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All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

The Importance of Meteorite Collections to Sample Return Missions: Past, Present, and Future Considerations

While much of the scientific community s current attention is drawn to sample return missions, it is the existing meteorite and cosmic dust collections that both provide the paradigms to be tested by these missions and the context for interpreting the results. Recent sample returns from the Stardust and Hayabusa missions provided us with new materials and insights about our Solar System history and processes. As an example, Stardust sampled CAIs among the population of cometary grains, requiring extensive and unexpected radial mixing in the early solar nebula. This finding would not have been possible, however, without extensive studies of meteoritic CAIs that established their high-temperature, inner Solar System formation. Samples returned by Stardust also revealed the first evidence of a cometary amino acid, a discovery that would not have been possible with current in situ flight instrument technology. The Hayabusa mission provided the final evidence linking ordinary chondrites and S asteroids, a hypothesis that developed from centuries of collection and laboratory and ground-based telescopic studies. In addition to these scientific findings, studies of existing meteorite collections have defined and refined the analytical techniques essential to studying returned samples. As an example, the fortuitous fall of the Allende CV3 and Murchison CM2 chondrites within months before the return of Apollo samples allowed testing of new state-of-the-art analytical facilities. The results of those studies not only prepared us to better study lunar materials, but unanticipated discoveries changed many of our concepts about the earliest history and processes of the solar nebula. This synergy between existing collections and future space exploration is certainly not limited to sample return missions. Laboratory studies confirmed the existence of meteorites from Mars and raised the provocative possibility of preservation of ancient microbial life. The laboratory studies in turn led to a new wave of Mars exploration that ultimately could lead to sample return focused on evidence for past or present life. This partnership between collections and missions will be increasingly important in the coming decades as we discover new questions to be addressed and identify targets for for both robotic and human exploration . Nowhere is this more true than in the ultimate search for the abiotic and biotic processes that produced life. Existing collections also provide the essential materials for developing and testing new analytical schemes to detect the rare markers of life and distinguish them from abiotic processes. Large collections of meteorites and the new types being identified within these collections, which come to us at a fraction of the cost of a sample return mission, will continue to shape the objectives of future missions and provide new ways of interpreting returned samples.

Welzenbach, L. C.↗
NASA NTRS2020

Shock Deformation in Zircon, a Comparison of Results from Shock-Reverberation and Single-Shock Experiments

The utility of the mineral zircon, ZrSiO4, as a shock-metamorphic geobarometer and geochronometer, has been steadily growing within the planetary science community. Zircon is an accessory phase found in many terrestrial rock types, lunar samples, lunar meteorites, martian meteorites and various other achondrites. Because zircon is refractory and has a high closure temperature for Pb diffusion, it has been used to determine the ages of some of the oldest material on Earth and elsewhere in the Solar System. Furthermore, major (O) and trace-element (REE, Ti, Hf) abundances and isotope compositions of zircon help characterize the petrogenetic environments and sources from which they crystallized. The response of zircon to impact-induced shock deformation is predominantly crystallographic, including dislocation creep and the formation of planar and sub-planar, low-angle grain boundaries; the formation of mechanical {112} twins; transformation to the high pressure polymorph reidite; the development of polycrystalline microtextures; and dissociation to the oxide constituents SiO2 and ZrO2. Shock microstructures can also variably affect the U- Pb isotope systematics of zircon and, in some instances, be used to constrain the impact age. While numerous studies have characterized shock deformation in zircon recovered from a variety of terrestrial impact craters and ejecta deposits and Apollo samples, experimental studies of shock deformation in zircon are limited to a handful of examples in the literature. In addition, the formation conditions (e.g., P, T) of various shock microstructures, such as planar-deformation bands, twins, and reidite lamellae, remain poorly con-strained. Furthermore, previous shocked-zircon experimental charges have not been analyzed using modern analytical equipment. This study will therefore under-take an new set of zircon shock experiments, which will then be microstructurally characterized using state-of-the-art instrumentation within the Astromaterials Research and Exploration Science Division (ARES), NASA Johnson Space Center.

Erickon, T. M.↗
NASA NTRS1991

Science Community Interface

The interface is described between NASA HQ, NASA Goddard, and the rocket Principal Investigators. The proposal selection process is described along with the cycle time to flight, constraints imposed by science objectives on operations, campaign modes, and coordination with ground based facilities. There were questions about the success rate of proposals and the primary sources of funding for the payloads program from the branches of the science divisions in OSSA, especially space physics, astrophysics, Earth sciences, and solar system exploration. The presentation is given in the form of viewgraphs.

Neupert, Werner M.↗
DOE OSTI2026

Powering Up Secure and Reliable Operations at the Port of Honolulu's Kapalama Container Terminal

The National Laboratory of the Rockies (NLR) is providing resilience planning support to the Pasha Group, the operator of Kapalama Container Terminal (KCT) at the Port of Honolulu, by exploring how distributed clean energy resources could help the terminal sustain a 36-hour outage and continue emergency operations. The Department of Energy's Energy Transitions Initiative (ETI) aims to advance self-reliant island and remote communities by promoting resilient, affordable, and sustainable clean energy resources.

25 ENERGY STORAGE↗
DOE OSTI2024

Energy Transitions Initiative Partnership Project: Bainbridge Island, Washington - Cohort 2 Technical Assistance: Pathways to 100% Renewable Energy

The City of Bainbridge Island (COBI) applied for and received technical assistance from the Energy Transitions Initiative Partnership Program (ETIPP) in part to achieve their goal of 100% renewable electricity generation by 2040, five years ahead of the Washington State goal, and to increase its energy resilience in the face of natural disasters. To help address these goals, the City of Bainbridge Island (COBI) applied for and received technical assistance from the Energy Transitions Initiative Partnership Program (ETIPP) during 2022-2024. Supported by the U.S. Department of Energy, ETIPP provides technical assistance to remote coastal and island communities interested in approaches to renewable and resilient energy transitions. Pacific Northwest National Laboratory (PNNL) completed the technical analysis aspects of the project, supported by the community partner Spark Northwest and the program administrator, the National Renewable Energy Laboratory (NREL). This report begins by describing the approach to technical assistance in the ETIPP project, followed by the development of future scenarios for electric demand based on current use. Potential pathways to 100% renewable energy are identified and analyzed by technology contributions from solar energy, anaerobic biodigestion, distributed wind, and marine energy. The combinations of these technologies and contributions to meet demand are discussed, along with potential policies and programs for implementation of the most relevant technologies moving forward. The report concludes with recommendations for next steps for COBI to meet the goal of 100% renewable energy generation by 2040 on- and off-island, and key caveats to consider.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
NASA NTRS1986

Initial results of the Global Thermospheric Mapping Study (GTMS)

The Global Thermospheric Mapping Study (GTMS) is a multi-technique experimental study of the thermosphere designed to map simultaneously its spatial and temporal morphology with a thoroughness and diversity of measurement techniques heretofore unachieved. The GTMS is designed around the Incoherent Scatter Radar Chain in the western hemisphere. The European incoherent scatter radars and the worldwide communities of Fabry-Perot interferometers, meteor wind radars, partial reflection drifts radars, MST radars, and satellite probes are included to extend the spatial coverage and types of measurements available. Theoretical and modeling support in the areas of thermospheric and ionospheric structure, tides, and electric fields are included to aid in program planning and data interpretation. Solar activity was low on the three observation days (F10.7 = 97, 98, 96) and magnetic conditions were unsettled to active (A = 10, 12, 20). All six incoherent scatter radar facilities collected data. Each collected F region data day and night while Saint Santin and Millstone Hill additionally collected E region data during daylight hours. Initial results from Sondrestrom and Millstone Hill are presented. Good quality Fabry Perot data were collected at Fritz Peak and San Jose dos Campos. Weather conditions produced poor results at Arequipa and Arecibo. Initial results from Fritz Peak are presented. Mesosphere/lower-thermosphere observations were conducted under the ATMAP organization. The magnetometer chains also were operational during this campaign. Initial thermospheric general circulation model predictions were made for assumed solar-geophysical conditions, and selected results are presented.

Oliver, W. L.↗
NASA NTRS1989

A NASA heliospheric program

Direct exploration of the heliosphere out to distances of about 40 AU has been carried out with Pioneer 10, 11 and Voyager 1, 2 while making use of supplementary observations by various spacecraft near 1 AU. In the past, these heliospheric observations have involved at least three divisions in the NASA Office of Space Science and Applications: Solar System Exploration, Astrophysics and Earth Observations. Consideration is now being given to combining the various missions into a single coordinated heliospheric program. A committee has been formed, the Heliospheric Science Working Group, consisting of the project scientists of the ongoing as well as future missions. The HSWG has drawn on appropriate members of the scientific community to assist in the development of a plan and in documenting it in a report. The highlights of the plan, with emphasis on both short range and long range scientific objectives, are described.

Smith, E. J.↗
NASA NTRS1992

Performance of thermal control tape in the protection of composite materials

The selection of materials for construction of long duration mission spacecraft has presented many challenges to the aerospace design community. After nearly six years in low earth orbit, NASA's Long duration Exposure Facility (LDEF), retrieved in January of 1990, has provided valuable information on both the nature of the space environment as well as the effects of the space environment on potential spacecraft materials. Composites, long a favorite of the design community because of a high strength-to-weight ratio, were flown in various configurations on LDEF in order to evaluate the effects of radiation, atomic oxygen, vacuum, micrometeoroid debris, and thermal variation on their performance. Fiberglass composite samples covered with an aluminum thermal control tape were flown as part of the flight experiment A0171, the Solar Array Materials Passive LDEF Experiment (SAMPLE). Visual observations and test results indicate that the thermal control tape suffered little degradation from the space exposure and proved to be a reliable source of protection from atomic oxygen erosion and UV radiation for the underlying composite material.

Kamenetzky, Rachel R.↗
NASA NTRS2001

Development And Application Of The Ion Microprobe For Analysis Of Extraterrestrial Materials

This report covers the work carried out under NASA Grant NAG5-4083. The research was directed toward analyses of early solar system material, of presolar grains preserved in meteorites, and toward theoretical studies of nucleosynthesis in stars related to the chemical evolution of the galaxy and the formation of the solar system. The work was carried out over the time period 15 February 1998 - 31 May 2001 and involved the participation of the following individuals: M. Busso, Visiting Associate, Professor of Astrophysics, Perugia University, Italy; B.-G. Choi, research fellow, now Associate Professor at Seoul National University, Korea; H. C. Connolly, research fellow, now at Kingsborough Community College, CUNY; R. Gallino, Visiting Associate, Professor of Astrophysics, University of Torino; Y. Guan, Smithsonian Institution; C. Hohenberg, Professor of Physics, Washington University, St. Louis; M. Heinrich, electronics and systems engineer, Caltech; W. Hsu, research fellow, Caltech; T. LaTourrette, research fellow, now at Rand Corporation; G. R. Huss, Senior Research Scientist, now at Arizona State University; N. Krestina, research fellow in geochemistry, Caltech; G. J. MacPherson, Smithsonian Institution; K. Nollett, research fellow in astrophysics; Y.-Z. Qian, Professor of Physics, University of Minnesota; G. Srinivasan, research fellow, now Research Scientist, Physical Research Laboratory, Ahmedabad, India.

Wasserburg, G. J.↗
NASA NTRS2016

On-Orbit Calibration and Performance of S-NPP VIIRS DNB

The S-NPP VIIRS instrument has successfully operated since its launch in October 2011. The VIIRS Day-Night Band (DNB) is a panchromatic channel covering wavelengths from 0.5 to 0.9 m that is capable of observing Earth scenes during both day and nighttime orbits at a spatial resolution of 750 m. To cover the large dynamic range, the DNB operates at low, mid, or high gain stages, and it uses an onboard solar diffuser (SD) for its low gain stage calibration. The SD observations also provide a means to compute gain ratios of low-to-mid and mid-to-high gain stages. This paper describes the DNB on-orbit calibration methodologies used by the VIIRS Characterization Support Team (VCST) in supporting the NASA earth science community with consistent VIIRS sensor data records (SDRs) made available by the Land Science Investigator-led Processing Systems (SIPS). It provides an assessment and update of DNB on-orbit performance, including the SD degradation in the DNB spectral range, detector gain and gain ratio trending, stray light contamination and its correction. Also presented in this paper are performance validations based on earth scenes and lunar observations.

Chen, H.↗
NASA NTRSDate not supplied

Changes in Characteristics of Future Climate Across the U.S.: Time Series Analysis of Climate Model Data by NASA POWER

NASA’s Prediction of Worldwide Energy Resource (POWER) project facilitates the use of NASA Earth Science data holdings within the energy, agricultural, and building heating/cooling design industries. POWER packages solar and meteorological data at various temporal levels from several NASA projects in a user friendly GIS-enabled web services system (https://power.larc.nasa.gov). Data users can access these data either through an intuitive data viewer, image services fully integrable with GIS analysis, connections in the cloud through an Amazon Web Services S3 Bucket, or fully customizable access through an API. Data provided by POWER has been used to remotely monitor solar array fields and integrated in a sizing tool for off-grid solar and storage systems. POWER data has also been coupled with key building decision tools to support design and retrofitting of building energy systems for energy efficiency and reduction of greenhouse gases. POWER is now developing capabilities to provide time series of the projected future evolution of surface quantities important to future energy production and use, such as heating/cooling degree days, temperature, wind speed, and downwelling solar flux. We present here a range of possible future changes in these quantities at locations throughout the continental United States. We show how both average and extreme values of the quantities will evolve from present-day to future climate conditions. We plan to provide these projections for users in the energy and sustainable energy communities.

Bradley M. Hegyi↗
DOE OSTI2020

The Impact of Nuclear Physics Uncertainties on Galactic Chemical Evolution Predictions

Modeling the evolution of the elements in the Milky Way is a multidisciplinary and challenging task. In addition to simulating the ~13 billion years evolution of our Galaxy, chemical evolution simulations must keep track of the elements synthesized and ejected from every astrophysical site of interest (e.g., supernova, compact binary merger). The elemental abundances of such ejecta, which are a fundamental input for chemical evolution codes, are usually taken from theoretical nucleosynthesis calculations performed by the nuclear astrophysics community. Therefore, almost all chemical evolution predictions rely on the nuclear physics behind those calculations. In this proceedings article, we highlight the impact of nuclear physics uncertainties on galactic chemical evolution predictions. We demonstrate that nuclear physics and galactic evolution uncertainties both have a significant impact on interpreting the origin of neutron-capture elements in our Solar System. Those results serve as a motivation to create and maintain collaborations between the fields of nuclear astrophysics and galaxy evolution.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1989

Science opportunities in the human exploration of moon

Human exploration of the moon will open up science opportunities not only in lunar science, but also in astronomy and astrophysics, life science, solar and space physics, earth science, and even evolutionary biology. These opportunities may be categorized as those involving study of the moon itself, those in which the moon is used as a platform for investigations, and those conducted in transit between earth and the moon. This paper describes some of these opportunities, and calls on the science community to continue and expand its efforts to define the opportunities, and to work toward their inclusion in plans to return humans permanently to the moon.

Pilcher, Carl B.↗
NASA NTRS2017

Suomi-NPP VIIRS Day-Night Band On-Orbit Calibration and Performance

The Suomi national polar-orbiting partnership Visible Infrared Imaging Radiometer Suite (VIIRS) instrument has successfully operated since its launch in October 2011. The VIIRS day-night band (DNB) is a panchromatic channel covering wavelengths from 0.5 to 0.9 microns that is capable of observing Earth scenes during both daytime and nighttime at a spatial resolution of 750 m. To cover the large dynamic range, the DNB operates at low-, middle-, and high-gain stages, and it uses an on-board solar diffuser (SD) for its low-gain stage calibration. The SD observations also provide a means to compute the gain ratios of low-to-middle and middle-to-high gain stages. This paper describes the DNB on-orbit calibration methodology used by the VIIRS characterization support team in supporting the NASA Earth science community with consistent VIIRS sensor data records made available by the land science investigator-led processing systems. It provides an assessment and update of the DNB on-orbit performance, including the SD degradation in the DNB spectral range, detector gain and gain ratio trending, and stray-light contamination and its correction. Also presented in this paper are performance validations based on Earth scenes and lunar observations, and comparisons to the calibration methodology used by the operational interface data processing segment.

Chen, Hongda↗
NASA NTRS2015

Improving the Discoverability and Availability of Sample Data and Imagery in NASA's Astromaterials Curation Digital Repository Using a New Common Architecture for Sample Databases

The Astromaterials Acquisition and Curation Office at NASA's Johnson Space Center (JSC) is the designated facility for curating all of NASA's extraterrestrial samples. The suite of collections includes the lunar samples from the Apollo missions, cosmic dust particles falling into the Earth's atmosphere, meteorites collected in Antarctica, comet and interstellar dust particles from the Stardust mission, asteroid particles from the Japanese Hayabusa mission, and solar wind atoms collected during the Genesis mission. To support planetary science research on these samples, NASA's Astromaterials Curation Office hosts the Astromaterials Curation Digital Repository, which provides descriptions of the missions and collections, and critical information about each individual sample. Our office is implementing several informatics initiatives with the goal of better serving the planetary research community. One of these initiatives aims to increase the availability and discoverability of sample data and images through the use of a newly designed common architecture for Astromaterials Curation databases.

Todd, N. S.↗
NASA NTRS2018

Verification of Real-Time WSA-ENLIL+Cone Simulations of CME Arrival-Time at the CCMC from 2010 to 2016

The Wang-Sheeley-Arge (WSA)-ENLIL+Cone model is used extensively in space weather operations world-wide to model coronal mass ejection (CME) propagation. As such, it is important to assess its performance. We present validation results of the WSA-ENLIL+Cone model installed at the Community Coordinated Modeling Center (CCMC) and executed in real-time by the CCMC space weather team. CCMC uses the WSA-ENLIL+Cone model to predict CME arrivals at NASA missions throughout the inner heliosphere. In this work we compare model predicted CME arrival-times to in situ interplanetary coronal mass ejection leading edge measurements at Solar TErrestrial RElations Observatory-Ahead (STEREO-A), Solar TErrestrial RElations Observatory-Behind (STEREO-B), and Earth (Wind and ACE) for simulations completed between March 2010 and December 2016 (over 1,800 CMEs). We report hit, miss, false alarm, and correct rejection statistics for all three locations. For all predicted CME arrivals, the hit rate is 0.5, and the false alarm rate is 0.1. For the 273 events where the CME was predicted to arrive at Earth, STEREO-A, or STEREO-B, and was actually observed (hit event), the mean absolute arrival-time prediction error was 10.4 +/- 0.9 h, with a tendency to early prediction error of -4.0 h. We show the dependence of the arrival-time error on CME input parameters. We also explore the impact of the multi-spacecraft observations used to initialize the model CME inputs by comparing model verification results before and after the STEREO-B communication loss (since September 2014) and STEREO-A sidelobe operations (August 2014- December 2015). There is an increase of 1.7 h in the CME arrival time error during single, or limited two-viewpoint periods, compared to the three-spacecraft viewpoint period. This trend would apply to a future space weather mission at L5 or L4 as another coronagraph viewpoint to reduce CME arrival time errors compared to a single L1 viewpoint.

MHD / modeling / validation / forecasting / corona↗
NASA NTRSDate not supplied

A Notional Artemis Lunar Surface Exploration Package (ArLSEP) based on the Gandalf Staff Platform

Introduction: The Artemis program is planning to deliver crew and cargo to the lunar surface, but there is no current package for supporting lunar in-struments and experiments similar to the Apollo Lunar Surface Exploration Package (ALSEP). This abstract provides a possible concept for such a package using the Gandalf Staff Platform as a common core. Gandalf Staff: The Gandalf Staff is an early prototype system developed over FY’21/FY’22 using NASA Science Technology Mission Directorate (STMD) Center Information Fund (CIF) grants to de-sign, build and test “proof-of-concept” components. These components include a 24v battery powered monopole that powers a suite of subsystems, including a Graphical User Interface (GUI) for crew, surface voice and data communications, Lunar Search and Rescue (LunaSAR) navigation and communications, LiDAR, field site external lighting, 360-degree camera, and a geothermal instrument for measuring sub-surface temperature gradient. The staff can be carried independently by an Extra-Vehicular Activity (EVA) astronaut, or can be mounted into a tripod for “hands free” support at a surface site being investigated. The staff can be attached to an external solar array and power storage system for long-duration operations. [1,2] ALSEP: An ASLEP flew on each mission Apollo 12 to Apollo 17. For Apollo 11, a simplified packaged called the Early Apollo Scientific Experiments Pack-age (EASEP) was flown. Each package included a “Central Station” that provided the power and communications connected to a variety of instruments and sensors. The power was provided by a Radioisotope Thermoelectric Generator (RTG) fueled by Plutoni-um-238 generating 70 watts of power (initially, decayed over time) [3]. The communications system provide for direct to Earth data transfer from the lunar surface. Each pack-age was stowed externally in the Lunar Module (LM) Scientific Equipment (SEQ) bay with a mass up to 163 kg (Apollo 17). The crew unloaded the ALSEP from the LM and deployed the instruments on the lunar surface. Although designed to operate for only 1 year, many sites operated for up to 8 years successfully [4]. The Active Seismic Experiment (ASE) included 3 geophones for detecting seismic waves created by mortars and thumpers deployed by the crew. Other active experiments measured the lunar atmosphere, the heat flow in the subsurface, the lunar gravity and potential gravity waves, the lunar magnetic field, the solar wind and plasma interactions in cislunar space. Passive experiments included collectors for dust and cosmic rays, and retroreflectors for precise measurements of distance using a laser from Earth. The ALSEP program continues to generate insights into lunar formation and evolution. ArLSEP Concepts: The lunar surface science package for the Artemis program will hopefully exceed the capability of the ALSEP. There are multiple issues for discussion leading to the design of a new ArLSEP, needing requirements definition from the science community, NASA mission architecture, and NASA budget planners. 1. Delivery Mechanism Two possible projects currently provide capability to deliver scientific cargo to the lunar surface: 1) the Commercial Lunar Payload Services (CLPS) [5] and the Human Landing System (HLS) [6, 7]. Each project is controlled by a different organization within NASA and budgeted with different criteria although both support lunar exploration. The HLS system delivers crew (and potentially cargo) to human landing sites. If an ArLSEP is “predeployed” to such a site, the design must include power (either from the vehicle or independently) to keep the electronics functioning until deployed by the crew. If an ArLSEP is delivered on a vehicle after the crew is present on the lunar surface, safety protocols require adequate distance from the humans for impact from descent propelled sur-face regolith ejecta. This distance can not exceed the capability of the crew to walk (if no rover) to the vehicle for ArLSEP deployment. 2. Overall Guidelines The general design of ArLSEP will likely follow the ALSEP with a common system for communications and power; however, significant architecture differences between Apollo and Artemis exist. Power: The RTG will not be available for early Artemis missions nor likely follow-on Lunar Exploration Transportation Services (LETS) missions [8]. Thus, ArLSEP power must be supplied by solar arrays with sufficient battery capability to “keep alive” necessary electronics during any lunar surface eclipse period. Communication: The Artemis program is developing a series of communications satellites for lunar orbit to provide surface transmission of data and voice to Earth. Called “LunaNET”, this network is component useful for ArLSEP since south polar locations may not always have direct “line-of-sight” to Earth [9]. 3. Concept of Operations (ConOps) The general ConOps for ArLSEP is to deliver the package to lunar surface before the crew arrives, and then have the crew deploy the package after some period of time. This requires coordinated design (for power systems) and launch window (for schedule) on both the cargo and crew missions. Once the ArLSEP is deployed, it will operate autonomously for a number of years. It should be designed to be EVA compatible for crew maintenance and upgrade. 4. Notional Design (for discussion purpose only) The landing site near the South Pole is expected to have no eclipse cycle exceeding 5 days, so the “keep alive” power is 144 hours (6 days to include margin). A 12v ArLSEP will use rechargeable LiFePO4 cells, which are common in the Electric Vehicle (EV) industry. With a current of 5 amps and a 125 watt system, the mass is about 90kg. The comm. system and structure adds another 10kg, thus the “Central Station” is approximately 100kg. The solar power is collected on four arrays (each 2m above the surface), and the entire ArLSEP is designed to stow in a 2m x 1m x 1m volume. The experiment and instrument design will vary for each installation and add mass to the total (although they are expected to fit within the 2m3 volume). Seismic wave generation will likely not be provided with mortars, thus an electric “thumper” will be required. Active instruments such as imaging systems and sensing instruments will benefit from the additional power and communication capability provided by ArLSEP. Passive systems such as retroreflectors, witness plates, and cosmic dust collectors can be added to either the landing vehicle and/or the ArLSEP. With repeated HLS missions to the same human site, the ArLSEP can be expanded and easily maintained for long duration science collection on the lunar surface.

ALSEP↗
DOE OSTI2024

Graphitic Carbon Nitride Quantum Dots (g‐C 3 N 4 QDs): From Chemistry to Applications

Since their emergence in 2014, graphitic carbon nitride quantum dots (g-C 3 N 4 QDs) have attracted much interest from the scientific community due to their distinctive physicochemical features, including structural, morphological, electrochemical, and optoelectronic properties. Owing to their desirable characteristics, such as non-zero band gap, ability to be chemically functionalized or doped, possessing tunable properties, outstanding dispersibility in different media, and biocompatibility, g-C 3 N 4 QDs have shown promise for photocatalysis, energy devices, sensing, bioimaging, solar cells, optoelectronics, among other applications. As these fields are rapidly evolving, it is very strenuous to pinpoint the emerging challenges of the g-C 3 N 4 QDs development and application during the last decade, mainly due to the lack of critical reviews of the innovations in the g-C 3 N 4 QDs synthesis pathways and domains of application. Herein, an extensive survey is conducted on the g-C 3 N 4 QDs synthesis, characterization, and applications. Scenarios for the future development of g-C 3 N 4 QDs and their potential applications are highlighted and discussed in detail. In conclusion, the provided critical section suggests a myriad of opportunities for g-C 3 N 4 QDs, especially for their synthesis and functionalization, where a combination of eco-friendly/single step synthesis and chemical modification may be used to prepare g-C 3 N 4 QDs with, for example, enhanced photoluminescence and production yields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗