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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Does CO trace H2 at high galactic latitude

A CO survey of 342 Infrared Excess Clouds (IRECs) distributed uniformly across the sky is presented. Following comparison of the integrated CO brightness with the 100 micron infrared brightness B(sub 4) obtained from the IRAS data, evidence was found for a threshold in B(sub 4) of 4-5 MJy sr(exp -1) below which CO does not form. Evidence is also presented that the threshold effect can be seen within an individual cloud, providing evidence for a phase transition between atomic and molecular gas. While the main thrust was to examine the CO content of the IRECs, it was also attempted to detect CO toward a number of UV stars so that CO brightness could be correlated with direct measurements of H2 column density and E(B-V). Of the 26 observed stars CO was detected toward 6. It is consistent with the results obtained using infrared data.

Bazell, David↗
NASA NTRS1989

Comparison between observed and calculated distributions of trace species in the middle atmosphere

The purpose is to identify major discrepancies between empirical models and theoretical models and to stress the need for additional observations in the atmosphere and for further laboratory work, since these differences suggest either problems associated with observation techniques or errors in chemical kinetics data (or the existence of unknown processes which appear to play an important role). The model used for this investigation extends from the earth's surface to the lower thermosphere. It includes the important chemical and photochemical processes related to the oxygen, hydrogen, carbon, nitrogen and chlorine families. The chemical code is coupled with a radiative scheme which provides the heating rate due to absorption of solar radiation by ozone and the cooling rate due to the emission and absorption of terrestrial radiation by CO2, H2O and O3. The vertical transport of the species is expressed by an eddy diffusion parameterization.

Brasseur, G.↗
NASA NTRS1991

Trace gas and aerosol transports into and out of the Amazon Basin

Overviews of the wet season Amazon Boundary Layer Experiment (ABLE IIB) are presented which give the context of the wet season experiment and some of the results. Copies of all reprints and manuscripts published or accepted for publication are attached. A complete list of all papers published in the reviewed literature, papers presented as well as published as part of conference preceedings, and articles published in the news media are listed in the appendices. Two scales of interaction of the rain forest were pursued in this work: (1) global interactions; and (2) local and regional interactions. Under the first scale, the role of the rain forest in the global system was the central thrust of the work. Under the second scale, the role of the rain forest on the basin and smaller scales was emphasized. The appendices also provide a summary of future work and a listing of degrees awarded during this report period.

Garstang, Michael↗
NASA NTRS1990

Kelvin wave-induced trace constituent oscillations in the equatorial stratosphere

Kelvin wave induced oscillations in ozone (O3), water vapor (H2O), nitric acid (HNO3) and nitrogen dioxide (NO2) in the equatorial stratosphere are analyzed using Limb Infrared Monitor of the Stratosphere (LIMS) data. Power and cross-spectrum analyses reveal coherent eastward propagating zonal wave 1 and 2 constituent fluctuations, due to the influence of Kelvin waves previously documented in the LIMS data. Comparison is made between a preliminary and the archival versions of the LIMS data; significant differences are found, demonstrating the sensitivity of constituent retrievals to derived temperature profiles. Because Kelvin waves have vanishing meridional velocity, analysis of tracer transport in the meridional plane is substantially simplified. Kelvin wave vertical advection is demonstrated by coherent, in-phase temperature-tracer oscillations, co-located near regions of strong background vertical gradients.

Randel, William J.↗
NASA NTRS1990

Chemical studies of differentiated meteorites. I - Labile trace elements in Antarctic and non-Antarctic eucrites

Element contents of Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Sb, Se, Te, Tl, U, and Zn were analyzed, using RNAA, in 25 Antarctic and nine non-Antarctic eucrites to determine whether these two populations differ significantly in thermal history and derive from the same or different eucrite parent body. Data for these 15 elements indicate that basaltic Antarctic and non-Antarctic eucrite populations reflect the same genetic processes and, hence, come from the same parent asteroid.

Paul, Rick L.↗
NASA NTRS1990

Detection of trace helium in G104 - 27, a 26,000 K DA white dwarf

The detection of the He I 4471 A feature in the moderately hot DA white dwarf G104 - 27 places this star within the rather sparse class of DAB white dwarfs. It does not appear possible, on the basis of the present data, to distinguish between a stratified and a homogeneously mixed atmosphere. While a stratified structure would be natural for a DA white dwarf, G104 - 27 resides near the red edge of the DB gap, in a region where DA stars could transform into DB stars through convective mixing in the underlying He envelope and thereby destroy envelope stratification. Both atmospheres are consistent with the existing soft X-ray flux limit for this star.

Holberg, J. B.↗
NASA NTRS1991

Use of satellite data to constrain the model-calculated atmospheric lifetime for N2O - Implications for other trace gases

Model calculations of the zonal-mean concentrations of N2O in the upper stratosphere are presented showing that about 80 percent of N2O is removed in the stratosphere between 30 deg N and 30 deg S. A comparison of calculated N2O values with remote data on N2O concentrations obtained from Nimbus 7 SAMS instrument indicated that the two-dimensional model of Ko and Sze (1982) may have underestimated the concentration of N2O in the tropical lower stratosphere. It is concluded that the calculated lifetimes for N2O and chlorofluorocarbon-source gases could be 30 percent shorter than previously reported values.

Ko, Malcolm K. W.↗
NASA NTRS1990

Measurement of trace stratospheric constituents with a balloon borne laser radar

The objective of this research was to measure the concentration of the stratospheric hydroxyl radical and related chemical species as a function of altitude, season, and time of day. Although hydroxyl plays a very important role in the chemistry controlling stratospheric ozone, little is known about its behavior because it has been a difficult species to measure. The instrument employed in this program was a laser radar, employing the technique of remote laser induced fluorescence. This instrument offers a number of attractive features including extreme specificity and sensitivity, a straightforward relationship between observed quantity and the desired concentration, and immunity to self-contamination.

Heaps, William S.↗
NASA NTRS1990

ATLAS: Airborne Tunable Laser Absorption Spectrometer for stratospheric trace gas measurements

The ATLAS instrument is an advanced technology diode laser based absorption spectrometer designed specifically for stratospheric tracer studies. This technique was used in the acquisition of N2O tracer data sets on the Airborne Antarctic Ozone Experiment and the Airborne Arctic Stratospheric Expedition. These data sets have proved valuable for comparison with atmospheric models, as well as in assisting in the interpretation of the entire ensemble of chemical and meteorological data acquired on these two field studies. The N2O dynamical tracer data set analysis revealed several ramifications concerning the polar atmosphere: the N2O/NO(y) correlation, which is used as a tool to study denitrification in the polar vertex; the N2O Southern Hemisphere morphology, showing subsidence in the winter polar vortex; and the value of the N2O measurements in the interpretation of ClO, O3, and NO(y) measurements and of the derived dynamical tracer, potential vorticity. Field studies also led to improved characterization of the instrument and to improved accuracy.

Loewenstein, Max↗
NASA NTRS1992

Phase equilibria and trace element partitioning in a magma ocean to 260 kilobars

A magma ocean can solidify in a way that is intermediate between perfect equilibrium and perfect fractional crystallization. In order to model quantitatively any fractional crystallization scenario, it is necessary to understand the geochemical characteristics of the phases that crystallize from a magma ocean, and how they vary with pressure. The crystallizing phase is called the liquidus phase, and their identities were determined by numerous experiments utilizing the multianvil apparatus. For chondritic compositions the liquidus phases are as follows: olivine at 1 atmosphere to 100 kilobars; garnet from 100 to about 260 kilobars; silicate perovskite from 260 kilobars to possibly the core-mantle boundary in the Earth.

Herzberg, Claude↗
NASA NTRS1992

Trace gas and aerosol transports into and out of the Amazon Basin

Research under Agreement NCC1-106 during the interim period Oct. 1, 1991 to May 31, 1992 has continued to use the data collected during all three ABLE missions. The work reported on in this interim period includes published papers that cover the topic of global interactions between the rain forest of the Amazon Basin and local regional processes interior to the Basin itself.

Garstang, Michael↗
NASA NTRS1992

Laser Raman sensor for measurement of trace-hydrogen gas

A new optical hydrogen sensor based on spontaneous Raman scattering of laser light has been designed and constructed for rugged field use. It provides good sensitivity, rapid response, and the inherent Raman characteristics of linearity and background gas independence of the signal. Efficient light collection and discrimination by using fast optics and a bandpass interference filter compensate for the inefficiency of the Raman-scattering process. A multipass optical cavity with a Herriott-type configuration provides intense illumination from an air-cooled CW gas laser. The observed performance is in good agreement with the theoretical signal and noise level predictions.

Adler-Golden, Steven M.↗
NASA NTRS1992

Trace elements in chondritic stratospheric particles - Zinc depletion as a possible indicator of atmospheric entry heating

Major-element abundances in 11 C, C?, and TCA cosmic dust particles have been measured using SEM and TEM energy dispersive X-ray (EDX) systems. The Fe/Ni ratio, when coupled with major element abundances, appears to be a useful discriminator of cosmic particles. Three particles classified as C?, but having Fe/Ni peak height ratios similar to those measured on the powdered Allende meteorite sample in their HSC EDX spectra, exhibit chondritic minor-/trace-element abundance patterns, suggesting they are extraterrestrial. The one particle classified as C-type, but without detectable Ni in its JSC EDX spectrum, exhibits an apparently nonchondritic minor-/trace-element abundance pattern. A class of particles that are chondritic except for large depletions in the volatile elements Zn and S has been identified. It is likely that these particles condensed with a C1 abundance pattern and that Zn and S were removed by some subsequent process.

Flynn, G. J.↗
NASA NTRS1991

Airborne trace organic contaminant removal using thermally regenerable multi-media layered sorbents

A cyclic two-step process is described which forms the basis for a simple and highly efficient air purification technology. Low molecular weight organic vapors are removed from contaminated airstreams by passage through an optimized sequence of sorbent media layers. The contaminant loaded sorbents are subsequently regenerated by thermal desorption into a low volume inert gas environment. A mixture of airborne organic contaminants consisting of acetone, 2-butanone, ethyl acetate, Freon-113 and methyl chloroform has been quantitatively removed from breathing quality air using this technique. The airborne concentrations of all contaminants have been reduced from initial Spacecraft Maximum Allowable Concentration (SMAC) levels to below the analytical limits of detection. No change in sorption efficiency was observed through multiple cycles of contaminant loading and sorbent regeneration via thermal desorption.

Atwater, James E.↗
NASA NTRS1992

Isotopic, optical, and trace element properties of large single SiC grains from the Murchison meteorite

Ion probe mass spectrometry is used to analyze 41 large SiC grains from the Murchison CM2 chondrite, ranging up to 15 x 26 microns, for the isotopic compositions of C, N, Mg, and Si, and the concentrations of Al, Ti, V, Fe, Zr, and Ba. The majority were found to have large isotopic anomalies. Only two grains, characterized by extremely heavy carbon, give evidence for fossil Mg-26. On the basis of C and Si isotopic composition, 29 of the grains fall into three compact clusters, presumably from three discrete sources. The clustering of coarse-grained SiC stands in sharp contrast to the quasi-continuous distribution of finer-grained SiC and suggests that the top 0.1 percent of the mass distribution is a distinct population. The C and N isotopic compositions of the anomalous grains are not very diagnostic, being consistent with H-burning in the CNO cycle. The Si-isotopic compositions qualitatively show the signature of neutron capture in He-burning shells of highly evolved stars.

Virag, Alois↗
NASA NTRS1991

Improved Limb Atmospheric Spectrometer (ILAS) for polar stratospheric trace gas measurements

The Improved Limb Atmospheric Spectrometer (ILAS) is a grating spectrometer designed to measure vertical profiles of high latitude stratospheric constituents in a solar occultation mode. ILAS measurement gases are ozone (03), methane (CH4), nitrous oxide (N2O), nitric acid (HNO3), water vapor (H2O), nitrogen dioxide (NO2), and CFC-11 using an IR channel. Temperature, pressure, and aerosol are also measured using a visible channel. The IR channel consists of 44 detector elements which cover the spectral range 6.2 to 11.8 microns, and the visible channel is composed of 1024 pixels that cover 753 to 784 nm. ILAS will be installed on the Advanced Earth Observing Satellite (ADEOS) which will be launched in 1995. Instrument design data are outlined.

Yokota, Tatsuya↗