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At least 1,081 records · Page 60

Patterned functional carbon fibers from polyethylene

Patterned, continuous carbon fibers with controlled surface geometry were produced from a novel melt-processible carbon precursor. This portends the use of a unique technique to produce such technologically innovative fibers in large volume for important applications. The novelties of this technique include ease of designing and fabricating fibers with customized surface contour, the ability to manipulate filament diameter from submicron scale to a couple of orders of magnitude larger scale, and the amenable porosity gradient across the carbon wall by diffusion controlled functionalization of precursor. The geometry of fiber cross-section was tailored by using bicomponent melt-spinning with shaped dies and controlling the melt-processing of the precursor polymer. Circular, trilobal, gear-shaped hollow fibers, and solid star-shaped carbon fibers of 0.5 - 20 um diameters, either in self-assembled bundle form, or non-bonded loose filament form, were produced by carbonizing functionalized-polyethylene fibers. Prior to carbonization, melt-spun fibers were converted to a char-forming mass by optimizing the sulfonation on polyethylene macromolecules. The fibers exhibited distinctly ordered carbon morphologies at the outside skin compared to the inner surface or fiber core. Such order in carbon microstructure can be further tuned by altering processing parameters. Partially sulfonated polyethylene-derived hollow carbon fibers exhibit 2-10 fold surface area (50-500 m2/g) compared to the solid fibers (10-25 m2/g) with pore sizes closer to the inside diameter of the filaments larger than the sizes on the outer layer. These specially functionalized carbon fibers hold promise for extraordinary performance improvements when used, for example, as composite reinforcements, catalyst support media, membranes for gas separation, CO2 sorbents, and active electrodes and current collectors for energy storage applications.

36 MATERIALS SCIENCE↗

Primary transcripts: From the discovery of RNA processing to current concepts of gene expression ‐ Review

The main purpose of this review is to recall for investigators - and in particular students -, some of the early data and concepts in molecular genetics and biology that are rarely cited in the current literature and are thus invariably overlooked. There is a growing tendency among editors and reviewers to consider that only data produced in the last 10–20 years or so are pertinent. However this is not the case. In exact science, sound data and lucid interpretation never become obsolete, and even if forgotten, will resurface sooner or later. In the field of gene expression, covered in the present review, recent post-genomic data have indeed confirmed many of the earlier results and concepts developed in the mid-seventies, well before the start of the recombinant DNA revolution. Human brains and even the most powerful computers, have difficulty in handling and making sense of the overwhelming flow of data generated by recent high-throughput technologies. This was easier when low throughput, more integrative methods based on biochemistry and microscopy dominated biological research. Nowadays, the need for organising concepts is ever more important, otherwise the mass of available data can generate only {sup b}uilding ruins{sup }- the bricks without an architect. Concepts such as pervasive transcription of genomes, large genomic domains, full domain transcripts (FDTs) up to 100 kb long, the prevalence of post-transcriptional events in regulating eukaryotic gene expression, and the 3D-genome architecture, were all developed and discussed before 1990, and are only now coming back into vogue. Thus, to review the impact of earlier concepts on later developments in the field, I will confront former and current data and ideas, including a discussion of old and new methods. Whenever useful, I shall first briefly report post-genomic developments before addressing former results and interpretations. Equally important, some of the terms often used sloppily in scientific discussions will be clearly defined. As a basis for the ensuing discussion, some of the issues and facts related to eukaryotic gene expression will first be introduced. In chapter 2 the evolution in perception of biology over the last 60 years and the impact of the recombinant DNA revolution will be considered. Then, in chapter 3 data and theory concerning the genome, gene expression and genetics will be reviewed. The experimental and theoretical definition of the gene will be discussed before considering the 3 different types of genetic information - the {sup T}riad{sup }- and the importance of post-transcriptional regulation of gene expression in the light of the recent finding that 90% of genomic DNA seems to be transcribed. Some previous attempts to provide a conceptual framework for these observations will be recalled, in particular the {sup C}ascade Regulation Hypothesis{sup }(CRH) developed in 1967–85, and the {sup G}ene and Genon{sup }concept proposed in 2007. A knowledge of the size of primary transcripts is of prime importance, both for experimental and theoretical reasons, since these molecules represent the primary units of the {sup R}NA genome{sup }on which most of the post-transcriptional regulation of gene expression occurs. In chapter 4, I will first discuss some current post-genomic topics before summarising the discovery of the high Mr-RNA transcripts, and the investigation of their processing spanning the last 50 years. Since even today, a consensus concerning the real form of primary transcripts in eukaryotic cells has not yet been reached, I will refer to the viral and specialized cellular models which helped early on to understand the mechanisms of RNA processing and differential splicing which operate in cells and tissues. As a well-studied example of expression and regulation of a specific cellular gene in relation to differentiation and pathology, I will discuss the early and recent work on expression of the globin genes in nucleated avian erythroblasts. An important concept is that the primary transcript not only embodies protein-coding information and regulation of its expression, but also the 3D-structure of the genomic DNA from which it was derived. The wealth of recent post-genomic data published in this field emphasises the importance of a fundamental principle of genome organisation and expression that has been overlooked for years even though it was already discussed in the 1970–80ties. These issues are addressed in chapter 5 which focuses on the involvement of the nuclear matrix and nuclear architecture in DNA and RNA biology. This section will make reference to the Unified Matrix Hypothesis (UMH), which was the first molecular model of the 3D organisation of DNA and RNA. The chapter on the {sup R}NA-genome and peripheral memories{sup }discusses experimental data on the ribonucleoprotein complexes containing pre-mRNA (pre-mRNPs) and mRNA (mRNPs) which are organised in nuclear and cytoplasmic spaces respectively. Finally, {sup O}utlook {sup }will enumerate currently unresolved questions in the field, and will propose some ideas that may encourage further investigation, and comprehension of available experimental data still in need of interpretation. In chapter 8, some propositions and paradigms basic to the authors own analysis are discussed. {sup I}n conclusion{sup }the raison d'être of this review is recalled and positioned within the overall framework of scientific endeavour.

60 APPLIED LIFE SCIENCES↗

Analyzing Launch Operations using the Spaceport Throughput Analysis Resource (STAR)

NASA’s Kennedy Space Center (KSC) and Cape CanaveralSpace Force Station (CCSFS) are the world’s preeminent multi-user spaceport, providing facilities and launch capabilities to the agency, NASA’s commercial partners, and other government agencies. KSC works to ensure an environment in which NASA’s programs and other users can safely and effectively carry out their operations. Approximately 100 launches are expected to take place in 2024. KSC needs to meet the needs of customers who request launches based on their own schedules, but who may not be aware of KSC-wide resource limitations and external constraints on launch operations. KSC-wide resources include telecommunications, range tracking, commodities such as Helium and Nitrogen, and special equipment needed to support launches. External constraints include seasonal launch operations. Since space vehicles are complex and launch operations are uncertain, unexpected events can also cause delays in operations. The Spaceport Throughput AnalysisResource (STAR) assesses whether a specific set of pro-posed launches and associated activities can be performed given the resources KSC currently has available, and external constraints imposed on KSC operations. STAR integrates short-horizon scheduling and simulation of launches using a monte-carlo approach driven by configurable probabilities of different classes of event outcomes, including de-lays and worst-case use of resources. The resulting analyses inform stakeholders of key constraints preventing customers from being able to perform their missions as desired, and give insight into how to improve spaceport throughput. The rest of the paper is organized as follows. In 2 we de-scribe the problem STAR is intended to solve. In Section3 we formally describe the scheduling problem ingredients. In Section 4 we describe how manifests are simulated. InSection 5 we describe the constraints problem that is solved when rescheduling. In Section 6 we describe what information is recorded during manifest simulation in order to evaluate delays. In Section 7 we describe the specific problem solved for KSC. In Section 8 we describe the challenges of knowledge engineering for STAR.

Planning Scheduling Analysis↗

Program to Optimize Simulated Trajectories II (POST2) Surrogate Models for Mars Ascent Vehicle (MAV) Performance Assessment

The primary purpose of the multiPOST tool is to enable the execution of much larger sets of vehicle cases to allow for broader trade space exploration. However, this exploration is not achieved solely with the increased case throughput. The multiPOST tool is applied to carry out a Design of Experiments (DOE), which is a set of cases that have been structured to capture a maximum amount of information about the design space with minimal computational effort. The results of the DOE are then used to fit a surrogate model, ultimately enabling parametric design space exploration. The approach used for the MAV study includes both DOE and surrogate modeling. First, the primary design considerations for the vehicle were used to develop the variables and ranges for the multiPOST DOE. The final set of DOE variables were carefully selected in order to capture the desired vehicle trades and take into account any special considerations for surrogate modeling. Next, the DOE sets were executed through multiPOST. Following successful completion of the DOE cases, a manual verification trial was performed. The trial involved randomly selecting cases from the DOE set and running them by hand. The results from the human analyst's run and multiPOST were then compared to ensure that the automated runs were being executed properly. Completion of the verification trials was then followed by surrogate model fitting. After fits to the multiPOST data were successfully created, the surrogate models were used as a stand-in for POST2 to carry out the desired MAV trades. Using the surrogate models in lieu of POST2 allowed for visualization of vehicle sensitivities to the input variables as well as rapid evaluation of vehicle performance. Although the models introduce some error into the output of the trade study, they were very effective at identifying areas of interest within the trade space for further refinement by human analysts. The next section will cover all of the ground rules and assumptions associated with DOE setup and multiPOST execution. Section 3.1 gives the final DOE variables and ranges, while section 3.2 addresses the POST2 specific assumptions. The results of the verification trials are given in section 4. Section 5 gives the surrogate model fitting results, including the goodness-of-fit metrics for each fit. Finally, the MAV specific results are discussed in section 6.

Zwack, M. R.↗

A high temperature testing system for ceramic composites

Ceramic composites are presently being developed for high temperature use in heat engine and space power system applications. The operating temperature range is expected to be 1090 to 1650 C (2000 F to 3000 F). Very little material data is available at these temperatures and, therefore, it is desirable to thoroughly characterize the basic unidirectional fiber reinforced ceramic composite. This includes testing mainly for mechanical material properties at high temperatures. The proper conduct of such characterization tests requires the development of a tensile testing system includes unique gripping, heating, and strain measuring devices which require special considerations. The system also requires an optimized specimen shape. The purpose of this paper is to review various techniques for measuring displacements or strains, preferably at elevated temperatures. Due to current equipment limitations it is assumed that the specimen is to be tested at a temperature of 1430 C (2600F) in an oxidizing atmosphere. For the most part, previous high temperature material characterization tests, such as flexure and tensile tests, have been performed in inert atmospheres. Due to the harsh environment in which the ceramic specimen is to be tested, many conventional strain measuring techniques can not be applied. Initially a brief description of the more commonly used mechanical strain measuring techniques is given. Major advantages and disadvantages with their application to high temperature tensile testing of ceramic composites are discussed. Next, a general overview is given for various optical techniques. Advantages and disadvantages which are common to these techniques are noted. The optical methods for measuring strain or displacement are categorized into two sections. These include real-time techniques. Finally, an optical technique which offers optimum performance with the high temperature tensile testing of ceramic composites is recommended.

Hemann, John↗

MACHINING TEST SPECIMENS FROM HARVESTED ZION RPV SEGMENTS

The decommissioning of the Zion Nuclear Generating Station (NGS) in Zion, Illinois, presents a special and timely opportunity for developing a better understanding of materials degradation and other issues associated with extending the lifetime of existing nuclear power plants (NPPs) beyond 60 years of service. In support of extended service and current operations of the US nuclear reactor fleet, the Oak Ridge National Laboratory (ORNL), through the Department of Energy (DOE), Light Water Reactor Sustainability (LWRS) Program, is coordinating and contracting with Zion Solutions, LLC, a subsidiary of Energy Solutions, an international nuclear services company, the selective procurement of materials, structures, components, and other items of interest from the decommissioned reactors. In this paper, we will discuss the acquisition of segments of the Zion Unit 2 Reactor Pressure Vessel (RPV), cutting these segments into blocks from the beltline and upper vertical welds and plate material and machining those blocks into mechanical (Charpy, compact tension, and tensile) test specimens and coupons for microstructural (TEM, SEM, APT, SANS and nano indention) characterization. Access to service-irradiated RPV welds and plate sections will allow through wall attenuation studies to be performed, which will be used to assess current radiation damage models [1].

Reactor Pressure Vessel↗

A research program to measure the lifetime of spin polarized fuel

The use of spin polarized fuel could increase the deuterium-tritium (D-T) fusion cross section by a factor of 1.5 and, owing to alpha heating, increase the fusion power by an even larger factor. Issues associated with the use of polarized fuel in a reactor are identified. Theoretically, nuclei remain polarized in a hot fusion plasma. The similarity between the Lorentz force law and the Bloch equations suggests polarization can be preserved despite the rich electromagnetic spectrum present in a magnetic fusion device. The most important depolarization mechanisms can be tested in existing devices. The use of polarized deuterium and 3 He in an experiment avoids the complexities of handling tritium, while encompassing the same nuclear reaction spin-physics, making it a useful proxy to study issues associated with full D-T implementation. 3 He fuel with 65% polarization can be prepared by permeating optically-pumped 3 He into a shell pellet. Dynamically polarized 7 Li-D pellets can achieve 70% vector polarization for the deuterium. Cryogenically-frozen pellets can be injected into fusion facilities by special injectors that minimize depolarizing field gradients. Alternatively, polarized nuclei could be injected as a neutral beam. Once injected, the lifetime of the polarized fuel is monitored through measurements of escaping charged fusion products. Multiple experimental scenarios to measure the polarization lifetime in the DIII-D tokamak and other magnetic-confinement facilities are discussed, followed by outstanding issues that warrant further study.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Intense Photoneutron Sources For Nuclear Material Detection

Intense neutron sources are essential for cargo inspection for a broad range of threats from explosives, to contraband, to nuclear materials and especially SNM (Special Nuclear Materials). To be effective over a wide range of cargo materials, in particular for hydrogenous cargo such as food, and to offer practical inspection times, the neutron source must be very strong, typically >10{sup 10} neutrons per second. Unfortunately there are currently no reasonably compact and economical neutron generators with the required intensities. The insufficiency and inadequacy of intense neutron sources are especially conspicuous in the {<=}2.5 MeV range (low voltage (d,D) generator). This energy range is needed if the strong signature of prompt fission neutrons ({approx_equal}3 per fission) is to be detected and discerned from the numerous source neutrons. The photonuclear reactions of x-rays from commercial linacs in appropriate converters can provide ample intensities of neutrons. These converters have a very low ({gamma},n) energy threshold: 1.67 MeV for beryllium and 2.23 MeV for deuterium. The intense x-ray beams provided by commercial x-ray systems, more than compensate for the relatively low ({gamma},n) cross-sections which are in the milli-barn range. The choice of converter material, the geometrical shape, dimensions and location relative to the x-ray source, determine the efficiency of the neutron conversion. For electron accelerators with less than 10 MeV, the preferred converters, Be and D{sub 2}O, are also very good neutron moderators. Thus, while increasing the converters' thickness leads to an increase in the overall neutron yield, this causes the softening of the neutron spectrum, which reduces the neutron penetration especially in hydrogenous cargos. Photoneutron sources can be optimized to meet specific needs such as maximum fission signals in various cargo materials of interest. Efficient photoneutron sources with different energy spectra were investigated. Conversion efficiency of more than 10-4 neutron per 9 MeV electron yielding neutron intensities of more than 10{sup 11} n/s for commercial 100 {mu}Amp electron accelerators has been modeled and designed. The simulation was validated in laboratory experiments using small Be and D{sub 2}O converters.

43 PARTICLE ACCELERATORS↗

SILICON CARBIDE GRAINS OF TYPE C PROVIDE EVIDENCE FOR THE PRODUCTION OF THE UNSTABLE ISOTOPE {sup 32}Si IN SUPERNOVAE

Carbon-rich grains are observed to condense in the ejecta of recent core-collapse supernovae (SNe) within a year after the explosion. Silicon carbide grains of type X are C-rich grains with isotopic signatures of explosive SN nucleosynthesis have been found in primitive meteorites. Much rarer silicon carbide grains of type C are a special sub-group of SiC grains from SNe. They show peculiar abundance signatures for Si and S, isotopically heavy Si, and isotopically light S, which appear to be in disagreement with model predictions. We propose that C grains are formed mostly from C-rich stellar material exposed to lower SN shock temperatures than the more common type X grains. In this scenario, extreme {sup 32}S enrichments observed in C grains may be explained by the presence of short-lived {sup 32}Si ({tau}{sub 1/2} = 153 yr) in the ejecta, produced by neutron capture processes starting from the stable Si isotopes. No mixing from deeper Si-rich material and/or fractionation of Si from S due to molecular chemistry is needed to explain the {sup 32}S enrichments. The abundance of {sup 32}Si in the grains can provide constraints on the neutron density reached during the SN explosion in the C-rich He shell material. The impact of the large uncertainty of the neutron capture cross sections in the {sup 32}Si region is discussed.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

GRO/EGRET data analysis software: An integrated system of custom and commercial software using standard interfaces

The Energetic Gamma Ray Telescope Experiment (EGRET) on the Compton Gamma Ray Observatory has been in orbit for more than a year and is being used to map the full sky for gamma rays in a wide energy range from 30 to 20,000 MeV. Already these measurements have resulted in a wide range of exciting new information on quasars, pulsars, galactic sources, and diffuse gamma ray emission. The central part of the analysis is done with sky maps that typically cover an 80 x 80 degree section of the sky for an exposure time of several days. Specific software developed for this program generates the counts, exposure, and intensity maps. The analysis is done on a network of UNIX based workstations and takes full advantage of a custom-built user interface called X-dialog. The maps that are generated are stored in the FITS format for a collection of energies. These, along with similar diffuse emission background maps generated from a model calculation, serve as input to a maximum likelihood program that produces maps of likelihood with optional contours that are used to evaluate regions for sources. Likelihood also evaluates the background corrected intensity at each location for each energy interval from which spectra can be generated. Being in a standard FITS format permits all of the maps to be easily accessed by the full complement of tools available in several commercial astronomical analysis systems. In the EGRET case, IDL is used to produce graphics plots in two and three dimensions and to quickly implement any special evaluation that might be desired. Other custom-built software, such as the spectral and pulsar analyses, take advantage of the XView toolkit for display and Postscript output for the color hard copy. This poster paper outlines the data flow and provides examples of the user interfaces and output products. It stresses the advantages that are derived from the integration of the specific instrument-unique software and powerful commercial tools for graphics and statistical evaluation. This approach has several proven advantages including flexibility, a minimum of development effort, ease of use, and portability.

Laubenthal, N. A.↗

Neutrino-Argon Interaction with GENIE Event Generator

Neutrinos are very special particles, have only weak interactions, except gravity, and are produced in very different processes in Nuclear and Particle Physics. Neutrinos are, also, messengers from astrophysical objects, as well as relics from Early Universe. Therefore, its can give us information on processes happening in the Universe, during its evolution, which cannot be studied otherwise. The underground instrumentation including a variety of large and very large detectors, thanks to technical breakthroughs, have achieved new fundamental results like the solution of the solar neutrino puzzle and the evidence for Physics beyond the Standard Model of elementary interactions in the neutrino sector with non-vanishing neutrino masses and lepton flavour violation.Two of the LAGUNA(Large Apparatus studying Grand Unification and Neutrino Astrophysics) detectors, namely: GLACIER (Giant Liquid Argon Charge Imaging ExpeRiment) and LENA (Low Energy Neutrino Astrophysics) could be emplaced in 'Unirea' salt mine from Slanic-Prahova, Romania. A detailed analysis of the conditions and advantages is necessary. A few results have been presented previously. In the present work, we propose to generate events and compute the cross sections for interactions between neutrino and Argon-40, to estimate possible detection performances and event types. For doing this, we use the code GENIE(G lowbar enerates E lowbar vents for N lowbar eutrino I lowbar nteraction E lowbar xperiments). GENIE Code is an Object-Oriented Neutrino MC Generator supported and developed by an international collaboration of neutrino interaction experts.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Comments on galactic evolution and nucleocosmochronology

Long-lived nucleochronologies are calculated for several recently proposed models of the chemical evolution of the Galaxy. Special attention is paid to the Re-187/Os-187 chronometer, for which important data have recently become available. It is found that although the rate of star formation does vary with time in the different models, the quantity that is related to the effective net rate of nucleosynthesis is constant for most of the physically plausible recent-evolution models examined. This constant net rate implies that for these models, the age of the Galaxy at the time the solar system formed is twice the mean age of the stable elements. This mean age can be estimated by the parameter 'delta max', in which case the age of the Galaxy is twice this parameter plus the age of the solar system. The present uncertainties in 'delta max' yield an age for the Galaxy of 7 to 20 billion years. However, this range could be significantly reduced by an accurate measurement of the half-life of Re-187 and more knowledge on the effect of stellar temperatures on the Os-186/Os-187 neutron-capture cross-section ratio. In fact, experiments which could be carried out in the next few years can reduce these uncertainties tremendously and enable an age determination to be made which might severely restrict cosmological models.

Hainebach, K. L.↗

Ground Test Stand Development for One-step Electrochemical Production of High-Pressure Oxygen

NASA designed a test rig, High-Pressure Oxygen Generation Assembly (HPOGA) to test a novel method of electrolysis as an alternative technology to the state-of-the-art Oxygen Generation Assembly (OGA) currently on the International Space Station (ISS). This approach involves utilizing a specialized electrolysis cell stack designed to both generate and compress high-pressure oxygen up to 3600 PSIG. The design eliminates the need for an external compressor and hydrogen separator, streamlining the oxygen generation process. HPOGA tests the viability of an electrolysis cell stack for extended life usage. Within the system, there are several key subsystems: nitrogen, high/low pressure oxygen, hydrogen, water recirculation, and water injection. The water injection subsystem supplies deionized (DI) water to a centralized reservoir for consumption. Subsequently, a water recirculation loop transfers the DI water across the cathode side of the electrolysis cell stack with constant flow rate. The result is a supply of hydrogen in the water loop and oxygen accumulation on the anode side of the cell stack. Hydrogen is evaporated out as part of the hydrogen sub-system which also measures hydrogen/oxygen concentration for safety. The oxygen subsystem is responsible for managing high pressure oxygen, O2 exhaust, and conducting hydrogen/oxygen concentration measurements. The nitrogen subsystem serves dual functions, purging the hydrogen/oxygen subsystems, and regulating pressure in both high/low-pressure O2 sections via pneumatic back pressure regulators. Various sensors monitor pressure, temperature, humidity, gas concentration and flow rate in each subsystem. This paper presents the design and testing of a comprehensive test stand, which serves to operate and functionally verify the performance of the electrolysis cell while offering valuable lessons learned.

electrolysis↗

'Micromanaging de Sitter holography'

We develop tools to engineer de Sitter vacua with semi-holographic duals, using elliptic fibrations and orientifolds to uplift Freund-Rubin compactifications with CFT duals. The dual brane construction is compact and constitutes a microscopic realization of the dS/dS correspondence, realizing d-dimensional de Sitter space as a warped compactification down to (d-1)-dimensional de Sitter gravity coupled to a pair of large-N matter sectors. This provides a parametric microscopic interpretation of the Gibbons-Hawking entropy. We illustrate these ideas with an explicit class of examples in three dimensions, and describe ongoing work on four-dimensional constructions. The Gibbons-Hawking entropy of the de Sitter horizon [1] invites a microscopic interpretation and a holographic formulation of inflating spacetimes. Much progress was made in the analogous problem in black hole physics using special black holes in string theory whose microstates could be reliably counted, such as those analyzed in [2,3]; this led to the AdS/CFT correspondence [4]. In contrast, a microscopic understanding of the entropy of de Sitter space is more difficult for several reasons including its potential dynamical connections to other backgrounds (metastability), the absence of a non-fluctuating timelike boundary, and the absence of supersymmetry. In this paper, we develop a class of de Sitter constructions in string theory, built up from AdS/CFT dual pairs along the lines of [5], which are simple enough to provide a microscopic accounting of the parametric scaling of the Gibbons-Hawking entropy. These models realize microscopically a semi-holographic description of metastable de Sitter space which had been derived macroscopically in [6]. It would also be interesting to connect this to other approaches to de Sitter holography such as [7, 8] and to other manifestations of the de Sitter entropy such as [9]. The construction is somewhat analogous to neutral black branes analyzed in [11]. We will begin in section 2 by explaining the salient features of the holographic duality and of the de Sitter construction which realizes it microscopically. In section 3 we will lay out our methods in more detail, applying them to worked examples of dS{sub 3} in section 4. Finally, section 5 discusses further directions and ongoing work, including dS{sub 4} constructions in progress.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Anthropogenic Markers in Alta Irrigation District Water Supply Wells

In July 2016, LLNL produced a report for the Kings River Watershed Coalition Authority (KRWCA) entitled “Groundwater Age and Nitrate Isotopic Composition in Alta Irrigation District Water Supply Wells” (Esser et al., 2016). That report summarized groundwater age and nitrate isotopic composition data produced by LLNL for Alta Irrigation District (AID) groundwater wells sampled by KRWCA in a pilot project to test the utility of advanced isotopic methods for constraining the timing and source of nitrate in groundwater at selected sites in the Kings River service area. One section of that report made recommendations for follow-on study. The first and strongest recommendation was to measure a wider suite of source tracers including co-contaminants such as herbicides, pesticides, pharmaceuticals, personal care products, and food constituents and additives. KRWCA followed up on this recommendation in Phase II of the pilot study by re-sampling the original set of wells and submitting the samples to a commercial laboratory for analysis of a limited range of co-contaminants (including pharmaceuticals, personal care products , and food constituents and additives, but not including herbicides or pesticides). They have asked that LLNL review and interpret these data in the context of previous LLNL analyses and to evaluate the utility of such co-contaminant analyses in providing additional constraints on the source of groundwater nitrate contamination in Alta Irrigation District water supply wells. The goal of the second phase of this pilot project is to evaluate the utility of co-contaminant occurrence for constraining nitrate source in groundwater at selected sites in the Kings River service area, with special reference to the use of such data in conjunction with advanced isotopic methods such as nitrate isotopic composition and groundwater age. Nitrate isotopic composition alone cannot distinguish nitrate derived from animal manure from nitrate derived from human septic waste. The presence or absence of agricultural chemicals (herbicides, pesticides, veterinary pharmaceuticals) or chemicals associated with people (human pharmaceuticals, artificial sweeteners) can help make this distinction. Co-contaminant analyses using multi-analyte LC-MS-MS protocols are now commercially available and reasonably priced. The feasibility and utility of the using co-contaminants for nitrate source attribution can be evaluated by 1) determining the degree to which co-contaminants occur in distinct and easily attributable groupings (e.g. agricultural chemicals vs personal care products and food additives); 2) determining the degree to which co-contaminant occurrence is consistent with nitrate isotopic composition and groundwater age (e.g. no co-contaminant occurrence in very old groundwater; co-contaminants consistent with animal manure or human septic waste occurring in groundwaters having nitrate isotopic composition also consistent with animal manure or human septic waste); and 3) determining the degree to which co-contaminants provide additional constraint on nitrate source over and beyond nitrate isotopic composition and groundwater age (e.g. distinguishing between animal manure and human septic waste).

58 GEOSCIENCES↗

Bumper Implementation of LMEEM

The Hypervelocity Impact Technology (HVIT) group at the NASA Johnson Space Center (JSC) maintains the Bumper 3 computer program (referred to as “Bumper”) to perform Micrometeoroid and Orbital Debris (MMOD) risk assessments for spacecraft. To perform its calculations, this program requires detailed mathematical models of the space environments and can include those models representing orbital debris, micrometeoroids, and lunar ejecta. The lunar ejecta environment is a projectile environment specific to the lunar surface. Due to the Moon’s lack of an atmosphere, meteoroids frequently strike the lunar surface. When this happens, the impact ejects material radially away from the impact point, which can pose a potential impact hazard to surface-based hardware. This lunar ejecta environment was previously described in 1969, in NASA Special Publication SP-8013, which was used as the basis for a model that will be referred to in this document as the “SP-8013 environment model,” or simply, “SP-8013.” Since around 2020, this model has been used in MMOD risk assessments for the Human Landing System (HLS) program and other lunar surface programs. A new lunar meteoroid ejecta environment was developed via a computer code named Lunar Meteoroid Ejecta Engineering Model (LMEEM), produced by the Natural Environments Branch (NEB) at Marshall Space Flight Center (MSFC). A global lunar surface environment definition using LMEEM is to be provided in the Cross-Program Design Specification for Natural Environments (DSNE) Revision J in 2024. Contact the NASA MSFC Natural Environments Branch for an in-depth discussion of the LMEEM environment model and its derivation. This environment model will supersede SP-8013 for MMOD risk assessments. To perform such assessments, Bumper must read data from text files output by LMEEM and use that data in risk calculations. The purpose of this document is to: •Demonstrate verification that the Bumper code has properly implemented the LMEEM environment model (Section 3) •Discuss the LMEEM environment as understood through an initial environment file (Section 4) •Compare the calculated risk due to the SP-8013 and LMEEM models (Section 5)

Bumper↗

Surface conversion techniques for low energy neutral atom imagers

This investigation has focused on development of key technology elements for low energy neutral atom imaging. More specifically, we have investigated the conversion of low energy neutral atoms to negatively charged ions upon reflection from specially prepared surfaces. This 'surface conversion' technique appears to offer a unique capability of detecting, and thus imaging, neutral atoms at energies of 0.01 - 1 keV with high enough efficiencies to make practical its application to low energy neutral atom imaging in space. Such imaging offers the opportunity to obtain the first instantaneous global maps of macroscopic plasma features and their temporal variation. Through previous in situ plasma measurements, we have a statistical picture of large scale morphology and local measurements of dynamic processes. However, with in situ techniques it is impossible to characterize or understand many of the global plasma transport and energization processes. A series of global plasma images would greatly advance our understanding of these processes and would provide the context for interpreting previous and future in situ measurements. Fast neutral atoms, created from ions that are neutralized in collisions with exospheric neutrals, offer the means for remotely imaging plasma populations. Energy and mass analysis of these neutrals provides critical information about the source plasma distribution. The flux of neutral atoms available for imaging depends upon a convolution of the ambient plasma distribution with the charge exchange cross section for the background neutral population. Some of the highest signals are at relatively low energies (well below 1 keV). This energy range also includes some of the most important plasma populations to be imaged, for example the base of the cleft ion fountain.

Quinn, J. M.↗

Understanding hadronic interactions using advanced reconstruction techniques

ProtoDUNE-SP served as the prototype of the future Deep Underground Neutrino Experiment (DUNE). With a total liquid argon mass of 0.77 kt, it stood as the most extensive monolithic single-phase Liquid Argon Time Projection Chamber (LArTPC) ever constructed. Strategically located and operated at CERN, ProtoDUNE-SP benefited from a specialized charged-particle test beam, offering a momentum range of 0.3 - 7 GeV/c. This setup provided a unique opportunity to conduct in-depth studies on hadronic interactions within argon. Hadronic interactions play a fundamental role in neutrino physics, particularly in the intricacies of neutrino detection. We depend on analyzing the outcomes of these interactions to accurately determine both the flavor and energy of the interacting neutrinos. Pions, as one of the primary byproducts of neutrino interactions, are crucial for understanding the overall dynamics and kinematics of these processes. Accurately characterizing and understanding the interaction of pions with argon can significantly enhance the precision of neutrino simulations and measurements.Being a Liquid Argon Time Projection Chamber (LArTPC), ProtoDUNE-SP is distinguished by its ability to produce high-definition images of charged particles as they traverse through the detector's active volume. Yet, accurately reconstructing these particle interactions and determining their kinematic attributes remains a challenging task. The successes of deep learning in diverse domains, especially in image recognition, provide a promising approach for addressing this challenge in ProtoDUNE. This thesis discusses a measurement of the Piplus - argon inelastic cross section in the energy range of 2400 to 3000 MeV, using data taken by protoDUNE during the fall of 2018. Additionally, panoptic segmentation, a machine learning technique, is introduced and validated through its application in the reconstruction of the neutral pion rest mass. The aim is to showcase how these advanced methods can enhance the quality of event reconstruction.

Sarasty Segura, Carlos Eduardo↗