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NASA NTRS1985

A preliminary spectroscopic assessment of the Spacelab 1/Shuttle optical environment

Attention is given to the Space Lab/Space Shuttle-borne Imaging Spectrometric Observatory's 1150-8000 A spectral data, which was gathered while this instrument package was looking tangentially away from the earth and into the velocity vector. The spectrum is noted to contain the expected atmospheric features, together with bright molecular bands between 6400 and 8000 A. These bands appear to be part of the N2 First Positive system. If most of the emission is due to this system, two excitation mechanisms are implied: direct collisional excitation of the local Shuttle atmosphere by the terrestrial atmosphere, or alternatively a surface interaction which generates metastable N2(A); this subsequently radiates via inverse first positive N2 transitions, followed by first positive transitions.

Torr, M. R.↗

NASA NTRS1983

Developments with multispectral thermal-IR and active microwave systems - TIMS, SIR-A, SIR-B, and radarsat

An update of current and future systems for spectral scanning of geological features in the thermal-IR, and active microwave bands is presented. The design characteristics of four individual systems are described, including the NASA Thermal Infrared Multispectral Scanner (TIMS); the Shuttle Imaging Radars A and B (SIRA-A and SIRA-B); and the Canadian RADARSAT satellite for geological mapping and ice monitoring. The applications of spectral data from the Side Looking Airborne Radar (SLAR), the GEMS 100 mapping system, and the Landsat RBV instrument to the mapping of large geological structures are also described.

Harrison, P. G.↗

NASA NTRS1984

Balloon-borne and aircraft infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere

Quantitative infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere are reported. The results have been obtained from the analysis of absorption features of the nu9 band at 12.2 microns, which have been identified in high-resolution balloon-borne and aircraft solar absorption spectra. The balloon-borne spectral data were recorded at sunset with the 0.02/cm resolution University of Denver interferometer system, from a float altitude of 33.5 km near Alamogordo, New Mexico, on March 23, 1981. The aircraft spectra were recorded at sunset in July 1978 with a 0.06/cm resolution interferometer aboard a jet aircraft at 12 km altitude, near 35 deg N, 96 deg W. The balloon analysis indicates the C2H6 mixing ratio decreased from 3.5 ppbv near 8.8 km to 0.91 ppbv near 12.1 km. The results are consistent with the column value obtained from the aircraft data.

Goldman, A.↗

NASA NTRS1984

Organic matter in the Saturn system

Theoretical and experimental predictions of the formation (and outgassing) of organic molecules in the outer solar system are compared with Voyager IRIS spectral data for the Titan atmosphere. The organic molecules of Titan are of interest because the species and processes within the atmosphere of that moon may have had analogs in the early earth atmosphere 4 Gyr ago. The spacecraft data confirmed the presence of alkanes, ethane, propane, ethylene, alkynes, acetylene, butadiene, methylacetylene, nitriles, hydrogen cyanide, cyanoacetylene, and cyanogen, all heavier than the dominant CH4. Experimental simulation of the effects of UV photolysis, alpha and gamma ray irradiation, electrical discharges and proton and electron bombardment of similar gas mixtures has shown the best promise for modeling the reactions producing the Titan atmosphere chemicals.

Sagan, C.↗

NASA NTRS1984

Glass on the surfaces of Io and Amalthea

The results of laboratory tests of the spectral reflectances of sulfur and sulfur-silicate glasses are compared with Voyager UV and IR spectral data of Io and Amalthea. Sulfur glasses, without the S8 allotrope, are formed when molten sulfur is quickly quenched to temperatures below 150 K. The trials involved heating sulfur to temperatures from 430-700 K, then quenching and recording the color that resulted. It was observed that the insulating properties of sulfur are so high that the glasses would probably only form in volcanic plumes, yielding particles in the 10-100 micron diameter range. Fumarole droplets could impact cold ground and leave 1 mm glass particles. Basalt-sulfur specimens heated to 1400 K to melt the basalt, then cooled, produced glasses of a color which matches the color of darker areas detected on Io. The surface colors of Amalthea, although definitely contaminated with particles from Io mass loss, exhibited only a few color matches with the basalt-sulfur glasses. More refined spectra of Amalthea are required if the surface constituents are to be identified.

Gradie, J.↗

NASA NTRS1985

Measurements of absolute line intensities in carbon dioxide bands near 5.2 microns

A nonlinear least-squares spectral fitting procedure has been used to derive experimental absolute intensities for over 300 unblended lines belonging to twelve CO2 bands in the 5.2-micron region. The spectral data were recorded at 0.01/cm resolution and room temperature with the Fourier transform spectrometer in the McMath solar telescope complex at the National Solar Observatory on Kitt Peak and have a signal-to-rms noise ratio of 2000-4000. A natural sample of carbon dioxide was used as the sample gas. For each band, the measured line intensities have been analyzed to derive the vibrational band intensity and coefficients of the F factor. The results are compared to the values used to calculate the intensities in the 1982 Air Force Geophysics Laboratory line parameters compilation.

Rinsland, C. P.↗

NASA NTRS1985

He II lambda 1640/lambda 4686 and Ly-alpha/H-beta ratios in the extraordinary Seyfert galaxy Markarian 359

The exceptionally narrow-lined Seyfert 1 galaxy Mrk 359 is ideally suited for determining reddening via the He II lambda 1640/lambda 4686 emission-line ratio. Here the validity of He II lines as a reddening indicator for quasars and Seyfert galaxies is reexamined and confirmed in the context of the most complete photoionization models available. In addition, lambda 1640 equivalent width measurements are shown to support previous contentions of substantial differences between observed and intrinsic quasar far-ultraviolet continua. Then IUE satellite and ground-based spectral data are presented, with the surprising result that both the lambda 1640/lambda 4686 and Ly-alpha/H-beta ratios do not differ greatly from case B recombination values in Mrk 359. This object is only slightly reddened, and it shows no evidence for extended, high-optical-depth H(+)/H(0) transition regions in the line-emitting gas. The very narrow lines and lack of deep transition regions and/or reddening may be related. In addition, Mrk 359 has low luminosity compared with most other Seyfert 1 galaxies, measured emission lines suggest an unusually high ionization parameter, and there is a hint of low nitrogen abundance. Further work is needed to examine possible relationships among all these peculiar properties.

Macalpine, G. M.↗

NASA NTRS1986

Improved Spectrometer for Field Use

Proposed portable spectrometer for analyzing minerals in field generates spectral images like camera and process spectral data for real-time identification of materials. To identify unknown mineral, user locates significant peaks in displayed spectrum and matches them to spectrum in portfolio of reference spectra. Alternatively, user calls up display of prerecorded spectra in same wavelength region for comparison or allows spectrometer to determine best match automatically. New instrument makes it unnecessary to return data to laboratory or equipment trailer for processing.

Goetz, A. F. H.↗

NASA NTRS1986

Impact experimentation and the microgravity environment: An overview

Impact is an ubiquitous physical process in the solar system. It occurs on all solid bodies and operates over a spectrum of scales, influencing geologic processes ranging from accretion, the early evolution of planetary bodies, the petrogenetic and spatial relations of lunar samples, the surface characteristics and interpretation of spectral data of asteroidal bodies, to the nature of some meteorites. Understanding impact phenomena is therefore paramount in constraining and underpinning a large number of research efforts into fundamental planetary geology. Gravity is an important parameter in impact processes. The physical environment offered by the Space Station represents an unique opportunity to extend the experimental aspect of impact studies into the microgravity (less than 1 g) regime. Through the use of free floating targets, it may be possible to explore in detail phenomena associated with the collision of bodies. Such experiments can address questions regarding early and late accretional processes, catastrophic disruption and asteroidal evolution, as well as the effects of large impacts on the momentum and spin of the target bodies. The last question is of considerable topical interest with respect to the hypothesized origin of the moon by a Mars-sized impact on Earth.

Grieve, R. A. F.↗

NASA NTRS1986

Absolute line intensities in CO2 bands near 4.8 microns

Absolute intensities for 726 unblended lines in 20 bands of C-12(O-16)2, C-13(O-16)2, O-16C-12O-18, and O-16C-12O-17 in the 4.8-micron spectral region have been determined using a natural sample of ultrahigh-purity CO2. Spectral data were recorded at low pressure (less than 10 torr) and room temperature with the Fourier transform spectrometer in the McMath solar telescope complex on Kitt Peak. Derived vibrational band intensities and coefficients of the F factor for each band were compared to values of the 1982 Air Force Geophysics Laboratory line parameters compilation. The present work fills out the CO2 lines in the 5-micron band systems. Lines in the strongest of these measured bands are being used to infer atmospheric pressure from high-resolution stratospheric spectra recorded during the Spacelab 3 Atmospheric Trace Molecule Spectroscopy experiment.

Rinsland, C. P.↗

NASA NTRS1985

Einstein observations of Vela X and the Vela pulsar

The imaging detectors of the Einstein X-ray observatory have been used to study the Vela pulsar and its surrounding region. Although the pulsar is a relatively strong source of X-rays, there are not detectable pulsations at the pulsar period; the pulsed X-ray luminosity is less than approximately 10 to the 31st ergs/s in the 0.1-4.5 keV band. Nor is there evidence for other types of variability in the pulsar's X-ray emission. The images reveal structure on four spatial scales: (1) a pointlike object coincident with the pulsar; (2) a relatively bright, approximately 4-arcmin nebula of diffuse emission about the pulsar; (3) an approximately 1-degree nebula of hard emission that lies between the pulsar and the radio feature Vela X; and (4) thermal emission from the entire approximately 5-degree Vela supernova remnant. Spectral data from the small nebula are well fitted by a synchrotron model. Under the assumption that emission from the pulsar itself is thermal blackbody radiation, the surface temperature of the neutron star is calculated to be 1 million K.

Harnden, F. R., Jr.↗

NASA NTRS1985

Stress assessment and spectral characterization of suspected acid deposition damage in red spruce (Picea Rubens) from Vermont

The effects of acid deposition on Picea rubens are studied. The Picea rubens located at Camels Hump Mt., Mt. Ascutney, and Ripton, VT were analyzed using stress level evaluations, in situ spectral data, pressure bomb analysis, and aircraft sensors. Spruce stress per circular plot and percent spruce mortality are calculated. The relation between stress levels and elevation and exposure and weather patterns is examined. It is observed that variations in the reflectance curves of the foliage and branches are related to cellular health, the type of cellular arrangement, and the degree of leaf tissue hydration; the leaf and twig specimens from high stress sites are more reflective in the red portion of the visible and less reflective in the NIR portion of the spectrum. The pressure bomb data reveal that the xylem water tension is higher in specimens from high stress sites. It is noted that remote sensing permits discrimination and mapping of suspected acid deposition damage.

Rock, B. N.↗

NASA NTRS1985

Airborne atmospheric electricity experiments

During the 1984 U2 spring flight program, lightning spectra were measured in the wavelengths from 380 nm to 900 nm with a temporal resolution of 5 ms. With this capability, researchers simultaneously acquired both visible near-infrared lightning spectra on a pulse to pulse basis, so that the spectral variability within a flash, as well as flash to flash variations, can be studied. Preliminary results suggest that important variations do occur, particularly in the strengths of the hydrogen and singly ionized nitrogen emission lines. Also, the results have revealed significant differences in the integrated energy distributions between the lightning spectra measured above clouds and the spectral measurements of cloud-to-ground lightning made at the ground. In particular, the ratio of the energy in the near-IR to that in the visible is around 1 to 2 for cloud top spectra versus about 1/3 for surface observations. Detailed analyses of the 1984 lightning spectral data is being conducted. This data should provide improved understanding about the optical transmission properties of thunderclouds and the physics of the lightning discharge process. Efforts continue on developing and testing background signal removal algorithms using U2 spectometer and optical array sensor day-flight data sets. The goal of this research is to develop an algorithm satisfying Lightning Mapper Sensor requirements.

Blakeslee, R. J.↗

NASA NTRS1986

Spectroscopic detection of Ch3Cl in the upper troposphere and lower stratosphere

Absorptions due to the nu1 band of CH3Cl have been identified for the first time in infrared solar absorption spectra of the upper troposphere and lower stratosphere. The spectral data were obtained with the ATMOS Fourier transform spectrometer on board Spacelab 3 in May 1985 during four solar occultation events near latitudes of 30 deg N, 26 deg N, 25 deg N, and 49 deg S. Volume mixing ratio profiles of CH3Cl retrieved for the altitude range 12 to 23 km at these four latitudes do not show appreciable differences. Vertical mixing ratio distributions vary from 6 x 10 to the -10th at 12 km to 3 x 10 to the -10th at 23 km with an average uncertainty of about 25 percent. The retrieved mixing ratio does not decrease with altitude as rapidly as the data obtained by in situ techniques.

Park, J. H.↗

NASA NTRS1986

Potassium in the atmosphere of Mercury

Spectral data are reported from a search for potassium in the Mercury atmosphere. The data were collected with instrumentation at Kitt Peak (7699 A) and at McDonald Observatory (7698.98 and 7664.86 A). The equivalent mean widths of the potassium emission lines observed are tabulated, along with the estimated abundances, which are compared with sodium abundances as determined by resonance lines. The average column abundance of potassium is projected to be 1 billion atoms/sq cm, about 1 percent the column abundance of sodium.

Potter, A. E.↗

NASA NTRS1986

Self-regulated cooling flows in elliptical galaxies and in cluster cores - Is exclusively low mass star formation really necessary?

A self-consistent treatment of the heating by supernovae associated with star formation in a spherically symmetric cooling flow in a cluster core or elliptical galaxy is presented. An initial stellar mass function similar to that in the solar neighborhood is adopted. Inferred star-formation rates, within the cooling region - typically the inner 100 kpc around dominant galaxies at the centers of cooling flows in XD clusters - are reduced by about a factor of 2, relative to rates inferred when the heat input from star formation is ignored. Truncated initial mass functions (IMFs) are also considered, in which massive star formation is suppressed in accordance with previous treatments, and colors are predicted for star formation in cooling flows associated with central dominant elliptical galaxies and with isolated elliptical galaxies surrounded by gaseous coronae. The low inferred cooling-flow rates around isolated elliptical galaxies are found to be insensitive to the upper mass cutoff in the IMF, provided that the upper mass cutoff exceeds 2 M solar mass. Comparison with observed colors favors a cutoff in the IMF above 1 M solar mass in at least two well-studied cluster cooling flows, but a normal IMF cannot be excluded definitively. Models for NGC 1275 support a young (less than about 3 Gyr) cooling flow. As for the isolated elliptical galaxies, the spread in colors is consistent with a normal IMF. A definitive test of the IMF arising via star formation in cooling flows requires either UV spectral data or supernova searches in the cooling-flow-centered galaxies.

Silk, J.↗

NASA NTRS1986

High-resolution optical and ultraviolet absorption-line studies of interstellar gas

Recent progress in the characterization of the interstellar medium (ISM) by means of optical and UV spectral data is summarized. The gas is studied by focusing on background stars whose spectra can be accurately modeled to provide the light source for the absorption-line scans. The capabilities of earth- and space-based instruments which have been and are used for the surveys are delineated. The distributions of diffuse gas densities and characteristics of the cold, warm and hot gas in the Galaxy are described in terms of the elemental abundances, kinetics and distributions of the gas. Particular note is taken of gas in the solar neighborhood and around SNR, and of absorption-line data of cosmological significance.

Cowie, Lennox L.↗

NASA NTRS1987

Measurements of mesospheric water vapor in 1984 and 1985 - Results and implications for middle atmospheric transport

The detailed results of ground-based mesospheric water vapor measurements obtained by microwave spectroscopy at the Jet Propulsion Laboratory (JPL) from December 1984 to April 1985 (JPL 1984/85), and an overview of results obtained the previous year from April to June 1984 are presented. The JPL 1984/85 spectral data appeared to contain an instrumental baseline curvature which was bracketed and removed. In general, the JPL 1984/85 results are in good agreement with those of previous measurements. They indicate water vapor mixing ratios between 6 and 8 ppmv at 60 or 65 km and falling off steeply with height above this point to values of less than 2 ppmv at 80 km. In addition, there is a large amount of day-to-day variability indicated in the data. A major result of the study is that it is found that both the observed vertical gradient of water vapor mixing ratio and its seasonal variation are consistent with the hypothesis that vertical transport time scales are smaller, perhaps by an order of magnitude, than values currently used in both one- and two-dimensional photochemical/dynamical models.

Bevilacqua, Richard M.↗