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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Electronic Raman scattering in the 2D antiferromagnet NiPS 3

Correlated-electron systems have long been an important platform for various interesting phenomena and fundamental questions in condensed matter physics. As a pivotal process in these systems, d-d transitions have been suggested as a key factor toward realizing optical spin control in two-dimensional (2D) magnets. However, it remains unclear how d-d excitations behave in quasi-2D systems with strong electronic correlation and spin-charge coupling. Here, we present a systematic electronic Raman spectroscopy investigation on d-d transitions in a 2D antiferromagnet—NiPS 3 , from bulk to atomically thin samples. Two electronic Raman modes originating from the scattering of incident photons with d electrons in Ni 2+ ions are observed at ~1.0 eV. This electronic process persists down to trilayer flakes and exhibits insensitivity to the spin ordering of NiPS 3 . Our study demonstrates the utility of electronic Raman scattering in investigating the unique electronic structure and its coupling to magnetism in correlated 2D magnets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Photoinduced electron transfer from zinc meso -tetraphenylporphyrin to a one-dimensional perylenediimide aggregate: Probing anion delocalization effects

Organic photovoltaics incorporating non-fullerene acceptors based on perylenediimide (PDI) now rival fullerene acceptor-based devices in performance, although the mechanisms of charge generation in PDI-based devices are not yet fully understood. Fullerene-based systems are proposed to undergo electron transfer directly from the photoexcited donor into a band of delocalized acceptor states, thus increasing charge generation efficiency. Similarly, anion delocalization has been shown to enhance the rate of electron transfer from a photoexcited donor to two electronically coupled PDI acceptors. Here we investigate how additional electron acceptors may further increase the rate of electron transfer from the donor zinc meso-tetraphenylporphyrin (ZnTPP) to an aggregate of PDI acceptors (PDI[Formula: see text]. Femtosecond transient visible and mid-infrared absorption spectroscopies show that the rate of electron transfer from 1 *ZnTPP to the PDI assembly ZnTPP 2 -PDI 3 is statistically identical to that of the previously examined ZnTPP-PDI 2 . A Marcus theory analysis indicates that the parameters governing electron transfer are nearly identical for the two molecules, suggesting that the maximum electron transfer rate enhancement has been achieved in a cofacial PDI dimer because the ZnTPP directly couples to the first two PDI acceptors whereas the coupling to the third PDI is too weak.

bio-inspired↗
DOE OSTI2024

Uncertainty Quantification for Electronic Hamiltonian

This program will generate random points for electrons within the dimensions given by a parameter input file. Based on these randomly generated electron positions and the nuclear positions given by a position input file it will generate a value for the total electronic energy of an isolated system. This total electronic energy is calculated using the electronic Hamiltonian for a monoatomic system with atoms having the same number of protons and neutrons. The size of the system is defined by the parameter input file. The program will do this many times to generate a distribution of theoretically possible electronic total energies of the system. A user can then compare the total electronic energy given by their electronic structure method to make sure it falls within the distribution of theoretically possible values.

Savchick, JuniperC↗
DOE OSTI2020

Initial Steps Towards a Clinical FLASH Radiotherapy System: Pediatric Whole Brain Irradiation with 40 MeV Electrons at FLASH Dose Rates

In this work, we investigated the delivery of a clinically acceptable pediatric whole brain radiotherapy plan at FLASH dose rates using two lateral opposing 40-MeV electron beams produced by a practically realizable linear accelerator system. The EGSnrc Monte Carlo software modules, BEAMnrc and DOSXYZnrc, were used to generate whole brain radiotherapy plans for a pediatric patient using two lateral opposing 40-MeV electron beams. Electron beam phase space files were simulated using a model of a diverging beam with a diameter of 10 cm at 50 cm SAD (defined at brain midline). The electron beams were collimated using a 10-cm-thick block composed of 5 cm of aluminum oxide and 5 cm of tungsten. For comparison, a 6-MV photon plan was calculated with the Varian AAA algorithm. Electron beam parameters were based on a novel linear accelerator designed for the PHASER system and powered by a commercial 6-MW klystron. Calculations of the linear accelerator's performance indicated an average beam current of at least 6.25 µA, providing a dose rate of 115 Gy/s at isocenter, high enough for cognition-sparing FLASH effects. The electron plan was less homogenous with a homogeneity index of 0.133 compared to the photon plan's index of 0.087. Overall, the dosimetric characteristics of the 40-MeV electron plan were suitable for treatment. In conclusion, Monte Carlo simulations performed in this work indicate that two lateral opposing 40-MeV electron beams can be used for pediatric whole brain irradiation at FLASH dose rates of >115 Gy/s and serve as motivation for a practical clinical FLASH radiotherapy system, which can be implemented in the near future.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2021

Photoinjector Generation of High-Charge Magnetized Beams for Electron-Cooling Applications

The recently announced Electron-Ion Collider (EIC), to be built at Brookhaven National Laboratory, will collide high-energy ion-beams and electron beams to pursue nuclear physics research on quark-gluon plasma's. The facility performances (luminosity) would be improved if the ion-beam emittance degradation is mitigated via a phase-space-cooling technique. One potential cooling method uses a bright electron beam to cool the ion beams. The cooling rate for this electron-cooling method depends on the transverse emittance of the cooling electron beam and could benefit from using a beam with significant canonical angular momentum dubbed as a magnetized beam. This research focuses on simulation and experimental generation and characterization of high charge magnetized electron beams with parameters comparable to those required for electron cooling at an electron-ion collider. The experiment uses the 50-MeV photo-injector available at the Fermilab Accelerator Science and Technology (FAST) Facility. The measurements are benchmarked against simulations.

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Development and Use of an Ultra-High Resolution Electron Scattering Apparatus

In this LDRD project, we developed a versatile capability for high-resolution measurements of electron scattering processes in gas-phase molecules, such as ionization, dissociation, and electron attachment/detachment. This apparatus is designed to advance fundamental understanding of these processes and to inform predictions of plasmas associated with applications such as plasma-assisted combustion, neutron generation, re-entry vehicles, and arcing that are critical to national security. We use innovative coupling of electron-generation and electron-imaging techniques that leverages Sandia’s expertise in ion/electron imaging methods. Velocity map imaging provides a measure of the kinetic energies of electrons or ion products from electron scattering in an atomic or molecular beam. We designed, constructed, and tested the apparatus. Tests include dissociative electron attachment to O2 and SO2, as well as a new method for studying laser-initiated plasmas. This capability sets the stage for new studies in dynamics of electron scattering processes, including scattering from excited-state atoms and molecules.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Capturing Ultrafast Electron Driven Chemical Reactions in Molecules

The goals of this project are to develop experimental tools to investigate the dynamics of dissociative electron attachment (DEA) reactions in real time. In a DEA reaction, the attachment of a low energy electron to a molecule results in bond breaking and the fragmentation of the molecule. A new instrument has been designed and is under construction to perform time-resolved photoelectron and photo-fragment spectroscopy following electron transfer from an iodide anion to a molecule within a mass-selected molecular dimer. Iodide binds only weakly through the dipole interaction with many polar molecules, and such molecules forming a dimer with iodide undergo only small changes from the equilibrium geometry in isolation. When the electron is transferred from the iodide, the iodine atom is no longer bound, so the electron transfer step can be considered analogous to electron attachment and brings the key advantage of ultrafast timing precision. The experiments proposed here will establish the experimental tools to interrogate the dynamics of dissociative electron attachment on the fundamental timescales of the nuclear motion, by simultaneously probing the valence electronic structure and the fragmentation pathways.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Correlating Tomographic Chemical Inhomogeneity and Low Energy Electronic Structure in Layered Quantum Materials

Photoemission spectroscopy (PES) is a suite of experimental tools to learn about the electronic and chemical structure of materials and surfaces. Normally implemented in a surface-sensitive manner, the research performed under this grant focused on pushing PES into less explored regimes, to reveal bulk electronic structure, to reveal tomographic (layer-resolved) chemistry and electronic structure of layered materials and heterostructures, and to reveal interface phenomena at the junction of two different materials. Standing wave (SW) spectroscopies have also been applied to PdCoO2, a material of interest due to its high conductivity and electron-hydrodynamic tendencies. This material can be modeled as an alternating layered structure consisting of metallic Pd layers and insulating CoO2 layers. Using SW XPS, the total electronic structure has been decomposed into contributions from the two layers, and computations highlighted the different many-body interactions in the two layers (Comm. Phys. 4, 143 (2021)). We have also used hard-x-ray angle-resolved photoemission spectroscopy (ARPES), to investigate LaB6, a technologically important material with widespread application as a cathode material for electron microscopes. We measured the bulk electronic structure of this material and found that the one-step model of photoemission better captured the electronic structure and correlations. This model treats the three steps of the photoemission process—excitation, transport of the photoelectron to the crystal surface, and escape into the vacuum—as a single quantum mechanically coherent process (Phys. Rev. Mater. 5, 055002 (2021)). We also applied x-ray photoelectron spectroscopy, implemented in a near total reflection grazing incidence geometry to elucidate technologically relevant interfaces, such as those between a substrate and photoresist (J. Phys. D: Appl. Phys. 54 464002 (2021)).

36 MATERIALS SCIENCE↗
DOE OSTI2023

Energy Characterization of the UMD Electron Accelerator

Multiple different groups at Los Alamos National Laboratory have a cited interest in understanding the effects of ionizing radiation in materials. Of especial interest to the ISR division is understanding the effects in materials that are used in the space environment, where radiation is omnipresent and impossible to fully shield from. Development is under way to simulate the effects of radiation damage in detectors and electronics, primarily with particle transport codes such as Geant4 and RAMPART, a code that provides a user friendly interface to Geant4. However, these simulations need benchmarking to experimental tests, some of which have been performed at a variety of small electron accelerator facilities. One of these facilities is the Linear Electron Accelerator at the University of Maryland Radiation Facilities. This facility can provide electron beams on the order of 100 mA delivered in tight macropulse bunches, which allows for experiments where the behavior of electronics is monitored as a function of pulse number. While the beam rates per macropulse of this accelerator is monitored during an experiment via a current pick-off connected to a large graphite beamstop, the energy distribution of this electron beam is not measured during the experiment and has not been well characterized. The energy distribution of the beam is pertinent for these types of experiments, since dose is directly related to energy deposited in a medium. Further, these experiments are performed in open air and sample placement in the room can dictate what dose rate they receive per macropulse. We have created simulated dosemaps for the UMD vault room, but these simulations assume a given energy of the beam, both for calculating the dose and to simulate how much the beam diverges in the air. There have been two attempts now to characterize this accelerator beam energy with a plate type spectrometer, including the most recent experiment earlier this year to quantify the beam energy distribution. These results will also be compared to a dosimetry experiment performed by collaborators at the UMD facility, the details of which are described in Reference. Understanding the electron beam energy is important for future experiments, because the energy directly impacts the dose and radiation damage given to a sample and is important for properly simulating the electron beam when comparing simulation to experiment.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

Physics of the Aurora: Laboratory Measurements of Electron Acceleration by Inertial Alfven Waves (Final Technical Report)

The physics of the aurora is one of the foremost unsolved problems of space physics. The mechanisms responsible for accelerating electrons that precipitate onto the ionosphere are not fully understood. For more than three decades, particle interactions with Alfven waves have been proposed as a possible means for accelerating electrons and generating auroras. Due to the limitations of spacecraft conjunction studies and other multi-spacecraft approaches, it is unlikely that it will ever be possible, through spacecraft observations alone, to confirm definitively the proposed electron acceleration mechanism by making simultaneous measurements of both the accelerated electrons and the inertial Alfven wave responsible for the acceleration. Here, we show laboratory measurements of the resonant transfer of energy from Alfven waves to electrons under conditions relevant to the auroral zone. Experiments are performed by launching Alfven waves and simultaneously recording the electron velocity distribution. Numerical simulations and analytical theory support that the measured energy transfer process produces accelerated electrons capable of reaching auroral energies. The experiments, theory, and simulations demonstrate a clear causal relationship between Alfven waves and accelerated electrons that directly cause auroras.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Optical Properties of Wigglers for EIC Ring Electron Cooler

Electron Ion Collider (EIC) requires cooling of protons at top energy (275 GeV) to achieve the average design luminosity. Such a cooler must be capable of counteracting an IBS-driven emittance growth in proton bunches. The Ring Electron Cooler (REC) is a candidate for the EIC top energy cooler. The REC is a non-magnetized RF-based 150 MeV electron cooler, in which electrons are kept in the storage ring and re-utilized for several million turns. The REC is equipped with 18 damping wigglers, which keep electrons’ emittance constant by counteracting both electrons’ IBS and a proton electron beam-beam scattering happening in the cooling section. These wigglers operate at a relatively low energy but must have a rather high field to provide the required radiation cooling of electrons. As a result of this unique range of parameters, the wigglers’ optics exhibits interesting features The actual design parameters of the wigglers will be finalized in the REC lattice optimization.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Measuring the Electronic Bandgap of Carbon Nanotube Networks in Non-Ideal p-n Diodes

The measurement of the electronic bandgap and exciton binding energy in quasi-one-dimensional materials such as carbon nanotubes is challenging due to many-body effects and strong electron–electron interactions. Unlike bulk semiconductors, where the electronic bandgap is well known, the optical resonance in low-dimensional semiconductors is dominated by excitons, making their electronic bandgap more difficult to measure. In this work, we measure the electronic bandgap of networks of polymer-wrapped semiconducting single-walled carbon nanotubes (s-SWCNTs) using non-ideal p-n diodes. We show that our s-SWCNT networks have a short minority carrier lifetime due to the presence of interface trap states, making the diodes non-ideal. We use the generation and recombination leakage currents from these non-ideal diodes to measure the electronic bandgap and excitonic levels of different polymer-wrapped s-SWCNTs with varying diameters: arc discharge (~1.55 nm), (7,5) (0.83 nm), and (6,5) (0.76 nm). Our values are consistent with theoretical predictions, providing insight into the fundamental properties of networks of s-SWCNTs. The techniques outlined here demonstrate a robust strategy that can be applied to measuring the electronic bandgaps and exciton binding energies of a broad variety of nanoscale and quantum-confined semiconductors, including the most modern nanoscale transistors that rely on nanowire geometries.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Dynamical Modulation of Solar Flare Electron Acceleration due to Plasmoid-shock Interactions in the Looptop Region

A fast-mode shock can form in the front of reconnection outflows and has been suggested as a promising site for particle acceleration in solar flares. Recent developments in the study of magnetic reconnection have shown that numerous plasmoids can be produced in a large-scale current layer. Here we investigate the dynamical modulation of electron acceleration in the looptop region when plasmoids intermittently arrive at the shock by combining magnetohydrodynamics simulations with a particle kinetic model. As plasmoids interact with the shock, the looptop region exhibits various compressible structures that modulate the production of energetic electrons. The energetic electron population varies rapidly in both time and space. The number of 5–10 keV electrons correlates well with the compression area, while that of >50 keV electrons shows good correlation with the strong compression area but only moderate correlation with shock parameters. We further examine the impacts of the first plasmoid, which marks the transition from a quasi-steady shock front to a distorted and dynamical shock. The number of energetic electrons is reduced by ~20% at 15–25 keV and nearly 40% for 25–50 keV, while the number of 5–10 keV electrons increases. In addition, the electron energy spectrum above 10 keV evolves softer with time. We also find that double or even multiple distinct sources can develop in the looptop region when the plasmoids move across the shock. Our simulations have strong implications to the interpretation of nonthermal looptop sources, as well as the commonly observed fast temporal variations in flare emissions, including the quasi-periodic pulsations.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

Energy loss of fast electrons and positrons in a plasma.

Calculation of the stopping power of a plasma for fast electrons and positrons. First the classical limit is considered where beta = v/c is much less than alpha is the fine structure constant. Then the nonrelativistic Born-approximation formulas are derived; this domain corresponds to alpha much less than beta much less than 1. Finally, the general case of relativistic electrons and positrons is treated; in the relativistic case the scattering cross sections of Moller (electron-electron) and Bhabha (positron-electron) are used in the calculation. In all three energy domains the problem is broken up into cases of small and large momentum transfers. For large q, scattering off individual plasma electrons is considered, while in the limit of very small q for the quantum-mechanical domain, excitation of quantized plasma oscillations contributes to dE/dx; in the classical limit for small q the polarizability of the plasma provides the effective cutoff. The formulas for the stopping power differ slightly from those for a heavy ion going through a plasma because there are exchange effects and the fast electrons and positrons can lose a large fraction of their energy in one scattering off a plasma electron.

Gould, R. J.↗
NASA NTRS1972

Measurements of the UV and VUV transmission of optical materials during high energy electron irradiation

An experimental program was conducted in which the optical transmission of several transparent materials was measured during high energy electron irradiation. These experiments were conducted using the Dynamitron electron accelerator as a continuous source of 1.5 MeV electrons and the LINAC electron accelerator as a pulsed source of 5-7 MeV electrons. The experimental program consisted of three major portions. The first portion, the optical transmission of fused silica, BeO, MgF2, and LiF was measured at vacuum ultraviolet wavelengths in the range 1550-2000 A during ambient temperature, 1.5 MeV electron irradiation at ionizing dose rates to 0.5 Mrad/sec. In the second portion of the program, the optical transmission of fused silica and BeO was measured in the range 2000-3000 A during high dose rate, elevated temperature 1.5 MeV electron irradiation. In particular, accurate measurements of the optical transmission were made at ionizing dose rates as high as 10 Mrad/sec. In the final portion of the program, the optical transmission of fused silica and BeO was measured in the wavelength range 2000-3000 A during pulsed 5 and 7 MeV electron irradiation from the LINAC accelerator. The maximum time averaged ionizing dose rate was limited to 0.75 Mrad/sec due to accelerator limitations.

Palma, G. E.↗
NASA NTRS1972

Energy spectra in relativistic electron precipitation events.

Two events in August 1967, categorized as relativistic electron precipitation (REP) events by their effect on VHF transmissions propagated via the forward-scatter mode, have been examined with regard to the energy spectra of trapped and precipitated electrons. These two substorm-associated events August 11 and August 25 differ with respect to the relativistic, trapped electron population at synchronous altitude; in the August 25 event there was a nonadiabatic enhancement of relativistic (greater than 400 keV) electrons, while in the August 11 event no relativistic electrons were produced. In both events electron spectra deduced from bremsstrahlung measurements (made on a field line close to that of the satellite) had approximately the same e-folding energies as the trapped electron enhancements. However, the spectrum of electrons in the August 25 event was significantly harder than the spectrum in the event of August 11.

Rosenberg, T. J.↗
NASA NTRS1973

Auroral electrons of energy less than 1 keV observed at rocket altitudes.

Measurements of electrons of energy less than 1 keV in the auroral precipitation with detectors aboard three rocket flights are discussed. Detectors simultaneously measured the flux of electrons moving up and down the magnetic field lines. Electrons of energy less than a few hundred electron volts show directional intensities ranging from isotropic over the upper hemisphere, to field aligned into the atmosphere, to a net streaming out of the atmosphere. Cases of reflection coefficients greater than 1 for the few hundred electron volts and lower-energy electrons occur when measurements were made north of auroral forms. These electrons might represent the high-energy tail of the return Birkeland currents. The origin of the low-energy electrons is itself in question.

Arnoldy, R. L.↗
NASA NTRS1972

Some new results on electron transport in the atmosphere

The penetration, diffusion and slowing down of electrons in a semi-infinite air medium has been studied by the Monte Carlo method. The results are applicable to the atmosphere at altitudes up to 300 km. Most of the results pertain to monoenergetic electron beams injected into the atmosphere at a height of 300 km, either vertically downwards or with a pitch-angle distribution isotropic over the downward hemisphere. Some results were also obtained for various initial pitch angles between 0 deg and 90 deg. Information has been generated concerning the following topics: (1) the backscattering of electrons from the atmosphere, expressed in terms of backscattering coefficients, angular distributions and energy spectra of reflected electrons, for incident energies T(o) between 2 keV and 2 MeV; (2) energy deposition by electrons as a function of the altitude, down to 80 km, for T(o) between 2 keV and 2 MeV; (3) the corresponding energy depostion by electron-produced bremsstrahlung, down to 30 km; (4) the evolution of the electron flux spectrum as function of the atmospheric depth, for T(o) between 2 keV and 20 keV. Energy deposition results are given for incident electron beams with exponential and power-exponential spectra.

Berger, M. J.↗