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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61

Cost-effective valorization of 2,3-butanediol to high-value chemicals and jet fuel

Here, this work outlines an optimized process for converting 2,3-butanediol (BDO) into sustainable aviation fuel (SAF) and C4 chemicals. BDO is reactively separated from fermentation broth by forming dioxolanes, which are converted to isobutyraldehyde, methyl ethyl ketone (MEK), and 1,3-butadiene. These intermediates are reduced and dehydrated over Cu/ZSM-5 to form alkenes, which can be oligomerized and hydrotreated to jet-range alkanes. Previous BDO-dioxolane-alkene processes are limited by the requirement for a continuous aldehyde source for dioxolane formation. Brønsted acidic zeolites catalyze dioxolane deacetalization to form isobutyraldehyde and MEK in a >2:1 molar ratio, providing an internal, recyclable aldehyde source. Dioxolane formation optimization was performed to achieve >95% dioxolane yields over Amberlyst-15 and minimize isobutyraldehyde recycle. The overall BDO-dioxolane-fuel process yields an alkane mixture that enables at least a 50% v/v blend with Jet-A. Techno-economic analyses and life cycle assessments for this BDO-dioxolane-fuel process yield scenarios with <$2.50 per gallon gas equivalent and >58% reduction in CO2 emissions.

2,3-butanediol↗

Jet array impingement heat transfer characteristics

Two dimensional arrays of circular air jets impinging on a heat transfer surface parallel to the jet orifice plate are considered. The jet flow, after impingement, is constrained to exit in a single direction along the channel formed by the jet orifice plate and the heat transfer surface. In addition to the crossflow which originates from the jets following impingement, an initial crossflow is present which approaches the array through an upstream extension of the channel. The configurations considered are intended to model the impingement cooled midchord region of gas turbine airfoils in cases where an initial crossflow is also present. A major objective is determination of the effect of initial crossflow air temperature relative to jet array air temperature on impingement surface heat fluxes.

Florschuetz, L. W.↗

FuelLib (Fuel Library) [SWR-25-26]

FuelLib is a library that utilizes the group contribution method (GCM) for calculating thermodynamic properties of hydro-carbon jet fuels. FuelLib utilizes the tables and functions of the GCM as proposed by Constantinou and Gani (1994) and Constantinou, Gani and O'Connel (1995), with additional physical properties discussed in Govindaraju & Ihme (2016). The code is based on Pavan B. Govindaraju's Matlab implementation of the GCM, and has been expanded to include additional thermodynamic properties and mixture properties. The fuel library contains gas chromatography (GC x GC) data for a variety of fuels ranging from simple single component fuels to complex jet fuels. The GC x GC data for POSF jet fuels comes from Edwards (2020).

Montgomery, David [National Renewable Energy Labor↗

Cool GTL for the Conversion of Biogas to Jet Fuel

Cool GTL is a new process under development for conversion of biogas from digestors or CO2 +H2 to high quality drop in jet fuel. Cool GTL is designed to be a streamlined simplified low cost process which can be cost effective for small scale biogas applications. Cool GTL has the advantage that it uses a high activity bi-reforming catalyst, in a streamlined electric reformer design, to make the synthesis gas for a high conversion slurry fischer Tropsch process followed by a trailing wax cracking reactor. In this way high quality jet fuel can be directly produced. Recent experimental test data will be presented showing product quality. The life cycle analysis LCA will also be presented as well.

09 BIOMASS FUELS↗

Alternatives for jet engine control

The development of models of tensor type for a digital simulation of the quiet, clean safe engine (QCSE) gas turbine engine; the extension, to nonlinear multivariate control system design, of the concepts of total synthesis which trace their roots back to certain early investigations under this grant; the role of series descriptions as they relate to questions of scheduling in the control of gas turbine engines; the development of computer-aided design software for tensor modeling calculations; further enhancement of the softwares for linear total synthesis, mentioned above; and calculation of the first known examples using tensors for nonlinear feedback control are discussed.

Sain, M. K.↗

Design of a Subscale, Inert Gas Test for Plume-Surface Interactions in a Reduced Pressure Environment

Rocket plume-surface interaction is a multi-phase, complex discipline characterized by plume flow physics, erosion physics, and ejecta dynamics. To provide critical data for the validation of predictive modeling capabilities, an inert-gas, subscale ground test has been designed, with one test phase focused on cratering and ejecta and another test phase focused on plume structure and behavior. Using a supersonic, heated N2 jet impinging onto six different mechanical regolith simulants, visual data on the temporal evolution of cratering and ejecta are collected in a vacuum chamber at ambient pressures ranging from 600 Pa down to approximately 7 Pa. Using the same N2 jet impinging onto an instrumented plate, NO planar laser-induced fluorescence data are obtained at lower ambient pressures for the validation of both continuum and rarefied gas-phase physics. This paper discusses the design of this test and data products, with emphasis on the cratering and ejecta experiments, along with the physical scaling, challenges, and relevance of these data to the maturation of the plume-surface interaction discipline.

Ashley M Korzun↗

A shadowed flow in the stem of the Crab nebula?

The faint radio and emission line 'jet' outward from the northern boundary of the Crab Nebula which appears as a neat right cylinder is modelled here as the convected margin of a gas cloud that accidentially cast its shallow across the nearly ballistic flow of the stellar envelope ejected in the supernova explosion. It is shown that this model is consistent with known data on the jet, and that it accounts for the strikingly regular geometrical features in a natural way. In contrast, flow instability models do not easily result in so neat a cylinder.

Morrison, P.↗

2016 U.S. Petroleum Fuels Life Cycle Baseline

The National Energy Technology Laboratory (NETL) has performed a well-to-wheels life cycle assessment (LCA) of petroleum production and refining for the United States (US), both from international and domestic oil sources. This analysis largely follows the same methods and framework established by Cooney et al., which performed a greenhouse gas (GHG) LCA of crude products for the 2014 data year (Cooney et al., 2017). Results are presented for six major petroleum products (gasoline, diesel, jet fuel, fuel oil, coke, bunker/residual fuel oil) across each of the five Petroleum Administration for Defense Districts (PADDs) and at the national US level. However, there are at least seven other refinery outputs (liquified petroleum gas, refinery fuel gas, hydrogen, petrochemical feedstocks, asphalt, sulfur) that are modeled but not shown in this report for brevity. Petroleum product amounts are compared against those reported by US Energy Information Administration (EIA) for each region.

02 PETROLEUM↗

Thermochemically-Closed Sonic-Flow Inversion for Enthalpy and Temperature in Multispecies Arc-Jet Flows

A thermochemically-closed sonic-flow inversion framework (TSIF) is developed to infer bulk enthalpy and total temperature upstream of a choked nozzle in arc-jet flows. The formulation recasts a pressure-rise total enthalpy quantification technique as an inverse problem in characteristic-velocity c * space using measured mass flow rate, upstream total pressure, gas composition, and nozzle throat geometry as inputs. Unlike calorimetric energy-balance approaches or optical diagnostics, the method relies primarily on routinely measured facility quantities combined with explicit thermochemical closure. Thermochemical states are obtained using NASA’s open-source Chemical Equilibrium with Applications (CEA) code, enabling construction of a chemistry-consistent relation between characteristic velocity, total enthalpy, and total temperature under equilibrium or frozen assumptions. A discharge coefficient is self-calibrated using cold-flow (arc-off) operation data and applied to hot-flow (arc-on) measurements, enabling upstream losses to be accounted for without empirical correlations. The framework is applied to air, N 2 , and CO 2 –N 2 arc-jet flows and demonstrates expected trends for the inferred thermochemical states as function of arc power, specific energy input, mass-flow, heater configuration, and test gas. In the air limit, under equilibrium assumptions, the method recovers the classical high-enthalpy asymptotic correlation of Winovich with a mean residual of 4.4%, demonstrating compatibility with established sonic-flow scaling, while extending applicability to arbitrary multi-species mixtures and non-equilibrium chemistry. The framework provides a mixture-flexible methodology for determining bulk thermochemical states in modern arc-jet environments using routine facility pressure, mass-flow, gas-composition, and nozzle-geometry information together with a cold-flow calibration.

stagnation heat flux↗

Dijet Acoplanarity in CUJET3 as a Probe of the Nonperturbative Color Structure of QCD Perfect Fluids

Using the CUJET3=DGLV+VISHNU jet-medium interaction framework, we show that dijet azimuthal acoplanarity in high energy A + A collisions is sensitive to possible non-perturbative enhancement of the jet transport coefficient, $\hat{q}$(T,E), in the QCD crossover temperature T ~ 150–300 MeV range. With jet-medium couplings constrained by global RHIC& LHC χ 2 fits to nuclear modification data on R AA (p T > 20) GeV, we compare predictions of the medium induced dijet transverse momentum squared, $Q_s^2~\langle \hat{q}L\rangle~ΔΦ^2E^2$, in two models of the temperature, T, and jet energy E dependence of the jet medium transport coefficient, $\hat{q}$(T,E)). In one model, wQGP, the chromo degrees of freedom (dof) are approximated by a perturbative dielectric gas of quark and gluons dof. In the second model, sQGMP, we consider a nonperturbative partially confined semi-Quark-Gluon-Monopole-Plasma with emergent color magnetic dof constrained by lattice QCD data. Unlike the slow variation of the scaled jet transport coefficient, $\hat{q}_{wQGP}/T^3$, the sQGMP model $\hat{q}_{sQGMP}/T^3$ features a sharp maximum in the QCD confinement crossover T range. We show that the dijet path averaged medium induced azimuthal acoplanarity, Δφ 2 , in sQGMP is robustly ~ 2 times larger than in perturbative wQGP. even though the radiative energy loss in both models is very similar as needed to fit the same R AA data. Future A+A dijet acoplanarity measurements constrained together with single jet R AA and ν n measurements therefore appears to be a promising strategy to search for possible signatures of critical opalescence like phenomena in the QCD confinement temperature range.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Evolving winter atmospheric teleconnection patterns and their potential triggers across western North America

Abstract We present a comprehensive analysis diagnosing the primary factors driving the observed changes in major atmospheric teleconnection patterns in the Northern Hemisphere winter, including the Pacific North American pattern (PNA), North Atlantic Oscillation (NAO), and North American winter dipole (NAWD), with particular focus on their roles in shaping anomalous weather across North America. Our investigation reveals a consistent influence of the NAWD over seven decades, contrasting with fluctuating impacts from PNA and minor impacts from NAO. In particular, an emergent negative correlation between the NAWD and PNA, signaling a shifted phase of teleconnection patterns, is identified. Such a relationship change is traced to enhanced upper-level ridges across western North America, reflecting a reinforced winter stationary wave. Through attribution analysis, we identify greenhouse gas emissions as a probable driver for the northward drift of the Asia-Pacific jet core, which, aided by orographic lifting over the Alaskan Range, subsequently amplifies the winter stationary wave across western North America. This work emphasizes the pronounced effect of human-induced global warming on the structure and teleconnection of large-scale atmospheric circulation in the Northern Hemisphere winter, providing vital perspectives on the dynamics of current climate trends.

Meteorology & Atmospheric Sciences↗

Simulation of Methane Oxycombustion in Supercritical Carbon Dioxide

The Allam-Fetvedt Cycle (AFC) offers the potential for electricity generation with minimal or even negative carbon emissions by using oxycombustion in supercritical carbon dioxide (sCO2). Because of the extreme high temperatures and pressures encountered in these systems, simulation of oxycombustion requires use of a complex equation of state such as the modified Soave-Redlich-Kwong (SRK) equation, coupled with equally complex correlations for transport properties. The current work simulates a model combustor using both an ideal gas equation of state and the SRK equation of state. The model combustor features a jet of CH4 mixing with and reacting with O2 in the sCO2 ambient. Two jet configurations are considered: one of pure CH4, and one of CH4 mixed with sCO2. Comparison of results shows that key output properties such as combustor temperature and flow distribution are impacted by the choice of equations of state. Inspection of simulation results shows that mixing and reaction rates, as well as the uniformity of the flow, are impacted by the choice of equation of state. These results show that even though use of a complex equation of state greatly increases the computational costs of these simulations, it is critical to accurately capturing the physics of these systems.

computational fluid dynamics↗

Time-, space-, and molecule-resolved multiple plasma reactive species in complex settings using an innovative approach of cavity ringdown spectroscopy (Project Final Report)

The primary research goal of this 2-year project is to demonstrate the feasibility of an innovative approach to measure reactive plasma species in the most challenging settings: right on the surface of water and under water. We propose to use the Brewster angle-cavity ringdown spextroscopy (BA-CRDS). Research objectives include: 1) Measurements of OH and NO in the plasma gas-phase zone (Z1) using different types of LTP sources including continuous and pulsed plasma jets, sheets, torches, etc. 2) Measurements of OH and NO in the multiphase reaction zones, right on the surface of water (Z2) and under water (Z3). 3) RS formation and loss mechanisms and reaction dynamics in the three zones. 4) Generalization of the proposed system to be configurable with other selected innovative techniques for other LTP parameters; invitation of selected PIs to form a strong collaborative team to pursue the follow-up effort (Category-2).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evaluation of powder metallurgy superalloy disk materials

A program was conducted to develop nickel-base superalloy disk material using prealloyed powder metallurgy techniques. The program included fabrication of test specimens and subscale turbine disks from four different prealloyed powders (NASA-TRW-VIA, AF2-1DA, Mar-M-432 and MERL 80). Based on evaluation of these specimens and disks, two alloys (AF2-1DA and Mar-M-432) were selected for scale-up evaluation. Using fabricating experience gained in the subscale turbine disk effort, test specimens and full scale turbine disks were formed from the selected alloys. These specimens and disks were then subjected to a rigorous test program to evaluate their physical properties and determine their suitability for use in advanced performance turbine engines. A major objective of the program was to develop processes which would yield alloy properties that would be repeatable in producing jet engine disks from the same powder metallurgy alloys. The feasibility of manufacturing full scale gas turbine engine disks by thermomechanical processing of pre-alloyed metal powders was demonstrated. AF2-1DA was shown to possess tensile and creep-rupture properties in excess of those of Astroloy, one of the highest temperature capability disk alloys now in production. It was determined that metallographic evaluation after post-HIP elevated temperature exposure should be used to verify the effectiveness of consolidation of hot isostatically pressed billets.

Evans, D. J.↗

Results of tests using a 0.0125-scale model (70-QT) of the space shuttle vehicle orbiter in the AEDC VKF tunnel B (IA22), volume 2

Tabulated data of an experimental investigation are presented which was conducted in the AEDC/VKF Tunnel B to obtain interaction effects of RCS thruster jet plumes on SSV aerodynamics during staging to simulate RTLS abort. Interaction effects of the orbiter RCS thruster jet plumes on the orbiter and ET aerodynamics were investigated. RCS thruster jet plumes were simulated using both air and a 15 percent argon 85 percent helium gas mixture. The ET angle of attack range was -40 to +25 deg at sideslip angles of 0, 3, and 6 degrees. Orbiter angle of attack was varied from -15 to +10 degrees at sideslip angles of 0 and 3 deg. External tank full scale separation distances simulated were 0 to 1400 in. axially; 0 to 54 in. laterally; and a range of -100 to 1000 in. vertically. Data were also obtained on the ET in the interference-free flow field. Quiescent (no tunnel flow) thruster plume interaction data were obtained on the orbiter and orbiter-ET combination. Tests were conducted at Mach number 6 and a Reynolds number of 0.86 million per foot.

Daileda, J. J.↗

Ablation of carbonaceous materials in a hydrogen-helium arc-jet flow

The stagnation-point ablation rates of a graphite, a carbon-carbon composite, and four carbon-phenolic materials are measured in an arc-jet wind tunnel with a 50 percent hydrogen-50 percent helium mixture as the test gas. Flow environments are determined through measurements of static and impact pressures, heat-transfer rates to a calorimeter, and radiation spectra, and through numerical calculation of the flow through the wind tunnel, spectra, and heat-transfer rates. The environments so determined are: impact pressure approximately equal to 3 atm, Mach number approximately equal to 2.1, convective heat-transfer rate approximately equal to 14 kW/sq cm, and radiative heat-transfer rate approximately equal to 7 kW/sq cm in the absence of ablation. Ablation rates are determined from the measured rates of mass loss and recession of the ablation specimens. Compared with the predicted ablation rates obtained by running RASLE and CMA codes, the measured rates are higher by about 15 percent for all tested materials.

Park, C.↗

Properties of Combustion Gases

New series of reports: First report lists data from combustion of ASTM Jet A fuel and dry air; second report presents tables and figures for combustion-gas properties of natural-gas fuel and dry air, and equivalent ratios.

Wear, J. D.↗