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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Ceramic problems/challenges in high temperature oxide superconductors - Hysteretic force measurements as a new analysis tool

A technique is presented for analyzing high-temperature oxide superconductors using hysteretic magnetic force/distance measurements. Emphasis is placed on developing low weight, highly robust superconducting materials for space applications. Bi-Ca-Sr-Cu superconductors are prepared and characterized by standard techniques. It is found that standard techniques such as XRD, SEM, and TEM are insufficient to completely characterize superconductors. The magnetic properties of the superconductors are studied with the new technique, based on measuring the force between a magnet and the superconductor as a function of their separation.

Morgan, P. E. D.↗
NASA NTRS1992

Electrochemical characterization of InP structures

Electrochemical (EC) techniques represent a simple and yet accurate method to characterize InP and related materials structures. With EC techniques, uncertainties in the measurements arising from factors such as surface effects, the composition and thickness of a front dead layer, the contacts, etc., can be significantly reduced when both a suitable electrolyte is used and the measuring conditions are carefully selected. In this work, the use of photoelectrochemical techniques with InP structures is reported. The work focuses on both the characterization and the optimization of structures grown by thermal diffusion and by epitaxial methods. Characterization of the structures is done by studying the variation in the density of surface states, number of defects, and net majority carrier concentration as a function of material removed. A step-by-step optimization process of n(sup +)p and p(sup+)n InP structures is also described. This involves the passivation and subsequent removal of damaged layers in order to extract the performance parameters of solar cells fabricated with these structures.

Faur, Maria↗
DOE OSTI2024

Four-dimensional phase-space reconstruction of flat and magnetized beams using neural networks and differentiable simulations

Beams with cross-plane coupling or extreme asymmetries between the two transverse phase spaces are often encountered in particle accelerators. Flat beams with large transverse-emittance ratios are critical for future linear colliders. Similarly, magnetized beams with significant cross-plane coupling are expected to enhance the performance of electron cooling in hadron beams. Preparing these beams requires precise control and characterization of the four-dimensional transverse phase space. In this study, we employ generative phase-space reconstruction techniques to rapidly characterize magnetized and flat-beam phase-space distributions using a conventional quadrupole-scan method. The reconstruction technique is experimentally demonstrated on an electron beam produced at the Argonne Wakefield Accelerator and successfully benchmarked against conventional diagnostics techniques. Specifically, we show that predicted beam parameters from the reconstructed phase-space distributions (e.g., as magnetization and flat-beam emittances) are in excellent agreement with those measured from the conventional diagnostic methods. Published by the American Physical Society 2024

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Characterization of Nanoscale Pores in Tight Gas Sandstones Using Complex Techniques: A Case Study of a Linxing Tight Gas Sandstone Reservoir

Pore structures with rich nanopores and permeability in tight gas reservoirs are poorly understood up to date. Advanced techniques are needed to be employed to accurately characterize pore structures, especially tiny pores which include micron and nanopores. In this study, various experimental techniques such as scanning electron microscopy (SEM), nuclear magnetic resonance (NMR) T 2 , nitrogen adsorption method, and NMR cryoporometry (NMRC) are combined to interrogate the complex pore systems of the tight gas reservoir in the Linxing formation, Ordos Basin, China. Results show that tight gas sandstones are primarily comprised of residual interparticle and clay-dominated pores. Clay and quartz are two dominate minerals while pyrite occupies a nontrivial amount as well. The permeability of tight gas sandstones is very low, exhibiting an extremely poor positive correlation with porosity. While pore types and relative pore contents are more influential factors on the permeability, accurate characterization of pore size distribution is critical for the permeability of tight gas sandstones. Therefore, complementary characterization methods are carried out, indicating that neither small pores with radii < 100 nm (around peak 1 in NMR T 2 distribution) nor large pores with radii > 5 μ m (around peak 3 in NMR T 2 distribution) control the permeability by analyzing the connectivity of the pores in various size ranges, but rather pores averaging approximately 350 ± X nm (around peak 2 in NMR T 2 distribution) have sufficient connectivity to host and transmit hydrocarbons. The pore size of tight gas sandstones is dominated by the clay-rich mineral assemblage. The study shows that the NMRC technique can be a very promising method, especially when referred to as a promising “roadmap” on how to interrogate tight formations such as the tight gas sands or even shale especially for the nanopore characterization.

15 GEOTHERMAL ENERGY↗
NASA NTRS1979

Definition of Mutually Optimum NDI and Proof Test Criteria for 2219 Aluminum Pressure Vessels. Volume 2: Optimization and Fracture Studies

Certain behavioral aspects associated with fracture and crack extension that cannot be studied using other techniques were evaluated with the ultrasonic method. Characterization of collimated beam techniques showed that significant beam width reduction could be accomplished. Techniques for collimation are given. The crack-opening displacement-gage correction-factor study showed that displacement resulting from crack opening and that from plasticity could be readily differentiated. Crack closure studies using both ultrasonic and crack-opening displacement measurements showed an opening and closing behavior associated with load-unload curves. The results of this work were in general agreement with the closure concepts of Elber. Ultrasonic measurements used to study the nature of flaw extension characteristics associated with failure of the ligament between the flaw front and back surface showed that penetration could occur by an abrupt fracturing after subcritical growth or by continuous growth.

Schwartzberg, F. R.↗
NASA NTRS1979

Fabrication and surface characterization of composite refractory compounds suitable for thermionic converters

The techniques of fabricating and characterizing the surface properties of electrode materials were investigated. The basic surface properties of these materials were studied with respect to their utilization as thermionic energy converter electrodes. Emphasis was placed on those factors (e.g, cesium disorption kinetic and mechanisms of low work function production) which are of primary concern to thermionic converter performance.

Davis, P. R.↗
NASA NTRS1980

Quantitative ultrasonic evaluation of engineering properties in metals, composites, and ceramics

Ultrasonic techniques that have demonstrated potential for material characterization are reviewed. These techniques rely on physical acoustic properties of materials and the interaction of elastic stress waves with morphological factors in the ultrasonic regime. The speed of wave propagation and energy loss by interaction with material microstructure and geometrical factors underlie ultrasonic determination of material properties. Two categories of ultrasonic measurements are discussed: those related to material strengths (e.g., elastic moduli, tensile strength, and fracture toughness) and those related to morphology and material conditions that govern strength and performance (e.g., microstructure, void content, residual stress, fatigue damage). It is shown that large-scale industrial application of ultrasonic NDE will depend on advancement in such areas as theory development, instrumentation, system automation, standardization, and coordination with design.

Vary, A.↗
NASA NTRS2015

Nondestructive Evaluation for Aerospace Composites

Nondestructive evaluation (NDE) techniques are important for enabling NASA's missions in space exploration and aeronautics. The expanded and continued use of composite materials for aerospace components and vehicles leads to a need for advanced NDE techniques capable of quantitatively characterizing damage in composites. Quantitative damage detection techniques help to ensure safety, reliability and durability of space and aeronautic vehicles. This presentation will give a broad outline of NASA's range of technical work and an overview of the NDE research performed in the Nondestructive Evaluation Sciences Branch at NASA Langley Research Center. The presentation will focus on ongoing research in the development of NDE techniques for composite materials and structures, including development of automated data processing tools to turn NDE data into quantitative location and sizing results. Composites focused NDE research in the areas of ultrasonics, thermography, X-ray computed tomography, and NDE modeling will be discussed.

Leckey, Cara↗
DOE OSTI2026

Time of Flight Secondary Ion Mass Spectrometry for Characterization of Pt-Coated Porous Transport Layers in PEM Water Electrolyzers

Titanium-based porous transport layers (PTLs) and iridium-based catalyst layers (CLs) are two main components of proton exchange membrane water electrolyzers (PEMWEs). PTLs are typically coated with platinum to minimize interfacial losses and to support long-term operation. Optimizing coatings and the PTL-CL interface requires comprehensive characterization. This study establishes time-of-flight secondary ion mass spectrometry (ToF-SIMS) as a valuable technique for PTL characterization, addressing capabilities and limitations related to PTL morphology. A methodology was developed that uses a Cs + sputter beam for dynamic depth profiling, with data collected in both positive-ion (MCs + ) and negative-ion modes to generate depth profiles, 2D ion maps, and 3D ion reconstructions. ToF-SIMS detected relative differences in platinum-layer thickness between samples; these trends were validated by cross-sectional scanning transmission electron microscope (STEM) measurements and flat-titanium substrate controls. Interfacial oxide layers are identified in both ion modes, with enhanced oxide sensitivity in negative mode. The technique’s high sensitivity enables detection of nanometer-scale coatings and trace impurities within the bulk PTL structure. These results provide a methodological framework for analyzing Pt-coated PTLs, with the potential to extend to other components in PEMWEs and other electrolyzer systems.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Microstructural characterization of nuclear graphite: from the microscale to the nanoscale

Multiple reactor designs use graphite as a moderator of the nuclear reactions and as structural support. During the lifetime of the reactor, multiple aging factors such as neutron irradiation, oxidation, and temperature along with others induce changes in the microstructure and crystal lattice of graphite components. The pore morphology and crystal structure of some phases in graphite can be used to trace the evolution of irradiation defects and mechanical properties of graphite. We present a combination of results from several microscopy techniques to investigate the differences between nuclear graphite grades and the effects of neutron irradiation and oxidation at multiple length scales. This multiscale approach is needed to understand the microstructural variations caused by the raw materials and manufacturing processes as well as how the different phases of graphite are affected by the reactor environment. The results provide insight into the oxidation- and radiation-induced changes of graphite and create a robust baseline of microstructure information that can be used for the selection of materials for the next generation of nuclear power stations. Moreover, the experiments conducted in this work provide an overview of the advantages and limitations of the most common techniques used to characterize nuclear graphite and how these techniques might be applied to study other carbon-based materials used in the nuclear industry.

Arregui Mena, Jose'↗
DOE OSTI2024

Recommendations for improving rigor and reproducibility in site specific characterization

Heterogeneous catalysis is driven by the interaction of reactant molecules and the catalyst surface. The locus of this interaction as well as the surrounding ensemble of atoms is referred to as the catalyst active site. Active site characterization attempts to distinguish active catalytic sites from inactive surface sites, to elucidate the structural and chemical nature of active sites, and to quantify active site concentration. Numerous techniques have been demonstrated to provide compositional and structural information about the active sites within a catalyst. However, each technique has its own limitations and experimental pitfalls that can lead to data misinterpretation or irreproducible results. Further, this work aims to provide an overview of the types of data that can be collected, to outline common experimental challenges and how to avoid them, and to assemble relevant references for the most used active site characterization techniques. More broadly, we aim to outline best practices for researchers to collect, interpret, and report active site characterization data in a way that provides the most benefit to the broader catalysis community. Increasing the rigor and reproducibility of active site characterization offers a strategy to better link properties with catalytic performance and to enable the community to develop consensus concerning these relationships.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2005

Fabrication and Characterization of High Temperature Resin/Carbon Nanofiber Composites

As part of ongoing efforts to develop multifunctional advanced composites, blends of PETI-330 and carbon nanofibers (CNF) were prepared and characterized. Dry mixing techniques were employed and the effect of CNF loading level on melt viscosity was determined. The resulting powders were characterized for degree of mixing, thermal and rheological properties. Based on the characterization results, samples containing 30 and 40 wt% CNF were scaled up to approx.300 g and used to fabricate moldings 10.2 cm x 15.2 cm x 0.32 cm thick. The moldings were fabricated by injecting the mixtures at 260-280 C into a stainless steel tool followed by curing for 1 h at 371 C. The tool was designed to impart high shear during the injection process in an attempt to achieve some alignment of CNFs in the flow direction. Moldings were obtained that were subsequently characterized for thermal, mechanical and electrical properties. The degree of dispersion and alignment of CNFs were investigated using high-resolution scanning electron microscopy. The preparation and preliminary characterization of PETI-330/CNF composites will be discussed.

Ghose, Sayata↗
NASA NTRS2013

The Total Hemispheric Emissivity of Painted Aluminum Honeycomb at Cryogenic Temperatures

NASA uses high-emissivity surfaces on deep-space radiators or thermal radiation absorbers in test chambers. Aluminum honeycomb core material, when coated with a high-emissivity paint, provides a lightweight, mechanically robust, and relatively inexpensive black surface that retains its high emissivity down to low temperatures. At temperatures below about 100 Kelvin, this material performs much better than the paint itself. We measured the total hemispheric emissivity of various painted honeycomb configurations using an adaptation of an innovative technique developed for characterizing thin black coatings. These measurements were performed from room temperature down to 30 Kelvin. We describe the measurement technique and compare the results with predictions from a detailed thermal model of each honeycomb configuration.

Tuttle, J.↗
DOE OSTI2021

Characterization of mechanical deformation in aluminum by optical second harmonic generation

Second harmonic generation (SHG), a laser-based surface technique, was used to characterize near-surface defect evolution associated with mechanical deformation in 2024-T3 aluminum due to tensile loads. Electron backscatter diffraction (EBSD) measurements were also performed to determine the geometrically necessary dislocation density before and after tensile deformation. Comparison of the EBSD and SHG results found that dislocation density and SHG signal are inversely proportional; tensile deformation in the plastic regime led to an increase in dislocation density and a decrease in SHG response. A similar trend was seen in the SHG results on as-received (unpolished) Al samples; SHG response decreases with extent of plastic deformation. Furthermore, this study suggests that SHG has potential as a nondestructive evaluation technique.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Squeeze Film Damper Experimental and Numerical Correlation: Test Setup Description and Parameter Identification of Dry System

The process of characterizing a damper involves both experimental techniques and model simulation. Experiments characterize dynamic behavior of a system through empirical modal analysis using impact and shaker testing. The layout of the test setup is crucial for a low-mass, nonlinear system. Physical arrangement, orientation of the system, and instrumentation affect the results that are discussed in this paper. These results can be used to validate a numerical simulation of the same system. With a validated model, important physical input parameters and modeling techniques can be determined and implemented in future designs. In other words, this modeling can be used with confidence to design alternative dampers that may be difficult, costly, and time-consuming to characterize experimentally.

Cook, Jason↗
DOE OSTI2024

YOLO2U-Net: Detection-guided 3D instance segmentation for microscopy

Microscopy imaging techniques are instrumental for characterization and analysis of biological structures. As these techniques typically render 3D visualization of cells by stacking 2D projections, issues such as out-of-plane excitation and low resolution in the z-axis may pose challenges (even for human experts) to detect individual cells in 3D volumes as these non-overlapping cells may appear as overlapping. In this paper a comprehensive method for accurate 3D instance segmentation of cells in the brain tissue is introduced. The proposed method combines the 2D YOLO detection method with a multi-view fusion algorithm to construct a 3D localization of the cells. Next, the 3D bounding boxes along with the data volume are input to a 3D U-Net network that is designed to segment the primary cell in each 3D bounding box, and in turn, to carry out instance segmentation of cells in the entire volume. The promising performance of the proposed method is shown in comparison with current deep learning-based 3D instance segmentation methods.

3D instance segmentation↗
DOE OSTI2022

Applying Waveform Correlation and Waveform Template Metadata to Aftershocks in the Middle East to Reduce Analyst Workload

Organizations that monitor for underground nuclear explosive tests are interested in techniques that automatically characterize recurring events such as aftershocks to reduce the human analyst effort required to produce high-quality event bulletins. Waveform correlation is a technique that is effective in finding similar waveforms from repeating seismic events. In this study, we apply waveform correlation in combination with template event metadata to two aftershock sequences in the Middle East to seek corroborating detections from multiple stations in the International Monitoring System of the Preparatory Commission for the Comprehensive Nuclear-Test-Ban Treaty Organization. We use waveform templates from stations that are within regional distance of aftershock sequences to detect subsequent events, then use template event metadata to discover what stations are likely to record corroborating arrival waveforms for recurring aftershock events at the same location, and develop additional waveform templates to seek corroborating detections. We evaluate the results with the goal of determining whether applying the method to aftershock events will improve the choice of waveform correlation detections that lead to bulletin-worthy events and reduction of analyst effort.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2025

Detecting rare earth elements via optically detected magnetic resonance (ODMR) and spin-relaxometry using nitrogen vacancy centers in nanodiamonds

Nanodiamonds embedded with nitrogen-vacancy (NV) centers are emerging as powerful tools in quantum sensing due to their remarkable sensitivity to local variations in electromagnetic fields, temperature, and pressure. These point defects in the diamond lattice can be probed using optically detected magnetic resonance (ODMR) and spin relaxometry techniques, allowing for the detection and characterization of magnetic nanoparticles and ions. The sensing mechanism relies on laser-induced excitation of the NV center's non-degenerate triplet ground state, which promotes electrons to an excited state. Subsequent photoluminescence (PL) emission, which is spin-state dependent, is then measured. These spin states are highly responsive to magnetic perturbations in the surrounding environment. By analyzing changes in the ODMR spectra and spin relaxation times, we can effectively monitor how magnetic species influence the NV center's spin dynamics, thus enabling sensitive and selective characterization of nanoscale magnetic materials. These techniques have been applied for the characterization of transition metals and rare earth elements which shows natural ferromagnetic properties.

magnetic nanopartgicles and ions↗