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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Nanostructured Conductive Polymer Gels as a General Framework Material To Improve Electrochemical Performance of Cathode Materials in Li-Ion Batteries

Controlling architecture of electrode composites is of particular importance to optimize both electronic and ionic conduction within the entire electrode and improve the dispersion of active particles, thus achieving the best energy delivery from a battery. Electrodes based on conventional binder systems that consist of carbon additives and nonconductive binder polymers suffer from aggregation of particles and poor physical connections, leading to decreased effective electronic and ionic conductivities. Here we developed a three-dimensional (3D) nanostructured hybrid inorganic-gel framework electrode by in situ polymerization of conductive polymer gel onto commercial lithium iron phosphate particles. This framework electrode exhibits greatly improved rate and cyclic performance because the highly conductive and hierarchically porous network of the hybrid gel framework promotes both electronic and ionic transport. In addition, both inorganic and organic components are uniformly distributed within the electrode because the polymer coating prevents active particles from aggregation, enabling full access to each particle. The robust framework further provides mechanical strength to support active electrode materials and improves the long-term electrochemical stability. The multifunctional conductive gel framework can be generalized for other high-capacity inorganic electrode materials to enable high-performance lithium ion batteries.

25 ENERGY STORAGE↗
DOE OSTI2023

Purification of Lithium-Ion Battery Black Mass through Tailored Alkaline Corrosion

Obtaining high-purity material outputs is crucial to the viability of novel process aimed at direct recycling of lithium-ion batteries. Metallic impurities in recycled cathodes have been shown to inhibit performance, thereby threatening mainstream acceptance of recycled battery products. Thus, shredded black mass (BM) must be purified to remove metallic contaminants, and specifically Al and Cu originating from the electrode current collectors. We herein explore a process to ionize solid copper and aluminum to ionic form based on tailored alkaline chemistry, without incurring damage to the target cathode material (Li(NixMnyCo1-x-y)O2; NMC). Al and Cu corrosion may be enhanced through the addition of chloride salt, elevated temperatures, and the use of ultrasonication - all of which disrupt the formation of passivating films on the metallic surface, and thereby increase corrosion rate. We demonstrate optimized parameters for Al and Cu corrosion both from a kinetic and overall process cost perspective. Further, we analyze the impact of these conditions on the structural (XRD, SEM), chemical (EDS, ICP), and electrochemical (impedance, cycling, dQ/dV) properties of NMC, and suggest that the present purification method does not significantly disrupt NMC performance. Finally, we present preliminary results from a promising bench-scale demonstration of this purification process applied to a simulated black mass.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗
DOE OSTI2016

Freestanding three-dimensional core–shell nanoarrays for lithium-ion battery anodes

Here, structural degradation and low conductivity of transition-metal oxides lead to severe capacity fading in lithium-ion batteries. Recent efforts to solve this issue have mainly focused on using nanocomposites or hybrids by integrating nanosized metal oxides with conducting additives. Here we design specific hierarchical structures and demonstrate their use in flexible, large-area anode assemblies. Fabrication of these anodes is achieved via oxidative growth of copper oxide nanowires onto copper substrates followed by radio-frequency sputtering of carbon-nitride films, forming freestanding three-dimensional arrays with core–shell nano-architecture. Cable-like copper oxide/carbon-nitride core–shell nanostructures accommodate the volume change during lithiation-delithiation processes, the three-dimensional arrays provide abundant electroactive zones and electron/ion transport paths, and the monolithic sandwich-type configuration without additional binders or conductive agents improves energy/power densities of the whole electrode.

25 ENERGY STORAGE↗
DOE OSTI2013

Ion-acoustic K-dV and mK-dV solitons in a degenerate electron-ion dense plasma

A theoretical investigation has been made of the nonlinear propagation of ion-acoustic waves associated with a dense plasma system consisting degenerate electron and ion fluids. This fluid model, which is valid for both the non-relativistic and ultra-relativistic limits, has been employed with the reductive perturbation method. The K-dV and modified K-dV (mK-dV) equations have been derived and numerically analyzed. The basic features of solitons have been observed. It has been shown that the plasma system under consideration supports the propagation of solitons (electrostatic solitary structures) obtained from the solutions of K-dV and mK-dV equations. The implications of our results obtained from this investigation in compact astrophysical objects have been briefly discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2013

Mitigation of two-plasmon decay in direct-drive inertial confinement fusion through the manipulation of ion-acoustic and Langmuir wave damping

The extended Zakharov model of the two-plasmon decay instability in an inhomogeneous plasma [D. F. DuBois et al., Phys. Rev. Lett. 74, 3983 (1995); D. A. Russell and D. F. DuBois, Phys. Rev. Lett. 86, 428 (2001)] is further generalized to include the evolution of the electron distribution function in the quasi-linear approximation [cf., e.g., K. Y. Sanbonmatsu et al. Phys. Plasmas 7, 2824 (2000); D. A. Russell et al., paper presented at the Workshop on SRS/SBS Saturation, Wente Vineyards, Livermore, CA, 2–5 April 2002]. This makes it possible to investigate anomalous absorption of laser light and hot electron production due to the two-plasmon decay instability of multiple overlapping electromagnetic waves. Scalings of hot-electron production in the (stationary) nonlinearly saturated regime relevant to recent experiments [B. Yaakobi et al., Phys. Plasmas 19, 012704 (2012); D. H. Froula et al., Phys. Rev. Lett. 108, 165003 (2012)] have been obtained. They indicate a sensitivity to ion-acoustic wave (IAW) damping and to the collisional absorption of Langmuir waves. Such a sensitivity might be exploited in inertial confinement fusion target design by the use of mid-Z ablators.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Coupled ion acoustic and drift waves in magnetized superthermal electron-positron-ion plasmas

Linear and nonlinear coupled drift-ion acoustic waves are investigated in a nonuniform magnetoplasma having kappa distributed electrons and positrons. In the linear regime, the role of kappa distribution and positron content on the dispersion relation has been highlighted; it is found that strong superthermality (low value of κ) and addition of positrons lowers the phase velocity via decreasing the fundamental scalelengths of the plasmas. In the nonlinear regime, first, coherent nonlinear structure in the form of dipoles and monopoles are obtained and the boundary conditions (boundedness) in the context of superthermality and positron concentrations are discussed. Second, in case of scalar nonlinearity, a Korteweg–de Vries-type equation is obtained, which admit solitary wave solution. It is found that both compressive and rarefactive solitons are formed in the present model. The present work may be useful to understand the low frequency electrostatic modes in inhomogeneous electron positron ion plasmas, which exist in astrophysical plasma situations such as those found in the pulsar magnetosphere.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Note: {sup 6}Li III light intensity observation for {sup 6}Li{sup 3+} ion beam operation at Hyper-Electron Cyclotron Resonance ion source

The light intensity of {sup 6}Li III line spectrum at λ = 516.7 nm was observed during {sup 6}Li{sup 3+} beam tuning at the Hyper-Electron Cyclotron Resonance (ECR) ion source. Separation of ion species of the same charge to mass ratio with an electromagnetic mass analyzer is known to be an exceptionally complex process. However, {sup 6}Li III line intensity observation conducted in this study gives new insights into its simplification of this process. The light intensity of {sup 6}Li III line spectrum from the ECR plasma was found to have a strong correlation with the extracted {sup 6}Li{sup 3+} beam intensity from the RIKEN Azimuthal Varying Field cyclotron.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2016

Investigation on the electron flux to the wall in the VENUS ion source

The long-term operation of high charge state electron cyclotron resonance ion sources fed with high microwave power has caused damage to the plasma chamber wall in several laboratories. Porosity, or a small hole, can be progressively created in the chamber wall which can destroy the plasma chamber over a few year time scale. A burnout of the VENUS plasma chamber is investigated in which the hole formation in relation to the local hot electron power density is studied. First, the results of a simple model assuming that hot electrons are fully magnetized and strictly following magnetic field lines are presented. The model qualitatively reproduces the experimental traces left by the plasma on the wall. However, it is too crude to reproduce the localized electron power density for creating a hole in the chamber wall. Second, the results of a Monte Carlo simulation, following a population of scattering hot electrons, indicate a localized high power deposited to the chamber wall consistent with the hole formation process. Finally, a hypervapotron cooling scheme is proposed to mitigate the hole formation in electron cyclotron resonance plasma chamber wall.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2025

Dependence of ion-cyclotron range of frequencies instabilities on species mix and fast-ion distribution: II. Time evolution

Dedicated DIII-D experiments studied instabilities below the ion cyclotron frequency f ci and at cyclotron harmonics by injecting thirteen different neutral beam populations into plasmas with different thermal compositions of H and D at five different values of toroidal field. The resulting database of 2529 conditions is described in Part 1: Stability. This paper focuses on the temporal evolution. For some beam geometries, the ion cyclotron emission (ICE) is much stronger at the beginning of injection, suggesting the importance of ‘bump-on-tail’ energy drive. Sawtooth crashes cause the emission to cease for some beam types and emission bands, but the opposite effect occurs for others. When unstable, for virtually all conditions and frequency bands, the emission bursts in a cycle reminiscent of predator-prey oscillations. Evidence for nonlinear interaction between ICE harmonics is observed. Strongly unstable modes typically appear within 1 ms from the start of beam injection and often decay within 0.1 ms when the beam turns off, but both the initial rise and final decay of the mode power exhibit a wide variety of behavior.

electromagnetic ion cyclotron instabilities↗
DOE OSTI2017

Modeling Stationary Lithium-Ion Batteries for Optimization and Predictive Control

Accurately modeling stationary battery storage behavior is crucial to understand and predict its limitations in demand-side management scenarios. In this paper, a lithium-ion battery model was derived to estimate lifetime and state-of-charge for building-integrated use cases. The proposed battery model aims to balance speed and accuracy when modeling battery behavior for real-time predictive control and optimization. In order to achieve these goals, a mixed modeling approach was taken, which incorporates regression fits to experimental data and an equivalent circuit to model battery behavior. A comparison of the proposed battery model output to actual data from the manufacturer validates the modeling approach taken in the paper. Additionally, a dynamic test case demonstrates the effects of using regression models to represent internal resistance and capacity fading.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

The Role of Interfacial Thermal Resistance in Li-Ion Battery Thermal Management: Preprint

Temperature critically affects the performance, life and safety of lithium-ion batteries. Therefore, it is essential to understand heat generation and dissipation within individual battery cells and battery packs to plan a proper thermal management strategy. One of the key challenges is that interfacial heat transfer of a battery unit is difficult to quantify. The steady-state absolute method and the transient laser-flash-diffusivity method were employed to measure heat conductivities of battery layer stacks and individual battery layer separately. Results show flash diffusivity method gives higher thermal conductivity at both cross-plane and in-plane directions. The difference is primarily caused by interfacial thermal resistance so that it can be estimated by steady-state and transient measurements. To investigate the effects of interfacial thermal transport beyond individual cell level, a multiphysics battery model is used. The model is built upon a multi-scale multi-domain modeling framework for battery packs that accounts for the interplay across multiple physical phenomena. Benefits of a battery module using thermal management materials are quantified through numerical experiments. During a thermal runaway event, it is found interfacial thermal resistance can mitigate thermal runaway in a battery module by significantly reducing heat transfer between cells.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2014

A novel method for experimental characterization of large-angle scattered particles in scanned carbon-ion therapy

Purpose: It is essential to consider large-angle scattered particles in dose calculation models for therapeutic carbon-ion beams. However, it is difficult to measure the small dose contribution from large-angle scattered particles. In this paper, the authors present a novel method to derive the parameters describing large-angle scattered particles from the measured results. Methods: The authors developed a new parallel-plate ionization chamber consisting of concentric electrodes. Since the sensitive volume of each channel is increased linearly with this type, it is possible to efficiently and easily detect small contributions from the large-angle scattered particles. The parameters describing the large-angle scattered particles were derived from pencil beam dose distribution in water measured with the new ionization chamber. To evaluate the validity of this method, the correction for the field-size dependence of the doses, “predicted-dose scaling factor,” was calculated with the new parameters. Results: The predicted-dose scaling factor calculated with the new parameters was compared with the existing one. The difference between the new correction factor and the existing one was 1.3%. For target volumes of different sizes, the calculated dose distribution with the new parameters was in good agreement with the measured one. Conclusions: Parameters describing the large-angle scattered particles can be efficiently and rapidly determined using the new ionization chamber. The authors confirmed that the field-size dependence of the doses could be compensated for by the new parameters. This method makes it possible to easily derive the parameters describing the large-angle scattered particles, while maintaining the dose calculation accuracy.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2016

SU-G-IeP2-13: Toward Heavy Ion Computed Tomography with Carbon Ions: A Monte Carlo Study

Purpose: In the present Monte Carlo study, we investigated the use of Carbon ions for computed tomography (CT) with a relatively low imaging dose. This will enable us to avoid any conversion of X-ray CT numbers to the relative stopping power (or relative electron density) values and the associated uncertainties in Carbon dose calculation. Methods: In the first stage, we studied the propagation of Carbon nuclei through a water phantom using the Geant4 specially to understand their lateral displacement inside the phantom. In the second stage, we used our GPU-based Monte Carlo code, which has been cross validated against Geant4, to create the 2D map of the water equivalent path length (WEPL) inside a human head size phantom by acquiring 240 projections each 1.5° apart. Subsequently the 3D relative electron density map of the phantom was reconstructed from the 2D WEPL map using the Algebraic Reconstruction Technique (ART) coupled with total variation (TV) minimization Results: A high quality image of the relative electron density inside the phantom was reconstructed by ARTTV. The mean relative error between the reconstructed image for low contrast object (PMMA) was about 1.74%. The delivered dose per scan at the center of the phantom was about 0.1 Gy. Conclusion: We have been able to obtain a 3D map of the electron density using a human head size phantom while keeping the delivered dose to relatively low value. Using the GPU capabilities of our simulation engine, we believe that a real time CT with Carbon ions could be a reality in future.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2013

Chirped dissipative ion-cyclotron solitons in the Earth's low-altitude ionospheric plasma with two ion species

Conditions for the excitation of small-scale nonlinear ion-cyclotron gradient-drift dissipative structures in cold ionospheric plasma are considered. The solution for the wave electric field in this structure in the form of a chirped soliton satisfying the equation of the Ginzburg-Landau type is derived in the electrostatic approach. The dissipative structure as a whole represents the chirped soliton accompanied by the comoving quasineutral plasma hump. The possibility of the excitation of two modes of this type (the high- and low-frequency ones) in plasma containing light and heavy ion impurities is considered. The role of electromagnetic corrections and the possible contribution introduced by these structures to the transport processes in the ionosphere are discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Simultaneously Coupled Mechanical-Electrochemical-Thermal Simulation of Lithium-Ion Cells: Preprint

Understanding the combined electrochemical-thermal and mechanical response of a system has a variety of applications, for example, structural failure from electrochemical fatigue and the potential induced changes of material properties. For lithium-ion batteries, there is an added concern over the safety of the system in the event of mechanical failure of the cell components. In this work, we present a generic multi-scale simultaneously coupled mechanical-electrochemical-thermal model to examine the interaction between mechanical failure and electrochemical-thermal responses. We treat the battery cell as a homogeneous material while locally we explicitly solve for the mechanical response of individual components using a homogenization model and the electrochemical-thermal responses using an electrochemical model for the battery. A benchmark problem is established to demonstrate the proposed modeling framework. The model shows the capability to capture the gradual evolution of cell electrochemical-thermal responses, and predicts the variation of those responses under different short-circuit conditions.

25 ENERGY STORAGE↗