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At least 1,099 records · Page 61
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NASA NTRS1978

Airborne infrared interferometric observations and analysis of stratospheric trace constituents

Infrared interferometric observations of key trace constituents of the stratosphere have been obtained. The NASA Lear Airborne Observatory with the Grumman airborne interferometer system was flown in the lower stratosphere at an altitude of 13.7 km to obtain transmission spectra in the 2800-6000 per cm region at a resolution of 2.5 per cm using the moon as a source. An atmospheric modeling program and the AFGL line parameter atlas are used to identify H2O, CH4, O3 and other trace constituents and to derive stratospheric column densities (molecules/sq cm).

Smith, L. L.↗
NASA NTRS1978

The photochemical role of tropospheric nitrogen oxides

The role of nitrogen oxides in the tropospheric photochemical system is re-evaluated in the light of recent measurements of the rate constants for two key reactions. A model for nitrogen oxides is discussed which yields surface NO(x) (NO+NO2) levels approaching 1 ppb in NO(x) source regions but less than 0.1 ppb outside source regions. Applying the new rate coefficients implies increased radical concentrations and a more intense O3 and CO photochemistry. Even for densities of 0.1 ppb or less, NO(x) still leads to significant local O3 production and conversion of HO2 to OH. Unrealistic O3 profiles are obtained with the new rate coefficients for surface NO(x) densities of about 1 ppb, while reasonable agreement with observation is obtained with lower NO(x) densities. Feedback processes between CO, NO(x), OH, and CH4 are also discussed.

Chameides, W. L.↗
NASA NTRS1978

Evidence for CO in Jupiter's atmosphere from airborne spectroscopic observations at 5 microns

High-altitude (12.4 km) spectra of Jupiter recorded at the Kuiper Airborne Observatory are analyzed for the presence of CO absorption lines. A line-by-line comparison of Jupiter's spectrum with that of carbon monoxide is presented, as well as a correlation analysis that includes the influence of other gases present in Jupiter's atmosphere (CH4, NH3, H2O, PH3, and GeH4). The resulting evidence points strongly to the presence of carbon monoxide in Jupiter's atmosphere, thus strengthening Beer's evidence for it. Possible explanations for the existence and observability of Jovian CO, including convection from hotter, deeper layers or decomposition of organic molecules, are explored. A recent suggestion that the Jovian CO is restricted to stratospheric levels is not supported by the observations.

Larson, H. P.↗
NASA NTRS1978

Analysis of differential absorption lidar from the Space Shuttle

A parametric analysis of the Shuttle-borne differential absorption lidar concept for the measurement of atmospheric trace constituent profiles in the nadir viewing mode is presented. The criterion of an optimum constituent optical depth is developed and applied to generate estimates of range resolved measurement errors. These errors emphasize the fundamental limitations for establishing the feasibility of range-resolved differential absorption lidar measurements from Shuttle. With current lidar system technology, atmospheric backscatter density profiles may be adequately determined up to about 60-km altitude at the doubled-ruby wavelength, 3472 A, for a 1-J/pulse laser and a 1-sq m receiver. Potential range-resolved measurements of stratospheric and mesospheric trace constituents by differential absorption from Shuttle altitudes are limited to H2O, CH4, N2O, O3, and CO, species which can be more easily measured by passive limb viewing techniques. Range-resolved water vapor data for the lower troposphere may be obtained with accuracies which would be competitive with those from passive sensors.

Remsberg, E. E.↗
NASA NTRS1978

On the abundance of deuterium in Jupiter's atmosphere

The ratio of deuterium to hydrogen in the Jovian atmosphere has been calculated using a new approach. D/C is obtained from weak lines of HD and CH4 in the visible region of the spectrum while C/H is derived from stronger methane and hydrogen absorptions near 1 micron. This technique permits minimization of the varying effects on line formation caused by scattering in the Jovian atmosphere while relying on absorption bands whose strengths have been measured in the laboratory. The result is a deuterium-to-hydrogen ratio of 2.3 + or - 1.1 times 10 to the -5th power, within the range of local interstellar values

Combes, M.↗
NASA NTRS1978

Longwave radiative transfer in the atmosphere

The reported investigation has the objective to develop an accurate radiative transfer model for the thermal infrared region using a quasi-random band model. It is intended to use this model to examine the sensitivity of the outgoing radiance and flux density to the perturbations of such meteorological parameters on the surface emittance and temperature, atmospheric water vapor distribution, cloud altitude and fractional cover, and the concentrations of other infrared active constituents. It is found that the combined effect of N2O and CH4 on the flux is significant and exceeds 1 percent. These two constituents should, therefore, not be neglected in accurate modeling work. The effect of ozone on the flux is too large to be neglected and was partly responsible for the discrepancy between earlier model results and measurements. The effect of cloud depth should be taken into account to obtain better agreement with the measured limb darkening functions.

Gupta, S. K.↗
NASA NTRS1978

Limb brightening on Uranus - The visible spectrum. II

A detailed analysis is presented of photoelectric area-scanning photometry of the Uranus disk obtained during the 1976 apparition. Coarse quantitative information on the true radial intensity distribution over the Uranus disk is derived in four selected wavebands. Lack of circular symmetry in the intensity distributions indicates the presence of disk structure, especially polar brightening, in each waveband. For the 6190-A CH4 band, the distribution corresponds to a uniform disk upon which a hint of polar brightening is superimposed. For the 6400-A region, moderate limb darkening is found. It is pointed out that the coarse analytical technique used in the analysis to explore the information content of the photometric scans of Uranus has several basic limitations. Direct deconvolution of the Uranus scans is required to thoroughly investigate the two-dimensional photometric structure of its disk.

Price, M. J.↗
NASA NTRS1978

Uncertainty propagation in a stratospheric model. I - Development of a concise stratospheric model. II - Monte Carlo analysis of imprecisions due to reaction rates

The paper discusses the development of a concise stratospheric model which uses iteration to obtain coupling between interacting species. The one-dimensional, steady-state, diurnally-averaged model generates diffusion equations with appropriate sources and sinks for species odd oxygen, H2O, H2, CO, N2O, odd nitrogen, CH4, CH3Cl, CCl4, CF2Cl2, CFCl3, and odd chlorine. The model evaluates steady-state perturbations caused by injections of chlorine and NO(x) and may be used to predict ozone depletion. The model is used in a Monte Carlo study of the propagation of reaction-rate imprecisions by calculating an ozone perturbation caused by the addition of chlorine. Since the model is sensitive to only 10 of the more than 50 reaction rates considered, only about 1000 Monte Carlo cases are required to span the space of possible results.

Rundel, R. D.↗
NASA NTRS1978

On the excitation of Lyman beta and Balmer alpha radiation by electron-impact dissociation of methane

The cross sections for the excitation of Ly-beta and H-alpha when methane is dissociated by electron impact have values of 17.1 by 10 to the -19th power sq cm and 26.0 by 10 to the -19th power sq cm, respectively, at an electron impact energy of 100 eV. These results are in disagreement with the implications of recent polarization measurements of H-alpha radiation that suggest negligible H(3p) excitation in the dissociation of CH4 by electron impact.

Mclaughlin, R. W.↗
NASA NTRS1978

Evolution of a nitrogen atmosphere on Titan

Photochemical calculations indicate that if NH3 outgassed from Titan it should have been converted to a dense N2 atmosphere during the lifetime of the satellite. A crucial step in the process involves a gas phase reaction of N2H4 with H. The most favorable conditions for this step would be the intermediate production of a CH4-H2 greenhouse capable of raising the gas temperature to 150 K. Subsequently about 20 bars of N2 could have evolved. The pressure-induced opacity of 20 bars of N2 should suffice to explain the recently measured 200 K surface temperature. Unlike the situation on Jupiter, NH3 is not recycled on Titan by reactions involving N2 or N2H4. This may explain the failure of recent attempts to detect NH3 in the upper atmosphere of Titan.

Atreya, S. K.↗
NASA NTRS1978

Methane-producing bacteria - Natural fractionations of the stable carbon isotopes

Procedures for determining the C-13/C-12 fractionation factors for methane-producing bacteria are described, and the fractionation factors (CO2/CH4) for the reduction of CO2 to CH4 by pure cultures are 1.045 for Methanosarcina barkeri at 40 C, 1.061 for Methanobacterium strain M.o.H. at 40 C, and 1.025 for Methanobacterium thermoautotrophicum at 65 C. The data are consistent with the field determinations if fractionation by acetate dissimilation approximates fractionations observed in natural environments. In other words, the acetic acid used by acetate dissimilating bacteria, if they play an important role in natural methane production, must have an intramolecular isotopic fractionation (CO2H/CH3) approximating the observed CO2/CH4 fractionation.

Games, L. M.↗
NASA NTRS1978

Rate constant for the reaction of atomic chlorine with methane

The rate constant and temperature dependence of the Cl + CH4 reaction have been investigated by the techniques of competitive chlorination of CH4/C2H6 mixtures and by discharge-flow/mass spectroscopy. The objectives were to determine an accurate value for the rate constant for use in stratospheric modeling, and to clarify discrepancies in results previously obtained by different techniques. The results deduced from the competitive chlorination study are in good agreement with the absolute values measured by the mass spectrometric method, and at temperatures above 300 K are in good agreement with measurements by other techniques based on resonance fluorescence detection of atomic chlorine. However, in the 220-300 K region, the competitive experiments indicate lower rate constants than those obtained by resonance fluorescence methods, and do not reproduce the curved Arrhenius plots seen in some of those studies.

Lin, C. L.↗
NASA NTRS1978

Saturn's atmosphere: Results of recent investigations

Saturn apparently has a high clear layer of H2 under which lies a comparable layer rich in dusty material. Beneath this is a thicker layer consisting mostly of H2 mixed with haze particles. An NH3 cloud deck probably lies below this layer. Evidence for seasonal variations is presented in the form of changes in the NH3, CH4 and H2 absorptions. Finally, the latest mixing ratios for the gaseous constituents are summarized.

Trafton, L.↗
NASA NTRS1978

A Titan atmosphere with a surface temperature of 200K

The brightness temperature of Titan at 3 mm wavelength is around 200 K according to Ulich, Conklin, and Dickel (1978). Although an earlier measurement by Briggs is much colder, 200 K as the surface temperature was used to build an atmospheric model with a surface pressure of 21 bars. CH4 clouds form between 100 and 120 km altitude. The visual limb is near 200 km. The methane mixing ratio is 0.25 percent above the clouds and 7 percent below; the dominant gas is assumed to be N2. The thermal opacity is due to pressure-induced absorption in N2 and a trace (0.5 percent) of H2, with some help from cloud particles; unit opacity is reached at 600 mbar, 110 km from the surface. The radius of the solid body in this model is 2700 km, in reasonable agreement with 2600 km obtained if the density is the same as that of Ganymede and Callisto.

Hunten, D. M.↗
NASA NTRS1979

Molecules of significance in planetary aeronomy

This monograph is basically devoted to spectroscopic information of the molecules of planetary interest. Only those molecules have been dealt with which have been confirmed spectroscopically to be present in the atmosphere of major planets of our solar system and play an important role in the aeronomy of the respective planets. An introduction giving the general conditions of planets and their atmospheres including the gaseous molecules is given. Some typical planetary spectra is presented and supported with a discussion on some basic concepts of optical absorption and molecular parameters that are important to the study of planetary atmospheres. Quantities like dipole moments, transition probabilities, Einstein coefficients and line strengths, radiative life times, absorption cross sections, oscillator strengths, line widths and profiles, equivalent widths, growth curves, bond strengths, electronic transition moments, Franck-Condon factors and r-centroids, etc., are discussed. Spectroscopic information and relevant data of 6 diatomic (HF, HCL, CO, H2, O2, N2) and 6 polyatomic (CO2, N2), O3, HeO, NH3, CH4) molecules are presented.

Mohan, H.↗
NASA NTRS1979

Variability of Lyman-alpha emission from Jupiter

The Jovian Lyman-alpha emission line was again observed in 1978 using the high resolution spectrometer on the Copernicus satellite. In intensity of 8.4+3.0 kilo Rayleighs was measured. This value represents a significant increase in intensity over previous (1976) Copernicus observations, but is lower than the recent (1979) values obtained by Voyager I and IUE. The increase in intensity was accompanied by a significant increase in line width, giving strong support to the theory that the emission results from resonant scattering of the solar Ly-alpha line by H atoms in the upper Jovian atmosphere. The strength of Jovian Ly-alpha emission correlates well with the level of solar activity. The solar extreme ultraviolet radiation varies with the solar cycle. This radiation causes the dissociation of H2 and CH4 into H atoms in the Jovian atmosphere. Therefore, in times of high solar activity, the H column density will increase, causing the observed stronger Jovian Ly-alpha emission.

Source record↗
NASA NTRS1978

An analysis of the coma of comet Bennett 1970 II

Brightness profiles for emission features of H2O(+) in comet Bennett 1970 II are analyzed, taking into account the role of chemical reactions in the coma. By comparing the rates of transport processes derived from the brightness profile with known chemical rate constants, upper limits on the abundances and production rates of H2O, CH4, NH3, and other possible coma constituents are found. The derived upper limit on the H2O production rate inside 10 to the 4th power km is less than the observed OH production rate averaged over the coma of this comet. It is concluded that the brightness profiles of H2O(+) and OH in comet Bennett 1970 II which are presently available are inconsistent with production of OH primarily by photodissociation of H2O molecules sublimating from the nucleus. The existence of an extended source of H2O is not ruled out.

Oppenheimer, M.↗
NASA NTRS1978

Methane detected in Orion A

This letter reports the detection of line emission from the Orion Molecular Cloud corresponding to six distinct pure-rotational delta J = 0 transitions in CH4. The transitions observed and the transition frequencies are: J = 11 E(2) - E(1), 4600.359 MHz; J = 18 F1(4) - F2(1), 76,231.45 MHz; J = 18 A1(2) - A2(1), 76,700.02 MHz; J = 19 F1(4) - F2(1), 75,944.99 MHz; J = 19 F2(4) - F1(1), 78,233.59 MHz; and J = 20 F2(5) - F1(2), 82,873.59 MHz. The observed spectra at the six transition frequencies are plotted, and all but two of the methane lines are found to be very narrow (about 2 km/s). It is noted that the small velocity widths of the four weaker lines and an observed variability of the J = 18 A line are classic characteristics of a maser and that the excitation appears to be nonthermal. An effective excitation temperature of 1100 to 2100 K is estimated for the methane in Orion A.

Fox, K.↗