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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Three-dimensional hierarchically porous MoS 2 foam as high-rate and stable lithium-ion battery anode

Architected materials that actively respond to external stimuli hold tantalizing prospects for applications in energy storage, wearable electronics, and bioengineering. Molybdenum disulfide, an excellent two-dimensional building block, is a promising candidate for lithium-ion battery anode. However, the stacked and brittle two-dimensional layered structure limits its rate capability and electrochemical stability. Here we report the dewetting-induced manufacturing of two-dimensional molybdenum disulfide nanosheets into a three-dimensional foam with a structural hierarchy across seven orders of magnitude. Our molybdenum disulfide foam provides an interpenetrating network for efficient charge transport, rapid ion diffusion, and mechanically resilient and chemically stable support for electrochemical reactions. These features induce a pseudocapacitive energy storage mechanism involving molybdenum redox reactions, confirmed by in-situ X-ray absorption near edge structure. The extraordinary electrochemical performance of molybdenum disulfide foam outperforms most reported molybdenum disulfide-based Lithium-ion battery anodes and state-of-the-art materials. This work opens promising inroads for various applications where special properties arise from hierarchical architecture.

25 ENERGY STORAGE↗
DOE OSTI2020

Relative importance of nonlinear electron-phonon coupling and vertex corrections in the Holstein model

Determining the range of validity of Migdal’s approximation for electron-phonon (e-ph) coupled systems is a long-standing problem. Many attempts to answer this question employ the Holstein Hamiltonian, where the electron density couples linearly to local lattice displacements. When these displacements are large, however, nonlinear corrections to the interaction must also be included, which can significantly alter the physical picture obtained from this model. Using determinant quantum Monte Carlo and the self-consistent Migdal approximation, we compared superconducting and charge-density-wave correlations in the Holstein model with and without second-order nonlinear interactions. We find a disagreement between the two cases, even for relatively small values of the e-ph coupling strength, and, importantly, that this can occur in the same parameter regions where Migdal’s approximation holds. Our results demonstrate that questions regarding the validity of Migdal’s approximation go hand in hand with questions of the validity of a linear e-ph interaction.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

(S)TEM-EELS as an advanced characterization technique for lithium-ion batteries

Although the lithium-ion battery (LIB) has acquired commercial success as a sustainable power source, it still suffers from multiple challenges for the future applications. In order to further develop next-generation batteries, the dynamics of structure change, charge transfer, and ion diffusion occurring inside the battery need to be deeply understood by advanced characterization techniques. (Scanning) transmission electron microscopy-electron energy loss spectroscopy ((S)TEM-EELS) is an effective method for the nano-scale detection of structural and chemical information in materials. Herein, this review systematically introduces the advantages and fundamentals of (S)TEM-EELS and its unique applications in LIBs.

25 ENERGY STORAGE↗
DOE OSTI2020

CyDER: A Cyber Physical Co-simulation Platform for Distributed Energy Resources in Smartgrids

The CyDER project aimed at developing an open-source, modular and scalable co-simulation platform for power grids with large shares of Distributed Energy Resources (DERs). The project partners are the Lawrence Berkeley National Lab (LBNL), Lawrence Livermore National Lab (LLNL), PG&E, SolarCity, and ChargePoint. The prime recipient is LBNL; SolarCity and ChargePoint were partners for the project’s first two years. Increased DER integration introduces a number of challenges in power grid operation including a more dynamic interaction between the transmission grid and distribution grids, and increased modeling complexity. Although specialized software exists to precisely model different components of the power system, it is far from trivial to integrate all various models and perform a holistic simulation. Instead of replicating all models in a common simulation program, a commonly accepted approach to tackle this model diversity is to couple third-party simulators and models through a co-simulation platform that coordinates information exchange among the various components. Following this line of research, this project’s objective was to develop a co-simulation platform based on a widely accepted industrial standard called Functional Mockup Interface (FMI). Within this process, the project developed models compliant with the FMI standard, called Functional Mockup Units (FMUs), and used them to perform various operational and planning power system analyses. Relying and building upon an industrial standard is the main differentiation of this project compared with previous or parallel efforts in the co-simulation area. Particular emphasis was put on delivering software utilities to facilitate setting up and running co-simulations by end-users. Furthermore, a strong aspect of this project is demonstrating that co-simulation techniques can be used to perform Hardware-in-the-Loop (HIL) simulations that couple software components (e.g., simulated models) with hardware components (e.g., real devices such PV systems and batteries). The long-term goal of CyDER project is to help establish FMI as a powerful standard for co-simulation and promote adoption by electric utilities and other interested stakeholders. The main accomplishments of the project include the development of several FMUs including distribution and transmission grid models, PV inverters with Volt/Var/Watt controllers, batteries, and predictive optimal controllers. Additionally, a unique software package was developed, called SimulatorToFMU, which is capable of exporting any Python-driven simulator or Python script as an FMU. This is an important contribution towards establishing FMI as one of the main co-simulation standards, because more and more third-party programs for sub-system modeling and simulation are delivered with Python APIs. The CyDER platform was used to perform PV hosting capacity analyses in real utility feeders with and without smart inverter controls, battery storage, and EV charging. Smart inverter controls include conventional Volt/Var/Watt controls for reactive power support and active power curtailment, but also predictive controls that optimize the charging and discharging profile of the battery connected on the DC side in order to minimize the customer’s economic benefit. Finally, an important result of this project is delivering an experimental setup that consists of residential-scale PV inverters with battery storage, a real-time grid simulator with an ideal voltage source as grid emulator, and micro Phasor Measurement Units (PMUs). All these components and additional software modules are coupled to one another using the FMI standard and can be co-simulated with the CyDER platform.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1978

Gamma-ray line emission above 8 MeV

The spectra of energetic nuclei within astrophysical sources may be determined by studying gamma-ray line emissions above 8 MeV. Excited states which can be produced by inelastic scattering, charge exchange, and spallation reactions in the abundant nuclear species were considered in order to identify nuclear lines which may contribute to the gamma spectrum. The cross sections for production of most high-energy states are sparsely measured. Those which were determined are comparable to the cross section for production of the 15.11 MeV level in C-12 with few exceptions. The branching ratios for gamma-ray and particle emission are, however, better known. Of those states considered, 44 measured branching ratios greater than 40% for emission of a gamma-ray with energy above 8 MeV. For twelve more states the branching ratios, although not yet determined, are expected to be small. The gamma-ray emission from other individual nuclear states is not likely to be as great as that that for the 15.11 MeV state in C-12.

Crannell, C. J.↗
NASA NTRS1978

Solar Gamma Rays Above 8 MeV

Processes which lead to the production of gamma rays with energy greater than 8 MeV in solar flares are reviewed and evaluated. Excited states produced by inelastic scattering, charge exchange, and spallation reactions in the abundant nuclear species are considered in order to identify nuclear lines which may contribute to the Gamma ray spectrum of solar flares. The flux of 15.11 MeV Gamma rays relative to the flux of 4.44 MeV Gamma rays from the de-excitation of the corresponding states in C12 is calculated for a number of assumed distributions of exciting particles. This flux ratio is a sensitive diagnostic of accelerated particle spectra. Other high energy nuclear levels are not so isolated as the 15.11 MeV state and are not expected to be so strong. The spectrum of Gamma rays from the decay of Pi dey is sensitive to the energy distribution of particles accelerated to energies greater than 100 MeV.

Crannell, C. J.↗
NASA NTRS1979

Solar gamma rays above 8 MeV

Processes that lead to the production of gamma rays with energy greater than 8 MeV in solar flares are reviewed and evaluated. Excited states that can be produced by inelastic scattering, charge exchange, and spallation reactions in the abundant nuclear species are considered in order to identify nuclear lines that may contribute to the gamma-ray spectrum of solar flares. The flux of 15.11-MeV gamma rays relative to the flux of 4.44-MeV gamma rays from the deexcitation of the corresponding states in C-12 is calculated for a number of assumed distributions of exciting particles. This flux ratio is shown to be a sensitive diagnostic of accelerated particle spectra. Other high-energy nuclear levels are not so isolated as the 15.11-MeV state and are not expected to be so strong. The spectrum of gamma rays from the decay of neutral pions is shown to be sensitive to the energy distribution of particles accelerated to energies greater than 100 MeV.

Crannell, C. J.↗
NASA NTRS1982

Electric field observations of time constants related to charging and charge neutralization processes in the ionosphere

The Polar 5 electric field results are reviewed, and the transients from Polar 3 are presented. The phenomena are discussed from the standpoint of space charge. On the basis of the Polar 5 results, the large magnitude of the electric field from Polar 3 is seen as indicating that the observed space charge was probably within a few km or less of the payload. Reference is made to Cole's prediction (1960) that charges in the ionosphere would reach equilibrium with a time constant of the order of a few microsec. The processes involved in the two cases presented here require time constants of the order of ms. If the sheath dimensions are taken to be between 50 and 100 m, which is not considered unreasonable in view of the electric field measurements, then a qualitative estimate of the neutralization time would be the transit time for ions across the sheath. Since the kinetic velocity of a 1-eV proton is approximately 14 m/s, it would traverse the distance in 4 to 8 ms, assuming freedom of movement across magnetic field lines. This is the order of the decay times observed on Polar 5.

Maynard, N. C.↗
NASA NTRS1985

Propagation and secondary production of low energy antiprotons in the atmosphere

Current theories, in which the observed antiproton component is attributed strictly to secondary production in high energy inelastic collisions of protons with the interstellar medium or the atmosphere, apparently fail to explain the relatively high p vertical intensities measured at mountain and balloon altitudes. Therefore, a more careful calculation of the theoretical secondary intensity spectra is required before more exotic sources for these excess p's can be explored. A one dimensional diffusion equation is used to calculate the expected vertical intensity of p's due only to secondary production in the atmosphere; any assumed primary p spectrum is also included. Two adjustable parameters, the inelasticity and charge exchange in nucleon-nucleus collisions, were included in the algorithm. In order to obtain an independent estimate of their values the proton vertical intensities in the atmosphere were calculated, adjusting the parameters until the curves fit the experimental proton data, and then assumed that these values were identical in antinucleon-nucleus collisions.

Bowen, T.↗
NASA NTRS1989

Effective amplifier noise for an optical receiver based on linear mode avalanche photodiodes

The rms noise charge induced by the amplifier for an optical receiver based on the linear-mode avalanche photodiode (APD) was analyzed. It is shown that for an amplifier with a 1-pF capacitor and a noise temperature of 100 K, the rms noise charge due to the amplifier is about 300. Since the noise charge must be small compared to the signal gain, APD gains on the order of 1000 will be required to operate the receiver in the linear mode.

Chen, C.-C.↗
NASA NTRS1989

Doppler shifted H Ly alpha emission from Jupiter's aurora

High-spectral-resolution IUE observations of the aurora on Jupiter were obtained in order to search for Doppler shifted H-Ly-alpha emission produced through charge exchange by fast precipitating protons. Although no emission has been observed corresponding to proton energies greater than 200 eV, a large fraction of the H-Ly-alpha emission has appeared Doppler shifted, mainly toward the blue, by about 50 km/s. These results show that the acceleration of ionospheric plasma in an H2 atmosphere can lead to bright Ly-alpha emission, setting constraints on the production of the outer planet airglow emissions.

Clarke, John T.↗
NASA NTRS1989

National Aero-Space Plane technology development overview

The paper discusses the management structure and organization that was developed in early 1986 to focus the national technology resource pool on the enabling technologies for the NASP. The NASP program is developing technologies in parallel with total system studies that are aimed at single stage to orbit (SSTO) capability. In order to manage the technology development seven teams were established by discipline and charged with the task of recommending specific programs to be funded by the NASP Joint Program Office (JPO). The teams were staffed by representatives from NASA Research Centers, Johns Hopkins University, and the Air Force Laboratories at Wright-Patterson AFB. In addition several special teams were established to recommend development programs for specific areas of technical concern that became apparent when the total system studies identified the technology to be critical and sensitive in the analysis that would enable a single stage to orbit vehicle.

Wright, Howard T.↗
NASA NTRS1991

Cross section for production of low-energy electron-positron pairs by relativistic heavy ions

Starting with the lowest-order unscreened QED matrix element for electron-positron pair production by heavy charged particles, the paper calculates the cross section for this process differential in all independent variables and valid for all pair energies small compared to the incident particle energy. Integration over the possible emission angles of one of the pair members gives an expression that is valid for low-energy pairs that can be compared with previous work based on the Weizsaecker-Williams method. Integration over the possible angles of the other pair member then yields an expression identical to one derived by Racah. The high energy-transfer limit of the expression for the cross section integrated over electron and positron angles is found to be identical to that of Kelner in the unscreened case.

Eby, P. B.↗
NASA NTRS2019

Prognostics and Health Monitoring: Application to Electric Vehicles

As more and more electric vehicles emerge in our daily operation progressively, a very critical challenge lies in the prediction of remaining driving-time distance (for cars) or flying time-distance (for aircraft). This information is important, particularly in the case of unmanned vehicles, because such vehicles can become self-aware, autonomously compute its own capabilities, and identify how to best plan and successfully complete vehicular missions safely. In case of electric aircrafts, computing remaining flying time is also safety-critical, since an aircraft that runs out of power (battery charge) while in the air will eventually lose control leading to catastrophe. In order to tackle and solve the prediction problem, it is essential to have awareness of the current state and health of the system, especially since it is necessary to perform condition-based predictions. To be able to predict the future state of the system, it is also required to possess knowledge of the current and future operations of the vehicle.

Electric Vehicles↗
NASA NTRS2020

Prognostics for Systems Health Management - Model and Hybrid Based Approaches. Where are We Heading?

To facilitate and solve the prediction problem, awareness of the current state and health of the system is key, since it is necessary to perform condition-based system health predictions. To accurately predict the future state of any system, it is required to possess knowledge of its current health state and future operational conditional. In case of next generation electric aircrafts, computing remaining flying time is safety-critical, since an aircraft that runs out of power (battery charge) while in the air will eventually lose control leading to catastrophe. In order to tackle and solve the prediction problem, it is essential to have awareness of the current health state of the system, especially since it is necessary to perform condition-based predictions. To be able to predict the future state of the system, it is also required to possess knowledge of the current and future operational conditions and flight profiles for accurate estimation of end-of-discharge (EOD) for the batteries. Similar framework can be implemented to other complex systems and subsystems. Our research approach is to develop a system level health monitoring safety indicator which runs estimation and prediction algorithms to estimate remaining useful life predictions at system, subsystem swell as component levels. Given models of the current and future system behavior, a general approach of model-based prognostics is discussed as a solution to the prediction problem and further for decision making. Data driven prognostics approaches have been equally used with good results in the past, where respective approaches have their own challenges to tackle. This limits their applicability to complex real-world domains: (a) high complexity or incompleteness of physics-based models and (b) limited representativeness of the training dataset for data-driven models. With the advent of internet of things for data collection and increased use of ML algorithms, hybrid approaches are the next avenue to reduce the challenges and achieve better results. An hybrid framework for fusing information from physics-based performance models along with deep learning algorithms for prognostics of complex safety critical systems is presented. In this framework, we use physics-based performance models to infer unobservable model parameters related to the system's components health solving a calibration problem.

Prognostics↗
DOE OSTI2023

Enhancement of charge density wave correlations in a Holstein model with an anharmonic phonon potential

The Holstein Hamiltonian describes itinerant electrons whose site density couples to local phonon degrees of freedom. In the single-site limit, at half filling, the electron-phonon coupling results in a double-well structure for the lattice displacement, favoring empty or doubly occupied sites. In two dimensions and on a bipartite lattice in d ≥ 2, intersite hopping causes these doubly occupied and empty sites to alternate in a charge density wave (CDW) pattern when the temperature is lowered. Because a discrete symmetry is broken, this occurs in a conventional second-order transition at finite T cdw . In this paper, we investigate the effect of changing the phonon potential energy to one with an intrinsic double-well structure even in the absence of electron-phonon coupling. While this aids in the initial process of pair formation, the implications for subsequent CDW order are nontrivial. One expects that, when the electron-phonon coupling is too strong, the double wells become deep and the polaron mass gets large, an effect which reduces T cdw . Here, we show here the existence of regions of parameter space where the double-well potential, while aiding local pair formation, does so in a way which also substantially enhances long-range CDW order.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Magnetic properties of alternating Hubbard ladders

We explore the Hubbard Hamiltonian on ladders where the number of sites per rung alternates between two and three. These geometries are bipartite with nonequal or equal number of sites on the two sublattices. Thus they share a key feature of the Hubbard model in a class of lattices which Lieb has shown analytically to exhibit long-range ferrimagnetic order while being amenable to powerful numeric approaches developed for quasi-one-dimensional geometries. The density matrix renormalization group (DMRG) method is used to obtain the groundstate properties, e.g., excitation gaps, charge and spin densities as well as their correlation functions at half filling. We show the existence of long-range ferrimagnetic order in the one-dimensional ladder geometries. Our work provides detailed quantitative results which complement the general theorem of Lieb for generalized bipartite lattices. It also addresses the issue of how the alternation between quasi-long-range order and spin liquid behavior for uniform ladders with odd and even numbers of legs might be affected by a regular alternation pattern.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗