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At least 1,081 records · Page 60

Ring Current Modeling in a Realistic Magnetic Field Configuration

A 3-dimensional kinetic model has been developed to study the dynamics of the storm time ring current in a dipole magnetic field. In this paper, the ring current model is extended to include a realistic, time-varying magnetic field model. The magnetic field is expressed as the cross product of the gradients of two Euler potentials and the bounce-averaged particle drifts are calculated in the Euler potential coordinates. A dipolarization event is modeled by collapsing a tail-like magnetosphere to a dipole-like configuration. Our model is able to simulate the sudden enhancements in the ring current ion fluxes and the corresponding ionospheric precipitation during the substorm expansion.

Fok, M.-C.↗

Increasing the Dynamic Pressure Capability of the NASA Langley/ODU 6-inch MSBS

The 6-inch NASA/ODU Magnetic Suspension and Balance System (MSBS) has been configured for dynamic stability testing of blunt-body atmospheric entry capsules. Tests have been successfully accomplished in the low-speed, open-circuit wind tunnel, at speeds up to around 40 m/s. The wind tunnel is designed to reach around 150 m/s, resulting in dynamic pressures comparable to those projected to arise in a future supersonic MSBS facility. Extensive system upgrades are being undertaken to permit testing at higher speeds/dynamic pressures, including control system enhancements, revised position and attitude sensing, and activation of additional electromagnets in the existing array. This paper will review recent progress in all these areas.

Mark Schoenenberger↗

Effects of an External Magnetic Field on Keyhole Mode Laser Melting of 316 Stainless Steel

Keyhole-mode laser melting is an efficient method for joining or cutting large, thick components, but controlling keyhole depth and fluctuations has remained challenging. Applying an external magnetic field can control melt pool flows and indirectly influence keyhole morphology and dynamics. The induced Lorentz force, comprising Seebeck and damping components, plays a crucial role in the melt pool dynamics, depending on temperature gradient, flow rates, and magnetic field orientation and magnitude. This research investigates the effects of an external magnetic field on keyhole behavior during laser spot melting of 316 stainless steel using synchronized high-speed synchrotron X-ray and thermal imaging. Findings revealed that a longitudinal magnetic field (120 mT) increased keyhole depth but exacerbated lateral fluctuations, resulted in a 20% increase in the melt pool temperature gradient and a 27% decrease in cooling rate. Conversely, a transverse magnetic field (760 mT) reduced keyhole depth and improved porosity formation. The findings suggest that a decrease in keyhole depth correlates with a decrease in fluctuations, and vice versa. These insights enhance understanding of external magnetic fields’ impact on laser melting, with implications for improving part quality.

Alamdari, Aslan Bafahm [The Ohio State Univ., Colu↗

Solar Dynamics Observatory and Hinode Observations of a Blowout Jet in a Coronal Hole

A blowout jet occurred within the south coronal hole on 9 February 2011 at 09:00 UT and was observed by the Atmospheric Imaging Assembly (AIA) and Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamics Observatory, and by the EUV Imaging Spectrometer (EIS) and X-Ray Telescope (XRT) onboard the Hinode spacecraft during coronal-hole monitoring performed as part of Hinode Operations Program No. 177. Images from AIA show expanding hot and cold loops from a small bright point with plasma ejected in a curtain up to 30 Mm wide. The initial intensity front of the jet had a projected velocity of 200 km/s, and the line-of-sight (LOS) velocities measured by EIS are between 100 and 250 km/s. The LOS velocities increased along the jet, implying that an acceleration mechanism operates within the body of the jet. The jet plasma had a density of 2.7×10(exp 8) /cu.cm and a temperature of 1.4 MK. During the event a number of bright kernels were seen at the base of the bright point. The kernels have sizes of ≈ 1000 km, are variable in brightness, and have lifetimes of 1 - 15 minutes. An XRT filter ratio yields temperatures of 1.5 - 3.0 MK for the kernels. The bright point existed for at least ten hours, but disappeared within two hours after the jet, which lasted for 30 minutes. HMI data reveal converging photospheric flows at the location of the bright point, and the mixed-polarity magnetic flux canceled over a period of four hours on either side of the jet.

Spectral line↗

Interfacial Stability of Converging Plasma Jets for Magnetized Target Fusion

The merging of a spherical distribution of plasma jets to dynamically form a gaseous liner has been proposed for use in magnetized target fusion propulsion. In this paper, a study is made of the interfacial stability of the interaction of these jets. Specifically, the Orr-Sommerfeld equation is integrated to obtain the growth rate of a perturbation to the primary flow at the interface between the colliding jets. The analysis lead to an estimate on the tolerances on the relative flow velocities of the merging plasma jets to form a stable, imploding liner. The results show that during the merging of the jets to form a liner and before contact with the target plasma the growth of the perturbed flow at the jet interface is not likely to destabilize the liner. These data suggest that, as far as the stability of the interface between the merging jets is concerned, the formation of liner can withstand velocity variation up to 50% between the neighboring jets over the density and temperature ranges investigated.

Cassibry, J. T.↗

Experiments on current-driven three-dimensional ion sound turbulence. I - Return-current limited electron beam injection. II - Wave dynamics

Pulsed electron beam injection into a weakly collisional magnetized background plasma is investigated experimentally; properties of the electron beam and background plasma, as well as the low-frequency instabilities and wave dynamics, are discussed. The current of the injected beam closes via a field-aligned return current of background electrons. Through study of the frequency and wavenumber distribution, together with the electron distribution function, the low-frequency instabilities associated with the pulsed injection are identified as ion acoustic waves driven unstable by the return current. The frequency cut-off of the instabilities predicted from renormalized plasma turbulence theory, has been verified experimentally.

Stenzel, R. L.↗

On the spatial range of validity of the gas dynamic model in the magnetosheath of Venus

In the past, the global solar wind interaction with Venus has been treated with gas dynamic models which, while successful in modeling some of the global characteristics of the interaction, do not include the magnetic barrier in a self-consistent manner. This magnetic barrier is formed in the inner magnetosheath where it transfers solar wind momentum flux to the obstacle via magnetic pressure. In this study, we examine the extent to which the gas dynamic fluid approximation describes the magnetic field in the dayside Venus magnetosheath by comparing with two gas dynamic models, one which matches the observed ionopause location and one which matches the bow shock location. We find that each model predicts the field profile reasonably well in the vicinity of the matched bow shock or ionopause, but neither model provides an adequate model over the entire range from the ionopause to the bow shock.

Zhang, T. L.↗

Net energy gain in direct laser acceleration due to enhanced dephasing induced by an applied magnetic field

Even in the situation where an electron interacts with a single plane wave, the well-known dynamical adiabaticity can be broken when an applied magnetic field is present, which will act to increase the dephasing rate of the electron during the interaction. Here we demonstrate this for the case where there is a uniform static magnetic field which is oriented either parallel or perpendicular to the electric field of the incident plane wave, and perpendicular to the direction of its propagation. The described energy gain phenomenon has direct relevance to laser-plasma interactions that involve external magnetic fields generated by laser-driven capacitor coils.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The plasmapause period of magnetic recovery. Combined study of OGO 4, OGO 5 data and of grounded whistler reception

The equatorial structure and dynamics of the plasmasphere during the period of magnetic recovery, lasting from the 13 to 23 of September 1968, are studied. The H(+) ions density profiles measured in the night and afternoon sectors by the excentered orbital satellite OGO 5 and L sub p positions of the plasmapause deduced from the VLF records of the polar orbital satellite OGO 4, are included. Electron densities are calculated from the whistlers received at Kerguelen (L approximately 3, 7) and Byrd (L approximately 7), ground stations 150 degrees of longitude apart.

Corcuff, P.↗

The Role of Asparagine as a Gatekeeper Residue in the Selective Binding of Rare Earth Elements by Lanthanide‐Binding Peptides

Abstract Lanthanide‐binding tag (LBT) peptides selectively complex lanthanide cations (Ln 3+ ) in their binding pockets and are promising for lanthanide separation. However, designing LBTs that selectively target specific Ln 3+ cations remains a challenge due to limited molecular‐level understanding and control of interactions within the lanthanide‐binding pocket. In this study, we reveal that the N5 asparagine residue acts as a gatekeeper in the binding pocket, resulting in a 100‐fold selectivity for smaller Lu 3+ over larger La 3+ cations. Nuclear magnetic resonance spectroscopy and molecular dynamics simulations show that the N5 residue weakly binds to the larger La 3+ cation, permitting H 2 O molecules inside the pocket. For the smaller Lu 3+ cations, the N5 residue forms an inter‐arm hydrogen bond with the E14 glutamic acid residue, locking the Lu 3+ cation in the pocket and preventing H 2 O infiltration. Mutating the N5 asparagine to a D5 aspartic acid prevents such a hydrogen bond, eliminating the gatekeeping mechanism and precipitously reducing selectivity. The resulting binding affinity to Ln 3+ cations is non‐monotonic but generally increases with cation size. These results suggest a molecular design paradigm: the reduced affinity for larger lanthanides is due to open pocket conformations, while the selectivity of smaller Ln 3+ cations over larger ones is due to the gatekeeping hydrogen bond.

Chemistry↗

Atomic defects, functional groups and properties in MXenes

MXenes, a new family of functional two-dimensional (2D) materials, have shown great potential for an extensive variety of applications within the last decade. Atomic defects and functional groups in MXenes are known to have a tremendous influence on the functional properties. In this review, we focus on recent progress in the characterization of atomic defects and functional group chemistry in MXenes, and how to control them to directly influence various properties ( e.g ., electron transport, Li + adsorption, hydrogen evolution reaction (HER) activity, and magnetism) of 2D MXenes materials. Dynamic structural transformations such as oxidation and growth induced by atomic defects in MXenes are also discussed. The review thus provides perspectives on property optimization through atomic defect engineering, and bottom-up synthesis methods based on defect-assisted homoepitaxial growth of MXenes.

36 MATERIALS SCIENCE↗

Fast ionic conduction achieved through the design and synthesis of ceramic heterointerfaces

Lithium (Li) chloride and iron oxychloride (FeOCl), typically nonconductive, were combined to form a [Li 1+δ Cl] δ+ /[FeOCl] δ- heterointerface composite material (LFH), achieving ionic conductivities of >1 mS cm -1 . Analysis techniques (scanning transmission electron microscopy [STEM] and electron energy-loss spectroscopy [EELS]) indicated that the microstructure of LFH consisted of an amorphous LiCl-based shell surrounding a crystalline FeOCl-based core. Electrochemical measurements alongside solid-state 6,7 Li nuclear magnetic resonance (NMR) and molecular dynamic simulations revealed Li+ as the sole conductive species, with a diffusion barrier of ~0.25 eV. X-ray photoelectron spectroscopy (XPS) and X-ray absorption fine structure (XAFS) results further supported interstitial Li + diffusion at the heterointerface and within the LiCl phase, made possible by the heterointerface. Despite susceptibility to electronic conductivity, iron’s defects and multivalency (Fe³⁺, Fe²⁺) enable the Fe–O–Cl framework to accept Cl - , facilitating Li⁺ ionic conduction. Finally, a prototype solid-state cell (showing 97% Coulombic efficiency) demonstrated the viability of this heterointerface design for applications in energy storage.

36 MATERIALS SCIENCE↗

Anomalous neutron nuclear-magnetic interference spectroscopy

The electron–phonon interaction plays a critical role in materials’ electrical, thermal, optical, and superconducting properties. However, measuring the phonon mode-resolved electron–phonon interaction has been challenging. Here we propose neutron-scattering-based Anomalous Neutron nUclear-Magnetic Interference Spectroscopy (ANUBIS), where the co-existence of neutron nuclear scattering and magnetic scattering leads to anomalous dynamical structure factor under the presence of the electron–phonon interaction. Such anomalous structure factor is linear in electron–phonon coupling constant at the phonon wavevector, and is directly proportional to the momentum and energy-resolved dielectric function. The experimental configuration can be achieved using existing polarized inelastic neutron scattering setup, and an order-of-magnitude estimate shows the viability to observe the anomalous scattering signal is around to 10 –4 to 10 –3 relative to phonon scattering, which is examined through the preliminary experiments and achievable at emerging neutron facilities. As a result, our proposal offers an alternative neutron-based metrology to probe the crucial electronic properties.

Electron-phonon interactions↗

Polyethylene in Dead-End Silica Nanopores: Forces and Mobility from Non-Equilibrium Statistical Mechanics and Exchange Spectroscopy Nuclear Magnetic Resonance

Billions of tons of plastic have been produced, and only a small fraction of this has been recycled. Tennakoon et al. [Nature Catalysis 3, 893 (2020)] developed a catalyst that repeatedly cleaves C 10 –C 30 hydrocarbons from the end of a polyethylene chain. The reaction occurs at a Pt nanoparticle at the base of a cylindrical silica mesopore with a diameter of 2 nm and a length of 110 nm. Portions of the polymer situated inside the pore can be differentiated from those outside using 13 C nuclear magnetic resonance (NMR), allowing the dynamics and extent of polymer threading to be monitored using two-dimensional (2D) exchange spectroscopy NMR. Here we construct a Fokker–Planck equation for the polymer dynamics by assuming a reptation diffusivity and a graduated adsorption free energy that depends linearly on the depth of polymer penetration in the pore. The solutions allow us to predict the intensities of the 2D NMR resonances as a function of time. We use the solutions to extract a polymer diffusivity at each temperature and estimate the per-segment desorption free energy, enthalpy, and entropy. Random and systematic errors are examined to test key assumptions in the theory and interpretation of the experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cr-Doped Ge-Core/Si-Shell Nanowire: An Antiferromagnetic Semiconductor

An antiferromagnet offers many important functionalities such as opportunities for electrical control of magnetic domains, immunity from magnetic perturbations, and fast spin dynamics. Introducing some of these intriguing features of an antiferromagnet into a low dimensional semiconductor core–shell nanowire offers an exciting pathway for its usage in antiferromagnetic semiconductor spintronics. Here, using a quantum mechanical approach, we predict that the Cr-doped Ge-core/Si-shell nanowire behaves as an antiferromagnetic semiconductor. In this work, the origin of antiferromagnetic spin alignments between Cr is attributed to the superexchange interaction mediated by the p z orbitals of the Ge atoms that are bonded to Cr. A weak spin–orbit interaction was found in this material, suggesting a longer spin coherence length. The spin-dependent quantum transport calculations in the Cr-doped nanowire junction reveals a switching feature with a high ON/OFF current ratio (~41 times higher for the ON state at a relatively small bias of 0.83 V).

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A New Class of Ionically Conducting Fluorinated Ether Electrolytes with High Electrochemical Stability

Increasing battery energy density is greatly desired for applications such as portable electronics and transportation. However, many next-generation batteries are limited by electrolyte selection because high ionic conductivity and poor electrochemical stability are typically observed in most electrolytes. For example, ether-based electrolytes have high ionic conductivity but are oxidatively unstable above 4 V, which prevents the use of high-voltage cathodes that promise higher energy densities. In contrast, hydrofluoroethers (HFEs) have high oxidative stability but do not dissolve lithium salt. Here, we synthesize a new class of fluorinated ether electrolytes that combine the oxidative stability of HFEs with the ionic conductivity of ethers in a single compound. We show that conductivities of up to 2.7 × 10 –4 S/cm (at 30 °C) can be obtained with oxidative stability up to 5.6 V. The compounds also show higher lithium transference numbers compared to typical ethers. Furthermore, we use nuclear magnetic resonance (NMR) and molecular dynamics (MD) to study their ionic transport behavior and ion solvation environment, respectively. Finally, we demonstrate that this new class of electrolytes can be used with a Ni-rich layered cathode (NMC 811) to obtain over 100 cycles at a C/5 rate. The design of new molecules with high ionic conductivity and high electrochemical stability is a novel approach for the rational design of next-generation batteries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spectral Properties and Energy Injection in Mercury's Magnetotail Current Sheet

Mercury's magnetotail hosts a thin and highly dynamic current sheet (CS), where magnetic reconnection and strong fluctuations frequently occur. Here, we statistically analyze magnetic field power spectra across 370 magnetotail CSs observed by MESSENGER. About 20% of the events are quasi-laminar, showing single power-law spectra, whereas ∼80% are turbulent, exhibiting a spectral break separating inertial and kinetic ranges. A dawn–dusk asymmetry is identified: inertial-range slopes are systematically shallower on the dawnside, whereas kinetic-range slopes are steeper, indicating more developed turbulence there, consistent with the higher occurrence of reconnection-related processes on the dawnside. Component analysis shows that the transverse components, orthogonal to the tail-aligned principal field ( B X ), display shallow slopes near −1 in the inertial range, suggesting energy injection at ion scales rather than a classical inertial range. These results demonstrate that Mercury's unique plasma environment fundamentally reshapes the initiation of turbulence and the redistribution of energy in the magnetotail.

Mercury↗

Aberrant electronic and structural alterations in pressure tuned perovskite NaOsO 3

The perovskite NaOsO 3 has a metal–insulator transition at temperature 410 K, which is delicate, intriguing, and provokes a lot of debate on its nature. Our combined electrical resistance, Raman, and synchrotron x-ray diffraction experiments show that the insulating ground state in this osmate endures under high pressure up to at least 35 GPa. In this pressure range, compression reveals hidden hysteretic resistance properties with a transient metallic state near 200 K, manifested three electronic character anomalies (at 1.7, 9.0, and 25.5 GPa), and a structural transition to the singular polar phase (at ~18 GPa). We distinguish NaOsO 3 from the regular crystallographic behavior of perovskites, though the electrical specificities resemble iridates and nickelates. The theoretical first-principle band structure and lattice dynamics calculations demonstrate that the magnetically itinerant Lifshitz-type mechanism with spin–orbit and spin–phonon interactions is responsible for these pressure-induced changes. Our findings provide another new playground for the emergence of new states in 5d materials by using high-pressure methods.

36 MATERIALS SCIENCE↗