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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Space Satellite Dynamics with Applications to Sunlight Pressure Attitude Control

A research program into three aspects of space satellite dynamics was carried out. First, a four-dimensional space-time formulation of Newtonian mechanics is developed. This theory allows a new physical interpretation of the conservation theorems of mechanics first derived rigorously by Noether. Second, a new concept for estimating the three angles which specify the orientation in space of a rigid body is presented. Two separate methods for implementing this concept are discussed, one based on direction cosines, the other on quaternions. Two examples are discussed: constant orientation in space, and constant rate of change of the three angles with time. Third, two synchronous equatorial orbit communication satellite designs which use sunlight pressure to control their attitude are analyzed. Each design is equipped with large reflecting surfaces, called solar sails, which can be canted in different directions to generate torques to correct pointing errors.

Stuck, B. W.↗
NASA NTRS1975

Micrometeorites and solar flare particles in and out of the ecliptic

Using crystals grown into vugs from oriented lunar rocks as directional detectors of cosmic dust particles and solar flare nuclei, I have measured the angular distribution of the flux of micrometeoroids of mass 30 attograms to 80 femtograms. Hypervelocity impact craters of diameter 500 A to 10 microns and tracks from solar flare nuclei of energy 100 keV/amu to 20 MeV/amu were observed in crystals from rock 71055 facing lunar south and in crystals from rock 74255 facing lunar east. I have found that dust grains both in ecliptic orbits and in orbits inclined to the ecliptic have virtually identical mass-frequency distributions and similar shapes. I have evaluated the micrometeoroid fluxes after determining the exposure ages of the individual vug crystals by measuring the solar flare track density gradients in each crystal. The flux of particles of mass greater than 4 femtograms confined to the ecliptic is in good agreement with satellite measurements, suggesting that the micrometeoroid flux has been relatively constant over the past 35,000 yr. The flux of particles producing microcraters on a lunar surface facing south is lower than the ecliptic flux by a factor of about 7.

Hutcheon, I. D.↗
NASA NTRS1979

Chemical-vapor deposition of silicon from silane

Report lists tables of standard free-energy change, equilibrium constant, and heat of reaction for chemical vapor deposition (CVD) of silicon from silane over temperature range of 100 to 1000 K. Data indicates silicon CVD may be a commercially economical process for production of silicon for solar arrays and other applications.

Hsu, G. C.↗
NASA NTRS1978

The soft X-ray spectrum of Capella - Discovery of intense line emission

A soft X-ray spectrum of Capella has been obtained with the HEAO 1 satellite. Only models which include intense line emission at 0.85 keV can adequately explain the data. The spectrum is consistent with emission from an isothermal solar-abundance plasma with a temperature of 10.5 million (+ or - 2.8 million) K. It is also consistent with a blend of temperatures between 4 and 20 million K. The intensity of the X-ray emission is constant over 2 days and similar to the intensity observed by ANS.

Cash, W.↗
NASA NTRS1986

The velocity dispersion of the giant molecule clouds: A viscous origin

The observations of interstellar cloud motion show that the cloud velocity dispersion is nearly constant, to within a factor of 2, for clouds covering at least three orders of magnitude in mass. For example, the Giant Molecular Cloud (GMC) with typical masses of approx 5 x 10 to the 5th power solar masses have a one-dimensional planar, cloud-cloud, random velocity dispersion of approx 3-7 km/s. The HI clouds, of approx. 400 solar masses each, on the other hand, have a typical one-dimensional velocity dispersion of approx 6 km/s. Clearly, the clouds are not in kinetic energy equipartion. The GMC spatial distribution in the galactic disk is not that of an isolated, 3-D system; rather, the GMCs exhibit a very thin disk (approx nearly a monolayer) distribution; with the ratio of the diameter of a typical GMC to the vertical scale-height of the GMC distribution being approx 50 pc/150 pc = 0.3. The supernova shocks, which can accelerate the low mass clouds, are extremely ineffective in accelerating the GMCs because of the much larger mass/area ratio for the GMCs. The above points suggest that the GMCs do not constitute an isolated, 3-D system - rather, they indicate that the dynamics of the GMCs is mainly determined by the fact that they are located in a differentially rotating galactic disk, and that, as for particles in planetary rings, viscosity is the primary energy input. Specifically, it is proposed that gravitational scattering of the massive clouds off each other in the differentially rotating galactic disk constitutes an effective gravitational viscosity, which causes an increase in the random kinetic energy of the GMCs at the expense of their ordered, rotational kinetic energy.

Jog, C. J.↗
NASA NTRS1990

Spatial distribution of H2O(+) in Comet P/Halley

Comet Halley spectroscopic and imaging data near the time of the Vega 1 encounter in March 1986 have been analyzed for H2O(+) distribution and near-nucleus ion physics, using a data-reduction procedure encompassing flat fielding, sky removal, continuum subtraction, contamination correction, absolute flux calibration, and conversion to ion-column densities. A 25,000 km-radius collision zone within which collisions dominate the solar wind's sweeping effect is verified. A production rate of H2O(+) ions is calculated on the basis of the average velocity and column density integral across the tail. An analysis of the tailward ion flow indicates constant acceleration beyond 130,000 km from the nucleus.

Disanti, Michael A.↗
NASA NTRS1991

Pitch angle scattering of cometary ions into monospherical and bispherical distributions

Low frequency magnetic fluctuations generated by solar wind/cometary ion distributions cause pitch-angle scattering of cometary ions. The nature of this pitch angle scattering is examined by means of one-dimensional hybrid simulations, in which newborn ions are created at a constant rate, and for various injection angles, alpha, relative to the magnetic field. Pitch angle scattering in the quasi-perpendicular regime (alpha above 60 deg) results in a bispherical velocity distribution while in the quasi-parallel regime (alpha between 0 and 60 deg), pitch angle scattering can result in either a monospherical or bispherical distribution, depending on the injection angle and initial beam velocity.

Miller, Ronald H.↗
NASA NTRS1995

Formation Of the Giant Planets By Concurrent Accretion Of Solids And Gas

New numerical simulations of the formation of the giant planets are presented, in which for the first time both the gas and planetesimal accretion rates are calculated in a self-consistent, interactive fashion. The simulations combine three elements: 1) three-body accretion cross-sections of solids onto an isolated planetary embryo, 2) a stellar evolution code for the planet's gaseous envelope, and 3) a planetesimal dissolution code within the envelope, used to evaluate the planet's effective capture radius and the energy deposition profile of accreted material. Major assumptions include: The planet is embedded in a disk of gas and small planetesimals with locally uniform initial surface mass density, and planetesimals are not allowed to migrate into or out of the planet's feeding zone. All simulations are characterized by three major phases. During the first phase, the planet's mass consists primarily of solid material. The planetesimal accretion rate, which dominates that of gas, rapidly increases owing to runaway accretion, then decreases as the planet's feeding zone is depleted. During the second phase, both solid and gas accretion rates are small and nearly independent of time. The third phase, marked by runaway gas accretion, starts when the solid and gas masses are about equal. It is engendered by a strong positive feedback on the gas accretion rates, driven by the rapid contraction of the gaseous envelope and the rapid expansion of the outer boundary, which depends on the planet's total mass. The overall evolutionary time scale is generally determined by the length of the second phase. The actual rates at which the giant planets accreted small planetesimals is probably intermediate between the constant rates assumed in most previous studies and the highly variable rates that we have used. Within the context, of the adopted model of planetesimal accretion, the joint constraints of the time scale for dissipation of the solar nebula and the current high-Z masses of the giant planets lead to estimates of the initial surface density (sigma(sub init)) of planetesimals in the outer region of the solar nebula. The results show sigma(sub init) approx. = 10 g/sq cm near Jupiter's orbit and that sigma(sub init) proportional to alpha(sup -2), where alpha is the distance from the Sun. These values are a factor of 3 - 4 times as high as that of the "minimum mass" solar nebula at Jupiter's distance and a factor of 2 - 3 times as high it Saturn's distance. Our estimates for the formation time of Jupiter and Saturn are 1 - 10 million years while those for Uranus fall in the range of 2 - 16 million years. These estimates follow from the properties of our Solar System and do not necessarily apply to giant planets in other planetary systems.

Pollack, James B.↗
NASA NTRS2003

Two Components in Major Solar Particle Events

A study has been made of 29 intense, solar particle events observed in the energy range 25-100 MeV/nuc near Earth in the years 1997 through 2001. It is found that the majority of the events (19/29) had Fe to O ratios which were reasonably constant with time and energy, and with values above coronal. These all originated on the Sun s western hemisphere and most had intensities that rose rapidly at the time of an associated flare, and coronal mass ejection (CME), and then decayed more gradually. Few interplanetary shocks were observed during these increases. The spectra were mainly power laws. The remaining 10 events had different intensity-time profiles and Fe to O ratios that varied with time and energy with values at or below coronal. Most of these originated near central meridian and 6 had strong interplanetary shocks that were observed near Earth. In general the spectra were not power laws but steepened at high energies, particularly for Fe. There were four events with two peaks in the intensity-time profiles, the first near the time of the associated flare and the other at shock passage. The results, considered in the light of other recent work, suggest that the high energy particles that occur shortly after flares are indeed flare particles. At the highest rigidities considered here shock-accelerated particles are uncommon and are observed only in association with unusually fast shocks.

White, Nicholas E.↗
NASA NTRS2002

Lunar lava tube radiation safety analysis

For many years it has been suggested that lava tubes on the Moon could provide an ideal location for a manned lunar base, by providing shelter from various natural hazards, such as cosmic radiation, meteorites, micrometeoroids, and impact crater ejecta, and also providing a natural environmental control, with a nearly constant temperature, unlike that of the lunar surface showing extreme variation in its diurnal cycle. An analysis of radiation safety issues on lunar lava tubes has been performed by considering radiation from galactic cosmic rays (GCR) and Solar Particle Events (SPE) interacting with the lunar surface, modeled as a regolith layer and rock. The chemical composition has been chosen as typical of the lunar regions where the largest number of lava tube candidates are found. Particles have been transported all through the regolith and the rock, and received particles flux and doses have been calculated. The radiation safety of lunar lava tubes environments has been demonstrated.

Non-programmatic↗
NASA NTRS2018

A Hybrid Electrostatic Retarding Potential Analyzer for the Measurement of Plasmas at Extremely High Energy Resolution

Many space plasmas (especially electrons generated in planetary ionospheres) exhibit fine-detailed structures that are challenging to fully resolve with the energy resolution of typical space plasma analyzers (10% → 20%). While analyzers with higher resolution have flown, generally this comes at the expense of sensitivity and temporal resolution. We present a new technique for measuring plasmas with extremely high energy resolution through the combination of a top-hat Electrostatic Analyzer (ESA) followed by an internally mounted Retarding Potential Analyzer (RPA). When high resolutions are not required, the RPA is grounded, and the instrument may operate as a typical general-purpose plasma analyzer using its ESA alone. We also describe how such an instrument may use its RPA to remotely vary the geometric factor (sensitivity) of a top hat analyzer, as was performed on the New Horizons Solar Wind at Pluto and MAVEN SupraThermal and Thermal Ion Composition instruments. Finally, we present results from laboratory testing of our prototype, showing that this technique may be used to construct an instrument with 1.6% energy resolution, constant over all energies and angles.

Collinson, Glyn A.↗
NASA NTRSDate not supplied

OVIRS Visible to Near-IR Spectral Results at (101955) Bennu

The OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS) operates over a wavelength range of ~0.4 to 4.3 μm with a 4-mrad field of view.During the OSIRIS-REx mission, OVIRS collected more than 500,000 spectra of Bennu for spectral characterization of the surface. Constant phase angle observations were dedicated to global mapping at ~20 m resolution. Data with higher resolution (2–4 m) were obtained of the candidate sample sites. We analyzed low-phase-angle (12:30 pm local solar time) global data for surface color trends, surface temperatures, and the band depths of absorption features associated with hydrated minerals, carbon-bearing materials, iron oxides, and pyroxenes.

A.A. Simon↗
DOE OSTI2021

Solvent and Temperature Effects on Photoinduced Proton-Coupled Electron Transfer in the Marcus Inverted Region

Concerted proton-coupled electron transfer (PCET) in the Marcus inverted region was recently demonstrated. Understanding the requirements for such reactivity is fundamentally important and holds promise as a design principle for solar energy conversion systems. Herein, we investigate the solvent polarity and temperature dependence of photoinduced proton-coupled charge separation (CS) and charge recombination (CR) in anthracene–phenol–pyridine triads: 1 (10-(4-hydroxy-3-(4-methylpyridin-2-yl)benzyl)anthracene-9-carbonitrile) and 2 (10-(4-hydroxy-3-(4-methoxypyridin-2-yl)benzyl)anthracene-9-carbonitrile). Both the CS and CR rate constants increased with increasing polarity in acetonitrile:n-butyronitrile mixtures. The kinetics were semi-quantitatively analyzed where changes in dielectric and refractive index, and thus consequently changes in driving force (–ΔG°) and reorganization energy (λ), were accounted for. The results were further validated by fitting the temperature dependence, from 180 to 298 K, in n-butyronitrile. The analyses support previous computational work where transitions to proton vibrational excited states dominate the CR reaction with a distinct activation free energy (ΔG* CR ~ 140 meV). However, the solvent continuum model fails to accurately describe the changes in ΔG° and λ with temperature via changes in dielectric constant and refractive index. Satisfactory modeling was obtained using the results of a molecular solvent model, which predicts that λ decreases with temperature, opposite to that of the continuum model. To further assess the solvent polarity control in the inverted region, the reactions were studied in toluene. Nonpolar solvents decrease both ΔG° CR and λ, slowing CR into the nanosecond time regime for 2 in toluene at 298 K. This demonstrates how PCET in the inverted region may be controlled to potentially use proton-coupled CS states for efficient solar fuel production and photoredox catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1989

Expansion of solar-terrestrial low-beta plasmoid

A magnetized plasma system confined inside a finite volume may expand (or contract) when its surrounding pressure changes. In this paper, two possible expanding processes of a low-beta plasmoid are discussed: (1) linear expansion and (2) expansion with fixed footpoints of field lines. The constant-zeta expansion, discussed in this paper, may maintain a low-beta plasmoid in a nearly force-free state during the expanding process. This simple model is applied to the magnetic clouds observed in the interplanetary space. The estimated scale size and expanding speed of the magnetic cloud are found to be in reasonable agreement with the observation. The energy conversion process is investigated: the free 'magnetic potential energy' stored in a magnetized system, which is pressed by external pressure, may be released to accelerate the plasma. The concept of a 'magnetic burst' is briefly discussed.

Yang, Wei-Hong↗
NASA NTRS1990

Improved boundary layer heat transfer calculations near a stagnation point

A thermal design of a solar receiver has been developed for the solutions of problems involving phase-change thermal energy storage and natural convection loss. Two dimensional axisymmetrical solidification and melting of materials contained between two concentric cylinders of finite length has been studied for thermal energy storage analysis. For calculation of free convection loss inside receiver cavity, two dimensional axisymmetrical, laminar, transient free convection including radiation effects has been studied using integral/finite difference method. Finite difference equations are derived for the above analysis subject to constant or variable material properties, initial conditions, and boundary conditions. The validity of the analyses has been substantiated by comparing results of the present general method with available analytic solutions or numerical results reported in the literature. Both explicit and implicit schemes are tested in phase change analysis with different number of nodes ranging from 4 to 18. The above numerical methods have been applied to the existing solar receiver analyzing computer code as additional subroutines. The results were computed for one of the proposed Brayton cycle solar receiver models running under the actual environmental conditions. Effect of thermal energy storage on the thermal behavior of the receiver has been estimated. Due to the thermal energy storage, about 65% reduction on working gas outlet temperature fluctuation has been obtained; however, maximum temperature of thermal energy storage containment has been increased about 18%. Also, effect of natural convection inside a receiver cavity on the receiver heat transfer has been analyzed. The finding indicated that thermal stratification occurs during the sun time resulting in higher receiver temperatures at the outlet section of the gas tube, and lower temperatures at the inlet section of the gas tube when compared with the results with no natural convection. Due to heat supply from the air during the shade time, minimum temperature has been increased, while maximum temperature has been reduced due to convection loss to air. Consequently, cyclic temperature fluctuation has been reduced 29% for working gas and 16% for thermal energy storage containment. On the other hand, despite the presence of the natural convection the time-averaged temperatures for receiver components were found to be similar for two cases with/without natural convection (maximum difference was 1.8%).

Ahn, Kyung Hwan↗
DOE OSTI2024

Homomolecular Triplet–Triplet Annihilation in Metalloporphyrin Photosensitizers

Metalloporphyrins are ubiquitous in their applications as triplet photosensitizers, particularly for promoting sensitized photochemical upconversion processes. In this study, bimolecular excited state triplet–triplet quenching kinetics, termed homomolecular triplet–triplet annihilation (HTTA), exhibited by the traditional triplet photosensitizers–zinc(II) tetraphenylporphyrin (ZnTPP), palladium(II) octaethylporphyrin (PdOEP), platinum(II) octaethylporphyrin (PtOEP), and platinum(II) tetraphenyltetrabenzoporphyrin (PtTPBP)–were revealed using conventional transient absorption spectroscopy. Nickel(II) tetraphenylporphyrin was used as a control sample as it is known to be rapidly quenched intramolecularly through ligand-field state deactivation and, therefore, cannot result in triplet–triplet annihilation (TTA). The single wavelength transients associated with the metalloporphyrin triplet excited state decay–measured as a function of incident laser pulse energy in toluene–were well modeled using parallel first- and second-order kinetics, consistent with HTTA being operable. The combined transient kinetic data enabled the determination of the first-order rate constants (k T ) for excited triplet decay in ZnTPP (4.0 × 10 3 s –1 ), PdOEP (3.6 × 10 3 s –1 ), PtOEP (1.2 × 10 4 s –1 ), and PtTPBP (2.1 × 10 4 s –1 ) as well as the second-order rate constant (k TT ) for HTTA in ZnTPP (5.5 × 10 9 M –1 s –1 ), PdOEP (1.1 × 10 10 M –1 s –1 ), PtOEP (7.1 × 10 9 M –1 s –1 ), and PtTPBP (1.6 × 10 10 M –1 s –1 ). In most instances, triplet excited state extinction coefficients are either reported for the first time or have been revised using ultrafast transient absorption spectroscopy and singlet depletion: ZnTPP (78,000 M –1 cm –1 ) at 470 nm, PdOEP (67,000 M –1 cm –1 ) at 430 nm, PtOEP (51,000 M –1 cm –1 ) at 418 nm, and PtTPBP (100,000 M –1 cm –1 ) at 460 nm. Furthermore, the combined experimental results establish competitive time scales for homo- and heteromolecular TTA rate constants, implying the significance of considering HTTA processes in future research endeavors harnessing TTA photochemistry using common metalloporphyrin photosensitizers.

14 SOLAR ENERGY↗
DOE OSTI2026

A fresh perspective on the role of band bending, and related contributors, in light-driven production of electricity and chemicals

It is widely known that semiconductor-based solar energy conversion could power our planet. This is in part because high-quality semiconductor structures are unrivalled in their ability to separate photogenerated electrons and holes. One effective approach to achieving this photoinduced charge separation relies on a phenomenon known as “band bending”. But details to justify why band bending results in photoinduced charge separation are more complex than often appreciated. This underappreciation is an impediment to the rational, hypothesis-driven design of next-generation approaches to solar energy conversion. Herein we show, by means of derivations rooted in physical chemistry, that several phenomena – not just band bending – can facilitate photoinduced charge separation, and that each is influenced by nonequilibrium species concentration and a parameter, such as diffusion coefficient or rate coefficient, that introduces dynamics. To help visualize the impact of each phenomenon, we introduce plots that depict their contributions as free energy, force, flux, force constant, and rate. We reveal that spatial dopant distributions that define band bending are predictors of initial photogenerated species transport rates. But charge separation alone does not guarantee high-efficiency operation. A photogenerated change in energy that is freely available to do useful work is also essential, and is strongly dependent on semiconductor optical properties and reaction kinetics. Notably, this information reveals that specificity of interfacial chemical reactions – even when they are not preceded by charge separation elsewhere – can result in efficient solar energy conversion. We expect that this tutorial will guide researchers in their pursuit to uncover new mechanisms for light to perform useful work.

14 SOLAR ENERGY↗
DOE OSTI2021

High-Entropy Ceramic Coatings: Transformative New Materials for Environmentally-Compatible Thin-Film Insulators against High-T Molten Salts

An emerging new class of promising materials, High-Entropy Ceramics (HECs) or Compositionally-Complex Ceramics (CCCs), have been successfully fabricated in the last three years. This project evaluates HECs/CCCs in the concentrated solar power (CSP) context. In this project, we have identified a couple of simple, and key descriptors governing thermal conductivity in HECs. Size disorder among the cations was found to have a strong influence on the thermal conductivity across multiple systems and throughout a vast compositional space. Since identifying this, we have optimized previous compositions to achieve low thermal conductivities of $k$~$1-1.4Wm{-1}K{-1}$. We have further reduced our selection of promising compositions based on project guidelines and applied a theory that can potentially predict reactivity with molten salts to identify a small set of HECs that are suitable for further molten salt heat transfer media (HTM) stability testing. Many compositions reveal poor resistance to molten chloride salt after being exposed for 24 h compared to the reference structural alloy, Haynes 230. However, after 100 h, a few HECs/CCCs show strong parabolic rate constant effects and provide greater resistance to chloride salt compared to Haynes 230 alloy, which shows more linear kinetics. Postmortem characterization of the microstructure reveals the parabolic rate constant originates from a dense reaction layer form at the interface. This feature is absent in Haynes 230, which only shows grain boundary infiltration. The HECs/CCCs were also put in contact with the metal alloy under Ar for 800 h at 800°C and show negligible interaction. Lastly, parabolic rate constant HECs/CCCs also have low thermal conductivity $(<2 Wm^{-1} K^{-1})$ at 800°C. These specimens satisfy all project requirements and demonstrate their promising application in next-generation CSP.

14 SOLAR ENERGY↗