Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “decarbonize”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,081 records · Page 60

Temperature Field Reconstruction of Surfaces Heated Through Radiative Heat Transfer Using Convolutional Neural Networks

Microreactors could play a crucial role in decarbonizing our energy portfolio. However, their development and implementation come with specific challenges, particularly regarding cost. Due to their compact size and the harsh operational environment, collecting real-time data on reactor operation can be challenging. Many probe designs are unable to withstand extreme conditions (e.g., temperature, radiation) in the reactor. In this context, using convolutional neural networks (CNNs) can pave the way for developing a nonintrusive approach that relies solely on ex-core sensors. A well-trained physics-informed CNN can reconstruct the distribution of a given physical quantity over a domain using only a few sensors, allowing us to reconstruct the desired field distribution even in a limited space or complex geometries where a large array of sensors is impractical. In this work, we present the initial steps toward developing a real-time tool for monitoring the thermal behavior of nuclear reactor pressure vessels. Based on an experimental setup, a computational model using the Multiphysics Object-Oriented Simulation Environment (moose) framework was built, where the Ray Tracing and Heat Conduction modules were used to evaluate the temperature distribution over a convex metal surface heated through radiative heat transfer. This metal surface represents a section of a heated nuclear reactor vessel wall. The model also accounts for solid mechanics physics through the moose Solid Mechanics module. In situ experimental data, acquired from a Texas A&M facility, were used to validate the computational model. Part of the data generated by the moose model was used to train the convolutional neural network to reconstruct the vessel wall's outer surface temperature. The CNN generalization was then compared against the experimental and computational data.

Aldeia Machado, Luiz Carlos↗

Unified Modeling Architecture for Load Management in Extreme Heat: The New York City Case

Integration of renewable resources to meet growing energy demand is becoming a global priority under decarbonization mandates. This study contributes to ongoing efforts on this key subject by assessing the feasibility of using coastal-urban renewable energy resources, namely, offshore wind and rooftop photovoltaic systems, to meet electricity demand of New York City during the intense recent heat wave period of June 2025. A unified modeling framework, based on the urbanized weather research and forecasting model, is used to simulate climate, renewable resources, and energy demand variables. Findings show significant energy load mismatch of approximately 1150 GWh over the month, between the demand and the combined renewable generation outcome. Three storage integration scenarios are analyzed to mitigate the deficits, reducing said deficits by a minimum of approximately 9% over the duration of the month. This study provides a transferable modeling framework tool for evaluating renewable integration in dense urban environments that can be used by grid operators to support grid resilience during extreme heat events.

54 ENVIRONMENTAL SCIENCES↗

Modeling scale-up of particle coating by atomic layer deposition

Atomic layer deposition (ALD) is a promising technique to functionalize particle surfaces for energy applications including energy storage, catalysis, and decarbonization. In this work, we present a set of models of ALD particle coating to explore the transition from lab scale to manufacturing. Our models encompass the main particle coating manufacturing approaches including rotary bed, fluidized bed, and continuously vibrating reactors. These models provide key metrics, such as throughput and precursor utilization, required to evaluate the scalability of ALD manufacturing approaches and their feasibility in the context of energy applications. Our results show that designs that force the precursor to flow through fluidized particles transition faster to a transport-limited regime where throughput is maximized. They also exhibit higher precursor utilization. In the context of continuous processes, our models indicate that it is possible to achieve self-extinguishing processes with almost 100% precursor utilization. A comparison with past experimental results of ALD in fluidized bed reactors shows excellent qualitative and quantitative agreement.

25 ENERGY STORAGE↗

Manufacture and testing of biomass-derivable thermosets for wind blade recycling

Wind energy is helping to decarbonize the electrical grid, but wind blades are not recyclable, and current end-of-life management strategies are not sustainable. Here, to address the material recyclability challenges in sustainable energy infrastructure, we introduce scalable biomass-derivable polyester covalent adaptable networks and corresponding fiber-reinforced composites for recyclable wind blade fabrication. Through experimental and computational studies, including vacuum-assisted resin-transfer molding of a 9-meter wind blade prototype, we demonstrate drop-in technological readiness of this material with existing manufacture techniques, superior properties relative to incumbent materials, and practical end-of-life chemical recyclability. Most notable is the counterintuitive creep suppression, outperforming industry state-of-the-art thermosets despite the dynamic cross-link topology. Overall, this report details the many facets of wind blade manufacture, encompassing chemistry, engineering, safety, mechanical analyses, weathering, and chemical recyclability, enabling a realistic path toward biomass-derivable, recyclable wind blades.

17 WIND ENERGY↗

Proteomes reveal metabolic capabilities of Yarrowia lipolytica for biological upcycling of polyethylene into high-value chemicals

ABSTRACT Polyolefins derived from plastic wastes are recalcitrant for biological upcycling. However, chemical depolymerization of polyolefins can generate depolymerized plastic (DP) oil, comprising of a complex mixture of saturated, unsaturated, even, and odd hydrocarbons suitable for biological conversion. While DP oil contains a rich carbon and energy source, it is inhibitory to cells. Understanding and harnessing robust metabolic capabilities of microorganisms to upcycle the hydrocarbons in DP oil, both naturally and unnaturally occurring, into high-value chemicals are limited. Here, we discovered that an oleaginous yeast, Yarrowia lipolytica, undergoing short-term adaptation to DP oil robustly utilized a wide range of hydrocarbons for cell growth and production of citric acid and neutral lipids. When growing on hydrocarbons, Y. lipolytica partitioned into planktonic and oil-bound cells with each exhibiting distinct proteomes and amino acid distributions invested in establishing these proteomes. Significant proteome reallocation toward energy and lipid metabolism, belonging to 2 of the 23 Eukaryotic Orthologous Groups classes C and I, enabled robust growth of Y. lipolytica on hydrocarbons, with n-hexadecane as the preferential substrate. This investment was even higher for growth on DP oil where classes C and I were ranked one and two, respectively, and many associated proteins and pathways were expressed and upregulated including the hydrocarbon degradation pathway, Krebs cycle, glyoxylate shunt and, unexpectedly, propionate metabolism. However, a reduction in proteome allocation for protein biosynthesis, at the expense of the observed increase toward energy and lipid metabolisms, might have caused the inhibitory effect of DP oil on cell growth. IMPORTANCE Sustainable processes for biological upcycling of plastic wastes in a circular bioeconomy are needed to promote decarbonization and reduce environmental pollution due to increased plastic consumption, incineration, and landfill storage. Strain characterization and proteomic analysis revealed the robust metabolic capabilities of Yarrowia lipolytica to upcycle polyethylene into high-value chemicals. Significant proteome reallocation toward energy and lipid metabolisms was required for robust growth on hydrocarbons with n-hexadecane as the preferential substrate. However, an apparent over-investment in these same categories to utilize complex depolymerized plastic (DP) oil came at the expense of protein biosynthesis, limiting cell growth. Taken together, this study elucidates how Y. lipolytica activates its metabolism to utilize DP oil and establishes Y. lipolytica as a promising host for the upcycling of plastic wastes.

1-alkenes↗

From carbon to climate action: harnessing basalt for geological carbon dioxide (CO 2 ) storage onshore and offshore

Abating emissions and reducing atmospheric concentrations of carbon dioxide (CO 2 ) are crucial in avoiding catastrophic climate change. Basalt reservoirs offer suitable CO 2 storage sites and are present onshore and offshore. This study compares the geological, economic and social aspects of CO 2 storage in both domains using two basalt formations from the Republic of Ireland: the Limerick Igneous Suite and the Druid Formation. Offshore reservoirs offer larger storage resources but are more expensive to develop. Nevertheless, both offer gigatonne-scale theoretical CO 2 storage. Reviewing public perception studies on wind energy demonstrates that the commonly held belief that offshore projects face less opposition owing to their distance from communities has been dispelled, while similar studies on carbon capture and removal show no preference for onshore or offshore development. Instead, a general scepticism towards carbon removal is observed, with concerns that it hinders broader decarbonization efforts. The desire of all stakeholders to be involved throughout project development is consistently observed. Lessons from offshore natural gas projects highlight the consequences of failing to engage with local communities. The Republic of Ireland has significant potential to deploy geological CO 2 storage in basalt reservoirs, but policy hurdles such as legal limits on storage volumes must be overcome to reconcile climate ambition and legislative capacity.

54 - ENVIRONMENTAL SCIENCES/GLOBAL CLIMATE CHANGE ↗

Emerging Technologies for Privacy Preservation in Energy Systems

This study explores the intersection of digitalization and privacy within the energy sector, focusing on the emerging challenges and opportunities presented by integrating Distributed Energy Resources (DERs) and advanced metering infrastructure. The need for robust digital privacy measures has become crucial as the energy industry evolves towards a more decentralized, digitalized, and decarbonized future. This study delves into four cutting-edge privacy-preserving technologies—Homomorphic Encryption (HE), Secure Multiparty Computation (SMPC), Differential Privacy (DP), and Federated Learning (FL)—each offering unique solutions to safeguard consumer data by increasing digital connectivity and data exchange. Through a detailed examination of these methods, the study explains how each technology operates, its applications within the energy sector, and the specific privacy challenges it addresses. Homomorphic Encryption allows for secure computations on encrypted data, enabling data analysis without compromising privacy. Secure Multiparty Computation enables collaborative data analysis across different entities while protecting the confidentiality of the inputs. Differential Privacy introduces randomness into the assembled data set, preventing the identification of individual records in statistical databases. Lastly, Federated Learning offers a paradigm shift in data analysis, where machine learning models are trained at the edge, minimizing the centralization of sensitive data. The research underscores the significance of implementing these privacy-enhancing technologies to comply with strict data protection regulations, foster consumer trust, and enhance the security of the energy infrastructure. By providing a comprehensive overview of these methodologies and their practical implications for the energy sector, this study aims to contribute to the ongoing discourse on digital privacy, offering insights into how the energy industry can navigate the complexities of data privacy in the digital age.

Cali, Umit↗

Effect of Engineered Cracks in Catalyst Layers on PEMFC Catalyst Layer Durability

Proton exchange membrane fuel cells (PEMFCs) are expected to play a pivotal role in decarbonizing the transportation sector, and particularly heavy-duty vehicles (HDVs). However, improvements in durability are needed for PEMFCs to compete with state-of-the-art power sources for HDVs. Here, we examine how catalyst layer (CL) cracks that are engineered affect the CL durability by using patterned silicon templates to control the CL crack density at the micrometer scale. Electrochemical analyses show that the initial PEMFC performance is relatively unaffected by crack density, but the performance after durability testing was strongly affected. Specifically, CLs with high crack density showed higher performance relative to CLs without cracks after application of a carbon corrosion accelerated stress test. Electrochemical analyses coupled with X-ray computed tomography and scanning transmission electron microscopy with energy dispersive X-ray spectroscopy showed that the cracks provide shorter oxygen diffusion pathways to reaction sites, leading to decreased oxygen transport resistance. Additionally, we observed that the catalyst durability is unaffected by cracks. Our results provide a mechanistic explanation of the role of cracks in CL durability.

30 DIRECT ENERGY CONVERSION↗

Rechargeable Manganese Dioxide||Hard Carbon Lithium Batteries in an Ether Electrolyte

Earth-abundant, cost-effective electrode materials are essential for sustainable rechargeable batteries and global decarbonization. Manganese dioxide (MnO 2 ) and hard carbon both exhibit high structural and chemical tunability, making them excellent electrode candidates for batteries. Herein, we elucidate the impact of electrolytes on the cycling performance of commercial electrolytic manganese dioxide in Li chemistry. We leverage synchrotron X-ray analysis to discern the chemical state and local structural characteristics of Mn during cycling, as well as to quantify the Mn deposition on the counter electrode. By using an ether-based electrolyte instead of conventional carbonate electrolytes, we circumvent the formation of a surface Mn(II)-layer and Mn dissolution from Li x MnO 2 . Consequently, we achieved an impressive ~100% capacity retention for MnO 2 after 300 cycles at C/3. To create a lithium metal-lean full cell, we introduce hard carbon as the anode which is compatible with ether-based electrolytes. Commercial hard carbon delivers a specific capacity of ~230 mAh g -1 at 0.1 A g -1 without plateau, indicating a surface-adsorption mechanism. The resulting manganese dioxide||hard carbon full cell exhibits stable cycling and high Coulombic efficiency. Our research provides a promising solution to develop cost-effective, scalable, and safe energy storage solutions using widely available manganese oxide and hard carbon materials.

25 ENERGY STORAGE↗

Shorting at Long Duration: Impact of Extended Discharge Capacity on Battery Solid Electrolytes

Long-duration energy storage (LDES) is critical to a stable, resilient, and decarbonized electric grid. While batteries are emerging as important LDES devices, extended, high-power discharges necessary for cost-competitive LDES present new materials challenges. Here, focusing on a new generation of low-temperature molten sodium batteries, we explore here unique phenomena related to long-duration discharge through a well-known solid electrolyte, NaSICON. Specifically, molten sodium symmetric cells at 110°C were cycled at 0.1 A cm -2 for 1-23 h discharges. Longer discharges led to unstable overpotentials, reduced resistances, and decreased electrolyte strength, caused by massive sodium penetration not observed in shorter duration discharges. Scanning electron microscopy informed mechanisms of sodium penetration and even “healing” during shorter-duration cycling. Importantly, these findings show that traditional, low-capacity, shorter-duration tests may not sufficiently inform fundamental materials phenomena that will impact LDES battery performance. This case highlights the importance that candidate LDES batteries be tested under pertinent long-duration conditions.

25 ENERGY STORAGE↗

Pioneering Microporous Layers for Proton-Exchange-Membrane Water Electrolyzers via Tape Casting

The imperative shift towards decarbonization necessitates the production of clean hydrogen through water electrolysis, powered by renewable energy sources. Among electrolyzer technologies, proton-exchange-membrane (PEM) systems emerge as a promising option for large-scale hydrogen generation due to their modular design and rapid response, aligning well with the intermittency of renewable energy. In this study, we employ a tape casting method to fabricate microporous layers (MPLs), both as a single layer and as a bilayer over commercial porous transport layers (PTLs), to further enhance performance of water electrolyzers. We demonstrate that microporous layers require adequate pore sizes to facilitate gas removal, preventing gas flooding and preserving electrolyzer performance. Our single layer microporous layers exhibit lower overpotentials compared to commercial sintered Ti PTLs by 142 mV at 4 A·cm ⁻2 . Moreover, we show that having an effective microporous layer enhances electrolyzer performance irrespective of the substrate used, offering avenues for cost reduction. We also investigate novel PTL structures with reduced tortuosity and integrated MPL fabricated via phase inversion tape casting, resulting in a performance enhancement of 92 mV. Our findings unravel the critical role of microporous layer structures and their impact on electrolyzer performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Full-Cell Model for Direct Toluene Electro-Hydrogenation Electrolysis

Liquid organic hydrogen carriers (LOHCs) are organic molecules that undergo a hydrogenation/dehydrogenation cycle to enable storage and transportation of hydrogen fuel under ambient conditions. One promising LOHC candidate is toluene, which can be converted to methylcyclohexane (MCH) electrochemically, enabling a decarbonized process when green electricity is used. In this study, we developed a full-cell model for the direct electro-hydrogenation of toluene to MCH, utilizing a zero-gap membrane electrode assembly architecture. The model incorporates electrochemical kinetics, ionic transport, water transport across the membrane, and mass transport effects. Electrochemical kinetics are characterized using Tafel analysis on Pt/Ru catalyst. The model is validated against experimental data, including polarization curves, Faradaic efficiencies, and water crossover. A voltage breakdown analysis shows that the performance is dominated by kinetic losses, and the model is used to carry out a comparison of different toluene electro-hydrogenation reaction catalysts. Finally, a sensitivity analysis is conducted on key design parameters illustrating which can be modified to maximize electrolyzer performance. The cathode specific surface area and cathode porous transport layer thickness (PTL) have the largest impact on the current density, while the PTL thickness and Pt loading in the PTL have the largest impact on Faradaic efficiency.

Ehlinger, Victoria M. [Lawrence Livermore National↗

The Rise of US Photovoltaics: An Exploration of Land Use Density Trends in Large‐Scale Solar Facility Attributes, 2012–2021

An energy transition is underway in the United States; renewable energy generation is now on par with coal and nuclear generation. The number of large-scale solar photovoltaic facilities increased approximately tenfold between 2012 and 2021, with an associated 25-fold increase in cumulative installed capacity. With ambitious decarbonization and renewable energy deployment goals at both the federal and state levels, deployments of large-scale solar photovoltaic facilities will continue apace. This growth is likely to be complex with ripples of impacts felt throughout different aspects of society, and thus accurate solar land use metrics allowing more accurate predictions are of value to policymakers, planners, and other stakeholders in the future photovoltaic build-out. In this paper, we leverage data from the newly released US Large-Scale Solar Photovoltaic Database to examine recent trends in large-scale solar photovoltaic land use. We analyze the relationships between solar array capacity density (W/acre) and a range of facility attributes to better understand the future land requirements of solar capacity expansion over the coming years. Installed capacity was the single strongest determinant of solar array area. However, we found substantial variation in capacity density across facility attributes, including mount type, latitude, urbanicity, time, and prior land use.

14 SOLAR ENERGY↗

BuildingsBench: A Benchmark for Universal Building Load Forecasting [SWR-23-51]

The residential and commercial building stock in the United States is responsible for a significant percentage of energy consumption and greenhouse gas emissions. Electrification of end-uses, as well as decarbonizing the electrical grid through renewable energy sources such as solar and wind, constitutes the pathway to zero-emission buildings. Forecasting day-ahead building energy consumption is an integral part of this solution. Currently, specialized forecasting models are hand-made for each individual building, which is time-consuming, expensive, and leads to duplicated efforts. BuildingsBench is a Python software framework for training and comparing generalized machine learning models for universal building load forecasting. This challenge tasks a single foundational model to generalize its forecasts for a wide variety of buildings, across geographic regions, building types, weather patterns, and more. This software provide code for pre-training such models and subsequently evaluating their performance on a suite of hundreds of diverse real and synthetic buildings. BuildingsBench is a platform for: - Large-scale pretraining with the synthetic Buildings-900K dataset for short-term load forecasting (STLF). Buildings-900K is statistically representative of the entire U.S. building stock and is extracted from the NREL End-Use Load Profiles database. - Benchmarking on two tasks evaluating generalization: zero-shot STLF and transfer learning for STLF. We provide an index-based PyTorch Dataset for large-scale pretraining, easy data loading for multiple real building energy consumption datasets as PyTorch Tensors or Pandas DataFrames, simple (persistence) to advanced (transformer) baselines, metrics management, and more.

Emami, Patrick↗

EMF Biomass Data Interpreter [SWR-23-06]

EMF Biomass Data Interpreter was developed for the transportation team of the Energy Modeling Forum (EMF) 37: Deep Decarbonization and High Electrification Scenarios for North America project. It parses results from different modeling groups to show how biomass might be employed under electrification.

Wachs, Elizabeth↗

ALTRIOS (Advanced Locomotive Technology and Rail Infrastructure Optimization System) [SWR-22-54]

The Advanced Locomotive Technology and Rail Infrastructure Optimization System (ALTRIOS) is a unique, fully integrated, open-source software tool to evaluate strategies for deploying advanced locomotive technologies and associated infrastructure for cost-effective decarbonization. ALTRIOS simulates freight-demand driven train scheduling, mainline meet-pass planning, locomotive dynamics, train dynamics, energy conversion efficiencies, and energy storage dynamics of line-haul train operations. Because new locomotives represent a significant long-term capital investment and new technologies must be thoroughly demonstrated before deployment, this tool provides guidance on the risk/reward tradeoffs of different technology rollout strategies. An open, integrated simulation tool is invaluable for identifying future research needs and making decisions on technology development, routes, and train selection. ALTRIOS was developed as part of a collaborative effort by a team comprising the National Renewable Energy Laboratory (NREL), University of Illinois Urbana-Champaign (UIUC), Southwest Research Institute (SwRI), and BNSF Railway. Python Package: https://pypi.org/project/altrios/ Rust Crate: https://crates.io/crates/altrios-core

Baker, Chad↗

Behind-the-meter Infrastructure Costs for Electrification Progression (BICEP) Model

The Behind-the-meter Infrastructure Costs for Electrification Progression (BICEP) model quantifies the behind-the-meter (BTM) electrical upgrades required for decarbonization through electrification by comparing the expected change in capacity requirements from the electrification technologies to the existing capacity in distributed energy resources (DER) stock (including buildings).

Yoder, Tim↗