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DOE OSTI2025

Non-destructive identification of absorptive damage sites by photoluminescence brightening

We present a non-destructive photoluminescence (PL) imaging strategy for probing damage growth behavior in fused silica under laser irradiation. Transient wide-field PL image measurements were conducted at varying excitation intensities to investigate the dynamics of radiative defect generation and annihilation in laser-induced damage sites. Our results reveal that, while low excitation intensities predominantly induce PL quenching due to defect annihilation, high-intensity excitation (>0.3 GW/cm 2 at 532 nm) triggers pronounced PL brightening (PLB), indicative of radiative defect generation. Image analysis demonstrates that PLB events are strongly correlated with subsequent damage growth (10 J/cm 2 at 351 nm), whereas overall PL intensity is not. No optically detectable morphological changes were observed during PLB, confirming the non-destructive nature of the technique. We propose that PLB arises from defect-assisted absorption of multiple photons at pre-existing absorptive centers, which enhances local absorptivity and initiates further defect formation. These findings establish PLB monitoring as a sensitive diagnostic tool for identifying damage sites with elevated absorptivity, enabling targeted maintenance and improved laser damage management in optical materials.

Materials science↗

DOE OSTI2021

In situ ambient pressure XPS study of Pt/Cu(111) single-atom alloy in catalytically relevant reaction conditions

The presence of multiple reactant gases as well as reaction intermediates in a heterogeneous catalytic reaction results in a complex interaction between different components of the catalyst with each gas, which can alter the surface and chemical state of the catalyst differently than in the presence of an individual gas alone. In this study, we used in situ ambient pressure x-ray photoelectron spectroscopy to study the surface state of Pt/Cu(111) single-atom alloy model system in two catalytically relevant reaction conditions: CO 2 hydrogenation and CO oxidation. We found that the activation of CO 2 results in the formation of CO, which adsorbs on Pt sites at up to 400 K. In the presence of CO 2 and H 2 , Pt catalyzes the reverse water–gas shift reaction, which produces more CO and further stabilizes surface Pt atoms at 450 K. On the other hand, in CO oxidation condition, the presence of O 2 results in the formation of a thick Cu 2 O layer at higher temperatures, and Pt atoms are no longer detected in the surface and subsurface layers. When O 2 is introduced to the sample before CO, the formation of a complete Cu 2 O layer that covers all Pt atoms occurs immediately at room temperature. Finally, however, when CO is introduced at room temperature before O 2 , the presence of adsorbed CO on Pt sites stabilizes the surface Pt atoms and prevents the formation of a complete Cu 2 O layer, thus exposing the Pt atoms in 'holes' in the Cu 2 O layer.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Electrospun porous La–Sr–Co–Ni–O nanofibers for highly sensitive non-enzymatic glucose detection

Glucose biosensors are widely used for clinical, industrial, and environmental applications. Nonenzymatic electrochemical glucose biosensors based on metal oxides with a perovskite structure have exhibited high sensitivity, excellent stability, and cost efficiency. In this work, porous La–Sr–Co–Ni–O (LSCNO) nanofibers, with an ABO 3 -type perovskite structure, were prepared through optimizing the A-site and B-site elements by electrospinning, followed with calcination at 700 °C for 5 h. Characterized by scanning and transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy, fabricated nanofibers were confirmed to be porous and nanosized polycrystalline grains with high crystallinity. A novel La 0.75 Sr 0.25 Co 0.5 Ni 0.5 O 3 -based nonenzymatic electrochemical biosensor was developed, which is sensitive to glucose because of an electrochemically catalytic mechanism, a mediated electron transfer involving Ni(II)/Ni(III) or Co(II)/Co(III), accompanying with gluconic acid complexation. The glucose biosensor presented a linear response in the range of 0.1–1.0 mM with a calibration sensitivity of 924 ± 28 μA mM –1 , a proportion of the variance of 0.9926, and a lower limit of detection of 0.083 mM, respectively, demonstrating an outstanding analytical performance. The biosensor showed no response to the most widely used anionic surfactant, sodium dodecyl sulfate, and low sensitivity to other biomolecules, such as fructose, lactose, galactose, mannose, dopamine, and ascorbic acid. A urine sample was tested by this novel nonenzymatic electrochemical biosensor by standard addition method, suggesting a potential application for clinical test.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Inhomogeneous Enrichment of Radioactive Nuclei in the Galaxy: Deposition of Live 53 Mn, 60 Fe, 182 Hf, and 244 Pu into Deep-sea Archives. Surfing the Wave?

Abstract While modeling the galactic chemical evolution (GCE) of stable elements provides insights to the formation history of the Galaxy and the relative contributions of nucleosynthesis sites, modeling the evolution of short-lived radioisotopes (SLRs) can provide supplementary timing information on recent nucleosynthesis. To study the evolution of SLRs, we need to understand their spatial distribution. Using a three-dimensional GCE model, we investigated the evolution of four SLRs: 53 Mn, 60 Fe, 182 Hf, and 244 Pu with the aim of explaining detections of recent (within the last ≈1–20 Myr) deposition of live 53 Mn, 60 Fe, and 244 Pu of extrasolar origin into deep-sea reservoirs. We find that core-collapse supernovae are the dominant propagation mechanism of SLRs in the Galaxy. This results in the simultaneous arrival of these four SLRs on Earth, although they could have been produced in different astrophysical sites, which can explain why live extrasolar 53 Mn, 60 Fe, and 244 Pu are found within the same, or similar, layers of deep-sea sediments. We predict that 182 Hf should also be found in such sediments at similar depths.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2025

Defect Engineering in Large‐Scale CVD‐Grown Hexagonal Boron Nitride: Formation, Spectroscopy, and Spin Relaxation Dynamics

Recently, numerous techniques have been reported for generating optically active defects in exfoliated hexagonal boron nitride (hBN), which hold transformative potential for quantum photonic devices. However, achieving on-demand generation of desirable defect types in scalable hBN films remains a significant challenge. Here, it is demonstrated that formation of negative boron vacancy defects, V B − , in suspended, large-area CVD-grown hBN is strongly dependent on the type of bombarding particles (ions, neutrons, and electrons) and irradiation conditions. In contrast to suspended hBN, defect formation in substrate-supported hBN is more complex due to the uncontrollable generation of secondary particles from the substrate, and the outcome strongly depends on the thickness of the hBN. Different defect types are identified by correlating spectroscopic and optically detected magnetic resonance features, distinguishing boron vacancies (formed by light ions and neutrons and emitting at 800 nm) from other optically active defects emitting at 650 nm assigned to anti-site nitrogen vacancy (N B V N ) and reveal the presence of additional “dark” paramagnetic defects that influence spin-lattice relaxation time (T 1 ) and zero-field splitting parameters, all of which strongly depend on the defect density. These results underscore the potential for precisely engineered defect formation in large-scale CVD-grown hBN, paving the way for the scalable fabrication of quantum photonic devices.

CVD↗

DOE OSTI2023

Evaluation of riparian enhancement actions in the Columbia River Basin

Riparian enhancement is a common restoration technique in the Columbia River Basin (CRB) and the Pacific Northwest. However, relatively few studies have evaluated its success and even fewer studies include long-term monitoring. Forty-one riparian planting projects located in the CRB, each with a paired treatment and control reach, were evaluated in the summer of 2018 and 2019 using an extensive post-treatment (EPT) design. At each reach, we quantified woody plant abundance, richness, diversity, and vegetation and canopy cover as riparian response variables, and measured terrace height and documented individuals with bud browse, deceased, and with predator protection as potential explanatory variables. Species richness, woody plant abundance (all height classes combined and within shrub height class), and the proportion of woody plants with bud browse or deceased were all higher in treatment than control reaches. However, no significant improvements were observed for any other riparian response or explanatory variables. Implementation techniques, including invasive species removal efforts, follow-up planting, watering, and the type of restoration project (floodplain restoration and planting, in-stream restoration and planting, or solely planting) were also considered as potential explanatory variables and were found to have significant impacts on restoration response for abundance and cover variables. Further, our results suggest that planting implementation methods, site level physical factors, and time since planting all influence the success of riparian planting projects and if not addressed in restoration design and implementation can contribute to a lack of detectable response.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

An automated workflow to screen alkene reductases using high-throughput thin layer chromatography

Background: Synthetic biology efforts often require high-throughput screening tools for enzyme engineering campaigns. While innovations in chromatographic and mass spectrometry-based techniques provide relevant structural information associated with enzyme activity, these approaches can require cost-intensive instrumentation and technical expertise not broadly available. Moreover, complex workflows and analysis time can significantly impact throughput. To this end, we develop an automated, 96-well screening platform based on thin layer chromatography (TLC) and use it to monitor in vitro activity of a geranylgeranyl reductase isolated from Sulfolobus acidocaldarius (SaGGR). Results: Unreduced SaGGR products are oxidized to their corresponding epoxide and applied to thin layer silica plates by acoustic printing. These derivatives are chromatographically separated based on the extent of epoxidation and are covalently ligated to a chromophore, allowing detection of enzyme variants with unique product distributions or enhanced reductase activity. Herein, we employ this workflow to examine farnesol reduction using a codon-saturation mutagenesis library at the Leu377 site of SaGGR. We show this TLC-based screen can distinguish between fourfold differences in enzyme activity for select mutants and validated those results by GC–MS. Conclusions: With appropriate quantitation methods, this workflow can be used to screen polyprenyl reductase activity and can be readily adapted to analyze broader catalyst libraries whose products are amenable to TLC analysis.

09 BIOMASS FUELS↗

DOE OSTI2023

Soil architecture and subsurface stratigraphic heterogeneities across land-lake interfaces along Lake Erie.

Uploaded raw datasets from electrical resistivity tomography (ERT), ground penetrating radar (GPR), electromagnetic induction (EMI) and insitu sensors were acquired across land-lake interfaces along Lake Erie. These datasets were useful to delineate the soil architecture and subsurface stratigraphic heterogeneities. We combined multiple geophysical methods with lithostratigraphic logs from borehole cores and data from soil and borehole sensors to investigate spatial heterogeneities across land-lake interfaces. The apparent electrical conductivity (Eca) maps matched closely with the soil maps from public database and also detected additional soil units that were missing in the traditional soil maps. This implies that electromagnetic induction (EMI) could be relied upon for non invasive characterization of soils in sampling restricted sites where only non-invasive measurements are feasible. Results from electrical resistivity tomography (ERT) and Ground penetrating radar (GPR) are consistent with the surficial geology of the study area, and revealed that the vertical variabilities at the sites are mainly driven by stratigraphy.The ERT data (.stg) were acquired from three different sites portage river (PTR), crane creek (CRC) and old woman creek (OWC). The ".stg" files can be opened with ERT inversion software such as EarthImager, ResIpy or Res2DInv. The GPR data (.GPZ) were also acquired from the three sites, and the ".GPZ" data files can be opened with EKKO_project 5 software from Sensors & Software Inc., or with any other standard GPR software. The EM data (.csv) were acquired from the three sites while the soil sensor data (.csv) here were acquired only from crane creek site. The ".csv) files can be opened with MS Excel or any other spread sheet software.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

List Mode Data from the Modular Vehicle Detector System

In 2022 measurements were made with the Modular Vehicle Detectors (MVD) at the National Criticality Experiments Research Center (NCERC), located in the Device Assembly Facility (DAF) on the Nevada National Security Site (NNSS), Nevada. These detectors were supplied by the Naval Information Warfare Center (NIWC) Pacific. The MVDs were connected to an Advanced List Mode Module (ALMM) which records when an MVD detected a neutron. This is a summary of the measurement configurations as well as a list of the list-mode data files from each configuration. In addition to the measurements taken at NCERC additional measurements with the MVDs were taken at Los Alamos National Laboratory (LANL).

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2025

Where do the fish go in winter? A year of observing seasonal changes in Sequim Bay’s nearshore fish community

The use of environmental DNA (eDNA) sampling has been proposed as a complementary method to monitor fish species in marine environments. eDNA offers a non-invasive, cost-effective, and scalable way to detect aquatic species. It is appealing in environments where traditional methods are limited by access or visibility, especially in complex or sensitive habitats such as tidal channels and other marine energy sites. Before eDNA can be fully relied upon, we must verify its accuracy against established methods, like underwater photography. In this study, we collected eDNA samples and concurrently deployed a 360-degree camera near the floating dock of PNNL-Sequim in the tidal channel of Sequim Bay once a month for twelve consecutive months. During deployments, the camera remained on the seafloor for several hours overlapping slack tide and captured time-lapse photographs at ten second intervals. Counts and identifications of fish species observed in the images were used to calculate monthly Shannon diversity and Pielou evenness indices. These values were compared across the months using a Kruskal-Wallis test paired with a Conover-Iman post-hoc test. Cliff’s Delta was also calculated to quantify the effect size of the monthly differences. No fish were observed from December through April, likely due to seasonal behavior changes within the local fish community. Fish returned to the shoreline in May, with the greatest diversity and evenness recorded in September. These findings reveal substantial seasonal variation in nearshore fish communities. Many monthly comparisons were found to contain statistically significant differences within the diversity and evenness, and even more were found to have large effect sizes, signifying large ecological changes throughout the seasons. The absence of fish observed during the winter months is a key outcome of this survey that will hopefully be reflected in the eDNA results still to come, which would help validate the eDNA approach.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS1972

Application of ERTS-A data to the protection and management of New Jersey's coastal environment

The author has identified the following significant results. Apparent sewage sludge disposal by barge has been detected approximately 12 miles offshore in an area with an approximate radius of 2.5 nautical miles. Verification is underway to determine whether this dumping is within one of the approved dump sites in the Bight. Analysis of all available historical and routine meteorological data in correlation with the observed phenomenon is necessary before final conclusions can be reached with respect to the effects of currents on the disposal of dumped wastes. Four effluent plumes emanating from the shoreline just south of Sandy Hook were observed and are moving in a southerly direction. Another plume is evident north of Barnegat Inlet and is moving almost directly offshore. This suggests that the more northerly plumes are under the influence of the tidal regime around New York Harbor much more than are the plumes further south along the New Jersey coast. Of further interest are what appear to be an internal wave phenomena approximately 75 miles east of the New Jersey coast. This same sort of phenomena has been observed repetitively off the coast of Oregon.

Yunghans, R. S.↗

NASA NTRS1985

An EAS experiment at mountain altitude for the detection of gamma-ray sources

The plan of an extensive air shower experiment 2.200 m above sea level for the detection of 10 to the 14th power eV to 10 to the 17th power eV gamma rays from sources in the declination band 0 deg to + 60 deg is described. The site selection, detector array and electronic layout are detailed.

Allkofer, O. C.↗

NASA NTRS1984

Microstructural development of protective Al2O3 scales

Microstructural characteristics of Al2O3 scales grown as protective coatings on NiCrAl alloys used in jet engines are described. The alloys were pure or doped with 0.3 percent Zr or Y and oxidized in 1 atm air at 1100 C for 0.1, 1 or 20.0 hr. The scales were then examined under a microscope. Transient epitaxial scales, formed during the 0.1 hr treatment and containing Ni, Cr and Al, consisted of a mosaic of subgrains and precipitates of different phases. The Y and Zr dopants had no effect on the nucleation site locations. The appearance of intergranular porosity at 0.1 hr was exacerbated after the 1 hr treatment. A bimodal void distribution appeared after 20 hr, when no porosity was evident. The detection of local areas of preferred orientation is taken as a spur to further studies of scale growth to gain control of the grain size or even to produce single crystal scales.

Smialek, J. L.↗

NASA NTRS1992

Diurnal HO2 cycles at clean air and urban sites in the troposphere

HO2 concentrations at two Oregon sites were determined for continuous periods of 36 to 48 hours, using fluorescence assay with gas expansion. At the sea level coastal site, NNW winds prevailed during daytime, and a point measurement of very low total nonmethane hydrocarbon concentration indicated the presence of remote tropospheric air of oceanic origin. At the urban site, HO2 was determined during moderately low ozone pollution levels. At both sites, maximum daily (HO2) was in the range of 1-2 x 10 exp 8/cu cm under clear-sky conditions, with an estimated overall uncertainty of 40 percent. HO2 was detected by continuous low-pressure sampling with flowing chemical conversion to HO, which was detected by laser-excited fluorescence. The instrumental response to HO2 was calibrated by the self-decay of HO2 at atmospheric pressure. Interference in the measured daytime HO2 concentrations by RO2 was estimated at less than 20 percent.

Hard, T. M.↗

NASA NTRS1995

Urban remote sensing applications: TIMS observations of the City of Scottsdale

A research program has been initiated between Arizona State University and the City of Scottsdale, Arizona to study the potential applications of TIMS (Thermal Infrared Multispectral Scanner) data for urban scene classification, desert environmental assessment, and change detection. This program is part of a long-term effort to integrate remote sensing observations into state and local planning activities to improve decision making and future planning. Specific test sites include a section of the downtown Scottsdale region that has been mapped in very high detail as part of a pilot program to develop an extensive GIS database. This area thus provides excellent time history of the evolution of the city infrastructure, such as the timing and composition of street repavement. A second area of study includes the McDowell intensive study by state and local agencies to assess potential sites for urban development as well as preservation. These activities are of particular relevance as the Phoenix metropolitan area undergoes major expansion into the surrounding desert areas. The objectives of this study in urban areas are aimed at determining potential applications of TIMS data for classifying and assessing land use and surface temperatures. Land use centers on surface impermeability studies for storm runoff assessment and pollution control. These studies focus on determining the areal abundance of urban vegetation and undeveloped soil. Highly experimental applications include assessment and monitoring of pavement condition. Temperature studies focus on determining swimming pool area and temperature for use in monitoring evaporating and urban water consumption. These activities are of particular relevance as the Phoenix metropolitan area undergoes major expansion into the surrounding desert area.

Christensen, Philip R.↗

NASA NTRS2002

Mapping The Ancient Maya Landscape From Space

The Peten region of northern Guatemala is one of the last places on earth where major archeological sites remain to be discovered. It was in this region that the Maya civilization began, flourished, and abruptly disappeared. Remote sensing technology is helping to locate and map ancient Maya sites that are threatened today by accelerating deforestation and looting. Thematic Mapper and IKONOS satellite and airborne Star3-I radar data, combined with Global Positioning System (GPS) technology, are successfully detecting ancient Maya features such as cities, roadways, canals, and water reservoirs. Satellite imagery is also being used to map the bajos, which are seasonally flooded swamps that cover over 40% of the land surface. The use of bajos for farming has been a source of debate within the professional community for many years. But the recent detection and verification of cultural features within the bajo system by our research team are providing conclusive evidence that the ancient Maya had adapted well to wetland environments from the earliest times and utilized them until the time of the Maya collapse. The use of the bajos for farming is also an important resource for the future of the current inhabitants who are experiencing rapid population growth. Remote sensing imagery is also demonstrating that in the Preclassic period (600 BC- AD 250), the Maya had already achieved a high organizational level as evidenced by the construction of massive temples and an elaborate inter-connecting roadway system. Although they experienced several setbacks such as droughts and hurricanes, the Maya nevertheless managed the delicate forest ecosystem successfully for several centuries. However, around AD 800, something happened to the Maya to cause their rapid decline and eventual disappearance from the region. The evidence indicates that at this time there was increased climatic dryness, extensive deforestation, overpopulation, and widespread warfare. This raises a question that is relevant to the contemporary world-namely, how severe do internal stresses in a civilization have to become before relatively minor climate shifts can trigger a widespread cultural collapse?

Sever, Tom↗

NASA NTRS2012

Conformal Ablative Thermal Protection System for Planetary and Human Exploration Missions

The Office of Chief Technologist (OCT), NASA has identified the need for research and technology development in part from NASAs Strategic Goal 3.3 of the NASA Strategic Plan to develop and demonstrate the critical technologies that will make NASAs exploration, science, and discovery missions more affordable and more capable. Furthermore, the Game Changing Development Program (GCDP) is a primary avenue to achieve the Agencys 2011 strategic goal to Create the innovative new space technologies for our exploration, science, and economic future. In addition, recently released NASA Space Technology Roadmaps and Priorities, by the National Research Council (NRC) of the National Academy of Sciences stresses the need for NASA to invest in the very near term in specific EDL technologies. The report points out the following challenges (Page 2-38 of the pre-publication copy released on February 1, 2012): Mass to Surface: Develop the ability to deliver more payload to the destination. NASA's future missions will require ever-greater mass delivery capability in order to place scientifically significant instrument packages on distant bodies of interest, to facilitate sample returns from bodies of interest, and to enable human exploration of planets such as Mars. As the maximum mass that can be delivered to an entry interface is fixed for a given launch system and trajectory design, the mass delivered to the surface will require reductions in spacecraft structural mass more efficient, lighter thermal protection systems more efficient lighter propulsion systems and lighter, more efficient deceleration systems. Surface Access: Increase the ability to land at a variety of planetary locales and at a variety of times. Access to specific sites can be achieved via landing at a specific location(s) or transit from a single designated landing location, but it is currently infeasible to transit long distances and through extremely rugged terrain, requiring landing close to the site of interest. The entry environment is not always guaranteed with a direct entry, and improving the entry systems robustness to a variety of environmental conditions could aid in reaching more varied landing sites. The National Research Council (NRC) Space Technology Roadmaps and Priorities report highlights six challenges and they are: 1) Mass to Surface, 2) Surface Access, 3) Precision Landing, 4) Surface Hazard Detection and Avoidance, 5) Safety and Mission Assurance, and 6) Affordability. In order for NASA to meet these challenges, the report recommends immediate focus on Rigid and Flexible Thermal Protection Systems. Rigid TPS systems such as Avcoat or SLA are honeycomb based and PICA is in the form of tiles. The honeycomb systems is manufactured using techniques that require filling of each (3/8 cell) by hand and within a limited amount of time once the ablative compound is mixed, all of the cells have to be filled and the entire heat-shield has to be cured. The tile systems such as PICA pose a different challenge as the mechanical strength characteristic and the manufacturing limitations require large number of small tiles with gap-fillers between the tiles. Recent investments in flexible ablative systems have given rise to the potential for conformal ablative TPS> A conformal TPS over a rigid aeroshell has the potential to solve a number of challenges faced by traditional rigid TPS materials.

Beck, R.↗

NASA NTRSDate not supplied

Topographic Quintet: Comparing Five Methods for Measuring Ultra-High Resolution Topography

We compare different methods for collecting ultra-high resolution topography data within an analog planetary, human landing site scale area. Our aim is to investigate the cost and benefits of different 3D terrain mapping techniques, their associated data collection methods, and how their different specifications (e.g., range, spatial resolution, scanning-time, mobility, operating constraints, GPS-Denied operation, etc.) might be applied to landing-site characterization and mission operations. We compare 3D terrain data collected during a field campaign in November 2021 from an outcrop at Kilbourne Hole in southern New Mexico using different Light Detection and Ranging (LiDAR) sensors on the ground and stereo-derived 3D data from framing cameras mounted on small uncrewed aerial systems (sUAS).Our foci for this experiment are ground-based, surveying, and autonomous vehicle-type 3D scanning sensors that might be used for planetary surface exploration from landed assets (e.g., lander, rover, astronaut-mounted sensors, decent imaging, hoppers, or drones).[e.g. 1]This test is not meant to benchmark these scanners against one another, nor provide a recommendation for a specific make or model. Rather, our goal is to quantify time, effort, resolution, and operational trade-offs that are important for selecting a topographic instrument/methodology for a given scope of terrain characterization. Our results indicate that each technique is capable of exceptional quality terrain characterization for planetary exploration and scientific inquiry, but we hypothesize the appropriate technique is highly dependent on the scope of operational specifications and science requirements.

P Whelley↗