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At least 1,081 records · Page 60

The Cell Utilized Partitioning Model as a Predictive Tool for Optimizing Counter-Current Chromatography Processes

Counter-current chromatography (CCC) is capable of unique elution modes that isolate analytes using the movement of the stationary phase in addition to moving the mobile phase. These modes include elution-extrusion CCC (EECCC) and dual-mode CCC (DM CCC) that are not possible in traditional solid-liquid chromatography systems. Although EECCC and DM CCC are widely used to recover highly retained components, to our knowledge, optimizing the elution process in these modes with predictive models has not been reported. To address this gap, we developed a predictive model for CCC dubbed the Cell Utilized Partitioning (CUP) model. The CUP model accurately predicts the effluents of multicomponent separations in EECCC and DM CCC modes when compared to experimental data. Furthermore, CUP model simulations were extended to investigate the influence of operating and intrinsic parameters on the yield and productivity, and to compare the separation performances of EECCC and DM CCC in various conditions. The results demonstrate that low distribution constants, usually a KD less than 1, and a selectivity > 1.3, under specific flowrate ranges, increase both productivity and yield. From these results, generalized optimization and scaleup guidelines are proposed that can apply to research settings and to industrial processes to maximize preparative CCC performance.

BIOMASS FUELS,INORGANIC, ORGANIC, PHYSICAL, AND AN↗

The historic biogeography of India: isolation or contact?

Geophysical maps depicting continental movement have consistently shown India, as it moved northward, to be located far out in the Tethys Sea. India split off from the African east coast about 148 m.y.a. From that time onward, according to almost all geophysical accounts, India was isolated from all of other continents until the early Miocene when it made contact with Eurasia. But the biological data, both fossil and Recent, indicate that this concept cannot be correct. If India had really existed as an isolated, oceanic continent for about 100 m.y., it should have developed a peculiar biota with many endemic genera and families in its terrestrial and shallow marine habitats. But there are virtually no remains of organisms indicating that India was isolated for any substantial time (millions of years). Instead, we find that almost all Indian taxa were possessed in common with other continents. As time went on, the northern relationships became stronger and the southern ones weaker. Most of the recent geophysical accounts show India not making contact with Eurasia until the early Miocene, but fossil materials show that this event must have taken place by the early Eocene. It has been postulated that, as India moved northward, it created a biogeographic barrier that separated marine fish populations and resulted in the east-west provinces that are now apparent in the Indian Ocean. At the same time, the barrier effect was supposed to have resulted in the formation of sister species that are now located far apart. Information currently available indicates that most living, tropical marine species are probably not over 3 m.y. old. Consequently, the northward movement of India, which took place primarily between 148 and 50 m.y.a., could have no bearing on the relationships of modern species.

NASA Discipline Exobiology↗

Migration of lymphocytes on fibronectin-coated surfaces: temporal evolution of migratory parameters

Lymphocytes typically interact with implanted biomaterials through adsorbed exogenous proteins. To provide a more complete characterization of these interactions, analysis of lymphocyte migration on adsorbed extracellular matrix proteins must accompany the commonly performed adhesion studies. We report here a comparison of the migratory and adhesion behavior of Jurkat cells (a T lymphoblastoid cell line) on tissue culture treated and untreated polystyrene surfaces coated with various concentrations of fibronectin. The average speed of cell locomotion showed a biphasic response to substrate adhesiveness for cells migrating on untreated polystyrene and a monotonic decrease for cells migrating on tissue culture-treated polystyrene. A modified approach to the persistent random walk model was implemented to determine the time dependence of cell migration parameters. The random motility coefficient showed significant increases with time when cells migrated on tissue culture-treated polystyrene surfaces, while it remained relatively constant for experiments with untreated polystyrene plates. Finally, a cell migration computer model was developed to verify our modified persistent random walk analysis. Simulation results suggest that our experimental data were consistent with temporally increasing random motility coefficients.

NASA Program Fundamental Space Biology↗

Coronal Imaging with the Solar Ultraviolet Imager

Coronal imaging capabilities of the Solar UltraViolet Imager (SUVI) on the Geostationary Operational Environmental Satellite-16 (GOES-16) are investigated. Launched in 2016, GOES-16 is stationed at 75.2 deg W longitude and accommodates both terrestrial and space weather instruments. SUVI is one of two instruments observing the Sun, providing solar images in six extreme ultraviolet (EUV) wavelengths: 94A, 131A, 171A, 195A, 284A and 304A. Mounted on a two axis gimballed Sun Pointed Platform (SPP), its 53 arc minute square field of view is nominally Sun-centered to provide high dynamic range images in all six wavelengths every four minutes. Analyses of on-orbit data indicated that SUVI had sufficient dynamic range and sensitivity in the 171A and 195A wavelengths to image the corona to the largest heights above the Sun to date while simultaneously imaging the Sun. The 1.6 megapixel Charge Coupled Device (CCD) detector enables the capture of the fine features of the corona. On-orbit calibration tests requiring movement of the SUVI line-of-sight off the Sun, demonstrated that the resulting dynamic disturbance didn't adversely impact the earth-pointing instrument performance. Combining these factors, we conducted a test to assess the performance of SUVI as an EUV extremely wide-field coronal imager by off-pointing the SPP around the Sun and synthesizing an image that's about 4 times the diameter of the Sun. The capability to perform coronal imaging at these two wavelengths is demonstrated by off-pointing the SUVI boresight to nine locations around the Sun and generating a composite coronal image that extends to approx. 4 solar radii. For this purpose, we exploited the satellite's ability to provide stable, fine pointing, even during the slews. Various exposure durations were considered during the first trial and a composite coronal image is obtained for each wavelength. The results are promising. The off-pointing locations and the exposure duration are being refined for the subsequent trials. The routine use of an ultraviolet solar imager as both an imager and a EUV coronagraph would be the first of its kind and is an exciting development. The on-orbit solar coronagraphs to date provide white light images with fields of view extending from 4-15 solar radii. Earlier, Seaton, et al investigated the evolution of the corona in EUV near the solar surface with the data from the Sun Watcher with Active Pixels and Image Processing (SWAP) EUV solar telescope on board the Project for On-Board Autonomy 2 (PROBA2). The presence of corona in EUV even to 4 solar radii is not known. The results of these experiments will begin to fill this void.

Tadikonda, Sivakumara K.↗

Coronal Imaging with the Solar Ultraviolet Imager

Coronal imaging capabilities of the Solar UltraViolet Imager (SUVI) on the Geostationary Operational Environmental Satellite-16 (GOES-16) are investigated. Launched in 2016, GOES-16 is stationed at 75.2 deg W longitude and accommodates both terrestrial and space weather instruments. SUVI is one of two instruments observing the Sun, providing solar images in six extreme ultraviolet (EUV) wavelengths: 94A, 131A, 171A, 195A, 284A and 304A. Mounted on a two axis gimballed Sun Pointed Platform (SPP), its 53 arcminute square field of view is nominally Sun-centered to provide high dynamic range images in all six wavelengths every four minutes. Analyses of on-orbit data indicated that SUVI had sufficient dynamic range and sensitivity in the 171A and 195A wavelengths to image the corona to the largest heights above the Sun to date while simultaneously imaging the Sun. The 1.6 megapixel Charge Coupled Device (CCD) detector enables the capture of the fine features of the corona. On-orbit calibration tests requiring movement of the SUVI line-of-sight off the Sun, demonstrated that the resulting dynamic disturbance didn't adversely impact the earth-pointing instrument performance. Combining these factors, we conducted a test to assess the performance of SUVI as an EUV extremely wide-field coronal imager by off-pointing the SPP around the Sun and synthesizing an image that's about 4 times the diameter of the Sun. The capability to perform coronal imaging at these two wavelengths is demonstrated by off-pointing the SUVI boresight to nine locations around the Sun and generating a composite coronal image that extends to approx. 4 solar radii. For this purpose, we exploited the satellite's ability to provide stable, fine pointing, even during the slews. Various exposure durations were considered during the first trial and a composite coronal image is obtained for each wavelength. The results are promising. The off-pointing locations and the exposure duration are being refined for the subsequent trials. The routine use of an ultraviolet solar imager as both an imager and a EUV coronagraph would be the first of its kind and is an exciting development. The on-orbit solar coronagraphs to date provide white light images with fields of view extending from 4-15 solar radii. Earlier, Seaton, et al investigated the evolution of the corona in EUV near the solar surface with the data from the Sun Watcher with Active Pixels and Image Processing (SWAP) EUV solar telescope on board the Project for On-Board Autonomy 2 (PROBA2). The presence of corona in EUV even to 4 solar radii is not known. The results of these experiments will begin to fill this void.

Tadikonda, Sivakumara K.↗

A File Format and API for Dynamic Radar Cross Section Data

Often the Radar Cross-Section (RCS) of a target is incorrectly assumed to be a single number by those unfamiliar with electromagnetic scattering. In actuality, a target's RCS depends on many factors. These factors include radar signal frequency, radar observation angle, as well as target orientation. Another possible parameter (often not considered) is time. The RCS of targets may change over time due to movement, environmental changes, etc. In order to accurately represent the dynamic RCS of a target in a time-stepped analysis, the ability to interface with large RCS datasets efficiently is desired. To this end, a file format and API (written in C++) were developed and are described in this report.

42 ENGINEERING↗

Integrated Modeling Report for CO 2 Storage with Enhanced Oil Recovery in Northern Michigan

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. MRCSP has been investigating various reservoir characterization and modeling technologies related to Carbon Capture, Utilization, and Storage (CCUS) in conjunction with carbon dioxide enhanced oil recovery (CO 2 -EOR) operations in multiple Silurian-age (Niagaran), oil-bearing, carbonate pinnacle reefs in northern Michigan, USA. This report provides a comprehensive discussion of reservoir modeling studies that were conducted for tracking oil production, forecasting CO 2 plume migration, and estimating associated storage in a number of reefs that were at different stages of their CO 2 -EOR life cycle. The modeling process for simulating oil production, CO 2 injection, and associated storage in these reefs entails two phases. The first phase, geologic framework modeling, integrates all pertinent geological and geophysical data (from logs, cores and seismic surveys) about reservoir structure, geometry, rock types, and property distributions (porosity, permeability, water saturation) into a 3-D distributed grid-based static earth model (SEM). The second phase, dynamic reservoir modeling, uses the SEM as a platform to simulate the movement of oil, gas, water, and CO 2 within the reservoir during primary hydrocarbon production, as well as during subsequent phases such as CO 2 -injection assisted EOR, plume migration, and associated storage. In addition, an assessment of coupled process effects is also carried out, where the impacts of geochemical and geo-mechanical processed induced by CO 2 injection are studied.

01 COAL, LIGNITE, AND PEAT↗

HCMM and LANDSAT imagery for geological mapping in northwest Queensland

The author has identified the following significant results. Photographic prints made from negatives of day-visible and day-IR cover of selected areas were compared with enhanced color composites generated from LANDSAT computer compatible tapes and films. For geological mapping purposes, HCMM imagery is of limited value. While large scale features like the Mikadoodi anticlinorium, contrasting lithological units, and major structures may be distinguished on day-visible and day-IR cover, the spectral bands are too broad and the resolution too coarse even for regional mapping purposes. The imagery appears to be most useful for drainage studies. Where drainage is seasonal, sequential imagery permits monitoring of broad scale water movement while the day-IR imagery yields valuable information on former channels. In plains areas subject to periodic change of stream courses, comparable IR cover at a larger scale would offer considerable potential for reconstruction of former drainage patterns essential for the correct interpretation of geochemical data relative to mineral exploration.

Cole, M. M.↗

The life cycle of thunderstorm gust fronts as viewed with Doppler radar and rawinsonde data

This paper presents the time-dependent analysis of the thunderstorm gust front with the use of Project NIMROD data. RHI cross sections of reflectivity and Doppler velocity are constructed to determine the entire vertical structure. The life cycle of the gust front is divided into four stages: (1) the formative stage; (2) the early mature stage; (3) the late mature stage; and (4) the dissipation stage. A new finding is a horizontal roll detected in the reflectivity pattern resulting from airflow that is deflected upward by the ground, while carrying some of the smaller precipitation ahead of the main echo core of the squall line. This feature is called a 'precipitation roll'. As determined from rawinsonde data, the cold air behind the gust front accounts for the observed surface pressure rise. Calculations confirm that the collision of two fluids produce a nonhydrostatic pressure at the leading edge of the outflow. The equation governing the propagation speed of a density current accurately predicts the movement of the gust front.

Wakimoto, R. M.↗

Southern ocean sea-ice morphology and kinematics

A pilot satellite experiment is described which would employ shuttle imaging radar (SIR) to determine the applicability of imaging radar for the description of sea ice type and movement. The experimental objectives, design, and anticipated results are discussed. The results are expected to constitute an important contribution to the understanding of the role of sea ice in air-sea interactions in polar regions. It is proposed that shuttle photography, thematic mapper imagery, and SIR data be utilized in this remote sensing project.

Carsey, F.↗

X-ray Variability of the Magnetic Cataclysmic Variable V1432 Aql and the Seyfert Galaxy NGC 6814

V1432 Aquilae (=RX J1940.2-1025) is the X-ray bright, eclipsing magnetic cataclysmic variable approximately 37 (sup) away from the Seyfert galaxy, NGC 6814. Due to a 0.3% difference between the orbital (12116.3 s) and the spin (12150 s) periods: the accretion geometry changes over the approximately 50 day beat period. Here we report the results of an RXTE campaign to observe the eclipse 25 times, as well as of archival observations with ASCA and BeppoSAX. Having confirmed that the eclipse is indeed caused by the secondary, we use the eclipse timings and profiles to map the accretion geometry as a function of the beat phase. We find that the accretion region is compact, and that it moves relative to the center of white dwarf on the beat period. The amplitude of this movement suggest a low-mass white dwarf, in contrast to the high mass previously estimated from its X-ray spectrum. The size of the X-ray emission region appears to be larger than in other eclipsing magnetic CVs. We also report on the RXTE data as well as the long-term behavior of NGC 6814, indicating flux variability by a factor of at least 10 on time scales of years.

Mukai, K.↗

Comparison of A-SMGCS Requirements with Observed Performance of an Integrated Airport CNS System

The International Civil Aviation Organization (ICAO) has recently drafted a reference document describing the operational requirements for Advanced Surface Movement Guidance and Control Systems (A-SMGCS). During the summer of 1997, NASA, the FAA, industry, and academia partners demonstrated a holistic system approach that has the potential to meet many of the proposed A-SMGCS requirements. An assessment of the field tested system and data resulting from the field testing is presented to determine its compliance with A-SMGCS requirements. In those areas where compliance was not demonstrated, a recommendation is presented suggesting further research or a modification of the system architecture.

Young, Steven D.↗

Tilt/Tip/Piston Manipulator with Base-Mounted Actuators

A proposed three-degree-of-freedom (tilt/tip/piston) manipulator, suitable for aligning an optical or mechanical component, would offer several advantages over prior such manipulators: Unlike in some other manipulators, no actuator would support the weight of another actuator: All of the actuators would be mounted on a base. Hence, there would be less manipulated weight. The basic geometry of the manipulator would afford mechanical advantage: that is, actuator motions would be larger than the motions they produce in the manipulated object. Mechanical advantage inherently increases the accuracy and resolution of manipulation. Unlike in some other manipulators, it would not be necessary to route power and/or data lines through manipulator joints. The proposed manipulator (see figure) would include three prismatic actuators (T1N1, T2N2, and T3N3) mounted on the base and operating in the same plane. Examples of suitable prismatic actuators include lead-screw mechanisms, linear hydraulic motors, piezoelectric linear drives, inchworm-movement linear stepping motors, and linear flexure drives. The actuators would control the lengths of links R1T1, R2T2, and R3T3. Three spherical joints (P1, P2, and P3) would be located at the corners of an equilateral triangle of side length q on the platform holding the object to be manipulated. Three inextensible limbs (R1P1, R2P2, and R3P3) having length r would connect the spherical joints on the platform to revolute joints (R1, R2, and R3) at the ends of the actuator-controlled links R1T1, R2T2, and R3T3. By varying the lengths of these links, one could control the tilt, tip, and piston coordinates of the platform. Closed-form equations for direct or forward kinematics of the manipulator (given the lengths of the variable links, find the tilt, tip, and piston coordinates) have been derived. The equations of inverse kinematics (find the variable link lengths needed to obtain the desired tilt, tip, and piston coordinates) have also been derived.

Tahmasebi, Farhad↗

Prolonged Rock Exhumation at the Rims of Kilometer-scale Lunar Craters

Fresh impact ejecta deposits on the lunar surface can be characterized as heterogeneous mixtures of boulders, cobbles, and fine-grained regolith that are deposited on the lunar surface during the impact crater formation process. Over time, the surface boulders associated with ejecta deposits break down into fine-grained regolith due to a combination of later impacts and thermal fatigue. Nonetheless, observations of old (>2.0 Ga) kilometer-scale (0.8–2.0 km) lunar impact craters in high-resolution images reveal >1 m boulders along their rims and in their near-proximal ejecta deposits on the lunar maria. Here, we use a combination of radar and thermal-infrared data from the Lunar Reconnaissance Orbiter spacecraft to show that the rims of kilometer-sized impact craters exhibit elevated rock abundances for the lifetime of the lunar maria. We interpret these results as indicating that boulders are continually being uncovered at crater rims due to downslope movement of the overlying regolith. Moreover, rocks found at crater rims that have been exhumed from depth in geologically recent times are locally derived and unlikely to have come from other areas of the Moon. Future collection of lunar samples at crater rims will serve to mitigate the potential for sample contamination from distal sources, helping to ensure accurate geologic interpretations from the collected samples.

moon↗

Mapping Phyllosilicates on the Asteroid Bennu Using Thermal Emission Spectra and Machine Learning Model Applications

Bennu, the target of the OSIRIS-REx mission, is an asteroid with compositions analogous to low petrologic type CI, CM, CR, and/or ungrouped carbonaceous chondrites. Asteroids like Bennu provide information about the building blocks of the early Solar System. Analysis of the mid-infrared remote sensing data informs mineral quantification. We apply a phyllosilicate specific model, developed by Breitenfeld et al. (2021) that distinguishes between Mg and Fe serpentines, to Baseball Diamond 1 (BBD1), Equatorial Station 3 (EQ3), and Touch-And-Go OSIRIS-REx Thermal Emission Spectrometer data. The average total phyllosilicate predictions are 73 (BBD1) and 72 vol% (EQ3). We observe higher Fe-cronstedtite and lower Mg-rich serpentine content in the equatorial region of Bennu than average. Mid-infrared spectral variability may be explained by sorting effects through mass movement.

Bennu↗

The Knowledge-based Digital Platform Concept for Advanced Air Mobility Research and Development

National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) is spearheading an innovative digital engineering approach to integrate, communicate, and facilitate the research of multi-modal transportation systems. The Knowledge-based Digital Platform (KbDP) is a concept being developed that ties the workflows of Project Managers (PM), Principal Investigators (PI), and System Engineers (SE) together across organizational boundaries. The overarching vision for the KbDP Concept for AAM R&D is a substantial undertaking. The initial concept and implementation will focus on UAM operations to tractably learn and adjust the concept with a manageable database. Lessons learned and best practices with a smaller scope will enable successful scalability to AAM R&D or even to the entire modes of transportation and logistics. The UAM vision is one in which advanced technologies and new operational procedures enable practical and cost-effective air transport as an integrated mode of movement of people and goods throughout metropolitan areas. Initial implementation of three KbDP concepts of use shows promising benefits to NASA’s Air Traffic Management-Exploration (ATM-X) UAM Airspace Subproject. It is envisioned that the KbDP will manage an information database defined by mathematical, data science, and system engineering principles. AIML algorithms play a vital role in this KbDP concept by extracting meaningful knowledge from the information database, which the human user leverages to improve the efficiency and effectiveness of their research greatly.

ATM↗

Stabilization of gaze during circular locomotion in light. I. Compensatory head and eye nystagmus in the running monkey

1. A rhesus and cynomolgus monkey were trained to run around the perimeter of a circular platform in light. We call this "circular locomotion" because forward motion had an angular component. Head and body velocity in space were recorded with angular rate sensors and eye movements with electrooculography (EOG). From these measurements we derived signals related to the angular velocity of the eyes in the head (Eh), of the head on the body (Hb), of gaze on the body (Gb), of the body in space (Bs), of gaze in space (Gs), and of the gain of gaze (Gb/Bs). 2. The monkeys had continuous compensatory nystagmus of the head and eyes while running, which stabilized Gs during the slow phases. The eyes established and maintained compensatory gaze velocities at the beginning and end of the slow phases. The head contributed to gaze velocity during the middle of the slow phases. Slow phase Gb was as high as 250 degrees/s, and targets were fixed for gaze angles as large as 90-140 degrees. 3. Properties of the visual surround affected both the gain and strategy of gaze compensation in the one monkey tested. Gains of Eh ranged from 0.3 to 1.1 during compensatory gaze nystagmus. Gains of Hb varied around 0.3 (0.2-0.7), building to a maximum as Eh dropped while running past sectors of interest. Consistent with predictions, gaze gains varied from below to above unity, when translational and angular body movements with regard to the target were in opposite or the same directions, respectively. 4. Gaze moved in saccadic shifts in the direction of running during quick phases. Most head quick phases were small, and at times the head only paused during an eye quick phase. Eye quick phases were larger, ranging up to 60 degrees. This is larger than quick phases during passive rotation or saccades made with the head fixed. 5. These data indicate that head and eye nystagmus are natural phenomena that support gaze compensation during locomotion. Despite differential utilization of the head and eyes in various conditions, Gb compensated for Bs. There are various frames of reference in which an estimate of angular velocity that drives the head and eyes could be based. We infer that body in space velocity (Bs) is likely to be represented centrally to provide this signal.

Non-NASA Center↗

SSRS (Stochastic Soaring Raptor Simulator)

SSRS (Stochastic Soaring Raptor Simulator) is a generalizable, probabilistic, and predictive tool for wind energy developers, ecologists, wildlife managers and industry consultants to estimate the potential for soaring raptors to interact with operating wind turbines, without the need for site-specific data collection. Rapid expansion of wind energy development across the world has exposed the risk of turbine collisions for birds and bats. The risk to obligate soaring raptors such as golden eagles is of particular concern due to their small population and influence on ecological balance. Golden eagles rely heavily on updrafts to subsidize their flight, putting them in direct conflict with operational wind turbines that utilize the same wind resource. Understanding the behavior of soaring raptors with varying atmospheric conditions is crucial for predicting and mitigating the risk of turbine collision. This software contains a predictive movement model that simulates individual flight paths of golden eagles during updraft-subsidized long-distance flight, including migration. For a given set of atmospheric conditions, the model simulates thousands of eagles at turbine-scale spatial resolution (50m) to produce a relative presence density map. The simulated eagles rely on updrafts to pursue uninterrupted directional flight with minimal energy expenditure, following fluid-flow principles. The simulator includes a stochastic model of eagle behavior and a systematic method of accounting for spatiotemporal variations in atmospheric conditions. This framework only requires publicly available atmospheric data to estimate orographic and thermal updrafts, ensuring general usability.

Sandhu, Rimple↗