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At least 1,081 records · Page 60

Pre-exercise glycerol hydration improves cycling endurance time

The effects of glycerol ingestion (GEH) on hydration and subsequent cycle ergometer submaximal load exercise were examined in well conditioned subjects. We hypothesized that GEH would reduce physiologic strain and increase endurance. The purpose of Study I (n = 11) was to determine if pre-exercise GEH (1.2 gm/kg glycerol in 26 ml/kg solution) compared to pre-exercise placebo hydration (PH) (26 ml/kg of aspartame flavored water) lowered heart rate (HR), lowered rectal temperature (Tc), and prolonged endurance time (ET) during submaximal load cycle ergometry. The purpose of Study II (n = 7) was to determine if the same pre-exercise regimen followed by carbohydrate oral replacement solution (ORS) during exercise also lowered HR, Tc, and prolonged ET. Both studies were double-blind, randomized, crossover trials, performed at an ambient temperature of 23.5-24.5 degrees C, and humidity of 25-27%. Mean HR was lower by 2.8 +/- 0.4 beats/min (p = 0.05) after GEH in Study I and by 4.4 +/- 1.1 beats/min (p = 0.01) in Study II. Endurance time was prolonged after GEH in Study I (93.8 +/- 14 min vs. 77.4 +/- 9 min, p = 0.049) and in Study II (123.4 +/- 17 min vs. 99.0 +/- 11 min, p = 0.03). Rectal temperature did not differ between hydration regimens in both Study I and Study II. Thus, pre-exercise glycerol-enhanced hyperhydration lowers HR and prolongs ET even when combined with ORS during exercise. The regimens tested in this study could potentially be adapted for endurance activities.

Non-NASA Center↗

Non-standard interactions in radiative neutrino mass models

Models of radiative Majorana neutrino masses require new scalars and/or fermions to induce lepton-number-violating interactions. We show that these new particles also generate observable neutrino non-standard interactions (NSI) with matter. We classify radiative models as type-I or II, with type-I models containing at least one Standard Model (SM) particle inside the loop diagram generating neutrino mass, and type-II models having no SM particle inside the loop. While type-II radiative models do not generate NSI at tree-level, popular models which fall under the type-I category are shown, somewhat surprisingly, to generate observable NSI at tree-level, while being consistent with direct and indirect constraints from colliders, electroweak precision data and charged-lepton flavor violation (cLFV). We survey such models where neutrino masses arise at one, two and three loops. In the prototypical Zee model which generates neutrino masses via one-loop diagrams involving charged scalars, we find that diagonal NSI can be as large as (8%, 3.8%, 9.3%) for (ε$_{ee}$, ε$_{μμ}$, ε$_{ττ}$), while off-diagonal NSI can be at most (10$^{–3}$%, 0.56%, 0.34%) for (ε$_{eμ}$, ε$_{eτ}$, ε$_{μτ}$). In one-loop neutrino mass models using leptoquarks (LQs), (ε$_{μμ}$, ε$_{ττ}$) can be as large as (21.6%, 51.7%), while ε$_{ee}$ and (ε$_{eμ}$, ε$_{eτ}$, ε$_{μτ}$) can at most be 0.6%. Other two- and three-loop LQ models are found to give NSI of similar strength. The most stringent constraints on the diagonal NSI are found to come from neutrino oscillation and scattering experiments, while the off-diagonal NSI are mostly constrained by low-energy processes, such as atomic parity violation and cLFV. We also comment on the future sensitivity of these radiative models in long-baseline neutrino experiments, such as DUNE. While our analysis is focused on radiative neutrino mass models, it essentially covers all NSI possibilities with heavy mediators.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Nucleon momentum fraction, helicity and transversity from 2+1-flavor lattice QCD

A detailed analysis of the systematic uncertainties in the calculation of the isovector momentum fraction, ( x ) u - d , helicity moment, ( x ) Δ u - Δ d , and the transversity moment, ( x ) δu - δd , of the nucleon is presented using high-statistics data on seven ensembles of gauge configurations generated by the JLab/W&M/LANL/MIT collaborations using 2 + 1-flavors of dynamical Wilson-clover quarks. The much higher statistics have facilitated better control over all systematics compared to previous lattice calculations. The least understood systematic — excited-state contamination — is quantified by studying the variation of the results as a function of different estimates of the mass gap of the first excited state, obtained from two- and three-point correlation functions, and as a function of the pion mass M π . The final results are obtained using a simultaneous fit in the lattice spacing a , pion mass M π and the finite volume parameter M π L keeping leading order corrections. The data show no significant dependence on the lattice spacing and some evidence for finite-volume corrections. Our final results, in the $ \overline{\mathrm{MS}} $ scheme at 2 GeV, are ( x ) u - d = 0 . 155(17)(20), ( x ) Δ u - Δ d = 0 . 183(14)(20) and ( x ) δu - δd = 0 . 220(18)(20), where the first error is the overall analysis uncertainty assuming excited-state contributions have been removed, and the second is an additional systematic uncertainty due to possible residual excited-state contributions. These results are consistent with phenomenological global fit values.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Dark Matter and Track Triggering with the CMS Experiment (Final Report)

This report summarizes the progress from DOE Early Career Award entitled “Dark Matter and Track Triggering with the CMS Experiment”. The first major goal of the project was to establish a sensitive Dark Matter (DM) search program for the CMS experiment in Run-2 of the LHC. Two related strategies were developed to accomplish this goal. First, we designed and executed searches for DM produced in association with heavy flavor quark pairs, top/anti-top (ttbar) and bottom/anti-bottom (bbbar). In addition, we sought to maximize the power of Run-2 DM searches through the development of a statistical combination of all major search channels within a consistent theoretical framework. The results of these aspects of the project are detailed in Section 1. The second major goal of the project was to develop a real-time “Level-1” tracking trigger system for the high-luminosity LHC (HL-LHC) CMS upgrade. Charged particle tracking in the first stage of the CMS trigger will be crucial for surviving the high-pileup environment expected at the HL-LHC. The L1 tracking trigger must process all front-end hit data sent from the inner Tracker and will have just 4us to output track primitives to the downstream L1 trigger without data loss. Our development of the CMS tracking trigger is described in Section 2. The team supported by the award is given in Section 3. The project resulted in 10 peer reviewed publications, a graduate student thesis, and contributions to the CMS Phase-2 Tracker Technical Design Report, as is detailed in Section 4. Our development work for the CMS tracking trigger has been integrated in the backend system architecture for the Tracker upgrade.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Search for a Sterile Neutrino in a 3+1 Framework using the Wire-Cell Inclusive Charged-Current $ν_e$ Selection from MicroBooNE

A search for a sterile neutrino is being carried out in the MicroBooNE experiment within the 3+1 (three flavors of active neutrinos + one flavor of sterile neutrino) framework using neutrinos from the Booster Neutrino Beam (BNB) at a baseline of about 470 m with an average neutrino energy of 800 MeV. The sensitivity of this search is built upon high performance inclusive charged-current electron neutrino ($ν_e$) and muon neutrino ($ν_µ$) event selections, which were utilized in the previous search for a low-energy excess (LEE) in the $ν_e$ energy spectrum at MicroBooNE. In this note, we present the results of a 3+1 oscillation fit considering both $ν_e$ appearance and $ν_e$/$ν_µ$ disappearance. Using the first three years’ BNB data, no evidence of a light sterile neutrino was found and 95% C.L. exclusion limits were calculated in the 3+1 neutrino oscillation parameter space. Notably, the cancellation between $ν_e$ disappearance and $ν_e$ appearance oscillations leads to a reduced oscillation effect in the $ν_e$ energy spectrum resulting in a degeneracy of the oscillation parameters. Such a degeneracy is expected to be mitigated by including the neutrino events from the off-axis Neutrino from the Main Injector (NuMI) beam. The prospect of a 3+1 oscillation analysis using both BNB and NuMI is reported and it is expected to considerably improve the sensitivity to 3+1 neutrino oscillations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Fast collective neutrino oscillations inside the neutrino sphere in core-collapse supernovae

Neutrinos are believed to have a key role in the explosion mechanism of core-collapse supernovae as they carry most of the energy released by the gravitational collapse of a massive star. If their flavor is converted fast inside the neutrino sphere, the supernova explosion may be influenced. This paper is reporting the results of the extended work of our previous paper. Here, we perform a thorough survey of the electron lepton number (ELN) crossing in one of our self-consistent, realistic Boltzmann simulations in two spatial dimensions under axisymmetry for the existence of the crossings between $ν_e$ and $\bar{ν}_e$ angular distributions, or the ELN crossing. We report for the first time the positive detections deep inside the core of the massive star in the vicinity of neutrino sphere at $\textit{r}$ ≈ 16 – 21 km . We find that low values of the electron fraction $Y_e$ produced by convective motions together with the appearance of light elements are critically important to give rise to the ELN crossing by enhancing the chemical potential difference between proton and neutron, and hence by mitigating the Fermi-degeneracy of $ν_e$. Since the region of positive detection are sustained and, in fact, expanding with time, it may have an impact on the explosion of core-collapse supernovae, observational neutrino astronomy, and nucleosynthesis of heavy nuclei.

79 ASTRONOMY AND ASTROPHYSICS↗

Neutrino-induced charged-current coherent pion production for constraining the muon neutrino flux at DUNE

We study neutrino-induced charged-current coherent pion production ( ν μ CC - Coh π ) as a tool for constraining the neutrino flux at the Deep Underground Neutrino Experiment (DUNE). The neutrino energy and flavor in the process can be directly reconstructed from the outgoing particles, making it especially useful to specifically constrain the muon neutrino component of the total flux. The cross section of this process can be obtained using the Adler relation with the π -Ar elastic scattering cross section taken either from external data or, as we explore, from a simultaneous measurement in the DUNE near detector. We develop a procedure that leverages ν μ CC - Coh π events to fit for the neutrino flux while simultaneously accounting for relevant effects in the cross section. We project that this method has the statistical power to constrain the uncertainty on the normalization of the flux at its peak to a few percent. This study demonstrates the potential utility of a ν μ CC - Coh π flux constraint, though further work will be needed to determine the range of validity and precision of the Adler relation upon which it relies, as well as to measure the π -Ar elastic scattering cross section to the requisite precision. We discuss the experimental and phenomenological developments necessary to unlock the ν μ CC - Coh π process as a “standard candle” for neutrino experiments.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

New method for detecting fast neutrino flavor conversions in core-collapse supernova models with two-moment neutrino transport

Fast-pairwise neutrino oscillations potentially affect many aspects of core-collapse supernovae (CCSNe): the explosion mechanism, neutrino signals, and nucleosynthesis in the ejecta. This particular mode of collective neutrino oscillations has a deep connection to the angular structure of neutrinos in momentum space; for instance, the appearance of electron-neutrino lepton number (ELN) angular crossings in momentum space is a good indicator of the occurrence of flavor conversions. However, many multidimensional CCSN simulations are carried out with approximate neutrino transport (such as two-moment methods), which limits access to the angular distributions of neutrinos, i.e., inhibits ELNcrossing searches. In this paper, we develop a new method of searching for ELN crossing in these CCSN simulations. The required data is the zeroth and first angular moments of neutrinos and the matter profile, all of which are available in CCSN models with the two-moment method. One of the novelties of our new method is the use of a ray-tracing neutrino transport to determine ELNs in the direction of the stellar center. It is designed to compensate for shortcomings of the crossing searches with only two angular moments. We assess the capability of the method by carrying out a detailed comparison with results of full Boltzmann neutrino transport in 1D and 2D CCSN models. In this work, we find that the ray-tracing neutrino transport improves the accuracy of crossing searches; indeed, the appearance/disappearance of the crossings is accurately detected even in the region of forward-peaked angular distributions. The new method is computationally cheap and has the benefit of efficient parallelization; hence, it will be useful for ELN-crossing searches in any CCSN models that employ two-moment neutrino transport.

79 ASTRONOMY AND ASTROPHYSICS↗

Standard versus non-standard CP phases in neutrino oscillation in matter with non-unitarity

We formulate a perturbative framework for the flavor transformation of the standard active three neutrinos but with a non-unitary flavor mixing matrix, a system which may be relevant for the leptonic unitarity test. We use the $\alpha$ parametrization of the non-unitary matrix and take its elements $\alpha_{\beta \gamma}$ ($\beta,\gamma = e,\mu,\tau$) and the ratio $\epsilon \simeq \Delta m^2_{21} / \Delta m^2_{31}$ as the small expansion parameters. Two qualitatively new features that hold in all the oscillation channels are uncovered in the probability formula obtained to first order in the expansion: (1) The phases of the complex $\alpha$ elements always come into the observable in the particular combination with the $\nu$SM CP phase $\delta$ in the form $[e^{- i \delta } \bar{\alpha}_{\mu e}, ~e^{ - i \delta} \bar{\alpha}_{\tau e}, ~\bar{\alpha}_{\tau \mu}]$ under the Particle Data Group convention of a unitary $\nu$SM mixing matrix. (2) The diagonal $\alpha$ parameters appear in particular combinations $\left( a/b - 1 \right) \alpha_{ee} + \alpha_{\mu \mu}$ and $\alpha_{\mu \mu} - \alpha_{\tau \tau}$, where $a$ and $b$ denote, respectively, the matter potential due to charged current and neutral current reactions. This property holds only in the unitary evolution part of the probability, and there is no such feature in the genuine non-unitary part, while the $\delta$–$\alpha$ parameter phase correlation exists for both. The reason for such remarkable stability of the phase correlation is discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Shedding Light on Primary Donors in Photosynthetic Reaction Centers

Chlorophylls (Chl)s exist in a variety of flavors and are ubiquitous in both the energy and electron transfer processes of photosynthesis. The functions they perform often occur on the ultrafast (fs–ns) time scale and until recently, these have been difficult to measure in real time. Further, the complexity of the binding pockets and the resulting protein-matrix effects that alter the respective electronic properties have rendered theoretical modeling of these states difficult. Recent advances in experimental methodology, computational modeling, and emergence of new reaction center (RC) structures have renewed interest in these processes and allowed researchers to elucidate previously ambiguous functions of Chls and related pheophytins. This is complemented by a wealth of experimental data obtained from decades of prior research. Studying the electronic properties of Chl molecules has advanced our understanding of both the nature of the primary charge separation and subsequent electron transfer processes of RCs. In this review, we examine the structures of primary electron donors in Type I and Type II RCs in relation to the vast body of spectroscopic research that has been performed on them to date. Further, we present density functional theory calculations on each oxidized primary donor to study both their electronic properties and our ability to model experimental spectroscopic data. This allows us to directly compare the electronic properties of hetero- and homodimeric RCs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Probing mass orderings in presence of a very light sterile neutrino in a liquid argon detector

Results from experiments like LSND and MiniBooNE hint towards the possible presence of an extra eV scale sterile neutrino. The addition of such a neutrino will significantly impact the standard three flavor neutrino oscillations. In particular, it can give rise to additional degeneracies due to additional sterile parameters. For an eV scale sterile neutrino, the cosmological constraints dictate that the sterile state is heavier than the three active states. However, for lower masses of sterile neutrinos, the sterile state can be lighter than one and/or more of the three states. In such cases, the mass ordering of the sterile neutrinos also becomes unknown, along with the mass ordering of the active states. In this paper, we explore the mass ordering sensitivity in the presence of a sterile neutrino assuming the mass squared difference |Δ 41 | to be in the range 10 –4 –1 eV 2 . We study (i) how the ordering of the active states, i.e. the determination of the sign of Δ 31 gets affected by the presence of a sterile neutrino in the above mass range, (ii) the possible determination of the sign of Δ 41 for Δ 41 in the range 10 –4 –0.1 eV 2 . This analysis is done in the context of a liquid argon detector using beam neutrinos traveling a distance of 1300 km and atmospheric neutrinos that propagate through a distance ranging from 10 – 10000 km, allowing resonant matter effects. Apart from presenting separate results from these sources, we also do a combined study and probe the synergy between these two in giving an enhanced sensitivity.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Production of b b ¯ at forward rapidity in p + p collisions at s = 510 GeV

The cross section of bottom quark-antiquark ( b b ¯ ) production in p + p collisions at s = 510 GeV is measured with the PHENIX detector at the Relativistic Heavy Ion Collider. The results are based on the yield of high mass, like-sign muon pairs measured within the PHENIX muon arm acceptance ( 1.2 < | y | < 2.2 ). The b b ¯ signal is extracted from like-sign dimuons by utilizing the unique properties of neutral B meson oscillation. We report a differential cross section of d σ b b ¯ → μ ± μ ± / d y = 0.16 ± 0.01 ( stat ) ± 0.02 ( syst ) ± 0.02 ( global ) nb for like-sign muons in the rapidity and p T ranges 1.2 < | y | < 2.2 and p T > 1 GeV / c , and dimuon mass of 5 – 10 GeV / c 2 . The extrapolated total cross section at this energy for b b ¯ production is 13.1 ± 0.6 ( stat ) ± 1.5 ( syst ) ± 2.7 ( global ) μ b . The total cross section is compared to a perturbative quantum chromodynamics calculation and is consistent within uncertainties. The azimuthal opening angle between muon pairs from b b ¯ decays and their p T distributions are compared to distributions generated using ps pythia 6, which includes next-to-leading order processes. The azimuthal correlations and pair p T distribution are not very well described by pythia calculations, but are still consistent within uncertainties. Flavor creation and flavor excitation subprocesses are favored over gluon splitting.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Detectability of collective neutrino oscillation signatures in the supernova explosion of a 8.8 M ⊙ star

In order to investigate the impact of collective neutrino oscillations (CNOs) on the neutrino signal from a nearby supernova, we perform three-flavor neutrino oscillation simulations employing the multiangle effect. The background hydrodynamic model is based on the neutrino hydrodynamic simulation of a 8.8 M ⊙ progenitor star. In this work, we find that CNO commences after some 100 ms post bounce. Before this, CNO is suppressed by matter-induced decoherence. In the inverted mass hierarchy, the spectrum of $\bar{ν}_e$ becomes softer after the onset of CNO. To evaluate the detectability of this modification, we define a hardness ratio between the number of high energy neutrino events and low energy neutrino events adopting a fixed critical energy. We show that Hyper-Kamiokande (HK) can distinguish the effect of CNO for supernova distances out to ~ 10 kpc. On the other hand, for the normal mass hierarchy, the spectrum of ν e becomes softer after the onset of CNO, and we show that DUNE can distinguish this feature for supernova distances out to ~ 10 kpc . More work is necessary to optimize the best value of critical energy for maximum sensitivity. We also show that if the spectrum of $\bar{ν}_e$ in HK becomes softer due to CNO, the spectrum of $ν_e$ in DUNE becomes harder, and vice versa. These synergistic observations in $\bar{ν}_e$ and $ν_e$, by HK and DUNE, respectively, will be an intriguing opportunity to test the occurrence of CNO.

79 ASTRONOMY AND ASTROPHYSICS↗

The NuMI Flux Prediction at ICARUS

The Deep Underground Neutrino Experiment (DUNE) is a next-generation long-baseline neutrino oscillation experiment seeking to probe fundamental symmetries within the structure of the Pontecorvo-Maki-Nakagawa-Sakata (PMNS) mixing matrix, and perform precision measurements its parameters including the neutrino mass ordering via the sign of $\Delta m^2_{31}$, and the charge-parity violating phase, $\delta_{CP}$. To make these measurements with high precision, DUNE will require external $\nu$-Ar scattering cross section data as a crucial input to the oscillation fit. Imaging Cosmic And Rare Underground Signals (ICARUS) is a 476 t liquid argon neutrino detector located at Fermi National Accelerator Laboratory (FNAL) where it is serving as the far detector for the Short-Baseline Neutrino (SBN) program along the Booster Neutrino Beam (BNB) axis. ICARUS additionally lies 795 m downstream and 100.1 mrad off-axis of the Neutrinos at the Main Injector (NuMI) neutrino beam. From this position, ICARUS is exposed to a large flux of NuMI (anti-)electron and (anti-)muon neutrinos, and poses a unique opportunity to provide high-statistics measurements of quasi-elastic and single pion-production cross sections for four neutrino flavors ($\nu_{\mu}$, $\nu_{e}$, $\bar{\nu}_{\mu}$, $\bar{\nu}_{e}$). This dissertation is centered around accurately characterizing the models and estimating their precision for use in making these measurements. This includes identifying major sources of uncertainty in the models such that they can be properly propagated to the cross section measurements. Specifically, this work focused on the model of the NuMI beamline and its impact on the neutrino fluxes, but also delved into the detector response model and its impact on reconstructed observables in the detector. Significant efforts were made to improve the characterization to enhance precision and thus reduce the level of propagated uncertainty. In particular, the NuMI flux was determined to be composed of 57% $\nu_{\mu}$, 38% $\bar{\nu}_{\mu}$, 3% $\nu_{e}$, and 2% $\bar{\nu}_{e}$ while the horns are operating in the positive-particle focusing configuration. The total uncertainty on the $\nu_{\mu} + \bar{\nu}_{\mu}$ ($\nu_{e} + \bar{\nu}_{e}$) flux while operating in the forward horn operating mode was determined to be 10.84% (9.04%). Compared to the on-axis flux, mesons that eventually decay to neutrinos more frequently reinteract within the NuMI structure, resulting in elevated uncertainty as these processes are not well-constrained by existing hadron interaction cross section measurements. Covariance matrices were calculated to propagate the flux uncertainty characterization to NuMI analyses.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Nucleon Isovector Axial Form Factors

We present results for the isovector axial vector form factors obtained using thirteen 2 + 1 + 1-flavor highly improved staggered quark (HISQ) ensembles generated by the MILC collaboration. The calculation of nucleon two- and three-point correlation functions has been done using Wilson-clover fermions. In the analysis of these data, we quantify the sensitivity of the results to strategies used for removing excited state contamination and invoke the partially conserved axial current relation between the form factors to choose between them. Our data driven analysis includes removing contributions from multihadron $Nπ$ states that make significant contributions. Our final results are $g_A$ = 1.292(53) stat (24) sys for the axial charge; $g_S$ = 1.085(50) stat (103) sys and $g_T$ = 0.991(21) stat (10) sys for the scalar and tensor charges; $\langle{r^2_A}\rangle$ = 0.439(56) sta t(34) sys fm 2 for the mean squared axial charge radius, $g^*_P$ = 9.03(47) stat (42) sys for the induced pseudoscalar charge; and $g_{πNN}$ = 14.14(81) stat (85) sys for the pion-nucleon coupling. We also provide a parametrization of the axial form factor $G_A(Q^2)$ over the range 0 ≤ $Q^2$ ≤ 1 GeV 2 for use in phenomenology and a comparison with other lattice determinations. We find that the various lattice data agree within 10% but are significantly different from the extraction of $G_A(Q^2)$ from the $ν$-deuterium scattering data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Search for heavy right-handed Majorana neutrinos in the decay of top quarks produced in proton-proton collisions at s = 13 TeV with the ATLAS detector

A search for heavy right-handed Majorana neutrinos is performed with the ATLAS detector at the CERN Large Hadron Collider, using the 140 fb -1 of proton–proton collision data at $\sqrt{s}$ =13 TeV collected during Run 2. This search targets $t\overline{t}$ production, in which both top quarks decay into a bottom quark and a W boson, where one of the W bosons decays hadronically and the other decays into an electron or muon and a heavy neutral lepton. The heavy neutral lepton is identified through a decay into an electron or muon and another W boson, resulting in a pair of same-charge same-flavor leptons in the final state. This paper presents the first search for heavy neutral leptons in the mass range of 15–75 GeV using $t\overline{t}$ events. No significant excess is observed over the background expectation, and upper limits are placed on the signal cross sections. Assuming a benchmark scenario of the phenomenological type-I seesaw model, these cross section limits are then translated into upper limits on the mixing parameters of the heavy Majorana neutrino with Standard Model neutrinos.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Elucidating the Role of Water on Limonene Oxidation with H 2 O 2 over γ -Al 2 O 3

Limonene oxide, which is produced from limonene epoxidation, is a valuable molecule that can be applied in flavor, fragrance, and renewable polymer applications. A catalytic reaction system using H 2 O 2 with γ-Al 2 O 3 and ethyl acetate (EtOAc) as the solvent has been explored as an effective system for this reaction. In these previous studies, a number of postulates have been proposed as to how water affects the reaction; therefore, the focus of this work is to elucidate the role of water in limonene epoxidation. While not impacting the selectivity to limonene oxide, the amount of water in the reaction system is shown to significantly impact the limonene reactivity. Furthermore, through both addition of excess water and removal of water with a Dean–Stark apparatus, the control of the H 2 O 2 /H 2 O ratio is demonstrated to be the primary factor controlling reactivity. In contrast, changes in limonene concentrations for a specific H 2 O 2 /H 2 O ratio are shown to have little impact on the reaction rate. This study shows that the competitive adsorption of H 2 O 2 and water on the catalyst surface is key in explaining the water impact on the reaction performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Detection of astrophysical tau neutrino candidates in IceCube

High-energy tau neutrinos are rarely produced in atmospheric cosmic-ray showers or at cosmic particle accelerators, but are expected to emerge during neutrino propagation over cosmic distances due to flavor mixing. When high energy tau neutrinos interact inside the IceCube detector, two spatially separated energy depositions may be resolved, the first from the charged current interaction and the second from the tau lepton decay. We report a novel analysis of 7.5 years of IceCube data that identifies two candidate tau neutrinos among the 60 “High-Energy Starting Events” (HESE) collected during that period. The HESE sample offers high purity, all-sky sensitivity, and distinct observational signatures for each neutrino flavor, enabling a new measurement of the flavor composition. The measured astrophysical neutrino flavor composition is consistent with expectations, and an astrophysical tau neutrino flux is indicated at 2.8σ significance.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗