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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Visual and near-IR spectrophotometry of asteroids

We have been continuing our studies of the spectral properties of dark asteroids in the solar system. From these studies we expect to learn about the distribution of volatile materials, such as water in clay materials (water of hydration) and how the asteroids may relate to the comets. Our most recent work has been concentrating on simultaneous visual and near infrared photometry near Earth, main belt, and trojan asteroids. We have made observations of some unusual asteroids such as Chiron, which has recently shown cometary activity, and 944 Hidalgo, which has a comet-like orbit. We have also begun studies of the small, dark satellites of Mars and Jupiter in order to understand better how they may relate to the steroids. Could they actually be captured asteroids or comets?

Lebofsky, Larry A.↗
NASA NTRS1991

Sprayable lightweight ablative coating

An improved lightweight, ablative coating is disclosed that may be spray applied and cured without the development of appreciable shrinkage cracks. The ablative mixture consists essentially of phenolic microballoons, hollow glass spheres, glass fibers, ground cork, a flexibilized resin binder, and an activated colloidal clay.

Simpson, William G.↗
NASA NTRS1992

Analysis of soil and species composition

Measurements were made during May to October, 1987 and June to August, 1989 over a tallgrass prairie near Manhattan, Kansas. Soil at the experimental site is predominantly Dwight silty clay loam. The prairie was burned on 16 April 1987 and on 28 April 1989 to improve the mix of grasses and forbs. The experimental area was not grazed during 1986 - 1989. A summary of results are given for soil moisture and plant growth; momentum flux and canopy aerodynamic characteristics; evapotranspiration, components of energy balance and canopy conductance; modeling canopy stomatal conductance; canopy photosynthesis, photosynthetic efficiency and water use efficiency; modeling canopy photosynthesis; the carbon dioxide budget in a temperate grassland ecosystem; and photosynthesis and stomatal conductance related to reflectance on the canopy scale.

Verma, Shashi B.↗
NASA NTRS1992

The nanophase iron mineral(s) in Mars soil

Iron-enriched smectites have been suggested as important mineral compounds of the Martian soil. They were shown to comply with the chemical analysis of the Martian soil, to simulate many of the findings of the Viking Labeled Release Experiments on Mars, to have spectral reflectance in the VIS-NIR strongly resembling the bright regions on Mars. The analogy with Mars soil is based, in a number of aspects, on the nature and behavior of the iron oxides and oxyhydroxides deposited on the surface of the clay particles. A summary of the properties of these iron phases and some recent findings are presented. Their potential relevance to Mars surface processes is discussed.

Banin, A.↗
NASA NTRS1992

Mars surface weathering products and spectral analogs: Palagonites and synthetic iron minerals

There are several hypotheses regarding the formation of Martian surface fines. These surface fines are thought to be products of weathering processes occurring on Mars. Four major weathering environments of igneous rocks on Mars have been proposed; (1) impact induced hydrothermal alterations; (2) subpermafrost igneous intrusion; (3) solid-gas surface reactions; and (4) subaerial igneous intrusion over permafrost. Although one or more of these processes may be important on the Martian surface, one factor in common for all these processes is the reaction of solid or molten basalt with water (solid, liquid, or gas). These proposed processes, with the exception of solid-gas surface reactions, are transient processes. The most likely product of transient hydrothermal processes are layer silicates, zeolites, hydrous iron oxides and palagonites. The long-term instability of hydrous clay minerals under present Martian conditions has been predicted; however, the persistence of such minerals due to slow kinetics of dehydration, or entrapment in permafrost, where the activity of water is high, can not be excluded. Anhydrous oxides of iron (e.g., hematite and maghemite) are thought to be stable under present Martian surface conditions. Oxidative weathering of sulfide minerals associated with Martian basalts has been proposed. Weathering of sulfide minerals leads to a potentially acidic permafrost and the formation of Fe(3) oxides and sulfates. Weathering of basalts under acidic conditions may lead to the formation of kaolinite through metastable halloysite and metahalloysite. Kaolinite, if present, is thought to be a thermodynamically stable phase at the Martian surface. Fine materials on Mars are important in that they influence the surface spectral properties; these fines are globally distributed on Mars by the dust storms and this fraction will have the highest surface area which should act as a sink for most of the absorbed volatiles near the surface of Mars. Therefore, the objectives of this study were to: (1) examine the fine fraction mineralogy of several palagonitic materials from Hawaii; and (2) compare spectral properties of palagonites and submicron sized synthetic iron oxides with the spectral properties of the Martian surface.

Golden, D. C.↗
NASA NTRS1992

Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results

Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.

Plumlee, Geoffrey S.↗
NASA NTRS1992

Ceramic processing: Experimental design and optimization

The objectives of this paper are to: (1) gain insight into the processing of ceramics and how green processing can affect the properties of ceramics; (2) investigate the technique of slip casting; (3) learn how heat treatment and temperature contribute to density, strength, and effects of under and over firing to ceramic properties; (4) experience some of the problems inherent in testing brittle materials and learn about the statistical nature of the strength of ceramics; (5) investigate orthogonal arrays as tools to examine the effect of many experimental parameters using a minimum number of experiments; (6) recognize appropriate uses for clay based ceramics; and (7) measure several different properties important to ceramic use and optimize them for a given application.

Weiser, Martin W.↗
NASA NTRS1991

Derivation of midinfrared (5-25 microns) optical constants of some silicates and palagonite

The 5-25 micron real and imaginary refraction indices are presented for palagonite and the silicates pyrophyllite, kaolinite, serpentine, montmorillonite, saponite, and orthopyroxene. Optical constants in the region of the H2O-bending fundamental near 6 microns are obtained for saponite, montmorillonite, and palagonite. It is established that, if a pellet of pure material can be polished to a mirror finish, the optical constants of such noncohesive materials as clays are easily derivable.

Roush, T.↗
NASA NTRS1992

Analyses of exobiological and potential resource materials in the Martian soil

Potential Martian soil components relevant to exobiology include water, organic matter, evaporites, clays, and oxides. These materials are also resources for human expeditions to Mars. When found in particular combinations, some of these materials constitute diagnostic paleobiomarker suites, allowing insight to be gained into the probability of life originating on Mars. Critically important to exobiology is the method of data analysis and data interpretation. To that end, methods of analysis of potential biomarker and paleobiomarker compounds and resource materials in soils and rocks pertinent to Martian geology are investigated. Differential thermal analysis coupled with gas chromotography is shown to be a highly useful analytical technique for detecting this wide and complex variety of materials.

Mancinelli, Rocco L.↗
NASA NTRS1992

Polygenetic origin of Hrad Vallis region of Mars

A variety of apparently genetically related landforms in the Hrad Vallis region of Mars is examined. It is found that the outer valley of Hrad and the neighboring valley are composite features formed by karst or thermokarst processes and the growth and coalescence of smaller fault-aligned depressions. The materials in the vicinity may be soluble carbonates or sulfates or clay-rich sediment subject to thixotropic collapse. Water circulating within fault and fissure systems removed materials or altered the stability of materials to allow formation of steep-sided depressions. After the emplacement of surface materials in early Amazonian time, water was probably discharged to the surface. Isolate topographic depressions probably formed synchronously with the early release of water. Open lakes may have existed for a time.

De Hon, Rene A.↗
NASA NTRS1992

Ar-40 to Ar-39 ages of the large impact structures Kara and Manicouagan and their relevance to the Cretaceous-Tertiary and the Triassic-Jurassic boundary

Since the discovery of the Ir enrichment in Cretaceous-Tertiary boundary clays in 1980, the effects of a 10-km asteroid impacting on the Earth 65 Ma ago have been discussed as the possible reason for the mass extinction--including the extinction of the dinosaurs--at the end of the Cretaceous. But up to now no crater of this age that is large enough (ca. 200 km in diameter) has been found. One candidate is the Kara Crater in northern Siberia. Kolesnikov et al. determined a K-Ar isochron of 65.6 +/- 0.5 Ma, indistinguishable from the age of the K-T boundary and interpreted this as confirmation of earlier proposals that the Kara bolide would have been at least one of the K-T impactors. Koeberl et al. determined Ar-40 to Ar-39 ages ranging from 70 to 82 Ma and suggested an association to the Campanian-Maastrichtian boundary, another important extinction horizon 73 Ma ago. We dated four impact melts, KA2-306, KA2-305, SA1-302, and AN9-182. Results from the investigation are discussed.

Trieloff, M.↗
NASA NTRS1992

Al Umchaimin depression, Western Iraq: An impact structure?

Al Umchaimin, in Arabic 'hiding place' or 'place of ambush', is located at latitude 32 degrees 35.5 N and longitude 39 degrees 25 E. The nearly circular depression averages 2.75 km in diameter and is 33-42 m deep. It is floored with fine-grained, clay-rich deposits, estimated to be 36 m thick, the surface of which shows well-developed desiccation fissures or mudcracks when dry. Because of its nearly circular planimetric shape and its apparent isolation from other surface and subsurface features, it has been considered by some to be a possible meteorite impact structure and by others to be a surface collapse feature that originated following removal of magma from the subsurface as the magma extruded elsewhere. Al Umchaimin was listed in the U.S. Geological Survey tabulation of 110 structures worldwide for which a meteorite impact origin had been suggested. It was placed in Category 6 Structures for which more data are required for classification. It is concluded that, on the basis of the studies that have been made of Al Umchaimin and on the basis of the brief site visit made, Al Umchaimin probably is not an impact structure but most likely resulted from the enlargement and coalescence of sink holes and eventual collapse of the roof material into the resulting cavity.

Underwood, James R., Jr.↗
NASA NTRS1993

Development of a Cone Penetrometer for Measuring Spectral Characteristics of Soils in Situ

A patent was recently granted to the U.S. Army for an adaptation of a soil cone penetrometer that can be used to measure the spectral characteristics (fluorescence or reflectance) of soils adjacent to the penetrometer rod. The system can use a variety of light sources and spectral analytical equipment. A laser induced fluorescence measuring system has proven to be of immediate use in mapping the distribution of oil contaminated soil at waste disposal and oil storage areas. The fiber optic adaptation coupled with a cone penetrometer permits optical characteristics of the in-situ soil to be measured rapidly, safely, and inexpensively. The fiber optic cone penetrometer can be used to gather spectral data to a depth of approximately 25 to 30 m even in dense sands or stiff clays and can investigate 300 m of soil per day. Typical detection limits for oil contamination in sand is on the order of several hundred parts per million.

Lee, Landris T., Jr.↗
NASA NTRS1993

Production of Ultrafine, High-purity Ceramic Powders Using the US Bureau of Mines Developed Turbomill

Turbomilling, an innovative grinding technology developed by the U.S. Bureau of Mines in the early 1960's for delaminating filler-grade kaolinitic clays, has been expanded into the areas of particle size reduction, material mixing, and process reaction kinetics. The turbomill, originally called an attrition grinder, has been used for particle size reduction of many minerals, including natural and synthetic mica, pyrophyllite, talc, and marble. In recent years, an all-polymer version of the turbomill has been used to produce ultrafine, high-purity, advanced ceramic powders such as SiC, Si3N4, TiB2, and ZrO2. In addition to particle size reduction, the turbomill has been used to produce intimate mixtures of high surface area powders and whiskers. Raw materials, TiN, AlN, and Al2O3, used to produce a titanium nitride/aluminum oxynitride (TiN/AlON) composite, were mixed in the turbomill, resulting in strength increases over samples prepared by dry ball milling. Using the turbomill as a leach vessel, it was found that 90.4 pct of the copper was extracted from the chalcopyrite during a 4-hour leach test in ferric sulfate versus conventional processing which involves either roasting of the ore for Cu recovery or leaching of the ore for several days.

Hoyer, Jesse L.↗
NASA NTRS1992

Composition of near-Earth asteroids

The continuing goal is to determine whether any of the near-Earth asteroids or the satellites of Mars contain hydrated phyllosilicate (clay) minerals. If these minerals are present, they would provide a ready source of water for propellant generation and use in life support systems. Many of the dark main belt asteroids have been shown to contain hydrated phyllosilicate minerals. Some of the near-Earth asteroids are also dark, but telescopic detection of water on these near-Earth asteroids is complicated because of the faintness of these small asteroids and because thermal emission masks the diagnostic spectral features beyond 3 microns due to water of hydration for objects within 2 AU of the Sun. New techniques for asteroid classification based on spectral reflectance and mineralogy will be necessary to determine whether the water absorption features are present on any of the near-Earth asteroids. This past year, better ways to classify 'wet' vs. 'dry' asteroids in the main belt were looked at. This new classification may allow us to determine the presence of water of hydration in the surface minerals of near-Earth asteroids even when we can only observe them at wavelengths that are not affected by thermal emission.

Lebofsky, Larry A.↗
NASA NTRS1993

Thermal Analyzer for Planetary Soil (TAPS): an in Situ Instrument for Mineral and Volatile-element Measurements

Thermal Analyzer for Planetary Soil (TAPS) offers a specific implementation for the generic thermal analyzer/evolved-gas analyzer (TA/EGA) function included in the Mars Environmental Survey (MESUR) strawman payload; applications to asteroids and comets are also possible. The baseline TAPS is a single-sample differential scanning calorimeter (DSC), backed by a capacitive-polymer humidity sensor, with an integrated sampling mechanism. After placement on a planetary surface, TAPS acquires 10-50 mg of soil or sediment and heats the sample from ambient temperature to 1000-1300 K. During heating, DSC data are taken for the solid and evolved gases are swept past the water sensor. Through ground based data analysis, multicomponent DSC data are deconvolved and correlated with the water release profile to quantitatively determine the types and relative proportions of volatile-bearing minerals such as clays and other hydrates, carbonates, and nitrates. The rapid-response humidity sensors also achieve quantitative analysis of total water. After conclusion of soil-analysis operations, the humidity sensors become available for meteorology. The baseline design fits within a circular-cylindrical volume less than 1000 cm(sup 3), occupies 1.2 kg mass, and consumes about 2 Whr of power per analysis. Enhanced designs would acquire and analyze multiple samples and employ additional microchemical sensors for analysis of CO2, SO2, NO(x), and other gaseous species. Atmospheric pumps are also being considered as alternatives to pressurized purge gas.

Gooding, J. L.↗
NASA NTRS1993

A DTA/GC for the in Situ Identification of the Martian Surface Material

The composition and mineralogy of the Martian surface material remain largely unknown. To determine its composition and mineralogy, several techniques are being considered for in situ analyses of the Martian surface material during missions to Mars. We have successfully developed, constructed, and tested a laboratory DTA/GC. The DTA is a Dupont model 1600 high temperature DTA coupled with a GC equipped with a MID detector. The system is operated by a Sun Sparc 11 workstation. When gas evolves during a thermal chemical event, it is shunted into the GC and the temperature is recorded in association with the specific thermal event. We have used this laboratory instrument to define experimental criteria necessary for determining the composition and mineralogy of the Martian surface in situ (e.g., heating of sample to 1100 C to distinguish clays). Our studies indicate that DTA/GC will provide a broad spectrum of mineralogical and evolved gas data pertinent to exobiology, geochemistry, and geology.

Mancinelli, R. L.↗
NASA NTRS1993

New materials: Fountainhead for new technologies and new science

The role of materials as the benchmark technologies which give epochs of human history their names continues into the present. The discovery of new materials has nearly always been the source of new materials science, and frequently of new technologies. This paper analyzes the actual processes by which new materials are synthesized, i.e. whether driven by serendipitous observations, new knowledge is pulled by the market, or integrated into a technological thrust. This analysis focuses on modern ceramic materials discoveries, since World War 2 and uses 45 years experience in materials synthesis in the author's own laboratory as case studies. A dozen different families of materials or processes are involved: hydrothermal reactions; sol-gel processing; clays and zeolites; electroceramics; zero expansion ceramics; diamond films; and radioactive waste host phases. Nanocomposite concepts introduced by the author a decade ago offer an entire, large, new class of materials which will dominate synthesis for the next period. The future of materials research for the next 25 years cannot be extrapolated from the past 25 years. We are near the asymptote for materials utilization in most metals. Likewise we are approaching saturation in improvement of many useful properties. Justifying much further 'basic' R/D for incremental improvement in civilian-oriented industries will not be easy. In materials synthesis, the near-term future is sure to emphasize not new phases, but tailored micro- and nanocomposites for chemical, electrical, optical, and magnetic uses. Unexpected new discoveries such as the Lanxide process may offer rarer chances for step function advances. The new structure of knowledge management will rely less on local research than on integration of worldwide inputs. Better scientific and technological opportunities will lie in designing knowledge intensive materials to meet the new environmental and conservation goals, and the human needs of the very large numbers at the bottom of the socio-economic structures of the world.

Rustum, Roy↗