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At least 1,081 records · Page 60

The interplay between surface facet and reconstruction on isopropanol conversion over SrTiO 3 nanocrystals

Strontium titanate (SrTiO 3 ) is an extensively investigated perovskite for various applications due to its optical, electrical and chemical properties. To gain an in-depth understanding of the active sites involved in heterogeneous catalysis over the broadly used SrTiO 3 (STO), we studied a model reaction, isopropanol conversion, on three differently shape-controlled nanocrystals: cube, truncated cube and dodecahedra. SEM, XRD and XPS confirmed the morphology, phase and composition of STO shapes. Low energy ion scattering (LEIS) revealed the occurrence of surface reconstruction over STO shapes during O 2 pretreatment at different temperatures. Based on the catalytic activities, scanning transmission electron microscopy images and density functional theory calculations, the step sites on STO derived from surface reconstruction were proposed to be the active sites for isopropanol conversion. This was further confirmed by steady state isotopic kinetic analysis (SSITKA) which demonstrated similar intrinsic turnover frequencies (TOFs) for the differently reconstructed STO shapes. It is concluded that the crystal facets impose an indirect effect on the catalysis of STO via controlling the degrees of surface reconstruction: the less stable STO (1 1 0) facet (dodecahedra) leads to more step sites after reconstruction and hence higher overall reaction rate than the more stable (1 0 0) facet (cube). This work highlights the important interplay between the crystal facet and surface reconstruction in controlling the nature and density of active sties and thus catalysis over complex oxides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Crater frequency age determinations for the proposed Apollo 17 site at Taurus-Littrow.

On the assumption that the vast majority of craters are of impact origin, relative age dates can be obtained by counting craters. Returned lunar samples are helping to resolve problems regarding the magnitude of the meteoritic flux. The samples provide a means for empirically calibrating crater count data. The characteristics of the Taurus-Littrow area are considered, giving attention to four different units. The crater frequency distribution is discussed, together with its significance for the age of the corresponding lunar features.

Greeley, R.↗

Further buffeting tests in a cryogenic wind tunnel

Further measurements of buffeting, using wing-root strain gauges, were made in the NASA Langley 0.3 m Cryogenic Wind Tunnel to refine techniques which will be used in larger cryogenic facilities such as the United States National Transonic Facility (NTF) and European Transonic Wind Tunnel (ETW). The questions addressed included the relative importance of variations in frequency parameter and Reynolds number, the choice of model material (considering both stiffness and damping) and the effects of static aeroelastic distortion. The main series of tests was made on half models of slender 65 deg delta wings with a sharp leading edge. The three delta wings had the same planform but widely different bending stiffness and frequencies (obtained by varying both the material and the thickness of the wings). It was known that the flow on this configuration would be insensitive to variations in Reynold number. Additional tests were made on one unswept half-wing of aspect ratio 1.5 with an NPL 9510 aerofoil section, known to be sensitive to variations in Reynolds number at transonic speeds. For brevity the test Mach numbers were restricted to M = 0.21 and 0.35 for the delta wings and to M = 0.30 for the unswept wing.

Mabey, D. G.↗

Buffeting tests in a cryogenic windtunnel

Measurements of wing buffeting, using root strain gages, were made in the NASA Langley 0.3 m cryogenic wind tunnel to refine techniques which will be used in larger cryogenic facilities such as the United States National Transonic Facility (NTF) and the European Transonic Wind Tunnel (ETW). The questions addressed included the relative importance variations in frequency parameter and Reynolds number, the choice of model material (considering both stiffness and damping) and the effects of static aeroelastic distortion. The main series of tests was made on three half models of slender 65 deg delta wings with a sharp leading edge. The three delta wings had the same planform but widely differing bending stiffnesses and frequencies (obtained by varying both the material and the thickness of the wings). It was known that the steady flow on this configuration would be insensitive to variations in Reynolds number. On this wing at vortex breakdown the spectrum of the unsteady excitation is unusual, having a sharp peak at particular frequency parameter. Additional tests were made on one unswept half-wing of aspect ratio 1.5 with an NPL 9510 aerofoil section, known to be sensitive to variations in Reynolds number at transonic speeds. The test Mach numbers were M = 0.21 and 0.35 for the delta wings and to M = 0.30 for the unswept wing. On this wing the unsteady excitation spectrum is fairly flat (as on most wings). Hence correct representation of the frequency parameter is not particularly important.

Mabey, D. G.↗

Total Ionizing Dose Effects on Voltage-to-Frequency Converters

This paper discusses total dose effects on voltage-to-frequency converters which impose different requirements on internal circuitry, and are also very high-precision devices (for example, linearity is typically specified between 0.002 and 0.05%).

low dose rate (LDR) Voltage-to-Frequency Converter↗

Beam dynamics corrections to the Run-1 measurement of the muon anomaly $a_{\mu}$ at Fermilab

The Fermi National Accelerator Laboratory (FNAL) Muon $g\!-\!2$ Experiment has measured the positive muon magnetic anomaly $a_{\mu} \equiv (g_{\mu}-2)/2$ with a precision of 0.46 parts per million, with data collected during its first physics run in 2018. The experimental result combined with the measurement from the former experiment at Brookhaven National Laboratory increases the tension with the Standard Model expectation to $4.2\sigma$, thus strengthening evidence for new physics.The magnetic anomaly is determined from the precision measurements of the muon spin precession frequency, relative to the muon momentum, and the average magnetic field seen by the beam. In an ideal case with muons orbiting in a horizontal plane with a uniform vertical magnetic field, the anomalous precession frequency $\omega_a$ is given by the difference between the spin ($s$) and cyclotron ($c$) frequencies, $\omega_a = \omega_s - \omega_c$. The observable $\omega_a$ is proportional to $a_{\mu}$.This proceeding presents the beam dynamics systematic corrections that are required to adjust the measured muon precession frequency $\omega^{m}_{a}$ to its true physical value $\omega_{a}$.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The Cold Land Processes Experiment (CLPX-1): Analysis and Modelling of LSOS Data (IOP3 Period)

Microwave brightness temperatures at 18.7,36.5, and 89 GHz collected at the Local-Scale Observation Site (LSOS) of the NASA Cold-Land Processes Field Experiment in February, 2003 (third Intensive Observation Period) were simulated using a Dense Media Radiative Transfer model (DMRT), based on the Quasi Crystalline Approximation with Coherent Potential (QCA-CP). Inputs to the model were averaged from LSOS snow pit measurements, although different averages were used for the lower frequencies vs. the highest one, due to the different penetration depths and to the stratigraphy of the snowpack. Mean snow particle radius was computed as a best-fit parameter. Results show that the model was able to reproduce satisfactorily brightness temperatures measured by the University of Tokyo s Ground Based Microwave Radiometer system (CBMR-7). The values of the best-fit snow particle radii were found to fall within the range of values obtained by averaging the field-measured mean particle sizes for the three classes of Small, Medium and Large grain sizes measured at the LSOS site.

Tedesco, Marco↗

Peer-to-Peer Planning for Space Mission Control

Planning and scheduling for space operations entails the development of applications that embed intimate domain knowledge of distinct areas of mission control, while allowing for significant collaboration among them. The separation is useful because of differences in the planning problem, solution methods, and frequencies of replanning that arise in the different disciplines. For example, planning the activities of human spaceflight crews requires some reasoning about all spacecraft resources at timescales of minutes or seconds, and is subject to considerable volatility. Detailed power planning requires managing the complex interplay of power consumption and production, involves very different classes of constraints and preferences, but once plans are generated they are relatively stable.

Barreiro, Javier↗

Thermodynamic and kinematic drivers of atmospheric boundary layer stability in the central Arctic during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC)

Observations collected during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) provide a detailed description of the impact of thermodynamic and kinematic forcings on atmospheric boundary layer (ABL) stability in the central Arctic. This study reveals that the Arctic ABL is stable and near-neutral with similar frequencies, and strong stability is the most persistent of all stability regimes. MOSAiC radiosonde observations, in conjunction with observations from additional measurement platforms, including a 10 m meteorological tower, ceilometer, microwave radiometer, and radiation station, provide insight into the relationships between atmospheric stability and various atmospheric thermodynamic and kinematic forcings of ABL turbulence and how these relationships differ by season. We found that stronger stability largely occurs in low-wind (i.e., wind speeds are slow), low-radiation (i.e., surface radiative fluxes are minimal) environments; a very shallow mixed ABL forms in low-wind, high-radiation environments; weak stability occurs in high-wind, moderate-radiation environments; and a near-neutral ABL forms in high-wind, high-radiation environments. Surface pressure (a proxy for synoptic staging) partially explains the observed wind speeds for different stability regimes. Cloud frequency and atmospheric moisture contribute to the observed surface radiation budget. Unique to summer, stronger stability may also form when moist air is advected from over the warmer open ocean to over the colder sea ice surface, which decouples the colder near-surface atmosphere from the advected layer, and is identifiable through observations of fog and atmospheric moisture.

54 ENVIRONMENTAL SCIENCES↗

Numerical Simulations of the XR-5 Hall Thruster for Life Assessment at Different Operating Conditions

NASA's Jet Propulsion Laboratory has been investigating the applicability of Aerojet Rocketdyne's XR-5 thruster, a 4.5 kW class Hall thruster, for deep-space missions. Major considerations for qualifying the XR-5 for deep-space missions are demonstration of a wide throttling envelope and a usable life capability in excess of 10,000 h. Numerical simulations with the 2-D axisymmetric code Hall2De are employed to inform the qualification process by assessing erosion rates at the thruster surfaces in a wide range of throttling conditions without the need for conducting costly endurance testing. In previous work at JPL by Jorns et al., the anomalous collision frequency distribution for 11 different throttling conditions of the XR-5 spanning 0.3-4.5 kW were identified based on probe measurements of the electron temperature in the near plume region. In this paper, we provide estimates for the erosion rates at the channel walls and pole covers for the same 11 conditions. Uncertainties in the plasma measurements and in the anomalous collision frequency distribution are addressed by determining upper and lower bounds of the erosion rates. Results suggest that erosion of the walls only occurs in the last 5% of the acceleration channel and the rate of such erosion decreases as the geometry of the thruster changes in time due to magnetic shielding. A quasi-zero-erosion state is eventually achieved in all the examined throttling conditions. Examination of the results for pole surface erosion and estimated cathode life indicates that the XR-5 propellant throughput capability will exceed 700 kg, which provides 50% margin over the usable throughput capability of 466 kg as already demonstrated in wear testing.

Lopez Ortega, Alejandro↗

On discriminating tokamak sawtooth crash models via localized density and temperature measurements

The core electron temperature drops rapidly during the sawtooth crash in tokamak plasmas, which causes heat loss and may lead to fast particle losses or even a disruption. Several models have been proposed for the periodic crash, including the Kadomtsev model with magnetic reconnection and the quasi-interchange model with the growth of higher-mode-number pressure-driven instabilities. 3D MHD simulations were performed for these two models with a goal to develop intuition and to predict qualitatively how different types of sawtooth will appear in various diagnostics. The structures of electron density ne and electron temperature Te show a dominant (1, 1) mode for the Kadomtsev case and a dominant (4, 4) mode for the quasi-interchange case. The oscillations of ne and Te have a positive correlation near the inversion layer for both cases, while their frequencies and amplitudes are different depending on the dominant modes. Particularly, for the Kadomtsev case, we find a relation between the amount of flux reconnected during a sawtooth event and ne or Te oscillations. Therefore, we connect recently developed measurement capabilities for ne and Te to the internal sawtooth behavior. We propose that this method of analysis can help in identifying the type of sawtooth in future experiments augmented by simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

It's About Time!

Everything we do in VLBI is connected to time. In this contribution, we review 28 orders of magnitude of the spectrum of time ranging from a few hundred femtoseconds (i.e. one degree of phase at X-band - Pi x 10(exp -13) seconds) upwards to tens of millions of years (i.e. ten million years Pi x 10(exp 14) seconds). In this discussion, we will pay special attention to the relation between the underlying oscillator (the frequency standard that defines a clock's rate) and the time kept by the clock (which counts the oscillations of the frequency standard). We will consider two different types of time - time kept by counting an atomic frequency standard (Hydrogen Maser or Cesium), and time reckoned by the rotation of the Earth underneath the stars and sun.

Clark, Tom↗

Characterization of spatial statistics of distributed targets in SAR data

A statistical approach to the analysis of spatial statistics in polarimetric multifrequency SAR data, which is aimed at extracting the intrinsic variability of the target by removing variability from other sources, is presented. An image model, which takes into account three sources of spatial variability, namely, image speckle, system noise, and the intrinsic spatial variability of the target or texture, is described. It is shown that the presence of texture increases the image variance-to-mean square ratio and introduces deviations of the image autocovariance function from the expected SAR system response. The approach is exemplified by sea-ice SAR imagery acquired by the Jet Propulsion Laboratory three-frequency polarimetric airborne SAR. Data obtained indicate that, for different sea-ice types, the spatial statistics seem to vary more across frequency than across polarization and the observed differences increase in magnitude with decreasing frequency.

Rignot, E.↗

Highly nondegenerate all-resonant optical parametric oscillator

We show that a nondegenerate multi-frequency parametric oscillator has different properties compared with an usual three-wave parametric oscillator. We consider, as an example, a scheme of a resonant cw monolithic microwave-optical parametric oscillator based on high-Q whispering gallery modes excited in a nonlinear dielectric cavity. In this paper we recall main properties of usual three-mode OPO, discuss four-mode OPO, study conditions of generation of a frequency comb in all-resonant OPO with two-frequency optical pumping, and discuss stability of a cavity with moving mirrors.

whispering↗

Effect of frequency and applied voltage of an atmospheric-pressure dielectric-barrier discharge on breakdown and hydroxyl-radical generation with a liquid electrode

This work examines the effect of the frequency and peak applied voltage on hydroxyl-radical generation in a dielectric-barrier plasma discharge between a metallic needle electrode and one electrode covered with dielectric. The authors examine a system that can expose up to 96 liquid samples in an automated fashion without human intervention beyond setting the initial software configuration. Then, hydroxylradical concentration, measured through coumarin fluorescence, was measured for 5 s plasma exposures generated under different highvoltage conditions with frequencies from 2 to 16 kHz and amplitudes from 4 to 9 kV. Their results show that an increase in frequency and/or applied voltage, within the range prescribed above and the limits of the high-voltage power supply, can yield up to a 150% increase in fluorescence with an equivalent hydroxyl-radical increase. Applications using typical previous methods, such as the Fenton Reaction, are limited in that they continuously generate hydroxyl radicals over millisecond and longer intervals. These results establish the electrical parameters that can now be applied to polymers, like proteins, which show three dimensional structures that are flexible and fluctuate on a microsecond and nanosecond time scale, with hydroxyl-radical generation on this time scale using this device. Additionally, plasma exposures may be optimized for a great variety of proteins, devices and techniques, where hydroxyl-radical generation is of utmost importance, reducing exposure time and potential subjection of samples to harmful side effects.

42 ENGINEERING↗

A Comparison Study of Normal-Incidence Acoustic Impedance Measurements of a Perforate Liner

The eduction of the acoustic impedance for liner configurations is fundamental to the reduction of noise from modern jet engines. Ultimately, this property must be measured accurately for use in analytical and numerical propagation models of aircraft engine noise. Thus any standardized measurement techniques must be validated by providing reliable and consistent results for different facilities and sample sizes. This paper compares normal-incidence acoustic impedance measurements using the two-microphone method of ten nominally identical individual liner samples from two facilities, namely 50.8 mm and 25.4 mm square waveguides at NASA Langley Research Center and the University of Florida, respectively. The liner chosen for this investigation is a simple single-degree-of-freedom perforate liner with resonance and anti-resonance frequencies near 1.1 kHz and 2.2 kHz, respectively. The results show that the ten measurements have the most variation around the anti-resonance frequency, where statistically significant differences exist between the averaged results from the two facilities. However, the sample-to-sample variation is comparable in magnitude to the predicted cross-sectional area-dependent cavity dissipation differences between facilities, providing evidence that the size of the present samples does not significantly influence the results away from anti-resonance.

Schultz, Todd↗

Pre-emphasis determination for an S-band constant bandwidth FM/FM station

Pre-emphasis schedules are given for 11 constant-bandwidth FM subcarriers modulating an S band transmitter at three receiver signal to noise ratios (i.e., 9, 15, and 25 dB). The criterion for establishing these pre-emphasis curves is the achievement, at various receiver intermediate frequency signal to noise ratios, of equal receiver output signal to noise ratios for all channels. It is realized that these curves may not be the optimum pre-emphasis curves based on overall efficiency or maximum utilization of the allotted spectrum, but they are near-optimum for data with channels which require equal output signal to noise ratios, such as spectral densities. The empirically derived results are compared with a simplified, analytically derived schedule and the primary differences are explained. The S band pre-emphasis schedule differs from the lower frequency VHF case. Since most proportional bandwidth and constant bandwidth systems use ground based recorders and some use flight recorders (as the Saturn systems did on VHF proportional bandwidth telemetry), the effects of these recorders are discussed and a modified pre-emphasis schedule is presented showing the results of this study phase.

Wallace, G. R.↗

Dispersion curve regression – assisted wideband local wavenumber analysis for characterizing three-dimensional (3D) profile of hidden corrosion damage

Corrosion as common damage in civil, petrochemical, nuclear, and aerospace structures affects the integrity and safety of the structures and may lead to catastrophic failures. This paper presents dispersion curve regression-assisted local wavenumber analysis method, which can analyze the time–space wavefield containing wideband information of wave-damage interaction and further extract the structural information carried by such wavefield for characterizing hidden corrosion damage in an isotropic plate. To acquire the time–space wavefield, a noncontact scanning laser Doppler vibrometer is used. In our analysis method, the acquired time–space wavefield is firstly processed to generate a local wavenumber function. The derived wavenumber function is further analyzed with a dispersion curve regression step, which searches in a set of theoretical frequency-wavenumber dispersion curves for different plate thicknesses and identifies the optimal plate thickness whose theoretical curve best matches the frequency-wavenumber relation contained in the local wavenumber function. By this means, a 3D profile including both in plane and thickness dimensions of the structure can be constructed for corrosion visualization and quantification. The experimental study demonstrates that our method can quantify the profile of hidden uniform corrosion in metal plates in terms of its in-plane shape and size as well as its out-of-plane depth in the subwavelength scale. Moreover, compared to previous Lamb wave-based corrosion inspection methods, our technique allows for noncontact 3D characterization of hidden corrosion from a far distance to the structure. Finally, we believe this work will inspire new 3D damage quantification methods that are based on wavefield analysis as well as enable potential applications for the quantification of hidden corrosion in civil, petrochemical, nuclear, and aerospace structures.

42 ENGINEERING↗