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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

The Anisotropy of the Microwave Background to l=3500: Mosaic Observations with the Cosmic Background Imager

Using the Cosmic Background Imager, a 13-element interferometer array operating in the 26-36 GHz frequency band, we have observed 40 deg (sup 2) of sky in three pairs of fields, each approximately 145 feet x 165 feet, using overlapping pointings: (mosaicing). We present images and power spectra of the cosmic microwave background radiation in these mosaic fields. We remove ground radiation and other low-level contaminating signals by differencing matched observations of the fields in each pair. The primary foreground contamination is due to point sources (radio galaxies and quasars). We have subtracted the strongest sources from the data using higher-resolution measurements, and we have projected out the response to other sources of known position in the power-spectrum analysis. The images show features on scales approximately 6 feet-15 feet, corresponding to masses approximately 5-80 x 10(exp 14) solar mass at the surface of last scattering, which are likely to be the seeds of clusters of galaxies. The power spectrum estimates have a resolution delta l approximately 200 and are consistent with earlier results in the multipole range l approximately less than 1000. The power spectrum is detected with high signal-to-noise ratio in the range 300 approximately less than l approximately less than 1700. For 1700 approximately less than l approximately less than 3000 the observations are consistent with the results from more sensitive CBI deep-field observations. The results agree with the extrapolation of cosmological models fitted to observations at lower l, and show the predicted drop at high l (the "damping tail").

Pearson, T. J.↗
DOE OSTI2024

A multi-mass and multi-hit two-camera 3D ion momentum imaging system

We demonstrate an improved two-camera system for multi-mass and multi-hit three-dimensional (3D) momentum imaging of ions. The imaging system employs two conventional complementary metal–oxide–semiconductor cameras. We have shown previously that the system can time slice ion Newton spheres with a time resolution of 8.8 ns, limited by camera timing jitter [J. Chem. Phys., 158, 191104 (2023)]. In this work, a jitter correction method was developed to suppress the camera jitter and improve the time resolution to better than 2 ns. With this resolution, full 3D momentum distributions of ions can be obtained. We further show that this method can detect two ions with different masses when utilizing both the rising and falling edges of the cameras.

Instruments & Instrumentation↗
DOE OSTI2020

Nanomechanical sampling of material for nanoscale mass spectrometry chemical analysis

The ability to spatially resolve the chemical distribution of compounds on a surface is important in many applications ranging from biological to material science. To this extent, we have recently introduced a hybrid atomic force microscopy (AFM)-mass spectrometry (MS) system for direct thermal desorption and pyrolysis of material with nanoscale chemical resolution. However, spatially resolved direct surface heating using local thermal desorption becomes challenging on material surfaces with low melting points, because the material will undergo a melting phase transition due to heat dissipation prior to onset of thermal desorption. Therefore, here we developed an approach using mechanical sampling and collection of surface materials on an AFM cantilever probe tip for real-time analysis directly from the AFM tip. This approach allows for material to be concentrated directly onto the probe for subsequent MS analysis. We evaluate the performance metrics of the technique and demonstrate localized MS sampling from a candelilla wax matrix containing UV stabilizers avobenzone and oxinoxate from areas down to 250 nm × 250 nm. Overall, this approach removes heat dissipation into the bulk material allowing for a faster desorption and concentration of the gas phase analyte from a single heating pulse enabling higher signal levels from a given amount of material in a single sampling spot.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

Mass flow velocity distribution in the solar chromosphere

A study of chromospheric lines (those of Si-II and Si-III) was made using the data from high resolution telescope and spectrograph (HRTS). The optically thick line profiles such as lambda 1206 due to Si-III and lambda 1265 and lambda 1533 due to Si-II were to be investigated in detail using the techniques of spectrum synthesis in an attempt to model the mass flow velocity distribution in the region of the solar atmosphere.

Tripp, D. A.↗
NASA NTRS2004

Black Holes Masses in Seyfert Galaxies

There is increasing evidence for the existence of supermassive black holes at the centers of all galaxies, and much work is being devoted to understand the process that lead to their formation, the duty cycle for the active phase of these black holes and the relevant fueling mechanisms. Seyfert galaxies determined by HST high spatial resolution observations of the kinematics of the central regions. The study of the gas kinematics provides a unique tool to probe the gravitational potential of the nuclear regions of Seyfert galaxies down to a limit radius of a few parsecs. This is particularly important to detect and measure the mass associated with any central massive black hole. We have obtained high spatial resolution spectra of a number of Seyfert galaxies, with the STIS G430M and G750M gratings, and we have been able to separate the emission line components associated with different velocity systems. We have derived two-dimensional velocity fields and determined the mass of the central black hole with good precision for each of the galaxies.

Macchetto, F. D.↗
NASA NTRS1987

Detection of X-ray emission from the young low-mass star Rossiter 137B

Rst 137B, a close M-dwarf companion to the active K-star HD 36705, has been detected in a High Resolution Image in the Einstein Observatory Archive. The X-ray surface fluxes (0.2-4 keV) from both stars are close to the empirical saturation level, F(x)/F(bol) of about 0.001, defined by rapid rotators and very young stars. This supports the earlier results of the youthfulness of the system. This young couple is an excellent subject for studies of dependence of early evolution on stellar mass. Rst 137B is one of the latest spectral types and thus lowest-mass premain-sequence stars yet detected as an X-ray source.

Vilhu, O.↗
DOE OSTI2021

Improving Signal to Noise Ratios in Ion Mobility Spectrometry and Structures for Lossless Ion Manipulations (SLIM) using a High Dynamic Range Analog-to-Digital Converter

Signal digitization is a commonly overlooked part of ion mobility-mass spectrometry (IMS-MS) workflows, yet it is a significant contributor for determining signal-to-noise ratios and MS resolution. Here we report on the integration of a 2 GS/s, 14-bit ADC with a structures for lossless ion manipulations (SLIM)-IMS-MS and compare the performance to a commonly used 8-bit ADC. The 14-bit ADC provided an effective reduction in digitized noise by factor of ~6, owing largely to the use of smaller bit sizes. The low baseline allowed the threshold voltage levels to be set very close to the MCP baseline voltage, allowing for as much signal to be acquired as possible without causing overloading or excessive digitization of MCP baseline noise. Analyses of Agilent tuning mixture ions and a complex mixture of heavy labeled phosphopeptides showed that the 14-bit ADC (compared to the 8-bit ADC) provided a modest signal-to-noise increase (~1.5 to 2-fold) for high intensity ions, such as the Agilent tuning mixture ions and the 2+ and 3+ charge states of many phosphopeptide constituents. However, signal enhancements were as much as 10-fold for low intensity ions, and the 14-bit ADC enabled discernable signal intensities otherwise lost using an 8-bit digitizer. Additionally, the 14-bit ADC required ~14-fold fewer mass spectra to be averaged to produce a mass spectrum with similar S/N as the 8-bit ADC under identical conditions, potentially providing an order of magnitude higher measurement throughput. The high resolution, low baseline, and fast speed of the new 14-bit ADC enables high performance digitization of MS, IMS-MS, and SLIM-IMS-MS spectra, and allows a much fuller picture of analyte profiles in complex mixtures to be acquired.

data acquisition, digitization, ion mobility spect↗
DOE OSTI2021

Observational measures of halo properties beyond mass

Different properties of dark matter haloes, including growth rate, concentration, interaction history, and spin, correlate with environment in unique, scale-dependent ways. While these halo properties are not directly observable, galaxies will inherit their host haloes’ correlations with environment. In this paper, we show how these characteristic environmental signatures allow using measurements of galaxy environment to constrain which dark matter halo properties are most tightly connected to observable galaxy properties. Here, we show that different halo properties beyond mass imprint distinct scale-dependent signatures in both the galaxy two-point correlation function and the distribution of distances to galaxies’ kth nearest neighbours, with features strong enough to be accessible even with low-resolution (e.g. grism) spectroscopy at higher redshifts. As an application, we compute observed two-point correlation functions for galaxies binned by half-mass radius at $z$ = 0 from the Sloan Digital Sky Survey, showing that classic galaxy size models (i.e. galaxy size being proportional to halo spin) as well as other recent proposals show significant tensions with observational data. We show that the agreement with observed clustering can be improved with a simple empirical model in which galaxy size correlates with halo growth.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1994

Forecast skill of a high-resolution real-time mesoscale model designed for weather support of operations at Kennedy Space Center and Cape Canaveral Air Station

NASA funded Mesoscale Environmental Simulations and Operations (MESO), Inc. to develop a version of the Mesoscale Atmospheric Simulation System (MASS). The model has been modified specifically for short-range forecasting in the vicinity of KSC/CCAS. To accomplish this, the model domain has been limited to increase the number of horizontal grid points (and therefore grid resolution) and the model' s treatment of precipitation, radiation, and surface hydrology physics has been enhanced to predict convection forced by local variations in surface heat, moisture fluxes, and cloud shading. The objective of this paper is to (1) provide an overview of MASS including the real-time initialization and configuration for running the data pre-processor and model, and (2) to summarize the preliminary evaluation of the model's forecasts of temperature, moisture, and wind at selected rawinsonde station locations during February 1994 and July 1994. MASS is a hydrostatic, three-dimensional modeling system which includes schemes to represent planetary boundary layer processes, surface energy and moisture budgets, free atmospheric long and short wave radiation, cloud microphysics, and sub-grid scale moist convection.

Taylor, Gregory E.↗
NASA NTRS1992

The bow shock structure of IRS 7 - Wind-wind collision near the Galactic center

New structural details of ionized gas associated with IRS 7, a mass-losing supergiant near the Galactic center, are reported, and radio continuum and theoretical maps are compared. High-resolution multiconfiguration VLA observations of IRS 7 reveal ionized gas with a bow shock structure at a wavelength of 2 cm. The apex of the bow shock is facing more toward the cluster of blue stellar objects, known as IRS 16, than Sgr A*, the compact nonthermal source near the Galaxy's dynamical center. It is inferred that the shape of the mass-losing envelope of IRS 7 is influenced by Galactic winds from IRS 16. It is concluded from a comparison of the morphology of the ionized envelope of IRS 7 with simple theoretical modeling of the bow shock structure that the shape of the shock results from the collision between the Galactic center and stellar winds rather than from the motion of IRS 7 through the interstellar medium.

Yusef-Zadeh, Farhad↗
NASA NTRS1994

Acquisition and processing of data for isotope-ratio-monitoring mass spectrometry

Methods are described for continuous monitoring of signals required for precise analyses of 13C, 18O, and 15N in gas streams containing varying quantities of CO2 and N2. The quantitative resolution (i.e. maximum performance in the absence of random errors) of these methods is adequate for determination of isotope ratios with an uncertainty of one part in 10(5); the precision actually obtained is often better than one part in 10(4). This report describes data-processing operations including definition of beginning and ending points of chromatographic peaks and quantitation of background levels, allowance for effects of chromatographic separation of isotopically substituted species, integration of signals related to specific masses, correction for effects of mass discrimination, recognition of drifts in mass spectrometer performance, and calculation of isotopic delta values. Characteristics of a system allowing off-line revision of parameters used in data reduction are described and an algorithm for identification of background levels in complex chromatograms is outlined. Effects of imperfect chromatographic resolution are demonstrated and discussed and an approach to deconvolution of signals from coeluting substances described.

NASA Discipline Exobiology↗
DOE OSTI2020

High-resolution spectroscopy of gaseous 83m Kr conversion electrons with the KATRIN experiment

Abstract In this work, we present the first spectroscopic measurements of conversion electrons originating from the decay of metastable gaseous 83m Kr with the Karlsruhe Tritium Neutrino (KATRIN) experiment. The obtained results represent one of the major commissioning milestones for the subsequent direct neutrino mass measurement with KATRIN. The successful campaign demonstrates the functionalities of the KATRIN beamline. Precise measurement of the narrow K-32, L 3 -32, and N 2,3 -32 conversion electron lines allowed to verify the eV-scale energy resolution of the KATRIN main spectrometer necessary for competitive measurement of the absolute neutrino mass scale.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

IsoMatchMS : Open-Source Software for Automated Annotation and Visualization of High Resolution MALDI-MS Spectra

Due to its speed, accuracy, and adaptability to various sample types, matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) has become a popular method to identify molecular isotope profiles from biological samples. Often MALDI-MS data do not include tandem MS fragmentation data, and thus the identification of compounds in samples requires external databases so that the accurate mass of detected signals can be matched to known molecular compounds. Most relevant MALDI-MS software tools developed to confirm compound identifications are focused on small molecules (e.g., metabolites, lipids) and cannot be easily adapted to protein data due to their more complex isotopic distributions. Here, we present an R package called IsoMatchMS for the automated annotation of MALDI-MS data for multiple datatypes: intact proteins, peptides, and glycans. This tool accepts already derived molecular formulas or, for proteomics applications, can derive molecular formulas from a list of input peptides or proteins including proteins with post-translational modifications. In conclusion, visualization of all matched isotopic profiles is provided in a highly accessible HTML format called a trelliscope display, which allows users to filter and sort by several parameters such as match scores and the number of peaks matched. IsoMatchMS simplifies the annotation and visualization of MALDI-MS data for downstream analyses.

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

High-resolution hypernuclear decay pion spectroscopy at MAMI and future

Hypernuclear decay pion spectroscopy was established in 2012 at MAMI as a mass spectroscopy method for light hypernuclei. A monochromatic pion peak from $^4_Λ$H was successfully observed, and the Λ binding energy was determined to be B Λ = 2.157±0.005(stat.)±0.077(syst.) MeV in the 2014 run. In 2022, an upgrade experiment for $^3_Λ$H spectroscopy was conducted using a newly developed Li target. The absolute electron beam energy will be measured by the synchrotron radiation interferometry, which will be applied with the spectrometer calibration to improve the systematic error. The decay pion spectroscopy is planned to be performed at JLab Hall-C, which would significantly increase the statistics thanks to the higher energy beam, the better K + identification, and the faster data acquisition system. This experiment has been submitted as a Letter of Intent in JLab PAC51. The upgraded decay pion spectroscopy method is expected to provide new, accurate hypernuclear data, which will contribute to the advancement of our understanding of hypernuclear physics

47 OTHER INSTRUMENTATION↗
NASA NTRS1983

Far-infrared detection of low-luminosity star formation in the Bok globule B335

Measurements of far-infrared intensities in the Bok globule B335, made with higher spatial and spectral resolution than two earlier studies, are described. The NASA 3-m Infrared Telescope Facility was used in February 1981 and the Kuiper Airborne Observatory 0.9-m telescope was used in October 1981 and August 1982 for the observations. The far-infrared source in B335 was revealed to be more compact than previously assumed, ruling out the interstellar radiation field as the dominant heat source. The new far-infrared size, luminosity, and temperature derived suggest that these may be the first observations of low-mass star formation embedded deeply within a Bok globule. The far-infrared source does not have a near-infrared or radio continuum counterpart. High angular resolution at submillimeter wavelengths will be critical in further studies of low-mass star formation.

Davidson, J. A.↗
DOE OSTI2020

Toward nanoscale molecular mass spectrometry imaging via physically constrained machine learning on co-registered multimodal data

Mass spectrometry imaging (MSI) plays a pivotal role in investigating the chemical nature of complex systems that underly our understanding in biology and medicine. Multiple fields of life science such as proteomics, lipidomics and metabolomics benefit from the ability to simultaneously identify molecules and pinpoint their distribution across a sample. However, achieving the necessary submicron spatial resolution to distinguish chemical differences between individual cells and generating intact molecular spectra is still a challenge with any single imaging approach. Here, we developed an approach that combines two MSI techniques, matrix-assisted laser desorption/ionization (MALDI) and time-of-flight secondary ion mass spectrometry (ToF-SIMS), one with low spatial resolution but intact molecular spectra and the other with nanometer spatial resolution but fragmented molecular signatures, to predict molecular MSI spectra with submicron spatial resolution. The known relationships between the two MSI channels of information are enforced via a physically constrained machine-learning approach and directly incorporated in the data processing. We demonstrate the robustness of this method by generating intact molecular MALDI-type spectra and chemical maps at ToF-SIMS resolution when imaging mouse brain thin tissue sections. This approach can be readily adopted for other types of bioimaging where physical relationships between methods have to be considered to boost the confidence in the reconstruction product.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1987

Dynamical mass determinations for the white dwarf components of HZ 9 and Case 1

Radial-velocity curves for both components of the short-period, white dwarf M dwarf binary systems Case 1 and HZ 9 have been determined from 1-A-resolution spectra obtained at the MMT. The radial-velocity curves for the M dwarf components agree well with previous determinations. The new data have been used to estimate masses for the white dwarfs, yielding 0.38 solar mass for the Case 1 DA and 0.51 solar mass for the HZ 9 DA, with 1sigma uncertainties of about 0.1 solar mass.

Stauffer, John R.↗
DOE OSTI2023

Visualizing oxygen transport pathways during intergranular oxidation in Ni-Cr

The transport paths of O during intergranular oxidation in binary Ni-Cr were investigated. To isolate the selective oxidation of Cr, oxidation was performed with a CO/CO 2 gas mixture in which the oxygen partial pressure was kept under the NiO dissociation pressure. A combination of electron microscopy and atom probe tomography (APT) was used to study the nanometer-scale details of the passivation and penetrative intergranular oxidation processes at high-energy grain boundaries. Oxygen transport towards the terminating oxidation front is elucidated with dedicated usage of oxygen tracer exchange experiments. Secondary ion mass spectroscopy and APT support classical theories of internal oxidation, revealing preferred transport paths at the oxide/alloy interface with sub-nanometer resolution.

36 MATERIALS SCIENCE↗