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At least 1,081 records · Page 60

The crystallisation trends of spinels in tertiary basalts from Rhum and Muck and their petrogenetic significance

Spinels found in transitional olivine basalts from the Islands of Rhum and Muck in the British Tertiary Province are analyzed to determine their chemical variability and their relationship to silicate phases. Chemical zoning of the cores of spinels which spilled into the basaltic liquid may be due to a reaction between the spinel and the liquid resulting in more Fe- and Ti-rich spinels. In addition, a peritectic-type reaction seems to have occurred, causing the transformation of aluminum spinel to chrome spinel with precipitation of plagioclase. Changes in the basaltic liquid are reflected by these transformations in the spinel composition.

Ridley, W. I.↗

Chemical weathering on Mars - Thermodynamic stabilities of primary minerals /and their alteration products/ from mafic igneous rocks

Chemical weathering on Mars is examined theoretically from the standpoint of thermodynamic equilibrium between primary rock-forming minerals and the atmospheric gases O2, H2O, and CO2. The primary minerals considered are those common to mafic igneous rocks and include olivine, pyroxene, plagioclase, magnetite, troilite, pyrrhotite, and apatite. The importance of kinetics and reaction mechanisms in controlling possible weathering processes on Mars is discussed within the limits of currently available data, and the possible influence of liquid water on Martian weathering processes is evaluated where appropriate. For gas-solid weathering of mafic igneous rocks at the Martian surface, it is concluded that upon attainment of thermodynamic equilibrium: (1) oxides and carbonates should dominate the mineral assemblage of weathering products; (2) hematite rather than goethite should be the stable mineral form of Fe (III); (3) FeSO4 or FeSO4.H2O could be the stable weathering product of iron sulfides in the absence of liquid water; and (4) kaolinite is apparently the only clay mineral that should be thermodynamically stable over all ranges of temperature and water-vapor abundance at the Martian surface.

Gooding, J. L.↗

A test of the comet hypothesis of the Tunguska Meteor Fall - Nature of the meteor 'thermal' explosion paradox

The hypothesis that a comet was responsible for the Tunguska Meteor Fall is rejected because the hypothesis does not seem to account for the intense terminal spherical shock. A porous meteoroid model is proposed, and an analysis indicates that an entity of this type might produce an aerodynamic heat flux large enough to account for the terminal meteor explosion. It is suggested that the presence of olivine and of highly irregular macrostructure in meteors might indicate the presence of some porosity. For a highly porous meteoroid, it is postulated that during entry into the atmosphere the aerodynamic heat transfer at its external or pore walls would become so intensified as to cause either complete ablation with popping or a solid-liquid-vapor phase transition accompanied by an explosion.

Liu, V. C.↗

Tysnes Island - An unusual clast composed of solidified, immiscible, Fe-FeS and silicate melts

An inclusion found in the Tysnes Island gas-rich H4 chondrite is described. The clast consists of two distinct portions, separated by a smooth boundary; the portions are a tear-drop shaped Fe-FeS eutecticlike intergrowth (0.5 cm greatest dimension) and a silicate consisting primarily of olivine in glass. Nickel enrichment is found in the metal at the metal-sulfide boundaries and in nodules within the metal. It is thought that the portions separated from one another as immiscible liquids and that the modal composition of each portion agrees with the compositions predicted for a total melt of an H-group chondrite. The inclusion is discussed in terms of the process of metal-silicate fractionation suggested by Fodor and Keil (1976).

Wilkening, L. L.↗

The Inman, McPherson County, Kansas meteorite

The Inman meteorite (find, 1966) is a single relatively unweathered stone of 7.25 kg that contains fresh metal and only a few weathering products away from fractures. It has a pronounced chondritic texture, with 38 vol% of the meteorite being made up of chondrules of virtually all textural types. The recalculated bulk analysis, in particular ratios involving iron content, indicate that Inman is an L-group chondrite. The pronounced chondritic texture; the compositional variation of olivine, pyroxene, chromite, and ilmenite; and the presence of a fine-grained nearly opaque matrix, glass, and twinned monoclinic low-Ca pyroxene indicate that the chondrite belongs to petrologic type 3.

Keil, K.↗

Infrared /JHK/ photometry of meteorites and asteroids

The paper reports JHK colors observed for ten asteroids and synthesized JHK colors for seven meteorite groups, samples of iron and nickel metal, pyroxene, olivine, feldspar, a lunar anorthite and some terrestrial mineral samples. Pronounced differences are apparent between the chondritic and achondritic meteorite classes; the chondritic classes show less subdued trends in J-H color which reflect their metamorphic grade. We find small but significant differences between the JHK colors of the predominant C and S classes of asteroids. All JHK colors of asteroids observed here fall within the limited domain defined by the various chondritic and iron-rich meteorites but are strikingly different from those of most achondritic meteorites.

Leake, M.↗

Petrology of Apollo 15 black-and-white rocks 15445 and 15455 - Fragments of the Imbrium impact melt sheet

The paper describes two macroscopically similar black-and-white rocks, 15445 and 15455, which were collected from the rim of Spur Crater on the Apennine Front. The two Apollo 15 rocks are very similar in chemistry and clast population, but the matrix of 15455 is finer grained than that of 15445. The 15445 sample contains a lithic clast assemblage of plutonic/metamorphic spinel troctolite, troctolite, norite, and anorthosite, and its fine-grained vesicular black coherent matrix consists of a melt-bonded aggregate of small mineral clasts which are mainly olivine, plagioclase, and pink spinel. The two rocks are distinct from any other large samples from the Apollo 15 site. It is suggested that the rocks are samples of an impact melt sheet which forms a bedrock unit of the Apennine Front, and that this melt sheet did not form in a local small-scale event but was produced during the Imbrium impact event.

Ryder, G.↗

Apollo 15 breccia rake samples - Mineralogy of lithic and mineral clasts

Major features of 22 Apollo 15 breccia rake samples and 30 lithic clasts in these samples are described. The range of compositions of exsolved pyroxene grains (bulk and individual lamellae) indicates a slowly cooled mare basalt source. In terms of these data the pyroxenes closely resemble pyroxenes in large anorthosite 67075. It is suggested that the pyroxene-plagioclase-olivine clast in 15146 as well as some anomalous chemical data might result from metamorphism of a mare-type basalt or from plutonic crystallization of magma with mare basalt affinity. The bulk composition of the clast in 15146 closely matches that of Apollo 15 'green glass' to which it may be related. A unique ultrabasic clast in 15360 has an unusually low CaO content and other chemical features which suggest that this sample is unlike ultrabasic samples described to date.

Steele, I. M.↗

Experimental melting relations of 63545, 76015, and 76055

The experiments discussed were conducted for the purpose of placing additional constraints on the origin of lunar highlands noritic compositions. The sample 63545 represents a fine-grained, crystalline melt rock consisting of pink spinel, plagioclase, divine, interstitial glass, minor oxides, and metal. According to Chao (1973), 76055 is an olivine-bearing micronorite hornfels with abundant xenocrysts and xenoliths. The sample 76015 is a vesicular, poikilitic impact melt with a homogeneous matrix. The obtained experimental melting relations of 63545, 76055, and 76015, are examined, taking into account experimental petrology and trace element chemistry of mare basalts. It is concluded that the studied compositions do not represent magmas derived by partial melting of either cosmic or differentiated source regions at any pressure in the moon. Presently available information would seem to favor an origin by impact-fusion of several highlands components.

Delano, J. W.↗

Petrology of four clasts from consortium breccia 73215

One felsite ('granite') and three ANT-suite anorthositic gabbro clasts extracted from breccia 73215 are described. The felsite clast has two components - fragments of crystalline felsite and veins and patches of felsic glass. The crystalline felsite, which consists largely of a vermicular intergrowth of quartz and Ba-K-feldspar, crystallized from a highly differentiated melt between 3.90 and 4.05 b.y. The felsic glass component consists of crystallized brown and colorless glasses and uncrystallized colorless glass which are all K and Si rich. The relation of glass features to past heating and the breccia-forming event is considered. In the three anorthositic gabbros, which have similar mineralogies and gradational textures, plagioclase is dominant, and olivine and orthopyroxene are the major mafic minerals. The petrologic data suggest that the gabbros formed as heated, partly melted, and/or recrystallized polymict breccias. It is possible that the approximately 4.25 b.y. age obtained for the three rocks is the date of the melting/recrystallization event.

James, O. B.↗

Provenance of Apollo 15 deep drill core sediments

Modal analysis and electron probe microanalysis were performed on polished thin sections prepared from Apollo 15 deep drill core soils in an effort to characterize their provenance. The particles were in the 0.25-1.00 mm size range. The particles were classified into mineral fragments, agglutinates, glasses, rock fragments, and breccias. The results show that highland and mare material occur in the core in an approximately 60:40 ratio, with mare component generally increasing from bottom to top in the core. Quartz-normative basalts are nearly twice as abundant as olivine basalts. Nonmare sources include KREEP basalt flow units from some depth in the crust, excavated by cratering events and supplied to the site as 'rays'.

Basu, A.↗

Petrology and geochemistry of lithic fragments separated from the Apollo 15 deep-drill core

Petrological and geochemical analysis of lithic fragments separated from the Apollo 15 deep-drill core showed these fragments to fall into the essentially the same range of rock types as observed in surface soil samples and large rock samples. Three particles are singled out as being of special interest. One sample is a mare basalt containing extremely evolved phases. The particle may represent small-scale imperfect crystal/liquid separation in a lava flow. A green glass particle is not the ultramafic emerald green glass described from the Apollo 15 site, but rather an ANT-like light green color, and has a quite different chemical composition from the ultramafic variety. One mare basalt displays a positive Eu anomaly and is enriched in plagioclase relative to olivine plus pyroxene.

Lindstrom, M. M.↗

A model for eruption behavior of a volcanic vent in eastern Mare Serenitatis

The origin is considered of droplets of ultramafic composition which are present in all soils collected from the mare surface at the Apollo 17 landing site. The droplets consist of homogeneous orange glass or their partially crystallized equivalent, the black droplets. These clastic deposits have a mean grain size of 40 micrometers. The droplet formation ages range from 3.5 to 3.83 b.y. It has been proposed that the droplets formed as a spray of low viscosity melt during lava fountaining. Based upon the thermal history as determined by studying olivine and particle shapes, two models for the formation of the sequence of droplets represented by samples 74001 and 74220 are presented. Both models assume, as proposed by Heiken et al. (1974), that the droplets were formed as a spray from a lava fountain and the compound forms were evidence for 'recycling' of solid, cooler droplets back into the fountain, encountering molten droplets before being deposited.

Heiken, G.↗

Shock compression and adiabatic release of a titaniferous mare basalt

A report is presented regarding the dynamic properties of a rock indigenous to the mare basins of the moon. The reported data were obtained in a study of sample 70215, a very titanium-rich basalt (58% pyroxene, 18% ilmenite, 15% plagioclase, 6% olivine, and 3% quartz by weight). This rock is probably representative of a class of the earliest mare-filling extrusive rocks which are exposed on the present lunar surface. Two series of experiments were performed. One set of experiments involved the measuring of Hugoniot and release adiabats to 15.7 GPa with a propellant gun apparatus. In the second set of experiments, a light-gas gun was employed to yield Hugoniot data at about 120 GPa and release states at about 90 GPa. Lunar basalt 70215 appears to be among the densest rocks in the present lunar sample collection, having a crystal density of 3.38 g/cu cm and a porosity of about 1.3%. The results of the experiments have important implications for both the degree of shock metamorphism expected for impact processes and the extent of ejecta transport on mare surfaces with high-titanium basalt composition.

Ahrens, T. J.↗

The moon - Composition determined by nebular processes

The Ganapathy-Anders seven-component model is used as the basis for an analysis of conditions in the early solar nebula as they pertain to the formation of the moon. Calculations incorporating improved geological data and petrological constraints are presented in terms of a model moon which meets trace element restrictions and conforms to known parameters of heat flow, density, and moment of inertia ratio, ie., 40 ppb U, and a core of 2% by weight. It is noted that a melt of the model composition approximates that of Apollo 15 green glass, together with a residuum of olivine, plus 3-4% spinel.

Morgan, J. W.↗

Silica activity in lunar lavas

Calculated values of log alpha SiO2 in lunar magmas range from approximately -0.8 to unity in the temperature range of 1100-1300 C. High-titanium mare basalts begin crystallizing at silica activities insufficient for orthopyroxene saturation; in contrast to terrestrial lavas, silica activities rise substantially with crystallization and cause silica saturation in the residuum. Igneous rocks of the highland regions have relatively higher initial silica activities than mare basalts. Thermodynamic calculations indicate that high-titanium mare basalts could be derived from a 90 to 240-km deep source region containing olivine and orthopyroxene in addition to other phases.

Nash, W. P.↗

Petrologic evidence for a plutonic igneous origin of anorthositic norite clasts in 67955 and 77017

Clasts of anorthositic norite in 67955 and 77017, and several other samples, are suggested to represent material which crystallized from a silicate magma in a plutonic environment. Although no statement can be made regarding the ultimate origin of the parent melt, its composition was relatively felsic, starting within the primary field of crystallization of either plagioclase or spinel. The sequence of crystallization was: plagioclase (and/or spinel) olivine - low-Ca pyroxene - high-Ca pyroxene.

Ashwal, L. D.↗

Mare basalts - Melting experiments and petrogenetic interpretations

Equilibrium crystallization sequences are determined in melting experiments in vacuum at Fe saturation on synthetic mare basalt compositions 70215 and 15318 Red Glass (both high-Ti) as well as 15555-15016 (low-Ti). The experiments confirm that much of the chemical variation within both the high- and low-Ti suites is controlled by near-surface fractionation processes, although the two suites cannot be related by such mechanisms. The components and crystallization products of the liquidus at various temperatures and pressures are reported. Mare basalt petrogenesis is interpreted in terms of high-pressure equilibria at Fe saturation; it is suggested that low-Ti basalts represent partial melts of a differentiated olivine-pyroxenite lunar mantle at 240 km or deeper, while cumulus clinopyroxene in the source is responsible for their REE characteristics. The formation of high-Ti basalts is considered.

Kesson, S. E.↗