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Radiogenic transformation of human mammary epithelial cells in vitro

Cancer induction by space radiations is a major concern for manned space exploration. Accurate assessment of radiation risk at low doses requires basic understanding of mechanism(s) of radiation carcinogenesis. For determining the oncogenic effects of ionizing radiation in human epithelial cells, we transformed a mammary epithelial cell line (185B5), which was immortalized by benzo(a)pyrene, with energetic heavy ions and obtained several transformed clones. These transformed cells showed growth properties on Matrigel similar to human mammary tumor cells. To better understand the mechanisms of radiogenic transformation of human cells, we systematically examined the alterations in chromosomes and cancer genes. Among 16 autosomes examined for translocations, by using fluorescence in situ hybridization (FISH) technique, chromosomes 3, 12, 13, 15, 16, and 18 appeared to be normal in transformed cells. Chromosomes 1, 4, 6, 8, and 17 in transformed cells, however, showed patterns different from those in nontransformed cells. Southern blot analyses indicated no detectable alterations in myc, ras, Rb, or p53 genes. Further studies of chromosome 17 by using in situ hybridization with unique sequence p53 gene probe and a centromere probe showed no loss of p53 gene in transformed cells. Experimental results from cell fusion studies indicated that the transforming gene(s) is recessive. The role of genomic instability and tumor suppressor gene(s) in radiogenic transformation of human breast cells remains to be identified.

NASA Center JSC↗

A technique for determining cloud free vs cloud contaminated pixels in satellite imagery

Since the first earth orbiting satellite sent pictures of the earth back to them, atmospheric scientists have been focused on the possibilities of using that information as both a forecasting tool and as a meteorological research tool. With the latest generation of Geostationary Operational Environmental Satellites (GOES) now entering service, that view of the earth yields views at a frequency and resolution never before available. These satellites have imagers with a five band multi-spectral capability with high spatial resolution. In addition, the sounder has eighteen thermal infrared (IR) channels plus one low-resolution visible band. With a resolution as small as one kilometer, GOES provides scientists with a powerful eye on the atmosphere. Menzel and Purdom (1994) detail both the imager and sounder capability as well as other systems on the GOES satellites. Immediately apparent in the visible channel are the patterns of clouds swirling over both oceans and continents. These clouds range in size from huge planetary systems covering thousands of kilometers to puffy fair weather cumulus clouds on the order of half a kilometer in size. With the IR sensors temperature patterns are observed. High clouds appear very cold, while low stratus field show temperatures near that of the surface. The surface, in turn, generally appears warmer than the clouds. It would seem then a simple manner to determine cloud and surface temperature from the imagery, but such is not the case. While most of the atmospheric constituents are well mixed and homogeneous, water vapor is not. The water molecule, because of its unique structure and vibration modes, affects the transmittance of the atmosphere most notably in the infrared regions. There are regions of the IR spectrum where water vapor acts as a strong absorber, and at others it is nearly transparent. The transparent wavelengths are called windows, and one such window occurs at 11.2 microns. Adjacent to this window at 12.7 microns which is strongly absorbed by water vapor. These two wavelengths form what is known as a split window, the utility of which was used. Using the linearized form of the radiative transfer equation, they were able to use the split window to determine the amount of water vapor present in the atmosphere. Jedlovec developed the physical split-window (PSW) technique which determines the integrated water content (IWC). The PSW method using Visible Infrared Spin Scan Radiometer (VISSR) Atmospheric Sounder (VAS) found on the older versions of the GOES satellites was used. Recently, Jedlovec and colleagues have been attempting to apply the PSW method using full disk IR imagery obtained by the new generation of GOES satellites. IWC is essential for improved analysis and prediction of convective storms which have been observed to develop in regions of both strong and rapidly evolving moisture gradients. It has also been used in the prediction of clouds and precipitation.

Wohlman, Richard A.↗

Communication Research in Aviation and Space Operations: Symptoms and Strategies of Crew Coordination

The day-to-day operators of today's aerospace systems work under increasing pressures to accomplish more with less. They work in operational systems which are complex, technology-based, and high-risk; in which incidents and accidents have far-reaching and costly consequences. For these and other reasons, there is concern that the safety net formerly built upon redundant systems and abundant resources may become overburdened. Although we know that human ingenuity can overcome incredible odds, human nature can also fail in unpredictable ways. Over the last 20 years, a large percentage of aviation accidents and incidents have been attributed to human errors rather than hardware or environmental factors alone. A class of errors have been identified which are not due to a lack of individual, technical competencies. Rather, they are due to the failure of teams to utilize readily available resources or information in a timely fashion. These insights began a training revolution in the aviation industry called Cockpit Resource Management, which later became known as Crew Resource Management (CRM) as its concepts and applications extended to teams beyond the flightdeck. Then, as now, communication has been a cornerstone in CRM training since crew coordination and resource management largely resides within information transfer processes--both within flightcrews, and between flightcrews and the ground operations teams that support them. The research I will describe takes its roots in CRM history as we began to study communication processes in order to discover symptoms of crew coordination problems, as well as strategies of effective crew management. On the one hand, communication is often the means or the tool by which team members manage their resources, solve problems, maintain situational awareness and procedural discipline. Conversely, it is the lack of planning and resource management, loss of vigilance and situational awareness, and non-standard communications that are implicated in accidents and incidents. NASA/Ames Crew Factors researchers have been developing a model of effective crew coordination in order to understand the sources of performance breakdowns, and to develop effective solutions and interventions. Because communication is a primary mechanism by which information is received and transmitted, and because it is observable behavior, we focus on these group processes in order to identify patterns of communication that distinguish effective from less effective crew performance. Since a prime objective is to develop training recommendations for enhancing communication skills, we interpret our findings in the context of relevant task and environmental conditions, role and procedural constraints, and the normal real-time parameters of flight operations. Another research objective is to consider how communication and coordination can be enhanced through design. For example, flight deck and hardware design as well as procedural and software design may greatly influence the efficiency with which crews communicate and coordinate their work. In addition, teams and tasks may be designed, organized, and trained so that team interactions with each other are based upon appropriately shared knowledge, procedures and situation awareness. In short, we are interested in enhancing communication practices through (1) the training of specific communication skills, and (2) the design of equipment, tasks, procedures, and teams that optimize smooth, unambiguous communication processes. Two examples of communication research will be described; one in aviation and one in space operations. The first example is a high-fidelity full mission simulation study which investigates the affect of flightdeck automation on crew coordination and communication (contrasting crew performance in the DC-9 vs. MD88). Additional information is contained in the original extended abstract.

Kanki, Barbara G.↗

Small Particle Response to Fluid Motion Using Tethered Particles to Simulate Microgravity

This paper reports on ground based work conducted to support the Spaceflight Definition project SHIVA (Spaceflight Holography Investigation in a Virtual Apparatus). SHIVA will advance our understanding of the movement of a particle in a fluid. Gravity usually dominates the equations of motion, but in microgravity as well as on earth other terms can become important. Through an innovative application of fractional differential equations, two members of our team produced the first analytical solution of a fundamental equation of motion, which had only been solved numerically or by approximation before. The general solution predicts that the usually neglected history term becomes important in particle response to a sinusoidal fluid movement when the characteristic viscous time is in the same order as the fluid oscillation period and peaks when the two times are equal. In this case three force terms, the Stokes drag, the added mass, and the history drag must all be included in predicting particle movement. We have developed diagnostic recording methods using holography to save all of the particle field data, allowing the experiment to essentially be transferred from space back to earth in what we call the virtual apparatus for on-earth microgravity experimentation. We can quantify precisely the three-dimensional motion of sets of particles, allowing us to test and apply the new analytical solutions. We are examining the response of particles up to 2 mm radius to fluid oscillation at frequencies up to 80 Hz with amplitudes up to 200 microns. Ground studies to support the flight development program have employed various schemes to simulate microgravity. One of the most reliable and meaningful methods uses spheres tethered to a fine hair suspended in the fluid. We have also investigated particles with nearly neutral buoyancy. Recordings are made at the peak amplitudes of vibration of the cell providing a measure of the ratio of fluid to particle amplitude. The experiment requires precise location of the particle to within microns during recording, and techniques for achieving this are one of the project challenges. Focused microscopic images and diffraction patterns are used. To make the experiment more versatile, the spaceflight system will record holograms both on film and electronically. A cross correlation procedure enables sub pixel accuracies for electronic recordings, partially accommodating the lower spatial resolution of CCDs. The electronic holograms can be down linked providing real time data. Results of the ground experiments, the flight experiment design, and data analysis procedures are reported.

Trolinger, James↗

ISS Wastewater Pretreatment via DNA Pattern Picofilter Using Inorganic Brine Stimulant

Astronauts in the International Space Station (ISS) need as much water as they can access, whether it comes from people's breath, sweat or urine, recycled shower water or hand washing. It is of vital importance that any type of water is recycled and filtrated through different methods so it can be re-used. Recently, Cerahelix Inc. offered a ceramic tubular membrane element that uses DNA strands as a pattern in a sol-gel process that allows the sintered product to have a pore size in the picometer scale and claims to achieve ten times higher purity than other commercially available ceramic filters. This should allow higher purities and yields at reduced energy costs and theoretically allow near total dewatering of the reject stream and greater than 80% removal of polyvalent ions. Trials were performed with Cerahelix Inc. filters using an inorganic brine simulant at two pHs to test the efficiency of Pico Helix TM membranes and determine their feasibility for spacecraft wastewater treatment processes. Emphasis was placed on the polyvalent ions: SO42-, PO43-, Mg2+, and Ca2+. These ions should be rejected almost entirely from the feed solution and, not permeate through the filter. Results show that at a pH of 4.2, permeation of the polyvalent ions varied from 59% to 74% and at pH of 8.0, permeation varied from 72% to 87%. An Extended Nernst Planck (ENP) approach that describes the mass transfer process for a pico-filtration membrane was used to construct a model to inform the experimental expectations and outcome.

Carolina Franco↗

Laser Opto-Electronic Correlator for Robotic Vision Automated Pattern Recognition

A compact laser opto-electronic correlator for pattern recognition has been designed, fabricated, and tested. Specifically it is a translation sensitivity adjustable compact optical correlator (TSACOC) utilizing convergent laser beams for the holographic filter. Its properties and performance, including the location of the correlation peak and the effects of lateral and longitudinal displacements for both filters and input images, are systematically analyzed based on the nonparaxial approximation for the reference beam. The theoretical analyses have been verified in experiments. In applying the TSACOC to important practical problems including fingerprint identification, we have found that the tolerance of the system to the input lateral displacement can be conveniently increased by changing a geometric factor of the system. The system can be compactly packaged using the miniature laser diode sources and can be used in space by the National Aeronautics and Space Administration (NASA) and ground commercial applications which include robotic vision, and industrial inspection of automated quality control operations. The personnel of Standard International will work closely with the Jet Propulsion Laboratory (JPL) to transfer the technology to the commercial market. Prototype systems will be fabricated to test the market and perfect the product. Large production will follow after successful results are achieved.

Laser Opto-Electronic↗

Evidence for autotrophic growth of purple sulfur bacteria using pyrite as electron and sulfur source

ABSTRACT Purple sulfur bacteria (PSB) are capable of anoxygenic photosynthesis via oxidizing reduced sulfur compounds and are considered key drivers of the sulfur cycle in a range of anoxic environments. In this study, we show that Allochromatium vinosum (a PSB species) is capable of autotrophic growth using pyrite as the electron and sulfur source. Comparative growth profile, substrate characterization, and transcriptomic sequencing data provided valuable insight into the molecular mechanisms underlying the bacterial utilization of pyrite and autotrophic growth. Specifically, the pyrite-supported cell cultures (“py”’) demonstrated robust but much slower growth rates and distinct patterns from their sodium sulfide-amended positive controls. Up to ~200-fold upregulation of genes encoding various c - and b -type cytochromes was observed in “py,” pointing to the high relevance of these molecules in scavenging and relaying electrons from pyrite to cytoplasmic metabolisms. Conversely, extensive downregulation of genes related to LH and RC complex components indicates that the electron source may have direct control over the bacterial cells’ photosynthetic activity. In terms of sulfur metabolism, genes encoding periplasmic or membrane-bound proteins (e.g., FccAB and SoxYZ) were largely upregulated, whereas those encoding cytoplasmic proteins (e.g., Dsr and Apr groups) are extensively suppressed. Other notable differentially expressed genes are related to flagella/fimbriae/pilin(+), metal efflux(+), ferrienterochelin(−), and [NiFe] hydrogenases(+). Characterization of the biologically reacted pyrite indicates the presence of polymeric sulfur. These results have, for the first time, put the interplay of PSB and transition metal sulfide chemistry under the spotlight, with the potential to advance multiple fields, including metal and sulfur biogeochemistry, bacterial extracellular electron transfer, and artificial photosynthesis. IMPORTANCE Microbial utilization of solid-phase substrates constitutes a critical area of focus in environmental microbiology, offering valuable insights into microbial metabolic processes and adaptability. Recent advancements in this field have profoundly deepened our knowledge of microbial physiology pertinent to these scenarios and spurred innovations in biosynthesis and energy production. Furthermore, research into interactions between microbes and solid-phase substrates has directly linked microbial activities to the surrounding mineralogical environments, thereby enhancing our understanding of the relevant biogeochemical cycles. Our study represents a significant step forward in this field by demonstrating, for the first time, the autotrophic growth of purple sulfur bacteria using insoluble pyrite (FeS2) as both the electron and sulfur source. The presented comparative growth profiles, substrate characterizations, and transcriptomic sequencing data shed light on the relationships between electron donor types, photosynthetic reaction center activities, and potential extracellular electron transfer in these organisms capable of anoxygenic photosynthesis. Furthermore, the findings of our study may provide new insights into early-Earth biogeochemical evolutions, offering valuable constraints for understanding the environmental conditions and microbial processes that shaped our planet’s history.

59 BASIC BIOLOGICAL SCIENCES↗

Cu(II) Stability and UV-Induced Electron Transfer in a Metal–Organic Hybrid: An EPR, DFT, and Crystallographic Characterization of Copper-Doped Zinc Creatininium Sulfate

Single-crystal X-ray diffraction and electron paramagnetic resonance (EPR) spectroscopic experiments, complemented by quantum chemical DFT calculations, were carried out on the copper-doped metal–organic hybrid and Tutton salt analogue zinc creatininium sulfate to determine its crystal structure, to characterize the electronic structure of the doped Cu(II) binding site, and to propose a pathway for an excited-state, proton-coupled electron transfer (PCET) process in UV-exposed crystals. The crystal structure is isomorphous to that of cadmium creatininium sulfate, which has the transition ion, not in direct coordination with the creatinine, but forming a hexahydrate complex, which is bridged to a creatininium through an intervening sulfate ion. The EPR g (2.446, 2.112, 2.082) and copper hyperfine (A Cu : -327, -59.6, 10.8 MHz) tensor parameters are consistent with doped copper replacing host zinc in the metal–hexahydrate complex. These parameters are similar to those observed for copper hexahydrate in doped Tutton salt systems at low temperature, where the unpaired electron occupies mainly the copper 3d x 2 –y 2 orbital. At room temperature in the Tutton systems, vibration couplings stemming from a dynamic Jahn–Teller effect cause tensor averaging which results in a reduction in their maximum g-tensor and hyperfine tensor values. However, like for the doped isomorphous Cd creatinine crystal, the Cu(II) EPR exhibits little, or no room temperature averaging compared to its low temperature pattern. Samples exposed to 254 nm UV light generate a carbon-centered free radical species, characterized by an isotropic g-tensor (g = 2.0029) and an alpha-proton hyperfine coupling (-24 -14 +4 G). These parameters identify it as a creatinine radical cation formed by the oxidative release of one of its C2 methylene hydrogens. DFT calculations confirm the unpaired electronic structures of both the Cu(II) site and free radical. The growth in radical concentration with an increase in the UV exposure time coincides with a decrease in the copper EPR signal, indicating a coupled light-induced oxidation reduction process. A comparison of the crystal structure with the EPR parameters and DFT results provides evidence for a UV-induced PCET.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Editorial: Forest Rhizosphere Interactions: Cascading Consequences for Ecosystem-Level Carbon and Nutrient Cycling

Mycorrhizal fungimine organicmatter and subsequently transfer plant-available nutrients to roots. While there is disagreement considering the role of mycorrhizal fungi in ecosystem carbon (C) and nutrient cycling relative to factors such as climate (Cotton, 2018; Bennett and Classen, 2020), soil nutrient availability (Brzostek et al., 2015; Frey, 2019), or host plant community composition (Read and Perez-Moreno, 2003), it is now clear that mycorrhizal fungal symbionts control a substantial proportion of C and nutrient flow belowground (Steidinger et al., 2019). Yet, determining the relative importance of arbuscular mycorrhizal (AM) and ectomycorrhizal (EM) fungi to these processes is still an open field of inquiry in ecosystemecology (Averill et al., 2019a) and earth system modeling (Sulman et al., 2019). At large scales, ecosystems dominated by EM fungi are thought to store more soil C per unit nitrogen (N) (Averill et al., 2014), have slower N cycles (Phillips et al., 2013), and respond more strongly to global change drivers such as N-deposition (Jo et al., 2019). However, it is unclear how generalizable these patterns are across sites, and plant and mycorrhizal taxa. If site or species-dependent relationships exist between mycorrhizal plants, fungi, and soil biogeochemical cycles, forecasting hot spots and hot moments of mycorrhizal fungal activities and their consistency across space and time would be evenmore challenging (Averill et al., 2019b; Kivlin and Hawkes, 2020).

54 ENVIRONMENTAL SCIENCES↗

Antiferromagnetic Semiconductor BaFMn 0.5 Te with Unique Mn Ordering and Red Photoluminescence

Semiconductors possessing both magnetic and optoelectronic properties are rare and promise applications in opto-spintronics. In this work, we report the mixed-anion semiconductor BaFMn 0.5 Te with a band gap of 1.76 eV and a work function of 5.08 eV, harboring both antiferromagnetism (AFM) and strong red photoluminescence (PL). The synthesis of BaFMn 0.5 Te in quantitative yield was accomplished using the "panoramic synthesis" technique and synchrotron radiation to obtain the full reaction map, from which we determined that the compound forms upon heating at 850 degrees C via an intermediate unknown phase. The structure refinement required the use of a (3+1)-dimensional superspace group Cmme(alpha 01/2)0ss. The material crystallizes into a ZrCuSiAs-like structure with alternating [BaF] + and [Mn0.5Te] - layers and has a commensurately modulated structure with the q-vector of 1/6a* + 1/6b* + 1/2c* at room temperature arising from the unique ordering pattern of Mn 2+ cations. Long-range AFM order emerges below 90 K, with two-dimensional short-range AFM correlations above the transition temperature. First-principles calculations suggest that BaFMn 0.5 Te is an indirect band gap semiconductor with the gap opening between Te 5p and Mn 3d orbitals, and the magnetic interactions between nearest-neighbor Mn 2+ atoms are antiferromagnetic. Steady-state PL spectra show a broad strong emission centered at similar to 700 nm, which we believe originates from the energy manifolds of the modulated Mn 2+ sublattice and its defects. Time-resolved PL measurements reveal an increase in excited-state lifetimes with longer probe wavelengths, from 93 ns (at 650 nm) to 345 ns (at 800 nm), and a delayed growth (6.5 ± 0.3 ns) in the kinetics at 800 nm with a concomitant decay (4.1 ± 0.1 ns) at 675 nm. Together, these observations predict that there are multiple emissive states, with higher energy states populating lower energy states by energy transfer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Application of Remote Sensing Data to GIS Studies of Land Use, Land Cover, and Vegetation Mapping in the State of Hawaii

A land cover-vegetation map with a base classification system for remote sensing use in a tropical island environment was produced of the island of Hawaii for the State of Hawaii to evaluate whether or not useful land cover information can be derived from Landsat TM data. In addition, an island-wide change detection mosaic combining a previously created 1977 MSS land classification with the TM-based classification was produced. In order to reach the goal of transferring remote sensing technology to State of Hawaii personnel, a pilot project was conducted while training State of Hawaii personnel in remote sensing technology and classification systems. Spectral characteristics of young island land cover types were compared to determine if there are differences in vegetation types on lava, vegetation types on soils, and barren lava from soils, and if they can be detected remotely, based on differences in pigments detecting plant physiognomic type, health, stress at senescence, heat, moisture level, and biomass. Geographic information systems (GIS) and global positioning systems (GPS) were used to assist in image rectification and classification. GIS was also used to produce large-format color output maps. An interactive GIS program was written to provide on-line access to scanned photos taken at field sites. The pilot project found Landsat TM to be a credible source of land cover information for geologically young islands, and TM data bands are effective in detecting spectral characteristics of different land cover types through remote sensing. Large agriculture field patterns were resolved and mapped successfully from wildland vegetation, but small agriculture field patterns were not. Additional processing was required to work with the four TM scenes from two separate orbits which span three years, including El Nino and drought dates. Results of the project emphasized the need for further land cover and land use processing and research. Change in vegetation composition was noted in the change detection image.

Hogan, Christine A.↗

The Role of Flux Transfer Events in Solar Wind-Magnetosphere Coupling

Recent global MHD simulations of Flux Transfer Events (FTE's)[Dorelli and Bhattachar ee, JGR, 114, 2009] demonstrate that they are topologically complex flux ropes which extend large distances away from the subsolar magnetopause. Thus, FTE's represent a significant perturbation to the magnetopause magnetic field topology. Specifically, prior to the formation of the first FTE of the simulation, the dayside magnetopause has a relatively simple topology consisting of a single magnetic separator draping northward (even for southward IMF) over the dayside magnetopause (in a manner similar to the "overdraping" which occurs under northward IMF conditions). After the first FTE forms, however, the magnetopause becomes topologically more complex, consisting of multiple separators and braided flux domains. One consequence of this topological complexity is that open flux tubes have direct access to the magnetosphere near the subsolar region (such direct access is not possible during steady separator reconnection). Since the magnetopause topology affects the mapping of the solar wind electric field to the magnetosphere, an interesting question arises: What is the effect of FTE generation on the global magnetospheric convection pattern? In this talk, we address this question by exploring the differences between magnetospheric and ionospheric convection before and after the formation of the first FTE of the simulation.

Dorelli, John C.↗

Operando FTIR Studies of Electrolyte Solution Structures and Dynamics at Electrode-Electrolyte Interfaces

The well-stabilized electrode-electrolyte interface (EEI) is critical to battery performance and safety, thus understanding the electrolyte solution structures (e.g., ion solvation and ionic association) and dynamics within EEI is an important area of study. Unfortunately, due to the sensitive nature of the electrodes, ex-situ characterization methods are limited and challenging to interpret as chemical and structural changes occur upon deconstructing the cell. In this work, we present operando characterization of near-surface electrolyte solution structures and dynamics by ATR-FTIR spectroscopy during battery cycling. We studied two selected model electrodes, a lithium nickel manganese cobalt oxide (NMC) or a planar silicon (Si), in a standard Gen2 electrolyte of 1.2 M LiPF6 in ethylene carbonate (EC):ethyl methyl carbonate (EMC) (3:7 wt%). In the former case, the composite cathode on aluminum foil is placed face-down on an ATR crystal. A ring of lithium metal serves as the counter/reference electrode and no separator is required. In the latter case, a lightly doped p-type silicon wafer is phosphorous-doped at the surface to increase the conductivity of the sample without compromising infrared transparency. The ATR crystal is then pressed on the back of the silicon with a minimal air gap to ensure sufficient optical contact between the two materials. The front of wafer is then placed in a modified coin-type cell geometry with a minimal electrolyte, a separator, and a lithium metal counter/reference electrode. In both experiments, we analyze the electrolyte solution structures within the EEI and find similar patterns as a function of potential. Firstly, we find that EMC decomposes faster than EC -suggesting that EMC plays a greater role in the electrochemical reactions on the electrode surface (e.g., formation of a protective layer to prevent further electrolyte decomposition). Secondly, we monitor the increase/decrease of the vibrational absorption peaks attributed to carbonates coordinated with Li+ ions relative to the decrease/increase of their uncoordinated counterparts, as expected when changing the local concentration of Li+ ions near the electrode surface during deintercalation/intercalation into the electrode. Finally, we observe that the features assigned to the Li+-PF6 -/-solvent molecules contact ion pair relative to the uncoordinated PF6 - anion. These observations give important information regarding the electrolyte solution structures and dynamics near the electrode surfaces. We look forward to applying these techniques to additional lithiumion battery systems with different cathode or anode materials and beyond lithium-ion systems to characterize surface chemistry/evolution (on-going research) and solution structures/dynamics (in particular, (de)solvation behaviors) within the EEI, which can be a bottleneck to efficient ion transfer from the electrolyte to the electrode.

14 SOLAR ENERGY↗

NASA Tech Briefs, September 2007

Topics covered include; Rapid Fabrication of Carbide Matrix/Carbon Fiber Composites; Coating Thermoelectric Devices To Suppress Sublimation; Ultrahigh-Temperature Ceramics; Improved C/SiC Ceramic Composites Made Using PIP; Coating Carbon Fibers With Platinum; Two-Band, Low-Loss Microwave Window; MCM Polarimetric Radiometers for Planar Arrays; Aperture-Coupled Thin-Membrane L-Band Antenna; WGM-Based Photonic Local Oscillators and Modulators; Focal-Plane Arrays of Quantum-Dot Infrared Photodetectors; Laser Range and Bearing Finder With No Moving Parts; Microrectenna: A Terahertz Antenna and Rectifier on a Chip; Miniature L-Band Radar Transceiver; Robotic Vision-Based Localization in an Urban Environment; Programs for Testing an SSME-Monitoring System; Cathodoluminescent Source of Intense White Light; Displaying and Analyzing Antenna Radiation Patterns; Payload Operations Support Team Tools; Space-Shuttle Emulator Software; Soft Real-Time PID Control on a VME Computer; Analyzing Radio-Frequency Coverage for the ISS; Nanorod-Based Fast-Response Pressure-Sensitive Paints; Capacitors Would Help Protect Against Hypervelocity Impacts; Diaphragm Pump With Resonant Piezoelectric Drive; Improved Quick-Release Pin Mechanism; Designing Rolling-Element Bearings; Reverse-Tangent Injection in a Centrifugal Compressor; Inertial Measurements for Aero-assisted Navigation (IMAN); Analysis of Complex Valve and Feed Systems; Improved Path Planning Onboard the Mars Exploration Rovers; Robust, Flexible Motion Control for the Mars Explorer Rovers; Solar Sail Spaceflight Simulation; Fluorine-Based DRIE of Fused Silica; Mechanical Alloying for Making Thermoelectric Compounds; Process for High-Rate Fabrication of Alumina Nanotemplates; Electroform/Plasma-Spray Laminates for X-Ray Optics; An Automated Flying-Insect Detection System; Calligraphic Poling of Ferroelectric Material; Blackbody Cavity for Calibrations at 200 to 273 K; KML Super Overlay to WMS Translator; High-Performance Tiled WMS and KML Web Server; Modeling of Radiative Transfer in Protostellar Disks; Composite Pulse Tube; Photometric Calibration of Consumer Video Cameras; Criterion for Identifying Vortices in High- Pressure Flows; Amplified Thermionic Cooling Using Arrays of Nanowires; Delamination-Indicating Thermal Barrier Coatings; Preventing Raman Lasing in High-Q WGM Resonators; Procedures for Tuning a Multiresonator Photonic Filter; Robust Mapping of Incoherent Fiber-Optic Bundles; Extended-Range Ultrarefractive 1D Photonic Crystal Prisms; Rapid Analysis of Mass Distribution of Radiation Shielding; Modeling Magnetic Properties in EZTB; Deep Space Network Antenna Logic Controller; Modeling Carbon and Hydrocarbon Molecular Structures in EZTB; BigView Image Viewing on Tiled Displays; and Imaging Sensor Flight and Test Equipment Software.

Source record↗

R and D work on the constrained vapor bubble system for a microgravity experiment

We are working with Project Scientists R. Balasubramanian and Sang Young Son, and a NASA Projects Team headed by Sue Motil at the Glenn Research Center on the design and development of an experimental system for use on the International Space Station during the year 2006. John Eustace is the coordinator for the flight experiment at Zin-Tech (previously Northrop-Grumman) for the design and development of the Constrained Vapor Bubble Heat Exchanger, CVBHX, cell which will fit into the Light Microscope Module, LMM. Good progress is being made. The CDR for the LMM being developed was held on December 10-1 1,2003. Experimental results obtained under microgravity conditions will be compared with those obtained at Rensselaer. Basic and applied research at Rensselaer continues on the experimental and theoretical details associated with passive phase change heat transfer processes controlled by interfacial forces in the CVBHX. The extensive results of our current research are presented in the 23 external publications listed below. Twenty-two external presentations have been given. Briefly, evaporation/condensation data from both vertical and horizontal CVBHX systems were obtained and analyzed for both polar (wetting) and apolar (partially wetting) fluids. The vertical system is axi-symmetric, but strongly effected by gravity. Whereas, the horizontal system is asymmetric, but weakly effected by gravity. Therefore, there will be significant differences in the operation of the cell in the earth s environment versus the operation under microgravity conditions. Due to its relative large size, the system s performance should be optimum under micro-gravity conditions, where the CVBHX should be a very effective passive heat exchanger. The CVBHX was found to be an ideal experimental setup in which to study the effects of interfacial phenomena on both the evaporation and drop-wise condensation processes. The optical technique (Image Analyzing Interferometry, IAI), which is based on the measurement and analysis of the reflectivity pattern of a thin film, was significantly improved. The accuracy of the IAI system is of critical importance to the success of the mission because it is used to measure the details of the pressure field in the liquid by measuring the film thickness profile. The accuracy was found to be excellent and various publications/presentations documenting these new results were written. Significant new results were also obtained for the effect of the oscillating contact line region on evaporation. Three doctoral students graduated under this grant. All three work in US industry, two for Intel. Another doctoral student is in his third year of study and will finish under an extension of the NASA grant: # NNC05GA27G.

Wayner, P. C., Jr.↗

NASA Tech Briefs, September 2006

Topics covered include: Improving Thermomechanical Properties of SiC/SiC Composites; Aerogel/Particle Composites for Thermoelectric Devices; Patches for Repairing Ceramics and Ceramic- Matrix Composites; Lower-Conductivity Ceramic Materials for Thermal-Barrier Coatings; An Alternative for Emergency Preemption of Traffic Lights; Vehicle Transponder for Preemption of Traffic Lights; Automated Announcements of Approaching Emergency Vehicles; Intersection Monitor for Traffic-Light-Preemption System; Full-Duplex Digital Communication on a Single Laser Beam; Stabilizing Microwave Frequency of a Photonic Oscillator; Microwave Oscillators Based on Nonlinear WGM Resonators; Pointing Reference Scheme for Free-Space Optical Communications Systems; High-Level Performance Modeling of SAR Systems; Spectral Analysis Tool 6.2 for Windows; Multi-Platform Avionics Simulator; Silicon-Based Optical Modulator with Ferroelectric Layer; Multiplexing Transducers Based on Tunnel-Diode Oscillators; Scheduling with Automated Resolution of Conflicts; Symbolic Constraint Maintenance Grid; Discerning Trends in Performance Across Multiple Events; Magnetic Field Solver; Computing for Aiming a Spaceborne Bistatic- Radar Transmitter; 4-Vinyl-1,3-Dioxolane-2-One as an Additive for Li-Ion Cells; Probabilistic Prediction of Lifetimes of Ceramic Parts; STRANAL-PMC Version 2.0; Micromechanics and Piezo Enhancements of HyperSizer; Single-Phase Rare-Earth Oxide/Aluminum Oxide Glasses; Tilt/Tip/Piston Manipulator with Base-Mounted Actuators; Measurement of Model Noise in a Hard-Wall Wind Tunnel; Loci-STREAM Version 0.9; The Synergistic Engineering Environment; Reconfigurable Software for Controlling Formation Flying; More About the Tetrahedral Unstructured Software System; Computing Flows Using Chimera and Unstructured Grids; Avoiding Obstructions in Aiming a High-Gain Antenna; Analyzing Aeroelastic Stability of a Tilt-Rotor Aircraft; Tracking Positions and Attitudes of Mars Rovers; Stochastic Evolutionary Algorithms for Planning Robot Paths; Compressible Flow Toolbox; Rapid Aeroelastic Analysis of Blade Flutter in Turbomachines; General Flow-Solver Code for Turbomachinery Applications; Code for Multiblock CFD and Heat-Transfer Computations; Rotating-Pump Design Code; Covering a Crucible with Metal Containing Channels; Repairing Fractured Bones by Use of Bioabsorbable Composites; Kalman Filter for Calibrating a Telescope Focal Plane; Electronic Absolute Cartesian Autocollimator; Fiber-Optic Gratings for Lidar Measurements of Water Vapor; Simulating Responses of Gravitational-Wave Instrumentation; SOFTC: A Software Correlator for VLBI; Progress in Computational Simulation of Earthquakes; Database of Properties of Meteors; Computing Spacecraft Solar-Cell Damage by Charged Particles; Thermal Model of a Current-Carrying Wire in a Vacuum; Program for Analyzing Flows in a Complex Network; Program Predicts Performance of Optical Parametric Oscillators; Processing TES Level-1B Data; Automated Camera Calibration; Tracking the Martian CO2 Polar Ice Caps in Infrared Images; Processing TES Level-2 Data; SmaggIce Version 1.8; Solving the Swath Segment Selection Problem; The Spatial Standard Observer; Less-Complex Method of Classifying MPSK; Improvement in Recursive Hierarchical Segmentation of Data; Using Heaps in Recursive Hierarchical Segmentation of Data; Tool for Statistical Analysis and Display of Landing Sites; Automated Assignment of Proposals to Reviewers; Array-Pattern-Match Compiler for Opportunistic Data Analysis; Pre-Processor for Compression of Multispectral Image Data; Compressing Image Data While Limiting the Effects of Data Losses; Flight Operations Analysis Tool; Improvement in Visual Target Tracking for a Mobile Robot; Software for Simulating Air Traffic; Automated Vectorization of Decision-Based Algorithms; Grayscale Optical Correlator Workbench; "One-Stop Shopping" for Ocean Remote-Sensing and Model Data; State Analysis Database Tool; Generating CAHV and CAHVOmages with Shadows in ROAMS; Improving UDP/IP Transmission Without Increasing Congestion; FORTRAN Versions of Reformulated HFGMC Codes; Program for Editing Spacecraft Command Sequences; Flight-Tested Prototype of BEAM Software; Mission Scenario Development Workbench; Marsviewer; Tool for Analysis and Reduction of Scientific Data; ASPEN Version 3.0; Secure Display of Space-Exploration Images; Digital Front End for Wide-Band VLBI Science Receiver; Multifunctional Tanks for Spacecraft; Lightweight, Segmented, Mostly Silicon Telescope Mirror; Assistant for Analyzing Tropical-Rain-Mapping Radar Data; and Anion-Intercalating Cathodes for High-Energy- Density Cells.

Source record↗

When can we detect lianas from space? Toward a mechanistic understanding of liana‐infested forest optics

Abstract Lianas, woody vines acting as structural parasites of trees, have profound effects on the composition and structure of tropical forests, impacting tree growth, mortality, and forest succession. Remote sensing could offer a powerful tool for quantifying the scale of liana infestation, provided the availability of robust detection methods. We analyze the consistency and global geographic specificity of spectral signals—reflectance across wavelengths—from liana‐infested tree crowns and forest stands, examining the underlying mechanisms of these signals. We compiled a uniquely comprehensive database, including leaf reflectance spectra from 5424 leaves, fine‐scale airborne reflectance data from 999 liana‐infested canopies, and coarse‐scale satellite reflectance data covering 775 ha of liana‐infested forest stands. To unravel the mechanisms of the liana spectral signal, we applied mechanistic radiative transfer models across scales, establishing a synthesis of the relative importance of different mechanisms, which we corroborate with field data on liana leaf chemistry and canopy structure. We find a consistent liana spectral signal at canopy and stand scales across globally distributed sites. This signature mainly arises at the canopy level due to direct effects of more horizontal leaf angles, resulting in a larger projected leaf area, and indirect effects from increased light scattering in the near and short‐wave infrared regions, linked to lianas' less costly leaf construction compared with trees on average. The existence of a consistent global spectral signal for lianas suggests that large‐scale quantification of liana infestation is feasible. However, because the traits responsible for the liana canopy‐reflectance signal are not exclusive to lianas, accurate large‐scale detection requires rigorously validated remote sensing methods. Our models highlight challenges in automated detection, such as potential misidentification due to leaf phenology, tree life history, topography, and climate, especially where the scale of liana infestation is less than a single remote sensing pixel. The observed cross‐site patterns also prompt ecological questions about lianas' adaptive similarities in optical traits across environments, indicating possible convergent evolution due to shared constraints on leaf biochemical and structural traits.

Environmental Sciences & Ecology↗

Extending XBAER Algorithm to Aerosol and Cloud Condition

The retrieval of cloud optical properties for aerosol contaminated water cloud is challenging because of the complexity of physical processes in such situations. Conventionally, cloud optical data products are typically derived, ignoring the aerosol impacts on radiative transfer in the retrieval process. This is potentially a significant source of error. In this paper, the eXtensible Bremen Aerosol Retrieval (XBAER) algorithm has been optimized for the retrieval of aerosol/cloud properties for the aerosol contaminated cloud (ACC) scenarios. This version of XBAER delivers cloud optical thickness (COT) and cloud effective radius (CER) for ACCs and simultaneously retrieves aerosol optical thickness (AOT). The surface parameterization and aerosol types used in the standard XBAER algorithm have been adapted in this retrieval to account for the ACC conditions. Aerosol types in XBAER for the retrieval of ACC scenarios have been parameterized to comprise weak and strong absorptions. The comparisons of COT, CER, and AOT retrieved using this adapted XBAER algorithm and two new NASA algorithms show good agreements, especially for biomass burning aerosol. The correlation coefficients are >0.9 for AOT, ~0.8 for CER, and ~0.7 for COT. There is also a good agreement for dust plume contaminated cloud scene. The XBAER derived AOT values for dust aerosols are systematically smaller than the NASA retrieval, but both products have the same spatial distribution patterns. The comparison of COT retrieved using the adapted XBAER algorithm and that retrieved from ground-based microwave radiometer (MWR) measurements shows much better agreement for ACC conditions with high AOT.

satellite↗