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At least 1,099 records · Page 61

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NASA NTRS1990

Low NO(x) potential of gas turbine engines

The purpose is to correlate emission levels of gas turbine engines. The predictions of NO(x) emissions are based on a review of the literature of previous low NO(x) combustor programs and analytical chemical kinetic calculations. Concepts included in the literature review consisted of lean-premixed-prevaporized (LPP), rich burn/quick quench/lean burn (RQL), and direct injection. The NO(x) emissions were found to be an exponential function of adiabatic combustion temperature over a wide range of inlet temperatures, pressures and (lean) fuel-air ratios. A simple correlation of NO(x) formation with time was not found. The LPP and direct injection (using gaseous fuels) concepts have the lowest NO(x) emissions of the three concepts. The RQL data has higher values of NO(x) than the LPP concept, probably due to the stoichiometric temperatures and NO(x) production that occur during the quench step. Improvements in the quick quench step could reduce the NO(x) emissions to the LPP levels. The low NO(x) potential of LPP is offset by the operational disadvantages of its narrow stability limits and its susceptibility to autoignition/flashback. The Rich-Burn/Quick-Quench/Lean-Burn (RQL) and the direct injection concepts have the advantage of wider stability limits comparable to conventional combustors.

Tacina, Robert R.↗

NASA NTRS1990

Secondary arm coarsening and microsegregation in superalloy PWA-1480 single crystals: Effect of low gravity

Single crystal specimens of nickel base superalloy PWA-1480 were directionally solidified on ground and during low gravity (20 sec) and high gravity (90 sec) parabolic maneuver of KC-135 aircraft. Thermal profiles were measured during solidification by two in-situ thermocouples positioned along the sample length. The samples were quenched during either high or low gravity cycles so as to freeze the structures of the mushy zone developing under different gravity levels. Microsegregation was measured by examining the solutal profiles on several transverse cross-sections across primary dendrites along their length in the quenched mushy zone. Effect of gravity level on secondary arm coarsening kinetics and microsegregation have been investigated. The results indicate that there is no appreciable difference in the microsegregation and coarsening kinetics behavior in the specimens grown under high or low gravity. This suggests that short duration changes in gravity/levels (0.02 to 1.7 g) do not influence convection in the interdendritic region. Examination of the role of natural convection, in the melt near the primary dendrite tips, on secondary arm spacings requires low gravity periods longer than presently available on KC-135. Secondary arm coarsening kinetics show a reasonable fit with the predictions from a simple analytical model proposed by Kirkwood for a binary alloy.

Vijayakumar, M.↗

NASA NTRS1990

The heat of formation of CN radicals and radiative lifetimes of the A 1 Sigma - state of C2N2

Radiative lifetimes have been measured for the stable vibrational levels of the A 1 sigma - electronic state of C2N2. They range from 1.3 microsec for the 4(sub 0)(sup 1) level to 0.66 microsec for the 1(sub 0)(sup 1) 4(sub 0)(sup 1) level and in general decrease with increasing vibrational excitation. Self-quenching rate constants range from gas kinetic to ten times that. Foreign gas quenching rates are slower. Observation of emission from the 1(sub 0)(sup 1) 4(sub 0)(sup 1) level sets a lower limit for the heat of formation of CN of 439.11 kJ/mol.

Barts, Samuel A.↗

NASA NTRS1990

Processing Bi-Pb-Sr-Ca-Cu-O superconductors from amorphous state

Researchers produced superconducting ceramics of the Bi-Pb-Sr-Ca-Cu-O system started from a glass. To form the glass, the mixed oxide powder was melted at 1200 C in air. The liquid was quenched rapidly by pouring it onto an aluminum plate and rapidly pressing with another plate. The quenched compound was in the form of black amorphous solid, whose x-ray powder pattern has no crystalline peaks. After heat treatment at high temperatures, the glass crystallized into a superconductor. The crystalline phases in the superconductor identified using x-ray diffraction patterns. These phases were that associated with the superconducting phases of T(sub c) = 80 K (Bi2Ca1Sr2Cu2Ox) and of T(sub c) = 110 K (Bi2Ca2Sr2Cu3Ox). The dc resistivity and the ac susceptibility of these superconductors were studied.

Chiang, C. K.↗

NASA NTRS1989

Non-ideality near the monotectic composition of a miscibility-gap type system - Succinonitrile-water

Differential scanning calorimetry (DSC) of near monotectic succinonitrile-water solutions, fast-quenched in hydrophilic and hydrophobic DSC pans, indicate, by degree of undercooling, thst there may be significant dependence of final ingot microstructure on the pre-quench equilibration temperature. Partial molal-volume determinations from density data, along with DSC data, suggest the nature of temperature dependent component associations from 20 to 55 C in homogeneous solutions. The undercooling profile in a hydrophilic container is explained in terms of solution-composition shifts arising from the Gibbs surface excess. The evidence shows that temperature-dependent preferred component aggregates may modulate surface-composition gradients. Similar effects may be present through intermetallic compound formation in metallic monotectic alloys.

Frazier, D. O.↗

NASA NTRS1989

The effect of anti-phase domain size on the ductility of a rapidly solidified Ni3Al-Cr alloy

Tensile tests on splat-quenched Ni3Al-Cr alloys showed a sharp decrease in ductility with long-time annealing. The growth of the initially very-fine-size anti-phase domains showed a tenuous correlation with ductility up to a critical size, where ductility was lost. The grain size was relatively unaffected by these annealing treatments, but the grain-boundary curvature decreased, implying less toughness. An important observation was that, for the longest annealing time, a chromium-rich precipitate formed, which the data indicate could be a boride. Miniaturized tensile tests were performed on samples which were all obtained from the same splat-quenched foil, and the various domain sizes were controlled by subsequent annealing treatments.

Carro, G.↗

NASA NTRS1989

Synthesis and characterization of high-Tc superconductors in the Tl-Ca-Ba-Cu-O system

Both Tl2Ca2Ba2Cu3O10 and TlCa3BaCu3O8.5 are investigated for superconductivity as a function of the sintering temperature, time, atmosphere, and quench rate in an effort to synthesize the high-Tc superconducting phase in the thallium system. The samples are characterized by electrical resistivity measurements, X-ray diffraction, and scanning electron microscopy. Samples of starting composition Tl2Ca2Ba2Cu3O10 fired in air at 860-900 C and rapidly quenched show a Tc of 96-107 K. In contrast, specimens of starting composition TlCa3BaCu3O8.5 when baked at 900 C and slowly cooled in oxygen superconduct at 116 K and above and consist of Tl2Ca2Ba2Cu3O(10+x) as the dominant phase. The results also show that, in contrast to the case of YBa2Cu3O(7-x), doping with a small concentration of fluorine sharpens the resistive transition and produces a large Tc increase in thallium-based superconductors.

Bansal, Narottam P.↗

NASA NTRS1990

A vibrational analysis of the O2 (A 3Sigma/+/u) Herzberg I system using rocket data

An observation of the UV nightglow between 2670 and 3040 A was conducted over White Sands Missile Range on October 22, 1984. A 1/4-m spectrometer operating at 3.5-A resolution viewed the earth's limb at tangent heights between 90 and 110 km for 120 sec. A total of 41 spectral scans of the nightglow were obtained with the brightest feature being the O2 Herzberg I bands. The data were sorted into two groups, one from the top side of the layer and one containing the emission peak, and compared with synthetic spectra. The deduced vibrational distributions indicate that, at low altitudes, the higher vibrational levels (v-prime greater than 6) were relatively depleted; however, the magnitude of the vibrational shift is much less than that predicted from theories of vibrational relaxation. It is shown that increasing the electronic quenching with respect to the vibrational quenching can reduce the vibrational shift in the model and qualitatively explain the observations; however, several details of the vibrational distribution are not well reproduced.

Siskind, David E.↗

NASA NTRS1990

Preparation of 110K (Bi, Pb)-Sr-Ca-Cu-O superconductor from glass precursor

The Bi1.5Pb0.5Sr2Ca2Cu3O(x) glass, prepared by rapid quenching of the melt, showed T(sub g) of 383 C, crystallization temperature of approx. 446 C, melting temperature of approx. 855 C, and bulk density of 5.69 g/cu. cm. in air. The as-quenched glass was oxygen deficient. On heating in O2, it showed a slow, irreversible, and continuous weight gain starting at approx. 530 C. The influence of annealing conditions on the formation of various phases was investigated by XRD and electrical resistivity measurements. The 110K-T(sub c) phase did not form below 840 C. The amount of this phase increased with the sintering time at 840 C. A sample annealed at 840 C for 243 h in air and furnace cooled showed the highest T(sub c) (R=0) of 107.2 K and transition width delta T(sub c) (10 to 90 percent) of approx. 2 K.

Bansal, Narottam P.↗

NASA NTRS1991

The shear modulus of the neutron star crust and nonradial oscillations of neutron stars

Shear moduli are calculated for bcc crystalline and rapidly quenched Coulomb solids produced by the Monte Carlo simulation method. The shear moduli are calculated up to the transition temperature and include the effects of thermal fluctuations. An effective shear modulus appropriate to an approximate 'isotropic' body is introduced. It is found that the values of the 'average shear modulus' for the quenched solids remain about the same as those for the corresponding bcc crystals, although the individual shear moduli of the former, disordered solids deviate considerably from the cubic symmetry of the latter. These results are applied to analyses of neutron star oscillations. It is found that the periods of the two interfacial modes are increased by about 10 percent compared to previous results, and that s-mode periods are increased by about 30 percent. The periods of the f and p modes are hardly affected at all. The surface g-mode periods are not greatly affected, while the t-mode periods are increased by 20-25 percent.

Strohmayer, T.↗

NASA NTRS1991

Rapid solidification of polymorphic transition metals induced by nanosecond laser pulses

An Nd-YAG laser giving 5 ns, 266 nm pulses was used to melt and subsequently quench thin, pure metallic films on a liquid Al/Al2O3 substrate at 10 to the 10th - 10 to the 12th K/s. Transmission electron microscopy together with electron diffraction was used to study the competitive nucleation and growth behavior of the crystals from the undercooled melt. In the case of Fe and Co, the high-temperature bcc and fcc structures were retained after laser quenching. Ti and Zr in spite of the structural similarities exhibit different preferences for nucleation from the undercooled melt. In all the metals the solid-state transformations were completely suppressed and the crystal growth was found to be limited by the collisional frequency of the atoms onto the growing interface.

Vitta, Satish↗

NASA NTRS1991

Are Einstein's transition probabilities for spontaneous emission constant in plasmas?

An investigation is conducted with a ruby laser to experimentally confirm the quenching of spontaneous emission coefficients and propose a mechanism for the phenomenon. Results of previous experiments are examined to determine the consistency and validity of interpretations of the spontaneous emissions. For the C IV 3s-3p and 2s-3p transitions, the line-intensity ratios are found to be dependent on the separation of the laser from the target. Density gradients and Stark broadening are proposed to interpret the results in a way that does not invalidate the Einstein A values. The interpretation is extended to C III and N V, both of which demonstrate similar changes in A values in previous experiments. The apparent quenching of Ar II by photon collisions is explained by Rabi oscillations and power broadening in the argon-ion laser cavity. It is concluded that the changes in A values cannot result from dense plasma effects.

Griem, H. R.↗

NASA NTRS1991

Highly mobile oxygen hole-type charge carriers in fused silica

Some peculiar positive charge carriers are thermally generated in fused silica above 500 C. These charge carriers appear to be positive holes, chemically O-states, probably arising from dissociation of peroxy defects. The charge carriers give rise to a pronounced positive surface charge which disappears upon cooling but can be quenched by rapid quenching from about 800 C. Reheating to 200 C remobilizes these charge carriers and causes them to anneal below 400 C. The generation of positive holes charge carriers may be important to understand failure mechanisms of SiO2 insulators.

Freund, Friedemann↗

NASA NTRS1992

Glass formability of high T(sub c) Bi-Sr-Ca-Cu-O superconductors

A number of compositions of ceramic oxide high T(sub c) superconductors were evaluated for their glass formation ability by means of rapid thermal analysis during quenching, optical and electron microscopy of the quenched samples, and with subsequent DSC measurements. Correlations between experimental measurements and the methodical composition changes identified the formulations of superconductors that can easily form glass. The superconducting material was first formed as a glass, then with subsequent devitrification it was formed into bulk crystalline superconductor by a series of processing methods.

Kaukler, William F.↗

NASA NTRS1991

Containerless processing and rapid solidification of Nb-Si alloys of hypereutectic composition

A combination of bulk undercooling in an electromagnetic levitation apparatus and splat quenching between two copper plates is used to process Nb-Si alloys in order to maximize rapid solidification conditions and minimize the effects of recalescence, with emphasis on the solidification of characteristics of alloys in the 21 to 27 at. pct Si range of composition. SEM and TEM as well as X-ray diffraction are used to characterize the microstructures of the processed samples. In the range of compositions studied, the splat-quenched drops always formed the tetragonal Nb3Si phase directly from the liquid. Drops solidified in the coil were characterized by the presence of the primary intermetallic Nb5Si3 and the absence of both peritectic Nb3Si and the equilibrium eutectic. In these cases, a metastable alpha-Nb + beta-Nb5Si3 eutectic formed. The results are discussed in terms of possible metastable configurations of the Nb-Si phase diagram as well as concepts of nucleation and growth kinetics applied to the Nb3Si and Nb5Si3 intermetallics.

Hofmeister, W. H.↗

NASA NTRS1992

FAGE measurements of tropospheric HO with measurements and model of interferences

Ambient HO measurements by low-pressure laser-excited fluorescence with chemical modulation, and supporting ozone and water-vapor data, are presented for periods in May and August 1987. The observed peak daytime ambient HO concentrations are in the range (2.5 to 8) x 10 exp 6 molecules/cu cm and show small negative offsets due to photochemical interference. Direct measurements of the interference at fixed (O3) give the dependence on ambient (H2O) and on the modulating reagent (isobutane). At ambient (O3) = 30 ppb and 10 torr H2O, with excitation and detection at a total pressure of 4 torr, the net interference is equal to (HO) = -1.3 x 10 exp 6 molecules/cu cm. Production of HO by the reaction of isobutane with O(1D) accounts for the negative interference. Quenching of HO fluorescence by the modulating reagent contributes a smaller positive term to the interference; kinetic measurements of the quenching rate coefficient are reported. The experimental interference results are compared with a detailed kinetic model of HO production, excitation, relaxation, and detection; reasonable agreement is found.

Hard, T. M.↗

NASA NTRS1992

Quantitative fluorescence measurements of the OH radical in high pressure methane flames

A method for quantifying laser-induced fluorescence signals from the OH radical in high-pressure flames is presented. The fluorescence signal per unit OH mole fraction is modeled as a function of temperature, pressure, and overall flame stoichiometry. Known values of the collisional quenching cross sections as a function of temperature are used to model the electronic quench rate. The reverse A - X (1.0) Q15 transition is used with broadband collection to measure single-point fluorescence produced by a pulsed Nd:YAG-pumped, frequency-doubled dye laser. Laser absorption and thermocouples are used to measure absolute OH concentration and temperature, respectively, which are used to confirm the validity of the model. Measurements are made in CH4/O2/N2 flames up to 10 atm.

Battles, B. E.↗

NASA NTRS1992

Tektite origin by hypervelocity asteroidal or cometary impact: The quest for the source craters

Tektites are natural glasses that are chemically homogeneous, often spherically symmetrical objects several centimeters in size, and occur in four known strewn fields on the surface of the Earth: the North American, moldavite (or Central European), Ivory Coast, and Australasian strewn fields. Tektites found within such strewn fields are related to each other with respect to their petrological, physical, and chemical properties as well as their age. A theory of tektite origin needs to explain the similarity of tektites in respect to age and certain aspects of isotopic and chemical composition within one strewn field, as well as the variety of tektite materials present in each strewn field. In addition to tektites on land, microtektites (which are generally less than 1 mm in diameter) have been found in deep-sea cores. Tektites are classified into three groups: (1) normal or splash-form tektites, (2) aerodynamically shaped tektites, and (3) Muong Nong-type tektites (sometimes also called layered tektites). The aerodynamic ablation results from partial remelting of glass during atmospheric passage after it was ejected outside the terrestrial atmosphere and quenched from a hot liquid. Aerodynamically shaped tektites are known mainly from the Australasian strewn field where they occur as flanged-button australites. The shapes of splash-form tektites (spheres, droplets, teardrops, dumbbells, etc., or fragments thereof) are the result of the solidification of rotating liquids in the air or vacuum. Mainly due to chemical studies, it is now commonly accepted that tektites are the product of melting and quenching of terrestrial rocks during hypervelocity impact on the Earth. The chemistry of tektites is in many respects identical to the composition of upper crustal material.

Koeberl, Christian↗