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At least 1,081 records · Page 60

Prototype Development, Testing, and Modeling for a Solar Light-Trapping Planar-Cavity Particle Receiver

Many applications for concentrating solar thermal power (CSP) technologies of high efficiency power cycles or thermochemical processes require higher operating temperatures and alternative heat transfer media. Inert solid particles for next-generation CSP and reactive gas and/or solid media for solar thermochemical processes are common options; however, these have significantly lower heat transfer capabilities than thermal oil, molten salt, or molten metal media. Conventional solar receivers operating temperatures >700 degrees Celsius face challenges including thermal performance and thermal-mechanical issues. To overcome these limitations, we have developed a novel light-trapping, planar-cavity receiver (LTPCR) that can heat solid-phase media within an enclosed receiver while maintaining a high aperture solar flux concentration for high efficiency. This paper presents progress on design, fabrication, and testing of a 100 kWt prototype receiver to demonstrate the LTPCR operability and its commercial feasibility.

14 SOLAR ENERGY↗

Electrochemical Manipulation and Radiolytic Evaluation of Organic Phase Neptunium

Presentation for Seed LDRD proposal presentation: This Seed LDRD research proposes to test an innovative approach to precisely control the oxidation state distribution of neptunium (Np) under used nuclear fuel (UNF) reprocessing conditions using novel electrochemical methods. Current UNF reprocessing technologies are not financially viable in the US, requiring significant scientific and technological innovation to improve cost efficiency. Reducing the number of process cycles is one avenue for increasing cost efficiency, of which resolving the challenge associated with isolating Np is critical. Under envisioned process conditions, Np is present in a mixture of extractable (Np(IV) and Np(VI)) and inextractable (Np(V)) oxidation states, the distribution of which is dependent on several factors, including ionizing radiation dose, that change throughout a reprocessing scheme. Consequently, Np unintentionally partitions into various UNF reprocessing phases and product streams, ultimately increasing the number of process cycles to isolate UNF components. Here, we propose to employ novel, high surface area, optically transparent, Ligand Modified tin-doped indium oxide Electrodes (LMES). These LMEs bind Np, and therefore enable concurrent generation and spectroscopic characterization of Np oxidation states in organic solutions. These proof-of-concept experiments will: (i) facilitate optimization of the proposed electrochemical system conditions for Np oxidation state manipulation; (ii) identify the accessible electrochemical window for Np complexes in the organic phase; (iii) report characteristic optical spectra for each accessible complexed Np oxidation state; and (iv) determine the lifetime and partitioning of a given atypical Np oxidation state in the organic phase in the presence and absence of ionizing radiation fields. The data gathered by this Seed LDRD will provide support for the design of an electrochemical process concept for the precise manipulation of Np oxidation states in UNF reprocessing solvent systems, with the intention of providing advanced control over Np mass transfer, and thus greater process efficiency and economy.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Enhanced flow boiling heat transfer on chromium coated zircaloy-4 using cold spray technique for accident tolerant fuel (ATF) materials

Flow boiling heat transfer tests were conducted to evaluate the Critical Heat Flux (CHF) and Heat Transfer Coefficient (HTC) of conventional and accident tolerant fuel (ATF) cladding materials, i.e., bare Zircaloy-4 (Zr4), and Zircaloy-4 coated with Chromium using physical vapor deposition (PVD) (Zr4-Cr-PVD) and cold spray process (Zr4-Cr-CS), respectively. The tests were performed on a single heater rod with a uniform heat flux profile, at the atmospheric pressure, inlet temperature (24 °C) and mass flow rate (750 kg/m 2 s). HTC’s were increased by 5.2% and 3.3% on Zr4-Cr-CS compared to bare Zr4 and Zr4-Cr-PVD. Improved HTCwas attributed to the increased void fraction and high roughness (Ra = 532 nm) of the Zr4-Cr-CS. In detail, the micro-cavities, which act as bubble seeds, were entirely distributed on the Zr4-Cr-CS, and these micro-cavities generated smaller and faster bubbles, thus the void fraction increased by 10.9% compared to bare Zr4. HTC is improved by these smaller and faster bubbles which can remove heat from the heater rod surface more efficiently. To identify the exact location of CHF, the surface temperature profile was measured using advanced fiber-optic sensors which have high temporal/spatial resolution (distance between point to point: ~2.5 mm, frequency ~100 Hz). CHF occurred at 80–95% along the heated length and showed an 11.6% reduction on Zr4-Cr-CS compared to bare Zr4. We hypothesize the CHF reduction was caused by the lower wettability of the Zr4-Cr-CS which reduces the liquid supply to the surface, and vigorous bubble accumulation owing to high void fraction near the outlet, which results in early formation of the vapor film. During the post-CHF quenching phase, the rougher Zr4-Cr-CS showed larger cooling rates compared to the bare Zr4 and Zr4-Cr-PVD, preventing of oxidation by chromium layer. In conclusion, we demonstrate that the high roughness on the Zr4-Cr-CS increased the number of micro-cavities on the surface, resulting in 5.2% increase in HTC and improvement in the quenching heat transfer performance whereas CHF was 11.6% reduced compared to bare Zr4. Overall statistically there is little effect in the coating with regards to CHF and slight improvement in HTC.

42 ENGINEERING↗

Implementation of two-phase gas transport into VERA for molten salt reactor analysis

Molten salt reactors (MSRs) are a class of next-generation nuclear reactors that have received recent industrial and research interest. A generalized species transport solver was implemented in the Virtual Environment for Reactor Applications (VERA) computing suite to extend this tool to analyze liquid-fueled MSRs. This core simulator has been extended to model the transport of fission product gases into a collection of circulating gas bubbles with the purpose of removing the gases. This paper presents the governing species transport equation, along with various nuclear source terms. Development of the source term for phase migration is discussed, along with a simplified interfacial area tracking method. Finally, a case study on a simplified MSR loop is presented in which modeling parameters were varied to assess their impact on gas removal. The steady state results show that parameters such as bubble diameter, gas injection rate and mass transfer coefficient have a low to moderate effect on the fraction of xenon in the core region. Removal efficiency has the greatest effect on the fraction in the core region. After the pump bowl, bubble diameter has a minor effect on the fraction of xenon in the gas void. Finally, these results point out that increasing parameters such as mass transfer coefficient, gas injection rate, and removal efficiency drives the xenon into the circulating gas void, while decreasing bubble diameter also drives xenon into the gas void by increasing interfacial area.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Magnetic properties of intercalated quasi-2D Fe 3-x GeTe 2 van der Waals magnet

Among several well-known transition metal-based compounds, cleavable van der Waals (vdW) Fe 3-x GeTe 2 (FGT) magnet is a strong candidate for use in two-dimensional (2D) magnetic devices due to its strong perpendicular magnetic anisotropy, sizeable Curie temperature (T C ~154 K), and versatile magnetic character that is retained in the low-dimensional limit. While the T C remains far too low for practical applications, there has been a successful push toward improving it via external driving forces such as pressure, irradiation, and doping. Here we present experimental evidence of a room temperature (RT) ferromagnetic phase induced by the electrochemical intercalation of common tetrabutylammonium cations (TBA+) into quasi-2D FGT. We obtained Curie temperatures as high as 350 K with chemical and physical stability of the intercalated compound. The temperature-dependent Raman measurements, in combination with vdW-corrected ab initio calculations, suggest that charge transfer (electron doping) upon intercalation could lead to the observation of RT ferromagnetism. This work demonstrates that molecular intercalation is a viable route in realizing high-temperature vdW magnets in an inexpensive and reliable manner and has the potential to be extended to bilayer and few-layer vdW magnets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Zero-deadtime processing in beta spectroscopy for measurement of the non-zero neutrino mass

The Project 8 collaboration seeks to measure, or more tightly bound, the mass of the electron antineutrino by applying a novel spectroscopy technique to precisely measure the tritium beta-decay spectrum. The current system produces a single analog signal, which is digitized and processed in several stages before being saved to local disk storage. Online processing includes two stages, an FPGA connected to the analog to digital converter reduces the data down to the region of interest before shipping over the local network for further processing and storage. A normal CPU-based processing stage applies triggering logic to only save data at times when a signal is present, further reducing the total volume of data which needs to be written to disk or transferred for long-term storage. The next stage of the project will need to process many input channels and will integrate a necessary aggregation and combination step prior to applying the event search and triggering logic. We present the online processing system which has successfully been deployed for the current, singlechannel, phase. We also present the status and design for a many-channel platform.

Project 8 Collaboration↗

Advanced Multi-Tube Mixer Combustion for 65% Efficiency (Final Report)

This project targeted advanced low NOx combustion for advanced gas turbines capable of 65%, or greater, efficiency in combined cycle application. This technology advancement has further potential to benefit gas turbines used in coal based IGCC applications with pre-combustion carbon capture and hydrogen as the resulting fuel. The program developed and synthesized the most advanced combustion system capable of achieving low NOX emissions up to turbine inlet temperatures of 3100F while also supporting the load-following needs of a modern grid. The combustion system contributes to the overall gas turbine efficiency goal by setting the maximum cycle temperature achievable for a given NOX level and by minimizing the through-combustor air flow pressure drop. Focus areas for this project targeted maximizing the turbine inlet temperature entitlement, as constrained by emissions considerations. The design also minimized parasitic air flow pressure drop by using advanced cooling techniques and performance materials selections and by minimizing hot surface area. These two technology objectives (maximum, emissions-compliant cycle temperature and minimum air flow pressure drop) were integrated into a prototype design. The primarily analytical project sought to identify the most promising technologies to meet these objectives. Additional critical “jugular” data were obtained from multi-tube mixer tests to realize the potential of leveraging “micro flames” for minimizing overall hot surface area. This data was used, in conjunction with an understanding of advanced material and cooling design technologies, to analytically develop multiple design concepts. Phase I focused on in-depth engineering analysis and design, with minimal supporting laboratory testing to enable a selection of the top three combustion architectures for achieving these overall objectives. Phase II of the program developed the selected design through a combination of sub-scale testing and analytical efforts. Early tests included a cold-flow cascade to establish aerodynamic performance characteristics and a sub-scale fired test at GE Global Research in Niskayuna, NY, to establish cooling and heat transfer characteristics in conjunction with combustion performance. The data from these tests validated the analytical models to ultimately design a full-scale, test article to evaluate at prototypical pressure and temperature conditions at GE Gas Power’s Gas Turbine Technology Laboratory in Greenville, SC. GE Gas Power also developed, tested, and recommended a suitable seal design to be applied to the unique features of the combustor. To assess the technology challenges from prospective future production of the combustor from a ceramic matrix composite material, screening tests of Environmental Barrier Coatings were completed.

20 FOSSIL-FUELED POWER PLANTS↗

Topological terms with qubit regularization and relativistic quantum circuits

Qubit regularization provides a rich framework to explore quantum field theories. The freedom to choose how the important symmetries of the theory are embedded in the qubit regularization scheme allows us to construct new lattice models with rich phase diagrams. Some of the phases can contain topological terms which lead to critical phases. In this work we introduce and study the SU(3)-F qubit regularization scheme to embed the SO(3) spin-symmetry. We argue that qubit models in this regularization scheme contain several phases including a critical phase which describes the k = 1 Wess-Zumino-Witten (WZW) conformal field theory (CFT) at long distances, and two massive phases one of which is trvially gapped and the other which breaks the lattice translation symmetry. We construct a simple space-time Euclidean lattice model with a single coupling U and study it using the Monte Carlo method. We show the model has a critical phase at small U and a trivially massive phase at large U with a first order transition separating the two. Another feature of our model is that it is symmetric under space-time rotations, which means the temporal and spatial lattice spacing are connected to each other. The unitary time evolution operator obtained by a Wick rotation of the transfer matrix of our model can help us compute the physics of the k = 1 WZW CFT in real time without the need for tuning the temporal lattice spacing to zero. We use this idea to introduce the concept of a relativistic quantum circuit on a discrete space-time lattice.

Bhattacharya, Tanmoy↗

The Industry's Long-term, Yet Near-term, Issues: The Need for Radiation Protection Professionals - 20266

Since the discovery of X-rays and radioactivity, the civil use of nuclear technology has thrived for more than a half-century and has matured to be safer and more efficient. A balance between radiological and non-radiological knowledge and experience has been gained and retained through the years. Nevertheless, a slowly developing gap has emerged during the past few decades. National and international data show a declining trend in the existence of health physics programs and associated enrollment and training, which directly impact the pipeline of radiation professionals (i.e., educators, technicians, researchers, and regulators). This decline can be attributed to many factors including the lack of scientific inquisitiveness, declining funding, and the perception that existing protocols are sufficiently protective. Decommissioning and dismantling nuclear facilities is a complex and multi-phased process that generates large quantities of various levels of radioactive waste. With multiple facilities reaching their end of operational life, and others being shut down for economic reasons, the current pipeline for radiation protection experts cannot meet the future's need. Consequently, international organizations have proposed a variety of programs to transfer knowledge of radiation protection principles and practice. While many change-oriented efforts to counteract this trend aim to promote mobility, this is just a partial solution to the actual issue: long-term availability. This paper suggests multidisciplinary collaborations with modern technologies as a path forward to educate young professionals on the diversity of radiation-related applications to retain expert knowledge and foster innovation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Beyond Point Estimates: Benchmarking Uncertainty Quantification Methods on the AION-1 Astronomical Foundation Model

Foundation models for astronomical surveys offer powerful learned representations that can be transferred to downstream regression tasks such as galaxy property estimation. However, point predictions alone are insufficient for scientific inference; reliable uncertainty quantification (UQ) is essential. We compare seven UQ methods on galaxy property regression using frozen AION-1 foundation-model embeddings, predicting redshift, stellar mass, stellar-population age, gas-phase metallicity, and specific star-formation rate, from Legacy Survey photometry/imaging and DESI spectra, with PROVABGS-derived labels. Distribution-free conformal methods achieve marginal coverage within $\sim$1 pp of the nominal 90% across all properties, while non-conformal baselines (Deep Ensembles, MC~Dropout) fail to calibrate reliably. Among conformal approaches, Conformalized Quantile Regression (CQR) delivers the best coverage in the bin with the poorest model predictions. More importantly, only the Locally Valid and Discriminative (LVD) framework -- particularly when operating on AION-1 embeddings -- also provides finite-sample \emph{local validity}, producing intervals that adapt to each galaxy's local prediction difficulty rather than relying on marginal guarantees alone. These results establish conformal prediction, and LVD in particular, as the preferred UQ framework for uncertainty-aware inference on foundation-model embeddings in astrophysics.

Tame-Narvaez, Karla [Fermilab] (ORCID:000000022249↗

Flow maldistribution in plate heat exchangers – Impact, analysis, and solutions

Plate heat exchangers are commonly used in various industrial applications, such as refrigeration, air conditioning, heat pumps, powerplants, and chemical industries. Plate heat exchangers are well known for their superior heat transfer performance, compactness, and low refrigerant charge. Despite offering several advantages, they suffer from flow maldistribution issues. The flow maldistribution can deteriorate both the heat transfer and pressure drop performance, ultimately resulting in a lower system efficiency where plate heat exchangers are deployed. The flow maldistribution issues become more pronounced when the heat exchanger size is relatively large and the number of plates is higher, limiting the deployment of plate heat exchangers in larger industrial systems. Consequently, analyzing and understanding the flow maldistribution behavior in plate heat exchangers and finding ways to mitigate flow maldistribution related issues become essential topics of interest. Further, this review aims to address the effect of flow maldistribution on plate heat exchanger characteristics. First, the experimental and numerical works on flow maldistribution under single-phase and two-phase conditions are detailed. Subsequently, the end-channel and end-plate effects are discussed. Then, the methods to mitigate flow maldistribution in plate heat exchangers are outlined. Finally, based on a thorough literature survey and industrial requirements, future research directions are recommended.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A Study on Computational Cost Reduction of Simulations of Phase-Change Material (PCM) Embedded Heat Exchangers

Thermal storage can be implemented using Phase-Change Materials (PCM), which absorb significant latent heat with a relatively small temperature change. PCM phase-change processes are transient and are driven by thermal diffusion and natural convection – the latter, especially for melting process. Modeling and simulation of PCM heat exchangers (HX’s) is typically computationally intensive due to the relatively complex time-dependent physics. Most of the PCM modeling work in the literature uses high-order modeling tools such as Computational Fluid Dynamics (CFD) and Lattice-Boltzmann Method (LBM). For design purposes, the existing PCM modeling approaches are not practical, limiting researchers in their ability to investigate new ideas and different PCM’s with faster turnarounds. This paper presents a study investigating the reduction of computational cost of PCM embedded HX’s CFD models by evaluating the feasibility of spatial reduction without losing accuracy. The analysis consists of comparing full and partial domain under full melting conditions. The subject of this study is a single straight tube with circular transverse fins in the vertical orientation, using PCM’s with 35oC nominal melting temperature. Different tube and fin dimensions are investigated. Results indicate that the reduced domain reproduces - in half the run time - the same behavior as the full domain since the buoyancy effects are localized and patterned. The outputs from the partial domain simulation were used to build a non-general correlation for the PCM heat transfer characteristics and demonstrated how it can be implemented in a Finite Control Volume Reduced Order Model (ROM). The ROM can accurately reproduce the CFD simulations at 4 to 5 orders of magnitude faster.

25 ENERGY STORAGE↗

Outflowing photoionized plasma in Circinus X-1 using the high-resolution X-ray spectrometer Resolve onboard XRISM and the radiative transfer code cloudy

High-resolution X-ray spectroscopy is a key to understanding the mass inflow and outflow of compact objects. Spectral lines carry information about the ionization, density, and velocity structures through their intensity ratios and profiles. They are formed in non-local thermodynamic equilibrium conditions under the intense radiation field from the compact objects; thus radiative transfer (RT) calculation is a requisite for proper interpretations. We present such a study for a low-mass X-ray binary, Circinus X-1, from which the P Cygni profile was discovered using the X-ray grating spectrometer onboard Chandra. We observed the source using the X-ray microcalorimeter onboard XRISM at an orbital phase of 0.93–0.97 and revealed many spectral features unidentified before: the higher series transitions ($n{\rightarrow }1$; $n>2$) of highly ionized (H- and He-like) S, Ca, Ar, and Fe in emission and absorption, the Fe K$\alpha$ and K$\beta$ inner-shell excitation absorption of mildly ionized (O- to Li-like) Fe, and resolved fine-structure level transitions in the Fe Ly$\alpha$ and He$\alpha$ complexes. They blend with each other at different velocity shifts on top of apparently variable continuum emission that changed its flux by an order of magnitude within a 70 ks telescope time. Despite such complexity in the observed spectra, most of them can be explained by a simple model consisting of the photoionized plasma outflowing at $\sim$300 km s$^{-1}$ and the variable blocking material in the line of sight of the incident continuum emission from the accretion disk. We demonstrate this with the aid of the RT code cloudy for the line ratio diagnostics and spectral fitting. We further constrain the physical parameters of the outflow and argue that the outflow is launched close to the outer edge of the accretion disk and can be driven radiatively by being assisted by the line force calculated using the RT simulation.

X-rays: binaries↗

Phase Behavior of Charged Star Block Copolymers at Fluids Interface

The phase behavior of block copolymers (BCPs) at the water-oil interface is influenced by the segmental interaction parameter (χ) and chain architecture. We synthesized a series of star block copolymers (s-BCPs) having polystyrene (PS) as core and poly(2-vinylpyridine) (P2VP) as corona. The interaction parameters of block-block (χ PS-P2VP ) and block-solvent (χ P2VP-solvent ) were varied by adjusting the pH of the aqueous solution. Lowering pH increased the fraction of quaternized-P2VP (Q-P2VP) with enhanced hydrophilicity. By transferring the equilibrated interfacial assemblies, morphologies ranging from bicontinuous films at pH of 7 and 3.1 to nanoporous and nanotubular structure at pH of 0.65 were observed. The nanoporous films formed hexagonally packed pores in s-BCP matrix, while nanotubes comprised Q-P2VP as corona and PS as core. Control over pore size, d-spacing between pores, and nanotube diameters was achieved by varying polymer concentration, molecular weight, volume fraction and arm number of s-BCPs. Large-scale nanoporous films were obtained by freeze-drying emulsions. Remarkably, the morphologies of linear BCPs were inverted, forming hexagonal-packed rigid spherical micelles with Q-P2VP as core and PS as corona in multilayer. Here, this work provides insights of phase behaviors of BCP at fluids interface and offer a facile approach to prepare nanoporous film with well-controlled pore structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Gravitational Waves from Nnaturalness

Abstract We study the prospects for probing the Nnaturalness solution to the electroweak hierarchy problem with future gravitational wave observatories. Nnaturalness, in its simplest incarnation, predictsNcopies of the Standard Model with varying Higgs mass parameters. We show that in certain parameter regions the scalar reheaton transfers a substantial energy density to the sector with the smallest positive Higgs squared mass while remaining consistent with bounds on additional effective relativistic species. In this sector, all six quarks are much lighter than the corresponding QCD confinement scale, allowing for the possibility of a first-order chiral symmetry-breaking phase transition and an associated stochastic gravitational wave signal. We consider several scenarios characterizing the strongly-coupled phase transition dynamics and estimate the gravitational wave spectrum for each. Pulsar timing arrays (SKA), spaced-based interferometers (BBO, Ultimate-DECIGO,μAres, asteroid ranging), and astrometric measurements (THEIA) all have the potential to explore new regions of Nnaturalness parameter space, complementing probes from next generation cosmic microwave background radiation experiments.

Physics↗

Nonlinear simulations of GAEs in NSTX-U

A set of nonlinear simulations has been performed in order to study the nonlinear evolution of unstable global Alfvén eigenmodes in the National Spherical Torus Experiment-Upgrade (NSTX-U). Results of the single toroidal mode number, n, simulations are compared with a full nonlinear simulation (all toroidal harmonics included). In single-n simulations, the conservation of two integrals of motion of a particle in a cyclotron resonance with a monochromatic wave is demonstrated, resulting in a one-dimensional evolution of the particle distribution in (E,μ,pϕ) phase-space. Nonlinear simulations (both single-n and full nonlinear) show a significant redistribution of the resonant fast ions, especially in the pitch parameter. Thus, the changes in the resonant particle's parallel and perpendicular energies can be several times larger than the total particle energy change, with only a small fraction transferring into the excitation of the mode itself. This implies that even a relatively small amplitude mode can significantly modify the beam distribution in the resonant region. For the NSTX-U case considered, the single-n simulation results are close to full nonlinear simulation only for the most unstable mode, in which case the saturation amplitudes and changes in the fast ion distribution are comparable. In contrast, peak amplitudes of subdominant modes in all-n simulations are smaller by a factor of 3–10 compared to single-n runs due to the flattening of the beam ion distribution by the fastest growing mode.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Geo Thermal Cloud: Cloud Fusion of Big Data and Multi-Physics Models using Machine Learning for Discovery, Exploration, and Development of Hidden Geothermal Resources

The project is motivated by the challenges, risks, and costs associated with geothermal exploration and production. Many processes and parameters impacting geothermal conditions are poorly understood. Diverse datasets are available to help characterize subsurface geothermal conditions (public and proprietary; satellite, airborne surveys, vegetation/water sampling, geological, geophysical, etc.). Yet, it is not clear how to properly leverage these datasets for geothermal exploration due to an incomplete understanding of how physical processes impacting subsurface geothermal conditions are represented in these observations. Recent advancements in machine learning (ML) provide great promise to resolve these issues. The tremendous challenges and risks of geothermal exploration and production bring the demand for novel ML methods and tools that can (1) analyze large field datasets, (2) assimilate model simulations (large inputs and outputs), (3) process sparse datasets, (4) perform transfer learning (between sites with different exploratory levels), (5) extract hidden geothermal signatures in the field and simulation data, (6) label geothermal resources and processes, (7) identify high-value data acquisition targets, and (8) guide geothermal exploration and production by selecting optimal exploration, production, and drilling strategies. Our goals and work under Phases 1 and 2 (as proposed) of this project address all these needs.

15 GEOTHERMAL ENERGY↗

Retrieval of Transuranic Drums with Deflagration to Detonation Potential from a Vault at the Oak Ridge National Laboratory - 20207

During the final phase of a long-term project, a total of 80 TRU waste drums at ORNL have been retrieved from a below-grade storage vault in which they have remained untouched for about 25 years. The drums, which house material generated from past ORNL operations, are now stored and ready for eventual transfer to the Transuranic Waste Processing Center, located on Highway 95 in Oak Ridge. The Transuranic Waste Processing Center will process and ship the drums to WIPP in Carlsbad, New Mexico, for disposal. Workers lifted the drums one-by-one from the underground storage vault with a 110-ton crane over a one-week period in October 2017. Although the physical work was performed in one week, years of detailed planning preceded the fieldwork. A key obstacle needed to be overcome before the project could safely proceed. This obstacle involved the need to ensure controls were developed for the Deflagration to Detonation Transition (DDT) potential. DDT refers to a phenomenon in ignitable mixtures of a flammable gas and air (or oxygen) when a sudden transition takes place from a deflagration type of combustion to a detonation type of explosion. Basically, these drums, under certain circumstances, have a potential to detonate and overpressurize. Extensive analysis of the drums verified that detonation, while unlikely, was possible. Of the total 103 drums that were retrieved or moved in preparation for retrieval, 18 had DDT potential. Extensive security requirements were also necessary, due to the nature of the material, and this added another layer of complexity to the fieldwork. Prior to retrieving the drums from the underground storage vault, space needed to be made for them within the various above-grade facilities. Inventory and security requirements dictated what could be stored where, and the first step of the field work involved a number of drum movements in preparation for storage of the newly retrieved drums. This effort involved moving 21 drums already in the storage area to facilitate the addition of the newly retrieved ones. The retrieval project required a total of 107 critical lifts using the 110-ton crane, under 3 critical lift plans. The TRU waste storage facility is a Category 2 Nuclear Facility and is managed under an extensive Documented Safety Analysis. The TRU retrieval project was conducted in accordance with DOE Order 425.1D and included three Implementation Verification Reviews, two Management Assessments, one Readiness Assessment, and seven mock-ups in preparation for the field work. Despite being stored for 25 years, the drums were in good shape due to the integrity of the facilities where the drums were stored. Of the 80 drums that were retrieved, 12 were placed in special containers called 'overpacks' based on their content. The drums were removed safely and without incident, thanks to a lot of preparation and the efforts of a highly skilled team. Lessons learned through the DDT control development and the drum retrieval and overpacking process could be beneficial to others having to manage similar drums of TRU waste. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗