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At least 1,081 records · Page 60

Interpreting Lidar Measurements to Better Estimate Surface PM2.S in Study Regions of DISCOVER-AQ

The use of satellite AOD data to estimate surface PM2.5 has been broadly studied in various regions. Some showed good results while some showed relatively poor with the simple relationship between AOD and PM2.5. The key factor is the aerosol vertical distribution. Lidar extinction profiles provide insights into the aerosol mixing not only in the boundary layer but also quantifying residual aerosol abundance above boundary layer with e-folding scale height. The normalizing AOD by hazy layer height is proven better in correlating with PM2.5. In other words, extinction measurements near the surface can be a proxy for surface PM2.5. In this study, we will use NASA airborne HSRL (High Spectral Resolution Lidar) during SJV2007 (San Joaquin Valley, February 2007) and surface MPLNet (Micropulse Lidar Network) at GSFC between 2007 and 2010 to characterize the relationship for the DISCOVER-AQ (Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality) field experiments; the first over Baltimore-Washington was conducted in July 2011.

Chu, D. A.↗

Pollution technology program, can-annular combustor engines

A Pollution Reduction Technology Program to develop and demonstrate the combustor technology necessary to reduce exhaust emissions for aircraft engines using can-annular combustors is described. The program consisted of design, fabrication, experimental rig testing and assessment of results and was conducted in three program elements. The combustor configurations of each program element represented increasing potential for meeting the 1979 Environmental Protection Agency (EPA) emission standards, while also representing increasing complexity and difficulty of development and adaptation to an operational engine. Experimental test rig results indicate that significant reductions were made to the emission levels of the baseline JT8D-17 combustor by concepts in all three program elements. One of the Element I single-stage combustors reduced carbon monoxide to a level near, and total unburned hydrocarbons (THC) and smoke to levels below the 1979 EPA standards with little or no improvement in oxides of nitrogen. The Element II two-stage advanced Vorbix (vortex burning and mixing) concept met the standard for THC and achieved significant reductions in CO and NOx relative to the baseline. Although the Element III prevaporized-premixed concept reduced high power NOx below the Element II results, there was no improvement to the integrated EPA parameter relative to the Vorbix combustor.

Roberts, R.↗

He/+/ and other unusual ions in the solar wind - A systematic search covering 1972-1980

Using plasma data from IMPs 7 and 8 and ISEEs 1 and 3 for October 1972 to February 1980, a search for wind energy/charge spectra was conducted at the prompting of the discovery of large He(+) fluxes in the solar wind. Only three distinct events with identifiable levels of He(+) were found, all occurring within one year and during the rising phase of solar cycle 21, with minor ion abundances which were enhanced by comparison with normal solar wind abundances. The appearance of ionization states corresponding to both warm and very cold coronal freezing-in conditions within the same plasma is noted in all three events, as well as the observation of iron ions ranging from Fe(+10) to Fe(+5). One of the phenomenological results of this study is that certain unusual transient events eject both hot and unusually cold coronal plasma, mixed and coexisting on the same magnetic field lines.

Zwickl, R. D.↗

Tidal distortions in pairs of early-type galaxies

The authors are conducting an imaging survey of pairs of elliptical galaxies which has already produced interesting results. Some pairs present a common pattern of distortion interpreted in terms of tidal effects (Davoust and Prugniel, 1988; Prugniel et al., 1989). Other examples drawn from the literature (Borne and Hoessel, 1988; Colina and Perez-Fournon, 1990) share the same morphology. New cases and lists of the characteristics of 24 such systems. The authors' pairs are drawn from a sample of binary and multiple galaxies which has in turn been extracted from the CGCG, UGC (Nilson, 1973) and VV (Vorontsov-Velyaminov, 1959) catalogues. This sample includes that of Karachentsev (1972). It contains 1800 pairs, among which 700 are S - S or mixed morphology pairs. The authors are working on the remainder to produce a sample of close physical pairs of elliptical galaxies (they also include bulge dominated SO's since the morphological discrimination from ellipticals is often ambiguous, in particular for interacting galaxies). One of the interests of this work is to provide a sample selected on purely optical criteria, at variance with other works (e.g., Valentijn and Casertano, 1988). This will allow statistical studies of non-optical properties of these pairs (in particular radio emission). The authors have so far obtained charge-coupled device (CCD) images of 125 pairs with a 2m telescope and velocities' differences of 78 pairs were obtained using the 1.93 meter telescope of Observatoire de Haute Provence and from the literature. One is an optical pair (VV 190). Eighteen of our pairs present the morphological effect described in Davoust and Prugniel (1988): the external parts of each member are stretched in opposite senses in a direction rougly perpendicular to the pair axis. The proportion of 15 plus or minus 4 percent distorted pairs confirms previous estimates. Except for a few cases involving flattened galaxies with nearly aligned major axes which deserve careful detailed analysis (Prugniel, 1989), the apparent distortions do correspond to physical distortions. We have searched the literature for isophote maps showing this effect. In the survey of radio galaxies by Colina and Perez-Fournon (1990), 7 out of 20 pairs show this characteristic distortion.

Prugniel, Philippe↗

Evaluation of Impinging Stream Vortex Chamber Concepts for Liquid Rocket Engine Applications

To pursue technology developments for future launch vehicles, NASA/Marshall Space Flight Center (MSFC) is examining vortex chamber concepts for liquid rocket engine applications. Past studies indicated that the vortex chamber schemes potentially have a number of advantages over conventional chamber methods. Due to the nature of the vortex flow, relatively cooler propellant streams tend to flow along the chamber wall. Hence, the thruster chamber can be operated without the need of any cooling techniques. This vortex flow also creates strong turbulence, which promotes the propellant mixing process. Consequently, the subject chamber concepts not only offer system simplicity, but also enhance the combustion performance. Test results have shown that chamber performance is markedly high even at a low chamber length-to-diameter ratio (LD). This incentive can be translated to a convenience in the thrust chamber packaging. Variations of the vortex chamber concepts have been introduced in the past few decades. These investigations include an ongoing work at Orbital Technologies Corporation (ORBITEC). By injecting the oxidizer tangentially at the chamber convergence and fuel axially at the chamber head end, Knuth et al. were able to keep the wall relatively cold. A recent investigation of the low L/D vortex chamber concept for gel propellants was conducted by Michaels. He used both triplet (two oxidizer orifices and one fuel orifice) and unlike impinging schemes to inject propellants tangentially along the chamber wall. Michaels called the subject injection scheme an Impinging Stream Vortex Chamber (ISVC). His preliminary tests showed that high performance, with an Isp efficiency of 9295, can be obtained. MSFC and the U. S. Army are jointly investigating an application of the ISVC concept for the cryogenic oxygen/hydrocarbon propellant system. This vortex chamber concept is currently tested with gel propellants at AMCOM at Redstone Arsenal, Alabama. A version of this concept for the liquid oxygen (LOX) hydrocarbon fuel (RP-1) system has been derived from the one for the gel propellant. An unlike impinging injector was employed to deliver the propellants to the chamber. MSFC is also conducting an alternative injection scheme, called the chasing injector, associated with this vortex chamber concept. In this injection technique, both propellant jets and their impingement point are in the same chamber cross-sectional plane. Long duration tests (approximately up to 15 seconds) will be conducted on the ISVC to study the thermal effects. This paper will report the progress of the subject efforts at NASA Marshall Space Flight Center. Thrust chamber performance and thermal wall compatibility will be evaluated. The chamber pressures, wall temperatures, and thrust will be measured as appropriate. The test data will be used to validate CFD models, which, in turn, will be used to design the optimum vortex chambers. Measurements in the previous tests showed that the chamber pressures vary significantly with radius. This is due to the existence of the vortices in the chamber flow field. Hence, the combustion efficiency may not be easily determined from chamber pressure. For this project, measured thrust data will be collected. The performance comparison will be in terms of specific impulse efficiencies. In addition to the thrust measurements, several pressure and temperature readings at various locations on the chamber head faceplate and the chamber wall will be made. The first injector and chamber were designed and fabricated based on the available data and experience gained during gel propellant system tests by the U.S. Army. The alternate injector for the ISVC was also fabricated. Hot-fire tests of the vortex chamber are about to start and are expected to complete in February of 2003 at the TS115 facility of MSFC.

Trinh, Huu P.↗

Benchmark Wall Heat Flux Data for a GO2/GH2 Single Element Combustor

Wall heat flux measurements in a 1.5 in. diameter circular cross-section rocket chamber for a uni-element shear coaxial injector element operating on gaseous oxygen (GOz)/gaseous hydrogen (GH,) propellants are presented. The wall heat flux measurements were made using arrays of Gardon type heat flux gauges and coaxial thermocouple instrumentation. Wall heat flux measurements were made for two cases. For the first case, GOZ/GHz oxidizer-rich (O/F=l65) and fuel-rich preburners (O/F=1.09) integrated with the main chamber were utilized to provide vitiated hot fuel and oxidizer to the study shear coaxial injector element. For the second case, the preburners were removed and ambient temperature gaseous oxygen/gaseous hydrogen propellants were supplied to the study injector. Experiments were conducted at four chamber pressures of 750, 600, 450 and 300psia for each case. The overall mixture ratio for the preburner case was 6.6, whereas for the ambient propellant case, the mixture ratio was 6.0. Total propellant flow was nominally 0.27-0.29 Ibm/s for the 750 psia case with flowrates scaled down linearly for lower chamber pressures. The axial heat flux profile results for both the preburner and ambient propellant cases show peak heat flux levels a t axial locations between 2.0 and 3.0 in. from the injector face. The maximum heat flux level was about two times greater for the preburner case. This is attributed to the higher injector fuel-to-oxidizer momentum flux ratio that promotes mixing and higher initial propellant temperature for the preburner case which results in a shorter reaction zone. The axial heat flux profiles were also scaled with respect to the chamber pressure to the power 0.8. The results at the four chamber pressures for both cases collapsed to a single profile indicating that at least to first approximation, the basic fluid dynamic structures in the flow field are pressure independent as long as the chamber/njector/nozzle geometry and injection velocities remain the same.

Marshall, William M.↗

Theoretical computation of trace gases retrieval random error from measurements of high spectral resolution infrared sounder

The purpose of this paper is to demonstrate the trace gas profiling capabilities of future passive high spectral resolution (1 cm(exp -1) or better) infrared (600 to 2700 cm(exp -1)) satellite tropospheric sounders. These sounders, such as the grating spectrometer, Atmospheric InfRared Sounders (AIRS) (Chahine et al., 1990) and the interferometer, GOES High Resolution Interferometer Sounder (GHIS), (Smith et al., 1991) can provide these unique infrared spectra which enable us to conduct this analysis. In this calculation only the total random retrieval error component is presented. The systematic error components contributed by the forward and inverse model error are not considered (subject of further studies). The total random errors, which are composed of null space error (vertical resolution component error) and measurement error (instrument noise component error), are computed by assuming one wavenumber spectral resolution with wavenumber span from 1100 cm(exp -1) to 2300 cm(exp -1) (the band 600 cm(exp -1) to 1100 cm(exp -1) is not used since there is no major absorption of our three gases here) and measurement noise of 0.25 degree at reference temperature of 260 degree K. Temperature, water vapor, ozone and mixing ratio profiles of nitrous oxide, carbon monoxide and methane are taken from 1976 US Standard Atmosphere conditions (a FASCODE model). Covariance matrices of the gases are 'subjectively' generated by assuming 50 percent standard deviation of gaussian perturbation with respect to their US Standard model profiles. Minimum information and maximum likelihood retrieval solutions are used.

Huang, Hung-Lung↗

Oil Saving Seal

Driven under difficult field conditions, the Army Jeep shown went more than 22,000 miles without an oil change in a test conducted by the U.S. Army Mobility Equipment Research and Development Command. Key to this exceptionally long oil life was a set of piston ring seals made of a new synthetic rubber formula called RC-34; the seal pictured, photographed after its arduous Army trial, shows no signs of deterioration. The seal and the RC-34 material, which may soon be available for use in the family auto, were developed by Ramsey Corporation, St. Louis, Missouri, a division of TRW Automotive Worldwide. The oil in an automobile engine must be I replaced every few thousand miles not because it wears out but because it becomes contaminated. The contamination sources are gasoline and combustion gases which blow by the piston rings to mix with the oil, reducing the oil's ability to lubricate properly. Seeking to prolong oil life by eliminating "blowby," Ramsey Corporation looked for a better way to seal piston rings and used NASA technology as a departure point. The parent company TRW, under contract to NASA's Jet Propulsion Laboratory, had developed seals and bladders from a type of material called elastomers which where designed to withstand the environmental extremes of interplanetary flight. That effort formed a knowledge base for research which culminated in Ramsey's RC-34 elastomer.

Source record↗

Evaluation of the Danish Aerospace Corporation Portable Pulmonary Function System

A research project designed to investigate changes in maximal oxygen consumption (VO2max) during and following long duration flight on the International Space Station (ISS) has recently been completed. The device used to measure VO2 on board ISS, the Portable Pulmonary Function System (PPFS) manufactured by the Danish Aerospace Corporation (DAC), is based on previous-generation devices manufactured by DAC, but the PPFS has not been validated for analyzing metabolic gases or measuring cardiac output (Qc). The purpose of the present evaluation is to compare PPFS metabolic gas analysis measurements to measurements obtained using a clinically-validated system (ParvoMedics TrueOne(c) 2400 system; Parvo). In addition, Qc data collected with the PPFS were compared to Qc measurements from echocardiography. METHODS: Ten subjects completed three cycle exercise tests to maximal exertion. The first test was conducted to determine each subject's VO2max and set the work rates for the second and third (comparison) tests. The protocol for the two comparison tests consisted of three 5-minute stages designed to elicit 25%, 50%, and 75% VO2max (based upon results from the initial test), followed by 1-minute stages of increasing work rate (25 watt/minute) until the subject reached maximal effort. During one of the two comparison tests, metabolic gases and Qc were assessed with the PPFS; metabolic gases and Qc were assessed with the Parvo and by echocardiography, respectively, during the other test. The order of the comparison tests was counterbalanced. VO2max and maximal work rate during the comparison tests were compared using t tests. Mixed-effects regression modeling was used to analyze submaximal data. RESULTS: All of the data were within normal physiological ranges. The PPFS-measured values for VO2max were 6% lower than values obtained with the Parvo (PPFS: 3.11 +/- 0.75 L/min; Parvo: 3.32 +/- 0.87 L/min; mean +/- standard deviation; P = 0.02); this difference is probably due to flow restriction imposed by the PPFS Qc accessories. Submaximal VO2 values were slightly lower when measured with the PPFS, although differences were not physiologically relevant. The PPFS-measured values of submaximal carbon dioxide production (VCO2) were lower than the data obtained from Parvo, which could be attributed to lower fractions of expired carbon dioxide measured by the PPFS. The PPFS Qc values tended to be lower than echocardiography-derived values. CONCLUSIONS: The results of the present study indicate a need to further examine the PPFS and to better quantify its reproducibility; however, none of the findings of the current evaluation indicate that the PPFS needs to be replaced or modified.

Portable Pulmonary Function System (PPFS)↗

Experimental Investigation of a One-Sided Ejector Nozzle

A fundamental exploratory experiment is conducted assessing the performance of a one-sided ejector with the eventual goal of noise reduction for jet engines. The hardware is comprised of an 8:1 rectangular nozzle together with an ejector box whose lower surface is flush with the lower lip of the nozzle. Secondary flow is allowed through a gap between the upper lip of the nozzle and a flap that constitutes the upper surface of the ejector. Wall static pressures and Pitot probe surveys are conducted to evaluate the performance of the ejector with variation of geometric parameters. It is found that addition of vortex generating tabs at the upper lip of the nozzle significantly increases secondary flow entrainment. The entrainment is further enhanced by a divergence of the ejector upper surface. Limited noise measurements are done. The baseline ejector (without tabs) often encounters flow resonance with accompanying tones. The tabs have the additional benefit of eliminating those tones in all cases. However, for the tabbed case, addition of the ejector produces insignificant further noise reduction. This is due to the fact that the flow remains unmixed on the lower half of the ejector. The focus of ongoing and future efforts is to achieve sufficient mixing of the flow so that the exhaust velocities are uniformly low, while keeping the ejector hardware short and lightweight.

Ejectors↗

Study of various NH4+/NO3- mixtures for enhancing growth of potatoes

Two experiments were conducted to determine the effects of various NH4(+)-N/NO3(-)-N percentages on growth and mineral concentrations in potato (Solanum tuberosum L.) plants using a non-recirculating nutrient film system in a controlled environment. The first experiment included six NH4(+)-N/NO3(-)-N percentages at 0/100, 20/80, 40/60, 60/40, 80/20, and 100/0 with the same total N concentration of 4 mM. The second experiment included six NH4(+)-N/NO3(-)-N percentages at 0/100, 4/96, 8/92, 12/88, 16/84, and 20/80 again with the same total N of 4 mM. In each experiment, plants were harvested 35 days after transplanting when tubers had been initiated and started to enlarge. Dry weights of shoots, tubers, and whole plant at the harvest were increased significantly with all mixed nitrogen treatments as compared with single NH4+ or NO3- form. The enhanced growth with mixed nitrogen was greatest at 8% to 20% NH4(+)-N. Also, the concentrations and accumulation of total N in the shoots and roots were greater with mixed nitrogen than with separate NH4+ or NO3- nutrition. With NH4+ present in the solutions, the concentrations of P and Cl in the shoots were increased compared to NO3- alone, whereas the tissue concentrations of Ca and Mg were decreased. It was concluded that nitrogen fertilization provided with combined NH4+ and NO3- forms, even at small proportions of NH4+, can enhance nitrogen uptake and productivity in potato plants.

NASA Program CELSS↗

Digital Microfluidics Sample Analyzer

Three innovations address the needs of the medical world with regard to microfluidic manipulation and testing of physiological samples in ways that can benefit point-of-care needs for patients such as premature infants, for which drawing of blood for continuous tests can be life-threatening in their own right, and for expedited results. A chip with sample injection elements, reservoirs (and waste), droplet formation structures, fluidic pathways, mixing areas, and optical detection sites, was fabricated to test the various components of the microfluidic platform, both individually and in integrated fashion. The droplet control system permits a user to control droplet microactuator system functions, such as droplet operations and detector operations. Also, the programming system allows a user to develop software routines for controlling droplet microactuator system functions, such as droplet operations and detector operations. A chip is incorporated into the system with a controller, a detector, input and output devices, and software. A novel filler fluid formulation is used for the transport of droplets with high protein concentrations. Novel assemblies for detection of photons from an on-chip droplet are present, as well as novel systems for conducting various assays, such as immunoassays and PCR (polymerase chain reaction). The lab-on-a-chip (a.k.a., lab-on-a-printed-circuit board) processes physiological samples and comprises a system for automated, multi-analyte measurements using sub-microliter samples of human serum. The invention also relates to a diagnostic chip and system including the chip that performs many of the routine operations of a central labbased chemistry analyzer, integrating, for example, colorimetric assays (e.g., for proteins), chemiluminescence/fluorescence assays (e.g., for enzymes, electrolytes, and gases), and/or conductometric assays (e.g., for hematocrit on plasma and whole blood) on a single chip platform.

Pollack, Michael G.↗

Fabrication of Extruded Polyphenylsulfone – Boron Nitride Composite Tapes

Polyphenylsulfone (PPSU) is a high-temperature, chemically resistant thermoplastic with high impact resistance that is often used in interior aircraft cabin components, medical devices, and membranes. The aforementioned properties have led to interest investigating PPSU’s compatibility with hexagonal boron nitride (hBN) platelets as a thermally conductive, electrical composite insulator for high power-density electric machines. Preliminary trials extruding PPSU-hBN composite tapes showed promising dielectric properties and higher thermal conductivity as a function of hBN concentration compared to their neat analog. On the other hand, only few studies have reported on the extrusion process and resulting thermo-mechanical properties for PPSU and its composites made with chopped fiber reinforcement or fillers, none of which containing boron nitride filler. Prospects may exist for this type of material to be incorporated into extrusion-based additive manufacturing techniques to print other composites bearing unique properties useful for aerospace. Loading levels with up to approximately 23 wt% were achieved using micro-size BN platelets without observing any significant affects to PPSU’s glass-transition temperature. This work includes a description of the rheological properties of PPSU, the extrusion parameters for mixing and compounding the PPSU-hBN composite tapes, and the thermal and thermo-mechanical properties of PPSU-hBN composites.

polyphenylsulfone↗

Fabrication of Extruded Polyphenylsulfone – Boron Nitride Composite Tapes

Polyphenylsulfone (PPSU) is a high-temperature, chemically resistant thermoplastic with high impact resistance that is often used in interior aircraft cabin components, medical devices, and membranes. The aforementioned properties have led to interest investigating PPSU’s compatibility with hexagonal boron nitride (hBN) platelets as a thermally conductive, electrical composite insulator for high power-density electric machines. Preliminary trials extruding PPSU-hBN composite tapes showed promising dielectric properties and higher thermal conductivity as a function of hBN concentration compared to their neat analog. On the other hand, only few studies have reported on the extrusion process and resulting thermo-mechanical properties for PPSU and its composites made with chopped fiber reinforcement or fillers, none of which contained boron nitride filler. Prospects may exist for this type of material to be incorporated into extrusion-based additive manufacturing techniques to print other composites bearing unique properties useful for aerospace. Loading levels with up to approximately 23 wt% were achieved using micro-size BN platelets without observing any significant affects to PPSU’s glass-transition temperature. This work includes a description of the rheological properties of PPSU, the extrusion parameters for mixing and compounding the PPSU-hBN composite tapes, and the thermal and thermo-mechanical properties of PPSU-hBN composites.

Tiffany Williams↗

Dispersion of flammable vapor clouds resulting from large spills of liquid hydrogen

The purpose of this paper is to report the preliminary findings of hydrogen vapor cloud dispersion experiments conducted by NASA. The experiments were performed to obtain basic information regarding the physical phenomena governing the dispersion of flammable clouds formed as the result of spills of large quantities of liquid hydrogen. The experiments consisted of ground spills of up to 5.7 cubic meters (1500 gal) of liquid hydrogen, with spill durations of approximately 35 seconds. Instrumented towers, located downwind of the spill site, gather data on the temperature, hydrogen concentration, and turbulence levels as the hydrogen vapor cloud drifted downwind. Visual phenomena were recorded by motion picture and still cameras. Preliminary results of the experiments indicate that, for rapid spills, thermal and momentum induced turbulences cause the cloud to disperse to safe concentration levels and become positively buoyant long before mixing due to normal atmospheric turbulence becomes a major factor.

Witcofski, R. D.↗

A reexamination of the RB-SR isotopic systematics of lunar breccia 12013

Lunar breccia 12013 is one of the few rocks for which isotopic evidence has been interpreted as indicating a 4.5-AE age, and it is the only lunar rock which contains abundant granitic material that may date back to the initial lunar differentiation. An investigation of 12013 conducted by Quick et al. (1981) has led to the conclusion that 12013 is an extremely complex mixture of impact-generated melt and clastic components of uncertain affinities. It was found that the granitic component in 12013 need not be any older than 4.16-4.17 AE. In the present study a model is presented for the Rb-Sr evolution of 12013 which explains the isotopic data without resorting to a 4.5-AE age for any component. Attention is given to petrographic constraints, isotopic investigations, and an evaluation of the Rb-Sr isotopic data. It is concluded that lunar rock 12013 is an extremely complex polymict breccia in which the Rb-Sr isotopic systematics have been greatly influenced by mixing during breccia formation and by subsequent reequilibration.

Quick, J. E.↗

Transition of surface energy budget in the Gobi Desert between spring and summer seasons

The surface energetics of the southwest Gobi Desert, including the temporal variations and diurnally averaged properties of the surface energy budget components, was investigated. The field program was conducted during the spring and summer of 1984, with the measurement system designed to monitor radiative exchange, heat/moisture storage in the soil, and sensible and latent heat exhange between the ground and the atmosphere. Results of the analysis reveal a seasonal transition feature not expected of a midlatitude desert. Namely, the differences in both surface radiation exchange and the distibution of sensible and latent heat transfer arise within a radiatively forced environment that barely deviates from spring to summer in terms of available solar energy at the surface. Both similarities and differences in the spring and summer surface energy budgets arise from differences imparted to the system by an increase in the summertime atmospheric moisture content. Changes in the near-surface mixing ratio are shown to alter the effectiveness of the desert surface in absorbing radiative energy and redistibuting it to the lower atmosphere through sensible and latent heat exchange.

Smith, Eric A.↗

Synthesis of H2 in dirty ice mantles by fast ion energy loss: New experimental results increase the relevance of this mechanism

Recent experimental results support the importance of H2 production in molecular clouds by cosmic ray bombardment of the mantles of grains. The formation of molecules different from those originally present in the irradiated layer can be explained by the production of molecular fragments induced by the release of energy if the impinging fast particle. One way of considering the process is in terms of a transiently hot cylinder, initially about 50 A in diameter, that exists around the track of an individual fast ion. Since ice has a relatively low thermal conductivity, energy lost by the ion in the ice layers remains confined around the track for time long enough to be thermalized. The hot cylinder increases in diameter and decreases in temperature on a time scale of 10(exp -11) to 10(exp -10) sec. Molecular fragments that are formed in this high temperature region acquire enough mobility to recombine with different partners, forming new molecules. A Monte Carlo simulation of the interaction between cosmic rays and grain mantles, at various depths in the core of a spherical molecular cloud, was performed. The simulation was continued until 40,000 ions had hit each grain of the type and size chosen. During the performed experiments thin icy films made of H2O and CD4 mixed in the gas phase and deposited on a cold finger at 9 K were irradiated with 1.5 MeV helium beams. Among synthesized molecules were found H2, HD, and D2.

Pirranello, Valero↗