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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Increasing freshwater supply to sustainably address global water security at scale

While significant parts of the globe are already facing significant freshwater scarcity, the need for more freshwater is projected to increase in order to sustain the increasing global population and economic growth, and adapt to climate change. Current approaches for addressing this challenge, which has the potential to result in catastrophic outcomes for consumptive needs and economic growth, rely on increasing the efficient use of existing resources. However, the availability of freshwater resources is rapidly declining due to over-exploitation and climate change and, therefore, is unlikely to sustainably address future needs, which requires a rethink of our solutions and associated investments. Here we present a bold departure from existing approaches by establishing the viability of significantly increasing freshwater through the capture of humid air over oceans. We show that the atmosphere above the oceans proximal to the land can yield substantial freshwater, sufficient to support large population centers across the globe, using appropriately engineered structures. Due to the practically limitless supply of water vapor from the oceans, this approach is sustainable under climate change and can transform our ability to address present and future water security concerns. This approach is envisioned to be transformative in establishing a mechanism for sustainably providing freshwater security to the present and future generations that is economically viable.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Climate change impacts the spread potential of wheat stem rust, a significant crop disease

Abstract Long range atmospheric transport is an important pathway for the spread of plant pathogens, such as rust fungi which can devastate cereal crop health and food security worldwide. In recent years, serious concern has been caused by the evolution of new virulent races of Puccinia graminis f. sp. tritici , a pathogen causing wheat stem rust that can result in close to 100% yield losses on susceptible wheat cultivars in favourable weather conditions. We applied an Earth system model to compare the suitability of the current climate and a business-as-usual climate scenario (RCP 8.5) for 2100 for wheat stem rust. Although there are large uncertainties in modelling changes in disease spread, we focus in this paper on the changes which are likely to be robust to model assumptions. We show that the warmer climate with lower relative humidity and enhanced turbulence will lead to ∼40% increase in the urediniospore emitting potential of an infected field as global average. The main predicted changes in the atmospheric long-range transport include reduced connections between Europe, Africa and South Asia, and increased frequency of spores crossing the mid-latitude oceans. Due to reduction in subfreezing conditions, the overwintering areas of the fungus will expand. On the other hand, projected drier conditions will reduce substantially the probability of an infection starting from deposited spores, except in irrigated fields.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Abbreviated Technical Report: Experimentally Interrogating Detonation Chemistry on Sub-Nanosecond to Nanosecond Timescales

Direct experimental measurement of chemical reactions during high explosive detonation remains challenging. Theory and modeling have long preceded experiment in the fundamental physical and chemical kinetic properties of detonation, and experimentation at the relevant timescales are needed to both validate models and provide fundamental understanding of detonation. In this LDRD-ER project, two approaches, x-ray diffraction and core-level x-ray Raman, were developed and used to further experimental capabilities to address this gap. We further developed dynamic x-ray diffraction to directly detect nanodiamond formation during detonation, providing experimental data towards resolving longstanding controversy in the scientific literature, and although the full kinetics have not yet been fully mapped, diamond diffraction appears on the same timescales as detonation soot formation. In the second research thrust, we have developed core-level x-ray Raman for use with high explosives. This technique provides information analogous to x-ray absorption spectroscopy and electron energy loss spectroscopy, but uses inelastic scattering of hard x-rays that can interrogate chemistry around light elements much deeper into the material. The low cross section and requisite high solid angle collection have hindered its use for ultra-fast spectroscopy. We developed and tested a high-q spectrometer which will substantially increase cross section and signal-to-noise, showing this method will also not dramatically alter, compared to x-ray absorption, the most discriminating spectral features of C, N, and O from various high explosives and expected detonation products. We have also used x-ray Raman combined with OCEAN electronic structure calculations to explore dynamic photodegradation mechanisms in PETN and CL-20 explosives. This provides a pathway towards implementing capability to dynamically explore chemistry at an x-ray free electron laser.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Plastic additives in the ocean: Use of a comprehensive dataset for meta-analysis and method development

In excess of 13,000 chemicals are added to plastics (‘additives’) to improve performance, durability, and production of plastic products. They are categorized into numerous chemical classes including flame retardants, light stabilizers, antioxidants, and plasticizers. While research on plastic additives in the marine environment has increased over the past decade, there is a lack of methodological standardization. To direct future measurement of plastic additives, we compiled a first-of-its-kind dataset of literature assessing plastic additives in marine environments, delineated by sample type (plastic debris, seawater, sediment, biota). Using this dataset, we performed a meta-analysis to summarize the state of the science. Currently, our dataset includes 217 publications published between 1978 and May 2023. The majority of publications analyzed plastic additives in biota collected from Europe and Asia. Analyses concentrated on plasticizers, brominated flame retardants, and bisphenols. Common sample preparation techniques included Solvent - Agitation extraction for plastic, sediment, and biota samples, and Solid Phase Extraction for seawater samples with dichloromethane and solvent mixtures including dichloromethane as the organic extraction solvent. Finally, most analyses were performed utilizing gas chromatography/mass spectrometry. There are a variety of data gaps illuminated by this meta-analysis, most notably the small number of compounds that have been targeted for detection compared to the large number of additives used in plastic production. The provided dataset facilitates future investigation of trends in plastic additive concentration data in the marine environment (allowing for comparison to toxicity thresholds) and acts as a starting point for optimizing and harmonizing plastic additive analytical methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Principles and applications of x-ray light sources driven by laser wakefield acceleration

One of the most prominent applications of modern particle accelerators is the generation of radiation. In a synchrotron or an x-ray free electron laser (XFEL), high energy electrons oscillating in periodic magnetic structures emit bright x rays. In spite of their scientific appeal that will remain evident for many decades, one limitation of synchrotrons and XFELs is their typical mile-long size and their cost, which often limits access to the broader scientific community. Here, this tutorial reviews the principles and prospects of using plasmas produced by intense lasers as particle accelerators and x-ray light sources, as well as some of the applications they enable. A plasma is an ionized medium that can sustain electrical fields many orders of magnitude higher than that in conventional radio frequency accelerator structures and can be used to accelerate electrons. When short, intense laser pulses are focused into a gas, it produces electron plasma waves in which electrons can be trapped and accelerated to GeV energies. This process, laser-wakefield acceleration (LWFA), is analogous to a surfer being propelled by an ocean wave. Many radiation sources, from THz to gamma-rays, can be produced by these relativistic electrons. This tutorial reviews several LWFA-driven sources in the keV-MeV photon energy range: betatron radiation, inverse Compton scattering, bremsstrahlung radiation, and undulator/XFEL radiation. X rays from laser plasma accelerators have many emerging applications. They can be used in innovative and flexible x-ray imaging and x-ray absorption spectroscopy configurations, for use in biology, industry, and high-energy density science.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Climate responses in China to domestic and foreign aerosol changes due to clean air actions during 2013–2019

In recent years, to improve air quality, significant efforts have been made to reduce regional aerosols including China, Europe and North America, which have potential impacts on climate. In this study, fast and slow climate responses in China to changes in domestic and foreign anthropogenic emissions of aerosols and precursors from 2013 to 2019 are investigated using the Community Earth System Model version 1 (CESM1). Aerosol emissions changes, especially reductions in China, North America and Europe, during 2013–2019 resulted in surface air temperature increases across the Northern Hemisphere. Global aerosol changes induce a regional warming of 0.2 °C in China, equally contributed by domestic and foreign emissions changes. China’s domestic emission reductions lead to a regional average temperature rise of 0.1°C, primarily driven by rapid atmospheric adjustments over eastern China. Foreign aerosol changes, particularly reductions in North America and Europe, also contributed to a 0.1°C warming in China through slow oceanic processes. This warming in China induced by foreign aerosol changes is due to a teleconnection between the aerosol-induced anomalous regional warming in Eastern U.S.-North Atlantic Ocean-Europe and the downstream East Asian climate through anomalous wave trains propagation. The comparable influence of domestic and foreign aerosol changes on climate in China underscores the importance of international collaboration in climate mitigation endeavors.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Climatological sensitivities of shallow-cumulus bulk entrainment in continental and oceanic locations

Cumulus entrainment is a complex process that has long challenged conceptual understanding and atmospheric prediction. To investigate this process observationally, two retrievals are used to generate multi-year climatologies of shallow-cumulus bulk entrainment ( ϵ ) at two Atmospheric Radiation Measurement cloud observatories, one in the US southern Great Plains (SGP) and the other in the Azores archipelago in the eastern North Atlantic (ENA). The statistical distributions of ϵ thus obtained, as well as certain environmental and cloud-related sensitivities of ϵ , are consistent with previous findings from large-eddy simulations. The retrieved ϵ robustly increases with cloudlayer relative humidity and decreases in wider clouds and cloud ensembles with larger cloud-base mass fluxes. While ϵ also correlates negatively with measures of cloud-layer vigor (e.g., maximum in-cloud vertical velocity and cloud depth), the extent to which these metrics actually regulate ϵ (or vice-versa) is unclear. Novel sensitivities of ϵ include a robust decrease of ϵ with increasing subcloud wind speed in oceanic flows, as well as a decrease of ϵ with increasing cloud-base mass flux in individual cumuli. A strong land–ocean contrast in ϵ is also found, with median values of 0.5-0.6 km -1 at the continental SGP site and and 1.0-1.1 km -1 at the oceanic ENA site. This trend is associated with drier and deeper cloud layers, along with larger cloud-base mass fluxes, at SGP, all of which favor reduced ϵ . The flow-dependence of retrieved ϵ implies that its various sensitivities should be accounted for in cumulus parameterization schemes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Marine ice sheet experiments with the Community Ice Sheet Model

Ice sheet models differ in their numerical treatment of dynamical processes. Simulations of marine-based ice are sensitive to the choice of Stokes flow approximation and basal friction law and to the treatment of stresses and melt rates near the grounding line. We study the effects of these numerical choices on marine ice sheet dynamics in the Community Ice Sheet Model (CISM). In the framework of the Marine Ice Sheet Model Intercomparison Project 3d (MISMIP3d), we show that a depth-integrated, higher-order solver gives results similar to a 3D (Blatter–Pattyn) solver. We confirm that using a grounding line parameterization to approximate stresses in the grounding zone leads to accurate representation of ice sheet flow with a resolution of ~2 km, as opposed to ~0.5 km without the parameterization. In the MISMIP+ experimental framework, we compare different treatments of sub-shelf melting near the grounding line. In contrast to recent studies arguing that melting should not be applied in partly grounded cells, it is usually beneficial in CISM simulations to apply some melting in these cells. This suggests that the optimal treatment of melting near the grounding line can depend on ice sheet geometry, forcing, or model numerics. In both experimental frameworks, ice flow is sensitive to the choice of basal friction law. To study this sensitivity, we evaluate friction laws that vary the connectivity between the basal hydrological system and the ocean near the grounding line. CISM yields accurate results in steady-state and perturbation experiments at a resolution of ~2 km (arguably 4 km) when the connectivity is low or moderate and ~1 km (arguably 2 km) when the connectivity is strong.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Investigating controls on sea ice algal production using E3SMv1.1-BGC

We present the analysis of global sympagic primary production (PP) from 300 years of pre-industrial and historical simulations of the E3SMv1.1-BGC model. The model includes a novel, eight-element sea ice biogeochemical component, MPAS-Seaice zbgc, which is resolved in three spatial dimensions and uses a vertical transport scheme based on internal brine dynamics. Modeled ice algal chlorophyll-a concentrations and column-integrated values are broadly consistent with observations, though chl-a profile fractions indicate that upper ice communities of the Southern Ocean are underestimated. Simulations of polar integrated sea ice PP support the lower bound in published estimates for both polar regions with mean Arctic values of 7.5 and 15.5 TgC/a in the Southern Ocean. However, comparisons of the polar climate state with observations, using a maximal bound for ice algal growth rates, suggest that the Arctic lower bound is a significant underestimation driven by biases in ocean surface nitrate, and that correction of these biases supports as much as 60.7 TgC/a of net Arctic PP. Simulated Southern Ocean sympagic PP is predominantly light-limited, and regional patterns, particularly in the coastal high production band, are found to be negatively correlated with snow thickness.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Ejection of Dust From the Ocean as a Potential Source of Marine Ice Nucleating Particles

Oceans are, generally, relatively weak sources of ice nucleating particles (INPs). Thus, dust transported from terrestrial regions can dominate atmospheric INP concentrations even in remote marine regions. Studies of ocean-emitted INPs have focused upon sea spray aerosols containing biogenic species. Even though large concentrations of dust are transported over marine regions, resuspended dust has never been explicitly considered as another possible source of ocean-emitted INPs. Current models assume that deposited dust is not re-emitted from surface waters. Our laboratory studies of aerosol particles produced from coastal seawater and synthetic seawater doped with dust show that dust can indeed be ejected from water during bubble bursting. INP concentration measurements show these ejected dust particles retain ice nucleating activity. Doping synthetic seawater to simulate a strong dust deposition event produced INPs active at temperatures colder than -13 °C and INP concentrations one to two orders of magnitude greater than either lab sea spray or marine boundary layer measurements. The relevance of these laboratory findings is highlighted by single particle composition measurements along the Californian coast where at least 9% of dust particles were mixed with sea salt. Additionally, global modeling studies show that resuspension of dust from the ocean could exert the most impact over the Southern Ocean, where ocean-emitted INPs are thought to dominate atmospheric INP populations. More work characterizing the factors governing the resuspension of dust particles is required to understand the potential impact upon clouds.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Making a Superbolt: Reconciling Observations of the Optically Brightest Lightning on Earth From Different Satellites

We previously documented geographic distributions of the optically brightest lightning on Earth—known as “superbolts”—using two space-based instruments: the photodiode detector (PDD) on the Fast On-orbit Recording of Transient Events (FORTE) satellite and the Geostationary Lightning Mapper (GLM) on NOAA's Geostationary Operational Environmental Satellites. In this study, we further examine the superbolts identified by the PDD and GLM to reconcile the differences between their geographic distributions. We find that both the physical extent of the parent flash and the development speed of its leaders are important for making a superbolt. The oceanic PDD superbolts tend to occur early in flashes that rapidly expand laterally into long horizontal “megaflashes.” The top GLM superbolts occur over land at later times in particularly large megaflashes. These land-based flashes grow more slowly until they extend over multiple hundreds of kilometers. The FORTE PDD missed these delayed superbolts due to limitations in its triggering. Coincident Tropical Rainfall Measuring Mission measurements show that the warm season megaflash superbolts detected by Lightning Imaging Sensor/GLM and wintertime oceanic superbolts observed by the PDD occur in otherwise similar thunderstorm environments. Both are marked by: low storm heights (<10 km), widespread precipitation near the surface, small infrared brightness temperature gradients, and low flash rates. We suggest that the vertically compact, stratiform nature of these clouds provides favorable conditions for superbolt production.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Mechanisms Behind the Long‐Distance Diurnal Offshore Precipitation Propagation in Northwestern South America

Abstract Northwestern South America (NWSA) is the rainiest region on Earth, with diurnal precipitation exhibiting extensive westward offshore propagation of up to about 1,200 km in boreal spring (March‐May). The diurnal offshore precipitation propagation begins slowly (3–10 m s −1 ) near the coast of NWSA (<200 km) but accelerates significantly (∼20 m s −1 ) and shows an afternoon enhancement far from the coast (>400 km). However, the driving mechanisms behind this long‐distance precipitation propagation remain unclear. Using a new cloud tracking and classification data set, we found that mesoscale convective systems (MCSs) are the dominant precipitation contributors in the offshore region of NWSA. Cloud tracking shows that the long‐distance propagation and the afternoon enhancement of diurnal precipitation primarily originate from MCSs initiated in the early morning, either over open oceans or from the coast of Central America. Composite tendency analysis shows that MCSs initiated near the coast of Central America have significant upward cooling and moistening signals starting from the surface before initiation. Further analysis of surface diurnal perturbation fields indicates that the land breeze is the primary driving mechanism for MCS initiation. Conversely, for MCSs initiated over open oceans, a significant downward cooling signal from 400 hPa is observed ∼7 hr before initiation, corresponding to the passage of diurnal gravity waves emitted from the Andes. Additionally, our findings highlight the critical role of lower and mid‐level moisture conditions in MCS initiation, alongside the influence of gravity waves.

Hu, Jingyi [Department of Meteorology and Atmosphe↗
DOE OSTI2022

Microbial functional diversity across biogeochemical provinces in the central Pacific Ocean

Enzymes catalyze key reactions within Earth’s life-sustaining biogeochemical cycles. Here, we use metaproteomics to examine the enzymatic capabilities of the microbial community (0.2 to 3 µm) along a 5,000-km-long, 1-km-deep transect in the central Pacific Ocean. Eighty-five percent of total protein abundance was of bacterial origin, with Archaea contributing 1.6%. Over 2,000 functional KEGG Ontology (KO) groups were identified, yet only 25 KO groups contributed over half of the protein abundance, simultaneously indicating abundant key functions and a long tail of diverse functions. Vertical attenuation of individual proteins displayed stratification of nutrient transport, carbon utilization, and environmental stress. The microbial community also varied along horizontal scales, shaped by environmental features specific to the oligotrophic North Pacific Subtropical Gyre, the oxygen-depleted Eastern Tropical North Pacific, and nutrient-rich equatorial upwelling. Some of the most abundant proteins were associated with nitrification and C1 metabolisms, with observed interactions between these pathways. The oxidoreductases nitrite oxidoreductase (NxrAB), nitrite reductase (NirK), ammonia monooxygenase (AmoABC), manganese oxidase (MnxG), formate dehydrogenase (FdoGH and FDH), and carbon monoxide dehydrogenase (CoxLM) displayed distributions indicative of biogeochemical status such as oxidative or nutritional stress, with the potential to be more sensitive than chemical sensors. Enzymes that mediate transformations of atmospheric gases like CO, CO 2 , NO, methanethiol, and methylamines were most abundant in the upwelling region. Here, we identified hot spots of biochemical transformation in the central Pacific Ocean, highlighted previously understudied metabolic pathways in the environment, and provided rich empirical data for biogeochemical models critical for forecasting ecosystem response to climate change.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Summertime Marine Boundary Layer Cloud, Thermodynamic, and Drizzle Morphology over the Eastern North Atlantic: A Four-Year Study

Abstract Summertime remote sensor and in situ data from 2016 to 2019 collected at the ARM Eastern North Atlantic (ENA) Observatory are combined with aircraft measurements from the Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) campaign to quantify marine boundary layer (MBL) cloud, thermodynamic, and drizzle morphology in the region. A radar reflectivity–rainfall rate relationship ( Z – R ) is developed from aircraft data and 6-h cloud morphological regimes are identified from ENA data using a k -means algorithm driven by three independent inputs quantifying cloud thickness, drizzle intensity, and cloud field geometric complexity. Four separate MBL structural regimes representing non- or weakly drizzling single-layer stratocumulus, drizzling stratocumulus and cumulus-coupled stratocumulus, deep convection, and broken clouds embedded in northerly flow are identified. Single-layer stratocumulus is indicated when weak subtropical anticyclones are significantly west of the ENA site, and the MBL is cooler and drier than when drizzling and cumulus-coupled stratocumulus and broken clouds are observed. Drizzling and cumulus-coupled stratocumulus clouds are observed on the eastern flank of strong subtropical anticyclones in deep warm moist air masses with wind speeds exceeding 7 m s −1 and strong near-surface wind shear. Broken clouds exhibit strong wind shear near the inversion, while single-layer stratocumulus clouds have lower wind speeds and minimal shear. Net latent heat fluxes in the subcloud layer resulting from a combination of the ocean surface heat flux and evaporating drizzle average near zero over long periods in drizzling and cumulus-coupled stratocumulus. The ECMWF reanalysis version 5 (ERA5) is found to accurately represent single-layer stratocumulus properties, while producing significant discrepancies when drizzling stratocumulus and cumulus-coupled stratocumulus are observed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

A high-resolution planetary boundary layer height seasonal climatology from GNSS radio occultations

We present a new seasonal planetary boundary layer height (PBLH) climatology product derived from 14 years of Global Navigation Satellite System radio occultation (GNSS-RO) data from multiple missions including COSMIC, TerraSAR-X, KOMPSAT-5, and PAZ. PBLH estimates are derived from the minimum gradients of retrieved refractivity profiles, with a vertical resolution of ~200 m. The climatology is obtained from occultations observed between June 2006 and December 2019, and is divided into land and ocean regimes on a 2-degree grid. We provide seasonal climatologies at 2-degree resolution as well as climatologies of diurnal cycle amplitude and phase at 5-degree resolution. The new GNSS PBLH climatology is compared to radiosonde data from the ship-based Marine ARM GPCI Investigation of Clouds (MAGIC) campaign in the subtropical northeast Pacific ocean and to previous GNSS PBLH climatology estimates. The higher spatial resolution reveals new details such as seasonal PBLH modulation due to sea ice off the coast of Antarctica. The PBLH product is the first publicly available at 2-degree resolution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Predictive Proxies of Present and Future Lightning in a Superparameterized Model

Abstract A superparameterized climate model is used to assess the global performance of several previously proposed proxies for lightning. In particular, predictors incorporating hydrometeor (ice, graupel) profiles and convective vertical velocities are compared to observations, then used to estimate changes in flash rates with global warming. The choice of microphysics parameterization is also investigated, with all predictors showing higher correlations with Lightning Imaging Sensor/Optical Transient Detector observations when using a 2‐moment scheme compared to a 1‐moment representation. All proxies generally agree in their response to warming over tropical land, with notable decreases in Africa, the Middle East, and northern South America, but disagree over oceans and the midlatitudes. The product of convective available potential energy and precipitation predicts increases over these latter areas, as do the 2‐moment ice‐based proxies, while those of the 1‐moment model tend to show decreases, highlighting the importance of cloud microphysics when using climate models to simulate lightning.

54 ENVIRONMENTAL SCIENCES↗