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TiF6Zn(H2O)6 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three TiF6 clusters and three zinc hexahydrate molecules. In each TiF6 cluster, Ti4+ is bonded in an octahedral geometry to six equivalent F1- atoms. All Ti–F bond lengths are 1.89 Å. F1- is bonded in a single-bond geometry to one Ti4+ atom.
TiF6Zn(H2O)6 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three TiF6 clusters and three zinc hexahydrate molecules. In each TiF6 cluster, Ti4+ is bonded in an octahedral geometry to six equivalent F1- atoms. All Ti–F bond lengths are 1.90 Å. F1- is bonded in a single-bond geometry to one Ti4+ atom.
Ti6O is Hg_xSn structured and crystallizes in the trigonal P-31m space group. The structure is zero-dimensional and consists of one Ti6O cluster. Ti is bonded in a single-bond geometry to one O atom. The Ti–O bond length is 2.10 Å. O is bonded in an octahedral geometry to six equivalent Ti atoms.
Y4Ni is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Y4Ni clusters. Y is bonded in a single-bond geometry to one Ni atom. The Y–Ni bond length is 2.54 Å. Ni is bonded in a tetrahedral geometry to four equivalent Y atoms.
Zr4W is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Zr4W clusters. Zr is bonded in a single-bond geometry to one W atom. The Zr–W bond length is 2.52 Å. W is bonded in a tetrahedral geometry to four equivalent Zr atoms.
Ho4Mn is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ho4Mn clusters. Ho is bonded in a single-bond geometry to one Mn atom. The Ho–Mn bond length is 2.46 Å. Mn is bonded in a tetrahedral geometry to four equivalent Ho atoms.
Zr4Ir is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Zr4Ir clusters. Zr is bonded in a single-bond geometry to one Ir atom. The Zr–Ir bond length is 2.49 Å. Ir is bonded in a tetrahedral geometry to four equivalent Zr atoms.
Nd4Ni is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Nd4Ni clusters. Nd is bonded in a single-bond geometry to one Ni atom. The Nd–Ni bond length is 2.60 Å. Ni is bonded in a tetrahedral geometry to four equivalent Nd atoms.
TbGa6 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of two Ga clusters and two TbGa2 clusters. In each Ga cluster, Ga is bonded in an L-shaped geometry to two equivalent Ga atoms. Both Ga–Ga bond lengths are 2.58 Å. In each TbGa2 cluster, Tb is bonded in a linear geometry to two equivalent Ga atoms. Both Tb–Ga bond lengths are 2.86 Å. Ga is bonded in a single-bond geometry to one Tb atom.
Tm4Rh is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Tm4Rh clusters. Tm is bonded in a single-bond geometry to one Rh atom. The Tm–Rh bond length is 2.56 Å. Rh is bonded in a tetrahedral geometry to four equivalent Tm atoms.
(TaF6)2FeN6 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of four FeN6 clusters and eight TaF6 clusters. In each FeN6 cluster, Fe3+ is bonded in an octahedral geometry to six equivalent N+0.17- atoms. All Fe–N bond lengths are 2.01 Å. N+0.17- is bonded in a single-bond geometry to one Fe3+ atom. In each TaF6 cluster, Ta5+ is bonded in an octahedral geometry to six equivalent F1- atoms. All Ta–F bond lengths are 1.92 Å. F1- is bonded in a single-bond geometry to one Ta5+ atom.
Ho4Fe is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ho4Fe clusters. Ho is bonded in a single-bond geometry to one Fe atom. The Ho–Fe bond length is 2.43 Å. Fe is bonded in a tetrahedral geometry to four equivalent Ho atoms.
YbGa2(Ga)4 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of two Ga clusters and two YbGa2 clusters. In each Ga cluster, Ga is bonded in an L-shaped geometry to two equivalent Ga atoms. Both Ga–Ga bond lengths are 2.58 Å. In each YbGa2 cluster, Yb is bonded in a linear geometry to two equivalent Ga atoms. Both Yb–Ga bond lengths are 3.39 Å. Ga is bonded in a single-bond geometry to one Yb atom.
Ho4Ni is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ho4Ni clusters. Ho is bonded in a single-bond geometry to one Ni atom. The Ho–Ni bond length is 2.51 Å. Ni is bonded in a tetrahedral geometry to four equivalent Ho atoms.
Dy4Ni is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Dy4Ni clusters. Dy is bonded in a single-bond geometry to one Ni atom. The Dy–Ni bond length is 2.52 Å. Ni is bonded in a tetrahedral geometry to four equivalent Dy atoms.
TbTe2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one TbTe2 cluster. Tb4+ is bonded in a linear geometry to two equivalent Te2- atoms. Both Tb–Te bond lengths are 3.05 Å. Te2- is bonded in a single-bond geometry to one Tb4+ atom.
Tb4Mn is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Tb4Mn clusters. Tb is bonded in a single-bond geometry to one Mn atom. The Tb–Mn bond length is 2.48 Å. Mn is bonded in a tetrahedral geometry to four equivalent Tb atoms.
Lu4Rh is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Lu4Rh clusters. Lu is bonded in a single-bond geometry to one Rh atom. The Lu–Rh bond length is 2.54 Å. Rh is bonded in a tetrahedral geometry to four equivalent Lu atoms.