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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

Enhanced Eddy Activity in the Beaufort Gyre in Response to Sea Ice Loss

The Beaufort Gyre freshwater content has increased since the 1990s, potentially stabilizing in recent years. The mechanisms proposed to explain the stabilization involve either mesoscale eddy activity that opposes Ekman pumping or the reduction of Ekman pumping due to reduced sea ice?ocean surface stress. However, the relative importance of these mechanisms is unclear. Here, we present observational estimates of the Beaufort Gyre mechanical energy budget and show that energy dissipation and freshwater content stabilization by eddies increased in the late-2000s. The loss of sea ice and acceleration of ocean currents after 2007 resulted in enhanced mechanical energy input but without corresponding increases in potential energy storage. To balance the energy surplus, eddy dissipation and its role in gyre stabilization must have increased after 2007. Our results imply that declining Arctic sea ice will lead to an increasingly energetic Beaufort Gyre with eddies playing a greater role in its stabilization.

Armitage, Thomas W.K.↗
NASA NTRSDate not supplied

Thermal Control System Architecture and Technology Challenges for a Lunar Surface Habitat

NASA’s current plans for exploration of the Lunar South Pole region include a Surface Habitat (SH) to provide up to 60-day habitability for a crew of four. The SH concept is comprised of several elements including an inflatable volume for the habitable space and a metallic airlock for access to a pressurized rover and other surface assets. A conceptual architecture for the SH Thermal Control System (TCS) is presented. A TCS dual loop design is utilized with a water/propylene glycol mix for the internal crew spaces and an external loop with low temperature coolant. The internal loop is partitioned into low and moderate temperature service with a sublimator available for operational scenarios prior to thermal radiator deployment (or redeployment). Waste heat is rejected through thermal radiators contained in the external loop. Optimization of the thermal radiator geometry/orientation as well as the TCS internal/external loop architecture is accomplished via analytical models of the system. Low mass, dust tolerant, deployable/retractable thermal radiators (in partial gravity) and thermal control surfaces, along with accommodating infrequent eclipse periods lasting up to 100 hours, present the major technology challenges. Mitigation strategies to reduce the energy needed to maintain the SH and associated systems above survival temperature limits during the eclipse period are considered in the paper. Options include retractable radiators, re-generable heat exchangers, temperature excursions, thermal energy storage and optimized inflatable optical properties. TCS sensitivity to potential SH Electrical Power System (EPS) growth is also a consideration for both operational and dormant mission phases.

Thermal Control System↗
NASA NTRS2014

Natural Ocean Carbon Cycle Sensitivity to Parameterizations of the Recycling in a Climate Model

Sensitivities of the oceanic biological pump within the GISS (Goddard Institute for Space Studies ) climate modeling system are explored here. Results are presented from twin control simulations of the air-sea CO2 gas exchange using two different ocean models coupled to the same atmosphere. The two ocean models (Russell ocean model and Hybrid Coordinate Ocean Model, HYCOM) use different vertical coordinate systems, and therefore different representations of column physics. Both variants of the GISS climate model are coupled to the same ocean biogeochemistry module (the NASA Ocean Biogeochemistry Model, NOBM), which computes prognostic distributions for biotic and abiotic fields that influence the air-sea flux of CO2 and the deep ocean carbon transport and storage. In particular, the model differences due to remineralization rate changes are compared to differences attributed to physical processes modeled differently in the two ocean models such as ventilation, mixing, eddy stirring and vertical advection. GISSEH(GISSER) is found to underestimate mixed layer depth compared to observations by about 55% (10 %) in the Southern Ocean and overestimate it by about 17% (underestimate by 2%) in the northern high latitudes. Everywhere else in the global ocean, the two models underestimate the surface mixing by about 12-34 %, which prevents deep nutrients from reaching the surface and promoting primary production there. Consequently, carbon export is reduced because of reduced production at the surface. Furthermore, carbon export is particularly sensitive to remineralization rate changes in the frontal regions of the subtropical gyres and at the Equator and this sensitivity in the model is much higher than the sensitivity to physical processes such as vertical mixing, vertical advection and mesoscale eddy transport. At depth, GISSER, which has a significant warm bias, remineralizes nutrients and carbon faster thereby producing more nutrients and carbon at depth, which eventually resurfaces with the global thermohaline circulation especially in the Southern Ocean. Because of the reduced primary production and carbon export in GISSEH compared to GISSER, the biological pump efficiency, i.e., the ratio of primary production and carbon export at 75 m, is half in the GISSEH of that in GISSER, The Southern Ocean emerges as a key region where the CO2 flux is as sensitive to biological parameterizations as it is to physical parameterizations. The fidelity of ocean mixing in the Southern Ocean compared to observations is shown to be a good indicator of the magnitude of the biological pump efficiency regardless of physical model choice.

Antarctic Ocean↗
DOE OSTI2012

COMPARISON OF EXPERIMENTS TO CFD MODELS FOR MIXING USING DUAL OPPOSING JETS IN TANKS WITH AND WITHOUT INTERNAL OBSTRUCTIONS

This paper documents testing methods, statistical data analysis, and a comparison of experimental results to CFD models for blending of fluids, which were blended using a single pump designed with dual opposing nozzles in an eight foot diameter tank. Overall, this research presents new findings in the field of mixing research. Specifically, blending processes were clearly shown to have random, chaotic effects, where possible causal factors such as turbulence, pump fluctuations, and eddies required future evaluation. CFD models were shown to provide reasonable estimates for the average blending times, but large variations -- or scatter -- occurred for blending times during similar tests. Using this experimental blending time data, the chaotic nature of blending was demonstrated and the variability of blending times with respect to average blending times were shown to increase with system complexity. Prior to this research, the variation in blending times caused discrepancies between CFD models and experiments. This research addressed this discrepancy, and determined statistical correction factors that can be applied to CFD models, and thereby quantified techniques to permit the application of CFD models to complex systems, such as blending. These blending time correction factors for CFD models are comparable to safety factors used in structural design, and compensate variability that cannot be theoretically calculated. To determine these correction factors, research was performed to investigate blending, using a pump with dual opposing jets which re-circulate fluids in the tank to promote blending when fluids are added to the tank. In all, eighty-five tests were performed both in a tank without internal obstructions and a tank with vertical obstructions similar to a tube bank in a heat exchanger. These obstructions provided scale models of vertical cooling coils below the liquid surface for a full scale, liquid radioactive waste storage tank. Also, different jet diameters and different horizontal orientations of the jets were investigated with respect to blending. Two types of blending tests were performed. The first set of eighty-one tests blended small quantities of tracer fluids into solution. Data from these tests were statistically evaluated to determine blending times for the addition of tracer solution to tanks, and blending times were successfully compared to Computational Fluid Dynamics (CFD) models. The second set of four tests blended bulk quantities of solutions of different density and viscosity. For example, in one test a quarter tank of water was added to a three quarters of a tank of a more viscous salt solution. In this case, the blending process was noted to significantly change due to stratification of fluids, and blending times increased substantially. However, CFD models for stratification and the variability of blending times for different density fluids was not pursued, and further research is recommended in the area of blending bulk quantities of fluids. All in all, testing showed that CFD models can be effectively applied if statistically validated through experimental testing, but in the absence of experimental validation CFD model scan be extremely misleading as a basis for design and operation decisions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Optimum Aggregation and Control of Spatially Distributed Flexible Resources in Smart Grid

This paper presents an algorithm to optimally aggregate spatially distributed flexible resources at strategic microgrid/smart-grid locations. The aggregation reduces a distribution network having thousands of nodes to an equivalent network with a few aggregated nodes, thereby enabling distribution system operators (DSOs) to make faster operational decisions. Moreover, the aggregation enables flexibility from small distributed flexible resources to be traded to different power and energy markets. A hierarchical control architecture comprising a combination of centralized and decentralized control approaches is proposed to practically deploy the aggregated flexibility. The proposed method serves as a great operational tool for DSOs to decide the exact amount of required flexibilities from different network section(s) for solving grid constraint violations. The effectiveness of the proposed method is demonstrated through simulation of three operational scenarios in a real low voltage distribution system having high penetrations of electric vehicles and heat pumps. Finally, the simulation results demonstrated that the aggregation helps DSOs not only in taking faster operational decisions, but also in effectively utilizing the available flexibility.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2018

Assessment of Pump-and-Treat System Impacts on 200 West Aquifer Conditions

The 200 West P&T system is one of the key components of the final remedy selected for the 200-ZP-1 Operable Unit (OU), and the interim remedial action selected for 200-UP-1 OU at the Hanford Site. In addition, the facility has been receiving water from several other sources, such as 200-DV-1 OU perched water, groundwater from the 200-BP-5 OU, and leachate from the Environmental Restoration Disposal Facility. It is anticipated that the P&T system will continue to receive water from other sources, which may include Modular Storage Unit (purge) water, groundwater near the Waste Management Area C, and Gable Gap. Furthermore, maintaining the injection capacity of the system has been a significant issue since the facility startup in 2012. Fouling issues at the injection wells have necessitated frequent well redevelopment, resulting in decrease in injection capacity and the need to construct new injection wells—with significant effects on system performance and operational costs. Given the evolving nature of treatment plant effluent due to changes in influent, combined with issues observed at the injection wells, it is important to understand the impacts of the P&T operations on the 200 West aquifer where the treated water is injected. This study aims at determining these impacts and providing a quantitative evaluation of aquifer capacity for both current and future conditions. This information will provide a technical basis for decisions related to the P&T system operations that support remedy optimization efforts and short- and long-term remedy decisions related to multiple OUs in the Central Plateau.

Demirkanli, Deniz I.↗
DOE OSTI2023

Robust In-Situ Strain Measurements to Monitor CO 2 Storage

The goal of this project was to develop and demonstrate robust instrumentation to monitor the in-situ strain tensor in order to improve the reliability and security of CO 2 storage in geologic formations. We met the original goals of the project and the major overarching accomplishment is the advancement of strain tensor monitoring from an intriguing concept to a commercially available technology with a solid foundation of novel instruments supported by theoretical analyses and validation experiments. The main accomplishments of the project are summarized below. We designed, built and evaluated nine new optical fiber strainmeters and tiltmeters using Michelson interferometers to measure deformation with ultra-high resolution at both shallow and deep point locations in the subsurface. These are the robust strainmeters that motivated the title of the project. We designed, built and evaluated a novel method of measuring distributed strain in optical fibers with nanostrain resolution, and cm-scale location, and sampling into the seismic band. The new method is called Coherence-length-gated Microwave Photonics Interfereometry (CMPI). CMPI technology has advantages over existing commercial DAS and DSS methods. We developed and demonstrated capabilities to deploy instruments in the field and used them to measure strain caused by ambient signals like barometric pressure and tides, as well as induced signals like surface loading and pore pressure changes from pumping tests. We deployed a working strainmeter at 1,700 ft depth, slightly above an active reservoir. This is to our knowledge the greatest depth a strainmeter has been deployed and the techniques we used can readily be extended to greater depths. Optical fiber borehole tensor strainmeter techology was advanced from a TRL 4 at the start, to a TRL of 7 at the conclusion of the project. The project included advances in simulations and theoretical analyses. We developed and demonstrated a computational workflow that uses machine learning to reduce the computational requirements and make it practical to use Bayesian inversion to solve large numerical poroelastic analyses needed to interpret strain tensor field data. We evaluated the strain tensor fields and time series that would be caused by leaks of CO 2 or other fluids from reservoirs. These simulations demonstrated that signals from leaks could be measured with instruments developed for the project, opening a potentially new method for ensuring storage security. We showed that strains in caprock can be used to estimate pressure in a reservoir. This avoids the need to drill monitoring wells into the reservoir, and it expands the capabilities of monitoring in the caprock. The project includes a derivation and application of a novel analytical solution to the strains in the vicinity of a pressurized poroelastic inclusion. This solution explains field data measured during injeciton tests at the North Avant Field, and it will simplify future interpretation of strain tensor data. The project included a broad range of experiments, and of the most significant is the characterization of the strain tensor at an array three strainmeters during six injection tests at the North Avant Field, Oklahoma. This demonstrated repeatability of the strain signal measured by the new instruments developed for the project, and it showed similarities between the strain signal at shallow depths and pressure in the underlying reservoir. We also demonstrated that useful strain data can be measured at reservoir depths. This confirms that strain tensor data can be measured throughout the caprock over a reservoir. The project demonstrated the feasibility of using the strain tensor and distributed strain measured in caprock during a variety of different well tests where the pumping rate was constant, sinusoidal and positive, or a periodic square wave with zero net rate. This further strengthens the validity of using strain data to characterize reservoirs and aquifers. We also demonstrated that strain caused be fluctuations of air pressure and water pressure in the vadose zone can be measured and interpreted, suggesting that high resolution distributed strain measurements hold promise for monitoring the vadose zone. The project partially supported nine graduate students in the Environmental Engineering, Hydrogeology, Electrical Engineering programs at Clemson University. The research was described in nine journal papers, 23 talks and conference abstracts. Additional journal papers are in preparation. A new company called Tensora was started to provide strainmeter technology for commercial applications.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2022

Electron Cloud Simulations for the Electron-Ion Collider in Brookhaven National Laboratory

For high-intensity circular accelerators and storage rings, if the secondary electron emission yield (SEY) of the vacuum chamber surfaces is high, an EC (Electron Cloud) could build up with the passage of the circulating beam. The presence of EC can strongly affect the beam quality, such as transverse instabilities, transverse emittance growth, and beam loss. Furthermore, the heat load from EC can exceed the available cryogenic capability. For the RHIC superconducting (SC) arc magnets, to be used for the hadron storage ring of the Electron-Ion Collider (EIC), the dynamic heat load budget is 0.5 W/m to the 4.5 K stainless steel beam pipe. This can limit the maximum beam bunches or intensity of the EIC, hence diminishing the luminosity provided by the EIC. The EC has affected the beam instability and significantly contributed to cryogenic heat load in the Large Hadron Collider (LHC). Positron storage rings for which ECs have been a critical factor in the design and performance include KEKB in Japan and EC buildup remains one of the concerns for future high-intensity accelerators design. EC considerations have driven the SuperKEKB collider design and the positron damping ring for the proposed International Linear Collider (ILC). The LHC luminosity upgrade is contingent on reducing the bunch spacing to 25 ns; at this bunch spacing, severe EC buildup has been observed. The success of the upgrade is likely contingent on limiting EC buildup. To study the EC heat load, we did some EC simulations with PyECLOUD code for the dipole, quadrupole, sextupole magnets, and the warm (drift) section of the EIC hadron storage ring. PyECLOUD is an EC simulation code developed by CERN. The code has been validated and used to study EC in the LHC, SPS, and PS. To eliminate EC buildup, the sources of electrons must be minimized. First, we will reduce the production of electrons due to residual gas ionization by specifying the maximum gas density, which requires a vacuum chamber with low electron-stimulated desorption (ESD) yields and a sufficient (preferably distributed) pumping speed. Second, we should reduce the secondary electrons with a lower secondary electron yield (SEY) material.

43 PARTICLE ACCELERATORS↗
NASA NTRS1987

Solar Pump

Proposed pump moves liquid by action of bubbles formed by heat of sun. Tube of liquid having boiling point of 100 to 200 degrees F placed at focal axis of cylindrical reflector. Concentrated sunlight boils liquid at focus, and bubbles of vapor rise in tube, carrying liquid along with them. Pressure difference in hot tube sufficient to produce flow in large loop. Used with conventional flat solar heating panel in completely solar-powered heat-storage system.

Pique, Charles↗
NASA NTRS1998

Reduced levels of skeletal muscle Na+K+ -ATPase in McArdle disease

We evaluated the hypothesis that impaired sarcolemmal function associated with exaggerated potassium release, impaired potassium uptake, or both may contribute to exertional fatigue and abnormal circulatory responses to exercise in McArdle disease (MD). The cellular mechanism of exertional fatigue and muscle injury in MD is unknown but likely involves impaired function of the ATPases that couple ATP hydrolysis to cellular work, including the muscle sodium potassium pump (Na+K+-ATPase). However, the concentration of muscle Na+K+ pumps in MD is not known, and no studies have related exercise increases in blood potassium concentrations to muscle Na+K+ pump levels. We measured muscle Na+K+ pumps (3H-ouabain binding) and plasma K+ in response to 20 minutes of cycle exercise in six patients with MD and in six sex-, age-, and weight-matched sedentary individuals. MD patients had lower levels of 3H-ouabain binding (231 +/- 18 pmol/g w.w., mean +/- SD, range, 210 to 251) than control subjects (317 +/- 37, range, 266 to 371, p < 0.0004), higher peak increases in plasma potassium in response to 45 +/- 7 W cycle exercise (MD, 1.00 +/- 0.15 mmol/L; control subjects, 0.48 +/- 0.09; p < 0.0001), and mean exercise heart rate responses to exercise that were 45 +/- 12 bpm greater than control subjects. Our results indicate that Na+K+ pump levels are low in MD patients compared with healthy subjects and identify a limitation of potassium reuptake that could result in sarcolemmal failure during peak rates of membrane activation and may promote exaggerated potassium-activated circulatory responses to submaximal exercise. The mechanism of the low Na+K+ pump concentrations in MD is unknown but may relate to deconditioning or to disruption of a close functional relationship between membrane ion transport and glycolysis.

Non-NASA Center↗
DOE OSTI2024

Energy impact of heating electrification in mid-rise multifamily buildings in mixed-humid climates

Decarbonizing the electric grid in conjunction with electrifying residential heating is a critical step to combat climate change. Heating in multifamily buildings with the existing natural gas-fired central boiler is a complex process that not only leads to overheating in some apartment units but also results in energy waste and high gas bills. In this study, we consider a multifamily building in New York City, USA, to evaluate the performance of five different heating systems, which represent a step-by-step transition from the conventional to a fully electrified heating system, and determine their impact on the site energy consumption and source CO 2 emissions. Results indicate that overheating in a multifamily building can raise the indoor temperature by as much as 8°C above comfortable limits. Transitioning from conventional steam radiators to cold climate heat pumps can reduce annual site heating energy by up to 70% and source CO 2 emissions by up to 21%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

Energy demand reduction in the built environment using shallow geothermal integrated energy systems: Part II – Hybrid ground source heat pump for building heating

The research collection aims at finding the various possible opportunities for the effective integration of shallow geothermal energy (SGE) to decrease the energy demand in the built environment and to reduce emission associated with it. The direct utilization of SGE using a ground source heat pump (GSHP) has been reviewed in comprehensive review part I and part II. From the extensive review, we have found that the hybrid GSHP is needed to avoid ground thermal imbalance and peak demand. Hybrid GSHP can adopt various supplemental heat sources and sinks according to the local climatic conditions and the balance of energy demands. The primary focus on the integration of subsystems such as biomass, solar energy (PV, PVT, and collector), phase change material, micro gas turbine, and absorption heat pump with GSHP is presented for heating application. This comprehensive review part III highlights the recent research findings and a potential gap in hybrid GSHP for further research and developments

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Electronic and Vibrational Coherence in Heterogeneous Electron Transfer (Final Report)

Interfacial electron transfer reactions constitute key physical phenomena central to a variety of energy related transport and conversion processes such as catalysis, photocatalysis, photovoltaics, energy storage, molecular electronics, etc. Heterogeneous material systems like organic/inorganic interfaces are of particular interest because they provide great potential to tailor properties according to application specific requirements. While electron transfer dynamics has been studied intensively in heterogeneous systems many questions remain unanswered. The significance of electronic-vibrational coupling and coherence is one aspect that has yet to be fully explored. The objective of this project is to develop and implement new ultrafast spectroscopic techniques based on pump four-wave mixing spectroscopy (pump-FWM) for studying the dynamics of vibrational coupling and coherence in heterogeneous electron transfer (HET) at molecule/semiconductor interfaces. The implementation of the spectroscopic setup allows to explore different four-wave mixing techniques and thus to identify a suitable approach to study the significance of vibrational as well as electronic coherence in HET.

14 SOLAR ENERGY↗
DOE OSTI2017

From Ion Current to Electroosmotic Flow Rectification in Asymmetric Nanopore Membranes

Asymmetrically shaped nanopores have been shown to rectify the ionic current flowing through pores in a fashion similar to a p-n junction in a solid-state diode. Such asymmetric nanopores include conical pores in polymeric membranes and pyramidal pores in mica membranes. We review here both theoretical and experimental aspects of this ion current rectification phenomenon. A simple intuitive model for rectification, stemming from previously published more quantitative models, is discussed. We also review experimental results on controlling the extent and sign of rectification. It was shown that ion current rectification produces a related rectification of electroosmotic flow (EOF) through asymmetric pore membranes. We review results that show how to measure and modulate this EOF rectification phenomenon. Finally, EOF rectification led to the development of an electroosmotic pump that works under alternating current (AC), as opposed to the currently available direct current EOF pumps.Furthermore experimental results on AC EOF rectification are reviewed, and advantages of using AC to drive EOF are discussed.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Chemoresponsive Nanofluidic Pump That Turns Off in the Presence of Lead Ion

There are many applications that require the integration of a pump and a chemical sensor so that the solution being pumped can be analyzed in real time for a specific chemical species and the flow adjusted according to the measured concentration of that species. In this paper, we describe an alternative strategy: a chemoresponsive pump where a single device acts as both the sensor and pump simultaneously. We demonstrate this concept with a nanofluidic Pb 2+ -responsive pump that uses electroosmotic flow as the pumping technology, and a Pb 2+ -binding ionophore that allows the device to selectively respond to Pb 2+ . The pump yields high flow rates at low Pb 2+ concentrations (<1 μM), but flow rate decreases with concentrations above this threshold and ultimately goes to zero at concentrations above 100 μM.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1979

Sodium storage and injection system

A sodium storage and injection system for delivering atomized liquid sodium to a chemical reactor employed in the production of solar grade silicon is disclosed. The system is adapted to accommodate start-up, shut-down, normal and emergency operations, and is characterized by (1) a jacketed injection nozzle adapted to atomize liquefied sodium and (2) a supply circuit connected to the nozzle for delivering the liquefied sodium. The supply circuit is comprised of a plurality of replaceable sodium containment vessels, a pump interposed between the vessels and the nozzle, and a pressurizing circuit including a source of inert gas connected with the vessels for maintaining the sodium under pressure.

Keeton, A. R.↗
NASA NTRS1978

Cryogenic helium 2 systems for space applications

Two cryogenic systems are described which will provide cooling for experiments to be flown on Spacelab 2 in the early 1980's. The first system cools a scanning infrared telescope by the transfer of cold helium gas from a separate superfluid helium storage dewar. The flexible design permits the helium storage dewar and transfer assembly to be designed independent of the infrared experiment. Where possible, modified commerical apparatus is used. The second cryogenic system utilizes a specially designed superfluid dewar in which a superfluid helium experiment chamber is immersed. Each dewar system employs a porous plug as a phase separator to hold the liquid helium within the dewar and provide cold gas to a vent line. To maintain the low vapor pressure of the superfluid, each system requires nearly continuous prelaunch vacuum pump service, and each will vent to space during the Spacelab 2 flight.

Urban, E.↗
DOE OSTI2012

SLUDGE HEEL REMOVAL BY ALUMINUM DISSOLUTION AT SAVANNAH RIVER SITE 12390

High Level Waste (HLW) at the Savannah River Site (SRS) is currently stored in aging underground storage tanks. This waste is a complex mixture of insoluble solids, referred to as sludge, and soluble salts. Continued long-term storage of these radioactive wastes poses an environmental risk. Operations are underway to remove and disposition the waste, clean the tanks and fill with grout for permanent closure. Heel removal is the intermediate phase of the waste retrieval and tank cleaning process at SRS, which is intended to reduce the volume of waste prior to treatment with oxalic acid. The goal of heel removal is to reduce the residual amount of radioactive sludge wastes to less than 37,900 liters (10,000 gallons) of wet solids. Reducing the quantity of residual waste solids in the tank prior to acid cleaning reduces the amount of acid required and reduces the amount of excess acid that could impact ongoing waste management processes. Mechanical heel removal campaigns in Tank 12 have relied solely on the use of mixing pumps that have not been effective at reducing the volume of remaining solids. The remaining waste in Tank 12 is known to have a high aluminum concentration. Aluminum dissolution by caustic leaching was identified as a treatment step to reduce the volume of remaining solids and prepare the tank for acid cleaning. Dissolution was performed in Tank 12 over a two month period in July and August, 2011. Sample results indicated that 16,440 kg of aluminum oxide (boehmite) had been dissolved representing 60% of the starting inventory. The evolution resulted in reducing the sludge solids volume by 22,300 liters (5900 gallons), preparing the tank for chemical cleaning with oxalic acid.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗