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At least 1,081 records · Page 60

Understanding the role of flow dynamics in thermoacoustic combustion instability

Thermoacoustic combustion instability is one of the most challenging operational issues in several high-performance, low-emissions combustion technologies, including gas turbines, aircraft engines, rockets, and industrial boilers. Driven by the coupling between combustor acoustics and flame heat release rate fluctuations, thermoacoustic combustion instability can lead to reduced operability, increased emissions, and, in the most extreme cases, catastrophic failure of combustor components. The feedback loop between acoustics and combustion is often facilitated by fluid mechanic oscillations, referred to as “velocity coupling,” whereby acoustic oscillations drive flow fluctuations, which in turn create fluctuations in the flame. The character of these fluid mechanic oscillations is highly dependent on the structure of the flow field and the receptivity of the flow to external excitation. Combustor flow fields use features like fluid recirculation and shear to enhance flame holding and reduce emissions, but these are also the same features that can make the flow receptive to acoustic excitation or even drive self-excited oscillations. Here, in this paper, we discuss the basics of thermoacoustic instability with a focus on the role of hydrodynamic oscillations in typical combustor flows. To facilitate this discussion, we explore the hydrodynamic instability characteristics of several key combustor unit flows (wakes, swirling jets, etc.) and show how the hydrodynamic stability of a flow is an important consideration in determining a combustor’s propensity for thermoacoustic oscillations. Several examples of coupling between hydrodynamics and thermoacoustics are discussed to illustrate this important link. The paper concludes by discussing the potential for designing flow fields that are thermoacoustic instability resistant, either through a reduction in the receptivity of the flow or through nonlinear coupling mechanisms by which self-excited flow instabilities can suppress velocity-coupled combustion oscillations.

42 ENGINEERING↗

Specific Gamma-Ray Dose Constants with Current Emission Data

The specific gamma-ray dose constant represents the gamma effective dose rate due to a point source of unit activity of a given nuclide at 1 m. New tabulations of specific gamma-ray dose constants have been made using current gamma emission data from the SCALE 6.2.3 software package and International Commission on Radiological Protection Publication 107, combined with the effective dose per fluence conversion coefficients (antero-posterior orientation) of International Commission on Radiological Protection Publication 116. SCALE data cover 1,264 nuclides, and International Commission on Radiological Protection Publication 107 data include 1,192 nuclides, with only 777 nuclides in common between the two sets.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Quantifying uncertainty in Pareto estimates of global lake area

Abstract Size is a critical factor determining the rate and occurrence of specific lake processes such as carbon sequestration and greenhouse gas emissions and emerging evidence suggests that small lakes in particular have particularly large CO 2 flux rates. Because we do not have a complete census of all lakes, upscaling estimates of such processes to small lakes at broad spatial scales requires the use of lake size‐abundance distributions rather than empirical measurements of area. Existing lake census efforts are incomplete such that as lakes become smaller, they are more likely to be omitted either because they are too small to be resolved from remote sensing products or because of limited ground surveying effort (i.e., “censoring” of small lakes relative to large lakes). The present study explores one potential shortcoming of prior approaches estimating global lake area using lake size‐abundance distributions. Namely, that these prior approaches rely on frequentist curve fitting techniques combined with an ad‐hoc cutoff determination strategy (visual inspection to determine a likely censoring point). This yields an over‐exact lake area estimate that is typically reported with no uncertainty bounds. I show how these shortcomings can be addressed with a Bayesian model that produces larger estimates of lake area uncertainty relative to the typical approach. When used as part of a sensitivity analysis, such an approach has the potential to enable more robust intercomparisons among studies of aquatic processes upscaling.

54 ENVIRONMENTAL SCIENCES↗

Excessive charge, beam loading, and impedance collapse thresholds for a velvet emitter

Excess emission has been observed from velvet cathodes with total emission times >150 ns. In this diode experiment, we produce a sub-relativistic electron beam with the ability to consistently change γ from 1.2 to 1.5 and β = 0.5–0.75. Electron emission in this particular diode geometry requires electric fields >40 kV/cm. The current increases at steady rates >0.05 A/ns after the head of the pulse, indicating an expansion of the emission surface and reduction in the effective AK gap. Small transients of excess emission (or arcs) are consistently observed for current pulses exceeding 150 ns. The excess emission results in beam loaded levels ≥10 kV on the diode voltage. The effects described here are compounded as diode voltage is increased. The principal objective of these experiments is to quantify electric field emission thresholds, current ramps, excess emission delays, effective beam loading, and impedance collapse.

43 PARTICLE ACCELERATORS↗

Emission Lines of O III in The Optical and Ultraviolet Spectra of Planetary Nebulae

Recent R-matrix calculations of electron impact excitation rates in 0 III are used to calculate electron temperature and density-dependent emission line ratios R (sub 1) = I(4363 Angstroms)/ I(4960 Angstroms + 5007 Angstroms), R (sub 2) = I(1661 Angstroms + 1667 Angstroms)/ I(4960 Angstroms + 5007 Angstroms) and R (sub 3)= I(2322 Angstroms)/ I(1661 Angstroms + 1667 Angstroms), for a range of electron temperatures (7500 less than or equal to Te less than or equal to 30 000 K) and densities (10 (exp 4) less than or equal to N (sub e) less than or equal to 10 (exp 7) per cubic centimeters) applicable to gaseous nebulae. The ratio-ratio diagrams (R (sub 1), R (sub 2)) and (R (sub 1), R (sub 3)) should, in principle, allow the simultaneous determination of T (sub e) and N (sub e) from measurements of the 0 III features in a spectrum. Plasma parameters derived for a sample of high-excitation planetary nebulae from (R (sub 1), R (sub 2)) and (R (sub 1), R (sub 3)) measurements, produced using a combination of ultraviolet spectra obtained with the International Ultraviolet Explorer (IUE) and optical data from a number of observing runs, are found to show excellent internal consistency. They also show, in general, good agreement with the values of Te and Ne estimated from other line ratios in the nebulae, therefore providing observational support for the accuracy of the theoretical ratios and hence the atomic data adopted in their derivation.

Crawford, F. L.↗

Origin of 12 micrometer Emission Across Galaxy Populations from Wise and ADSS Surveys

We cross-matched Wide-field Infrared Survey Explorer sources brighter than 1 mJy at 12 micron with the Sloan Digital Sky Survey galaxy spectroscopic catalog to produce a sample of approx. 10(exp 5) galaxies at z = 0.08, the largest of its kind. This sample is dominated (70%) by star-forming (SF) galaxies from the blue sequence, with total IR luminosities in the range approx 10(exp 8)-10(exp 12) Solar L. We identify which stellar populations are responsible for most of the 12 micron emission. We find that most (approx 80%) of the 12 micron emission in SF galaxies is produced by stellar populations younger than 0.6 Gyr. In contrast, the 12 micron emission in weak active galactic nuclei (AGNs; L [O iii] < 10(exo 7) solar L ) is produced by older stars, with ages of approx 1-3 Gyr. We find that L(sub 12 micron) linearly correlates with stellar mass for SF galaxies. At fixed 12 micron luminosity, weak AGNs deviate toward higher masses since they tend to be hosted by massive, early-type galaxies with older stellar populations. SF galaxies and weak AGNs follow different L(sub 12 micron) - SFR (star formation rate) relations, with weak AGNs showing excess 12 micron emission at low SFR (0.02-1 solar M /yr). This is likely due to dust grains heated by older stars. While the specific star formation rate (SSFR) of SF galaxies is nearly constant, the SSFR of weak AGNs decreases by approx 3 orders of magnitude, reflecting the very different star formation efficiencies between SF galaxies and massive, early-type galaxies. Stronger type II AGNs in our sample (L(sub [O iii]) > 10(exp 7) solar L ), act as an extension of massive SF galaxies, connecting the SF and weak AGN sequences. This suggests a picture where galaxies form stars normally until an AGN (possibly after a starburst episode) starts to gradually quench the SF activity. We also find that 4.6-12 micron color is a useful first-order indicator of SF activity in a galaxy when no other data are available.

Donso, E.↗

3D Radiative Transfer in Eta Carinae: Application of the SimpleX Algorithm to 3D SPH Simulations of Binary Colliding Winds

Eta Carinae is an ideal astrophysical laboratory for studying massive binary interactions and evolution, and stellar wind-wind collisions. Recent three-dimensional (3D) simulations set the stage for understanding the highly complex 3D flows in eta Car. Observations of different broad high- and low-ionization forbidden emission lines provide an excellent tool to constrain the orientation of the system, the primary's mass-loss rate, and the ionizing flux of the hot secondary. In this work we present the first steps towards generating synthetic observations to compare with available and future HST/STIS data. We present initial results from full 3D radiative transfer simulations of the interacting winds in eta Car.We use the SimpleX algorithm to post-process the output from 3D SPH simulations and obtain the ionization fractions of hydrogen and helium assuming three different mass-loss rates for the primary star. The resultant ionization maps of both species constrain the regions where the observed forbidden emission lines can form. Including collisional ionization is necessary to achieve a better description of the ionization states, especially in the areas shielded from the secondary's radiation. We find that reducing the primary's mass-loss rate increases the volume of ionized gas, creating larger areas where the forbidden emission lines can form.We conclude that post processing 3D SPH data with SimpleX is a viable tool to create ionization maps for eta Car.

Eta Carinae↗

Membrane Carbonation for 100% Efficient Delivery of Industrial CO 2 Gases

Industrial processes generate about one quarter of all greenhouse gases emissions in the US, about 80% of which is carbon dioxide (CO 2 ). Biological processes are one of the largest natural sinks for atmospheric CO 2 , but the rate of capture is limited by the low concentration in air (~0.04%). Industrial emissions have significantly higher CO 2 concentrations, ranging from 5–80% CO 2 , which can significantly increase the rate of biological CO 2 capture, including many-fold improvements for cultivating microalgae to produce food, fertilizer, and renewable fuel. However, traditional methods for delivering CO 2 to microalgae using bubbling is < 40% efficient, leading to significant residual CO 2 emissions and increased cost. This project developed the Membrane Carbonation (MC) technology to significantly improve the CO 2 delivery efficiency to microalgae from power plant flue gas, wastewater treatment plant anaerobic digesters biogas (Figure 1), and other CO 2 -containing industrial sources.

09 BIOMASS FUELS↗

Regional Impacts of Woodland Expansion on Nitrogen Oxide Emissions from Texas Savannahs: Combining Field, Modeling and Remote Sensing Approaches

Woody encroachment has contributed to documented changes world-wide and locally in the southwestern U.S. Specifically, in North Texas rangelands encroaching mesquite (Prosopis glandulosa var. glandulosa) a known N-fixing species has caused changes in aboveground biomass. While measurements of aboveground plant production are relatively common, measures of soil N availability are scarce and vary widely. N trace gas emissions (nitric and nitrous oxide) flom soils reflect patterns in current N cycling rates and availability as they are stimulated by inputs of organic and inorganic N. Quantification of N oxide emissions from savanna soils may depend upon the spatial distribution of woody plant canopies, and specifically upon the changes in N availability and cycling and subsequent N trace gas production as influenced by the shift from herbaceous to woody vegetation type. The main goal of this research was to determine whether remotely sensible parameters of vegetation structure and soil type could be used to quantify biogeochemical changes in N at local, landscape and regional scales. To accomplish this goal, field-based measurements of N trace gases were carried out between 2000-2001, encompassing the acquisition of imaging spectrometer data from the NASA Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) on September 29, 2001. Both biotic (vegetation type and soil organic N) and abiotic (soil type, soil pH, temperature, soil moisture, and soil inorganic N) controls were analyzed for their contributions to observed spatial and temporal variation in soil N gas fluxes. These plot level studies were used to develop relationships between spatially extensive, field-based measurements of N oxide fluxes and remotely sensible aboveground vegetation and soil properties, and to evaluate the short-term controls over N oxide emissions through intensive field wetting experiments. The relationship between N oxide emissions, remotely-sensed parameters (vegetation cover, and soil type), and physical controls (soil moisture, and temperature) permitted the regional scale quantification of soil N oxides emissions. Landscape scale analysis linking N oxide emissions with cover change revealed an alleviation from N limitation following mesquite invasion. This study demonstrated the advantage of using N trace gases as a measure of ecosystem N availability combined with remote sensing to characterize the spatial heterogeneity in ecosystem parameters at a scale commensurate with field-based measurements of these properties. Woody vegetation encroachment provided an opportunity to capitalize on detection of the remotely-sensible parameter of woody cover as it relates to belowground biogeochemical processes that determine N trace gas production. The first spatially-explicit estimates of NO flux were calculated based on Prosopis fractional cover derived from high resolution remote sensing estimates of fractional woody cover (< 4 m) for a 120 sq km region of North Texas. An assessment of both N stocks and fluxes from the study revealed an alleviation of N limitation at this site experiencing recent woody encroachment. Many arid and semi-arid regions of the world are experiencing woody invasions, often of N-fixing species. The issue of woody encroachment is in the center of an ecological and political debate. Improving the links between biogeochemical processes and remote sensing of ecosystem properties will improve our understanding of biogeochemical processes at the regional scale, thus providing a means to address issues of land-use and land-cover change.

Asner, Gregory P.↗

Solid-Density Ion Temperature from Redshifted and Double-Peaked Stark Line Shapes

Heβ spectral line shapes are important for diagnosing temperature and density in many dense plasmas. This work presents Heβ line shapes measured with high spectral resolution from solid-density plasmas with minimized gradients. The line shapes show hallmark features of Stark broadening, including quantifiable redshifts and double-peaked structure with a significant dip between the peaks; these features are compared to models through a Markov chain Monte Carlo framework. Line shape theory using the dipole approximation can fit the width and peak separation of measured line shapes, but it cannot resolve an ambiguity between electron density n e and ion temperature T i , since both parameters influence the strength of quasistatic ion microfields. Here a line shape model employing a full Coulomb interaction for the electron broadening computes self-consistent line widths and redshifts through the monopole term; redshifts have different dependence on plasma parameters and thus resolve the n e – T i ambiguity. The measured line shapes indicate densities that are 80–100% of solid, identifying a regime of highly ionized but well-tamped plasma. This analysis also provides the first strong evidence that dense ions and electrons are not in thermal equilibrium, despite equilibration times much shorter than the duration of x-ray emission; cooler ions may arise from nonclassical thermalization rates or anomalous energy transport. Furthermore, the experimental platform and diagnostic technique constitute a promising new approach for studying ion-electron equilibration in dense plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Think before you throw! An analysis of behavioral interventions targeting PET bottle recycling in the United States

The United States generates 42 Mt of plastic waste each year and is one of the biggest contributors to ocean plastic waste. Consequently, plastic has become synonymous with the linear economy, and many scholars are studying and proposing circular economy solutions to mitigate plastic pollution. Recycling has received much attention from both social sciences and engineering as a circular economy strategy, but no study has yet quantified how behavioral interventions could asymmetrically affect different populations. Here, this study combines agent-based modeling, material flow analysis, system dynamics, and life cycle assessment to assess the effect of four behavioral interventions on the collection rates of polyethylene terephthalate bottle waste, displaced virgin plastic manufacturing, and avoided greenhouse gas (GHG) emissions. Results show that, while behavioral interventions would require about 300–900 GJ of additional energy at end-of-life due to improved collection rates, they would avoid about 500–700 thousand metric tons of GHG emissions. Results also illustrate the importance of habits in disposal behaviors and show that different forms of interventions can be better adapted to particular social contexts than others. While the circular economy and its application to plastic waste should certainly not be restricted to recycling, this study demonstrates that improved collection rates and recycling technologies can contribute to reducing the amount of plastic waste polluting our oceans.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Heat Loss Effects on Emissions in an NH 3 RRQL Combustor

Ammonia (NH 3 ) is a carbon-free energy carrier with an infrastructure for production, storage, and distribution. There is interest in direct NH 3 combustion, but managing pollutant emissions is a key challenge, particularly nitric oxides (NO x ) due to the fuel-bound nitrogen atom, nitrous oxide (N 2 O), which is a potent greenhouse gas, and unburned NH 3 , which is harmful to humans and the environment. Rich staged combustor concepts with extended primary residence times (τ res,primary ), like Rich-Relax- Quick-mix-Lean (RRQL), offer a viable pathway for direct NH 3 combustion with low levels of NO x formation. However, minimizing secondary emissions such as N 2 O and unburned NH 3 and hydrogen (H 2 ) remains a critical challenge. Prior atmospheric-pressure studies have demonstrated that RRQL operation with sufficiently long τ res,primary enables substantial NO x relaxation and promotes NH 3 cracking to H 2 , if heat losses from the relaxation stage are limited. However, the combined influence of elevated pressure and long residence time on RRQL performance has not been explored. The present work examines RRQL operation at pressures up to 5 bar and elevated τ res,primary . Exhaust measurements of NO x , NH 3 , and N 2 O are used to quantify the extent of NO x relaxation and NH 3 cracking under nonadiabatic conditions. To contextualize and quantify the effects of heat losses in the experimental data, chemical reactor networks (CRNs) incorporating prescribed heat loss rates are employed to assess the sensitivity of emissions to thermal losses in the relaxation stage. Collectively, the results demonstrate that management and quantification of heat losses are essential to preserve NO x relaxation and limit NH 3 and N 2 O emissions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Soft X-ray, microwave, and hard X-ray emission from a solar flare - Implications for electron heating and acceleration in current channels

The soft X-ray, microwave, and hard X-ray emissions from the solar flare of May 14, 1980 are studied. The flare consists of a gradual component in soft X-rays and microwaves and a superposed impulsive burst accompanied by hard X-ray emission. The impulsive phase of the flare appears in the soft X-ray emission as a temperature spike and as an increased rate of energy dissipation into the plasma. A new, spatially and spectrally distinct, microwave component appears during the impulsive burst. The data are interpreted in terms of Joule heating and the electric field acceleration of electrons in one or more current sheets. It is found that all three emissions can be generated with sub-Dreicer electric fields. The soft X-ray emitting plasma can be heated by a single current sheet only if the resistivity in the sheet is well above the classical, collisional resistivity. Conditions are also given for the hard X-ray emission to be from nonthermal electrons with classical resistivity.

Holman, Gordon D.↗

Low- to Mid-Latitude X-Ray Emission from Jupiter

The Chandra X-ray Observatory (CXO) observed Jupiter during the period 2003 February 24-26 for approx.40 hours (4 Jupiter rotations), using both the spectroscopy array of the Advanced CCD Imaging Spectrometer (ACIS-S) and the imaging array of the High-Resolution Camera (HRC-I). Two ACIS-S exposures, each approx.8.5 hr long, were separated by an HRC-I exposure of approx.20 hr. The low- to mid-latitude non-auroral disk X-ray emission is much more spatially uniform than the auroral emission. However, the low- to mid-latitude X-ray count rate shows a small but statistically significant hour angle dependence, and is higher in regions of relatively low surface magnetic field strength, confirming ROSAT results. In addition, the spectrum from the low surface field region shows an enhancement in the energy band 1.14- 1.38 keV, perhaps partly due to line emission from that region. Correlation of surface magnetic field strength with count rate is not found for the 2000 December HRC-I data, at a time when solar activity was high. The low- to mid-latitude disk X-ray count rate observed by the HRC-I in the 2003 February observation is about 50% of that observed in 2000 December, roughly consistent with a decrease in the solar activity index (F10.7 cm flux) by a similar amount over the same time period. The low- to mid-latitude X-ray emission does not show any oscillations similar to the -45 minute oscillations sometimes seen from the northern auroral zone. The temporal variation in Jupiter's non-auroral X-ray emission exhibits similarities to variations in solar X-ray flux observed by GOES and TIMED/SEE. The two ACIS-S 0.3-2 keV low- to mid-latitude X-ray spectra are harder than the auroral spectrum, and are different from each other at energies above 0.7 keV, showing variability in Jupiter s non-auroral X-ray emission on a time scale of a day. The 0.3-2.0 keV X-ray power emitted at low- to mid-latitudes is 0.21 GW and 0.39 GW for the first and second ACIS-S exposures, respectively. We suggest that X-ray emission from Jupiter's disk may be largely generated by solar X-rays resonantly and fluorescently scattered in its upper atmosphere, especially at times of high incident solar X-ray flux. However, the correlation of higher count rate with low surface magnetic-field strength indicates the presence of some secondary component, possibly ion precipitation from radiation belts closer to the planet than elsewhere at low- to mid-latitudes.

Bhardwaj, Anil↗

Systems Analysis of Biomass and Coal Co-firing Power Plants with Deep Carbon Capture Toward Net-zero Emissions

Achieving a net-zero emission economy in the United States requires integrating diverse low-carbon and negative-emission technologies into the existing fossil fuel-dominant power fleet. Potential technologies from the low-carbon portfolio include renewable power, fossil power with carbon capture and storage (CCS), bioenergy with CCS (BECCS), and direct air capture (DAC). Renewable power is a clean energy source but has to pair with costly battery storage to provide dispatchable electricity. Fossil power with CCS offers dispatchable electricity yet still relies on DAC to offset residual emissions, even when deploying deep CCS with more than 90% CO2 capture. Coal-biomass co-firing with CCS, a subset of BECCS, is a reliable energy production technology that can be retrofitted from existing electricity generation units (EGUs). Power plant retrofit maximizes the use of the current U.S. coal power fleet without the need for large-scale deployment of new renewable power, battery storage, or DAC. Retrofitting coal-biomass co-firing with deep CCS in EGUs is a promising option, but not a universal solution. Biomass co-firing at a power plant introduces economic challenges and indirectly poses pressure on land and water resources. Meanwhile, retrofitting deep CCS affects plant efficiency and raises electricity generation costs. Overall, the technical feasibility and economic viability of plant retrofits vary across EGUs, as they are contingent upon the regional availability of biomass, unit-specific characteristics, site-specific fuel supply costs, and adjacent CO2 storage potential. Government incentives like 45Q can improve the retrofit viability, though the impact requires further quantification. A comprehensive analysis at the unit level is essential to address the question regarding the fate of the U.S. coal-fired electricity generation fleet toward the net-zero emission goal. This study conducts a systematic techno-economic-environmental assessment of EGUs to identify the viability of biomass co-firing and deep CCS retrofits in the U.S. coal-fired power fleet. Specifically, it characterizes the techno-economic performance of deep carbon capture, estimates life cycle greenhouse gas (GHG) emissions, and conducts a fleet-level assessment on retrofit viability. The key objectives are (1) to estimate the unit-specific performance and retrofitted cost under various biomass co-firing levels and CO2 capture rates; (2) to determine the possibility of reaching net-zero emission at the fleet level; (3) to quantify the cumulative capacities that are suitable for plant retrofits under current and future biomass supply scenarios; and (4) to improve the understanding of policy impacts on such retrofits to help the power sector’s transition to a net-zero economy. Techno-economic Model of Deep Carbon Capture. This study develops the performance and economic models for Monoethanolamine-based post-combustion CO2 capture at 95–99% capture rates. The process is simulated in Aspen Plus, analyzing the performance of carbon capture technology by varying the plant sizes, solvent lean loading, CO2 concentrations, and flue gas inlet temperature. Based on the key inputs and output parameters of CO2 capture, a reduced-order performance model of deep carbon capture is formulated. In addition, an engineering-economic model integrating the performance metrics is developed to estimate the capital as well as operation and maintenance (O&M) costs. Capital cost estimations follow the framework of the Integrated Environmental Control Model (IECM) and incorporate data regressions from three technical reports by IECM, the National Energy Technology Laboratory (NETL), and the National Renewable Energy Laboratory. The O&M cost estimation utilizes the actual inventory consumption rate and labor requirements. Both performance and cost models are embedded into IECM v13.0-beta, a fossil-fuel power plant modeling tool. Life Cycle Assessment of Power Plants. This study estimates the GHG emissions of power plants through life cycle assessment (LCA). The LCA scope includes fuel supply, combustion-based power generation, and CO2 transport and storage. The fuel-based life cycle module is designed following the framework of the NETL Unit Process Library and CO2U LCA Guidance Toolkit. The module is then incorporated into IECM v13.0-beta. The process-based LCA is applied to estimate the GHG emissions of coal and biomass supply, coal- and coal-biomass co-firing power plant operation, as well as CO2 pipeline transport and geographical sequestration. An uncertainty analysis is conducted to quantify the variability and uncertainty associated with the LCA using the Latin Hypercube Sampling (LHS) method. Fleet-level Assessment. This study evaluates the technical and economic feasibility of selected coal-fired EGUs, examines the role of tax credits in retrofit viability, and assesses the competitiveness of retrofitted units against other low-carbon options. Unit screening identifies EGUs for the study, focusing on new, efficient baseload units with air pollution controls. The power plant databases are then established to organize unit-specific information on performance and operating conditions from the relevant public databases. Biomass for co-firing retrofits is selected based on home and neighboring county availability, ensuring sustained operation with at least a 5% co-firing level. The CO2 storage site is determined by state-level storage potential, with ArcGIS Pro and NETL CO2 Saline Storage Cost Model used to identify the optimal balance between the nearest transport distances and affordable storage costs. The latest IECM v13.0-beta is then employed to configure and evaluate the eligible EGUs with or without the deployment of deep CCS and biomass co-firing. A supply curve is established to illustrate the cumulative installed capacity suitable for retrofits at different cost levels. A sensitivity analysis on tax credits for carbon sequestration is performed. Finally, a unit-level cost comparison is conducted among retrofitted plants, renewable power with battery storage, and abated fossil fuels with DAC. Expected Results. This study evaluates the technical, economic, and environmental metrics of each EGU across an array of CO2 capture rates and biomass co-firing level scenarios. Unit-level comparisons will identify critical factors influencing technical performance. The supply curves with and without tax incentives will provide insights into the impact of tax credits on biomass co-firing and CCS deployment. The cost comparisons with renewables and DAC-retrofit will assess the competitiveness of the retrofitted units. Life cycle emissions from each unit will be assessed to identify the scenarios under which net-zero emissions can be achieved. These analyses are expected to determine the total coal-fired capacity suitable for serving as a low-carbon energy source with or without tax incentives. The study results are novel in identifying optimal unit-specific strategies for producing carbon-neutral power, whether through retrofitting EGUs with deep CCS, biomass co-firing, DAC, or installing renewable power with battery. The findings will provide insight into nationwide efforts to ensure reliable, affordable, and low-carbon electricity. It also will inform investment decisions and policies in the deployment of deep carbon capture and negative emission technologies for a net-zero energy future.

Biomass Co-firing↗

The long-term intensity behavior of Centaurus X-3

In three years of observation, the X-ray source Cen X-3 appears to alternate between 'high states', with an intensity of 150 counts/s (2-6 keV) or greater, and 'low states', where the source is barely detectable. The time scale of this behavior is of the order of months, and no apparent periodicity has been observed. Analysis of two transitions between these states is reported. During two weeks in July 1972, the source increased from about 20 counts/s to 150 counts/s. The detailed nature of this turn-on is interpreted in terms of a model in which the supergiant's stellar wind decreases in density. A second transition, a turnoff in February 1973, is similarly analyzed and found to be consistent with a simple decrease in accretion rate. The presence of absorption dips during transitions at orbital phases 0.4-0.5 as well as at phase 0.75 is discussed. The data are consistent with a stellar-wind accretion model and with different kinds of extended lows caused by increased wind density masking the X-ray emission or by decreased wind density lowering the accretion rate.

Schreier, E. J.↗

Observations of exoelectron emission associated with heterogeneous catalysis

It is suggested that the exoelectron emission from the catalyst may be used to monitor the rate of oxidation of CO and CH4 over palladium catalysts. Indirect heating of the catalyst and atmospheric pressure have no effect upon this monitoring system. Although the mechanism relating catalysis to exoelectron emission is not clear, it is considered possible that electron emission is triggered by the adsorption-desorption cycle.

Hoenig, S. A.↗

Global Warming in the 21st Century: An Alternate Scenario

A common view is that the current global warming rate will continue or accelerate. But we argue that rapid warming in recent decades has been driven by non-CO2 greenhouse gases (GHGs), such as CFCs, CH4 and N2O, not by the products of fossil fuel burning, CO2 and aerosols, whose positive and negative climate forcings are partially offsetting. The growth rate of non-CO2 GHGs has declined in the past decade. If sources of CH4 and O3 precursors were reduced in the future, the change of climate forcing by non-CO2 GHGs In the next 50 years could be near zero. Combined with a reduction of black carbon emissions and plausible success in slowing CO2 emissions, this could lead to a decline in the rate of global warming, reducing the danger of dramatic climate change. Such a focus on air pollution has practical benefits that unite the interests of developed and developing countries. However, assessment of ongoing and future climate change requires composition-specific longterm global monitoring of aerosol properties.

Hansen, James E.↗