spectra are found to be negligible in both cases. The results are consistent with a uniform mix of hydrogen and helium within Jupiter's interior, but a modest amount of helium depletion (Delta Y equal to or less than 0.05) cannot be excluded.

Gautier, D.↗

NASA NTRS1981

Martian CO abundance from the J = 1-0 rotational transition - Evidence for temporal variations

CO 2.6-mm wavelength observations of Mars during March 29-April 1, 1980, were analyzed using a model atmosphere based on Viking measurements. A least-squares fit of the model to the observed line profile yielded an average CO mixing ratio of 0.0032 + or - 0.0011, a value four times larger than that obtained by Kaplan (1969) from the analysis of an infrared spectrum obtained in 1967. Martian atmospheric chemistry models indicate that the temporal variation implied could exist, being due primarily to variations in H2O abundance.

Good, J. C.↗

NASA NTRS1981

Abundance enhancements in cosmic rays produced by collisionless shocks

It is shown that shocks preferentially accelerate partially ionized heavy elements over protons. Within the framework of a previously published model of injection, the spectra of different ion species are calculated from thermal to ultrarelativistic energies. For typical astrophysical parameters, the predicted enhancement is in qualitative agreement with observations for a 10 to the 6th K preshock plasma; ions with Z greater than 10 are enhanced by about an order of magnitude or so. The continuing increase with energy of the heavy-element abundances into the air-shower regime is discussed.

Eichler, D.↗

NASA NTRS1981

Abundances of refractory elements in quasars

A comparison of previous and new observations of iron, silicon, aluminum, magnesium and carbon lines in quasars with theoretical models shows that the gas-phase abundances of these refractory elements cannot be much less than solar, and that they do not show the order-of-magnitude depletions that are found in planetary nebulae and the interstellar medium. In light of this lack of refractory element depletions, it is suggested that the broad emission-line clouds must be devoid of dust.

Gaskell, C. M.↗

NASA NTRS1981

The abundances of neon, sulfur, and argon in planetary nebulae

New infrared observations of Ne II, Ar III, and S IV are used in optical observations of other ionization states of the considered elements to evaluate the abundances of neon, argon, and sulfur in 18 planetary nebulae. Attention is also given to one or more of the infrared lines in 18 other nebulae. It is pointed out that S IV was detected in approximately 90% of the observed objects, while Ar III was found in about 80%, and Ne II in roughly one-third. It is noted that optical observations typically include only a limited region of the nebula, while the infrared measurements frequently involve integration over the entire nebular image.

Beck, S. C.↗

NASA NTRS1981

Preacceleration in collapsing magnetic neutral sheets and anomalous abundances of solar flare particles

Levine's (1974) concept of a collapsing magnetic neutral sheet which can accelerate ambient protons to several times the mean thermal speed, provided that the collapse time scale is shorter than the proton Coulomb loss time, is applied to heavier elements in an investigation of the composition of the particles which can be accelerated by such a sheet. Tables of ionization equilibrium are combined with the thermal structure of a constant pressure loop in order to calculate phi sub x (the fraction of an element x which is accelerated) of 18 heavy elements, from carbon to nickel which satisfy a maximum-ionization criterion. Normalizing phi sub x to oxygen, it is found that relative to the composition of the ambient materials, C and N can be depleted by factors of up to 2-10, while other heavy elements, along with hydrogen, are enhanced. The numerical results obtained are qualitatively similar to anomalous abundances reported among solar flare particles.

Mullan, D. J.↗

NASA NTRS1981

Interstellar abundances derived from IUE data. I - Silicon depletions toward reddened stars

Surveys of abundances for species well suited to IUE's wavelength coverage and spectral resolution are undertaken to acquire interstellar line data for a large number of stars and column densities greater than those of previous instruments. A complex set of interactive computer programs has been developed for the efficient analysis of the IUE data, which is described along with results on Si II column densities toward two moderately reddened stars. Silicon depletions are inferred in the cases of the two stars, HD 42088 and HD 151804, and their H I column density determinations are used to estimate the total hydrogen column density.

Snow, T. P., Jr.↗

NASA NTRS1981

Heavy-element abundances in He/3/-rich events

Abundances of the elements He through Fe observed on the ISEE-3 during He(3) rich events are reported. Ratios of He(3)-He(4) of not less than about 1, and Fe/O of greater than 1 are found, and rather large event-to-event variations in C, O, Ne, Mg, Si, and S are seen superposed upon the general trend of heavy element enhancement. It is concluded that the discontinuous variation of the neighboring elements in the He(3) rich events could result from differences in the electron temperature of the material prior to injection that give rise to differences in the dominant charge states and cyclotron frequencies of different elements.

Reames, D. V.↗

NASA NTRS1982

The ionization equilibrium of astrophysically abundant elements

The paper presents new calculations of ionization equilibrium fractions of 11 abundant elements (C, N, O, Ne, Mg, Si, S, Ar, Ca, Fe, Ni) as functions of temperature. Convenient coefficients for fitting the rates of collisional ionization, radiative recombination, and dielectronic recombination are also tabulated. Many of the ionization rates are based on recent experimental measurements of cross sections for collisional ionization and autoionization following inner-shell excitation. These rates are used elsewhere in computations of nonequilibrium ionization, radiative cooling, radiative shock models, and plasma emission diagnostics.

Shull, J. M.↗

NASA NTRS1982

Metamorphic reactions in mesosiderites - Origin of abundant phosphate and silica

In light of a study of the Emery mesosiderite, it is determined that the high modal abundances of merrillite and tridymite in most mesosiderites are attributable to redox reactions between silicates and P-bearing Fe-Ni metal within a limited T-fO2 range at low pressure. The recalculated amounts of dissolved P and S in the metallic portion of Emery reduce the metal liquidus temperature to less than 1350 C, and the solidus to less than 800 C, so that the mixing of liquid metal with cold silicates would have resulted in silicate metamorphism rather than melting. This redox reaction and redistribution of components between metal and silicates illuminates the complexities of mesosiderite processing, with a view to the recalculation of their original components.

Harlow, G. E.↗

NASA NTRS1982

Solar wind iron abundance variations at solar wind speeds up to 600 km s sup -1, 1972 to 1976

The Fe/H ratios in the peaks of high speed streams (HSS) were analyzed during the decline of Solar Cycle 20 and the following minimum (October 1972 to December 1976). The response of the 50 to 200 keV ion channel of the APL/JHU energetic particle experiment (EPE) on IMP-7 and 8 was utilized to solar wind iron ions at high solar wind speeds (V or = 600 km/sec). Fe measurements with solar wind H and He parameters were compared from the Los Alamos National Laboratory (LANL) instruments on the same spacecraft. In general, the Fe distribution parameters (bulk velocity, flow direction, temperature) are found to be similar to the LANL He parameters. Although the average Fe/H ration in many steady HSS peaks agrees within observational uncertainties with the nominal coronal ratio of 4.7 x 0.00001, abundance variations of a factor of up to 6 are obtained across a given coronal-hole associated HSS.

Mitchell, D. G.↗

NASA NTRS1982

The abundance of the actinides in the cosmic radiation as measured on HEAO 3

The HEAO 3 detector of heavy cosmic-ray nuclei has observed one possible actinide nucleus and some 100 nuclei of the platinum-lead group of elements. The resulting upper limit of 3% for the abundance ratio of actinides to platinum-lead nuclides is significantly lower than previous results from other observations. This new limit is inconsistent with freshly synthesized, pure r-process sources for cosmic-ray nuclei in this charge interval but is consistent with a source having a composition similar to the solar system, or to aged r-process material. We observe no events with a charge greater than 96.

Binns, W. R.↗

NASA NTRS1982

X-ray emission from young supernova remnants - Nonionization equilibrium abundances and emissivities

X-ray line emission from hot, low-density plasma in young supernova remnants is strongly enhanced by departures from ionization equilibrium. The X-ray emission from a Sedov blast wave has been calculated using a nonequilibrium evolutionary treatment of the ionization structure, and the resulting spectrum has been fitted to HEAO 2 SSS data for Tycho's remnant. These models yield dramatically different elemental abundances for heavy elements (Ne, Mg, Si, S, Ar, Ca, and Fe), compared with two-temperature component equilibrium models of Becker et al. (1979, 1980). Nonequilibrium broad-band X-ray emissivities result in lower mass determinations for the supernova ejecta. Areas of further improvement of remnant X-ray modeling are suggested.

Shull, J. M.↗

NASA NTRS1982

The abundances of CH4, CH3D, NH3, and PH3 in the troposphere of Jupiter derived from high-resolution 1100-1200/cm spectra

High-resolution spectra of the 1100-1200/cm region of the central part of Jupiter obtained in March 1980 and April 1981 are analyzed. The best fit NH3 distribution curve reveals a higher than solar mixing ratio, the abundance of NH3 to that of H2 being (3.3 + or - 1.7) x 10 to the -4th, below the 147 K layer (greater than 0.6 atmosphere). If NH3 ice particles are introduced as an opacity source, the NH3 mixing ratio below the 147 K layer can be lowered, but the fit is worse than that given by the model that excludes NH3 ice particles. The best fit PH3 distribution curve exhibits a PH3/H2 mixing ratio of (8.3 + or - 2.0) x 10 to the -7th in the troposphere. In addition, a CH4/H2 mixing ratio of (2.5 + or - 0.4) x 10 to the -3rd is found in the troposphere.

Knacke, R. F.↗

NASA NTRS1983

Interstellar abundances of oxygen and nitrogen

Neutral nitrogen and oxygen column densities or limits are derived for 53 path lengths through the diffuse interstellar medium and compared with column densities of neutral hydrogen. For neither N nor O is a systematic increase of depletion found as reddening increases. The value found for forbidden O/N is 8, and the abundances of N and O are both between 40% and 70% of the solar values. Implications of these results for models of interstellar grains are briefly discussed.

York, D. G.↗

NASA NTRS1983

Cosmic-ray abundances of Sn, Te, Xe, and Ba nuclei measured on HEAO 3

The results of an analysis of HEAO 3 Heavy Nuclei Experimental data covering 440 days of observations of Sn-Ba nuclei in cosmic rays are reported. The particles were detected by a Cernkov counter, and a Z-squared ceiling was calculated to normalize the histograms produced. The observed large abundance of Sn and Ba relative to other elements in the region of interest indicated a predominance of the s-process in the source of the particles. When account was taken of first ionization potential effects, the data indicated that the material could be solar system in origin. A source dominated by the r-process nucleosynthesis was ruled out at the 0.93 confidence level.

Binns, W. R.↗