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Ultra-fast and sensitive magneto-optical hydrogen sensors using a magnetic nano-cap array

Magnetism in curved nano-geometries has opened a new path to design novel characteristics and phenomena that could greatly impact the future fundamental and applied studies of materials. Here, in this report, a hexagonally-packed array of magnetic nano-caps (or nano-patches, NP) exhibiting unique magnetic anisotropy and optimal nanostructure for fast hydrogen kinetics is explored as a sensing element for the spark-free magnetic-circular-dichroism (MCD) H 2 sensor. The MCD H 2 sensor outperforms the state-of-the-art optical sensors reported to date and satisfies the most challenging performance targets imposed by US Department of Energy. In particular, a Pd 67 Co 33 NP sensor exhibits response time of t 90 < 0.9 s, recovery time of t 10 < 9.0 s over the 1-100 mbar H 2 partial pressure range, and limit of detection (LOD) of ~1 ppm. The LOD improves to <700 ppb, when the signal-to-noise ratio is enhanced by stacking three NP arrays. Using a 30-nm TAF (Teflon AF 2400) polymer coating, the sorption kinetics of the Pd 67 Co 33 /TAF sensor are significantly accelerated, with t 90 < 0.4 s and t 10 < 2.8 s over the same pressure range. When the Pd 67 Co 33 /TAF sensor is further coated with a 100-nm poly(methyl methacrylate) (PMMA) layer, a rapid sorption time of t 90 < 0.5 s, LOD < 1 ppm and excellent sensor accuracy (<2.5% full scale) are maintained, while the sensor obtains strong selectivity against interference gases and moisture and a negligible aging effect. The MCD nano-cap sensor platform may have a great impact on the future deployment of H 2 fuel, H 2 environmental monitoring sensors, and fast proton-based magneto-ionic devices.

Fast and sensitive hydrogen sensors↗

New Evaporator Station for the Center for Accelerator Target Science

As part of an equipment grant provided by DOE-NP for the Center for Accelerator Target Science (CATS) initiative, the procurement of a new, electron beam, high-vacuum deposition system was identified as a priority to insure reliable and continued availability of high-purity targets. The apparatus is designed to contain TWO electron beam guns; a standard 4-pocket 270° geometry source as well as an electron bombardment source. The acquisition of this new system allows for the replacement of TWO outdated and aging vacuum evaporators. Also included is an additional thermal boat source, enhancing our capability within this deposition unit. Recommended specifications for this system included an automated, high-vacuum pumping station, a deposition chamber with a rotating and heated substrate holder for uniform coating capabilities and incorporating computer-controlled state-of-the-art thin film technologies. Design specifications, enhanced capabilities and the necessary mechanical modifications for our target work are discussed.

Greene, John P.↗

The First United States Microgravity Laboratory

The United States Microgravity Laboratory (USML-1) is one part of a science and technology program that will open NASA's next great era of discovery and establish the United States' leadership in space. A key component in the preparation for this new age of exploration, the USML-1 will fly in orbit for extended periods, providing greater opportunities for research in materials science, fluid dynamics, biotechnology, and combustion science. The major components of the USML-1 are the Crystal Growth Furnace, the Surface Tension Driven Convection Experiment (STDCE) Apparatus, and the Drop Physics Module. Other components of USML-1 include Astroculture, Generic Bioprocessing Apparatus, Extended Duration Orbiter Medical Project, Protein Crystal Growth, Space Acceleration Measurement System, Solid Surface Combustion Experiment, Zeolite Crystal Growth and Spacelab Glovebox provided by the European Space Agency.

Powers, C. Blake↗

The Supernova Remnant CTA 1

The supernova remnants G327.1-1.1 and G327.4+0.4 (Kes 27) are located 1.5 deg apart in the constellation Norma. In 1980, Einstein IPC observations discovered that both were irregular filled-center X-ray sources with possible point sources superposed. This paper describes new ROSAT position sensitive proportional counter (PSPC) observations which both map the diffuse structure and clearly show several unresolved sources in each field. Both remnants have bright emitting regions inside the limb which might indicate the presence of high energy electrons accelerated by a pulsar. The interior region is more prominent in G327.1-1.1 than in Kes 27. The spectra are relatively strongly absorbed, as expected from distant remnants close to the galactic plane. Comparison of the X-ray and radio maps of each remnant allows us to attribute some emission to a shell and some to the interior. With this information, a blast-wave model is used to derive approximate ages and energy release. Indications are that the Kes 27 supernova deposited approximately 10(exp 51) ergs in the surrounding medium. The G327.1-1.1 event probably deposited a factor of 3-10 less.

Seward, Frederick D.↗

The Ambivalent Role of Participants in Nuclear Waste Decisions - 16360

Today's global nuclear sector has entered a critical juncture. Waste management solutions have the potential to influence the prospects of whether new plants will be built and when aging plants will be decommissioned. Even in countries without nuclear power plants, the siting of nuclear waste can present communication challenges and opportunities for public involvement. As new nuclear programs withstand scrutiny, local communities share their want for solutions to nuclear waste before new plant construction commences. Developing nations have begun to explore the potential of adding nuclear power production to their energy mix. They carefully watch established nuclear players to accelerate their plans with lessons learned elsewhere. Some newcomers to nuclear energy will make decisions on new construction based on other operators' abilities to reconcile public concerns regarding radioactive waste. Distinct forms of government, cultural norms and means of public discourse present innovative approaches and changing expectations worldwide. This paper explores how practitioners are evaluating ways to activate stakeholders on nuclear waste siting in nations embarking on new nuclear programs. It investigates the incentives that people have to participate and legitimize the formation of laws, regulations and standards for nuclear materials management. Finally, it highlights examples of public participation techniques from established operating environments and posits that overly prescriptive requirements for stakeholder engagement can reduce the authenticity of public involvement and weaken confidence among participants in the decision making process. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Composition and persistence of soil organic matter along eroding and depositional transects in buried vs. modern soil layers: A case of the Brady paleosol at Wauneta, Nebraska

Paleosols form when soils are buried through deposition by aeolian, colluvial, alluvial or other processes. Burial of former topsoil isolates soil organic matter (SOM) from surface conditions, allowing carbon to accumulate and potentially remain stable for millennia. In this study, SOM composition, distribution, and persistence were analyzed in the Brady Soil of Nebraska, USA to compare SOM spatial variability in modern and buried soils, as well as the impact of erosional exposure on SOM stability. The Brady Soil, formed as a surface soil during the Pleistocene-Holocene transition and now a paleosol buried up to 6 m deep (or more) by loess deposition during the Holocene, was sampled along burial (up to 5.8 m depth) and erosional (up to 1.8 m depth) transects to compare SOM dynamics in different geomorphic settings. Fourier Transform Infrared Spectroscopy (FTIR) and Fourier Transform ion cyclotron resonance mass spectrometry (FTICR-MS) were used to analyze SOM composition, while δ 13 C isotope analyses identified SOM sources and radiocarbon values were used to estimate turnover rates. Results confirmed a vegetation shift from C3 to C4 plants after Brady Soil formation, reflecting warming climatic conditions. Increasing SOM age and decreasing δ 13 C and δ 15 N values with depth indicated slowing of decomposition rate in buried soils. Higher pH in the Brady Soil suggested greater base cation content, supporting SOM stabilization through organo-mineral associations and aggregate formation. However, exposure of the Brady Soil due to surface erosion caused faster SOM turnover. This result suggested susceptibility of buried SOM to losses via decomposition upon erosional exposure, possibly accelerated by priming in response to modern SOM inputs. These findings highlight the potential loss of carbon stocks in buried soils under future climate change, as shifts in soil physicochemical properties may destabilize long-preserved SOM.

Environmental sciences↗

Cosmic ray electrons of E greater than 1 Gev - Some new measurements and interpretations.

In the summer of 1971 new measurements were made of the primary electron spectrum from 1 to 20 GeV with an electron spectrometer telescope at Fort Churchill. This telescope has been calibrated by using electrons and pions of 0.5 to 15 GeV at the Stanford Linear Accelerator in early 1971 and again in 1972. The calibration results suggest that the events observed are due to interactions of high-energy protons. The measured primary electron spectrum is uncomfortably close to that calculated for secondary electrons produced by the interaction of cosmic ray nuclei with interstellar hydrogen in the Galaxy, and therefore the question of the origin of the high-energy electrons is reopened. The problem of the age of cosmic ray electrons must also be reexamined if the measured spectrum is found to extend to still higher energies.

Webber, W. R.↗

Gravity anomalies, compensation mechanisms, and the geodynamics of western Ishtar Terra, Venus

Pioneer Venus line-of-sight orbital accelerations were utilized to calculate the geoid and vertical gravity anomalies for western Ishtar Terra on various planes of altitude z sub 0. The apparent depth of isostatic compensation at z sub 0 = 1400 km is 180 + or - 20 km based on the usual method of minimum variance in the isostatic anomaly. An attempt is made here to explain this observation, as well as the regional elevation, peripheral mountain belts, and inferred age of western Ishtar Terra, in terms of one or three broad geodynamic models.

Grimm, Robert E.↗

Computational Design of Batteries from Materials to Systems

Computer models are helping to accelerate the design and validation of next generation batteries and provide valuable insights not possible through experimental testing alone. Validated 3-D physics-based models exist for predicting electrochemical performance, thermal and mechanical response of cells and packs under normal and abuse scenarios. The talk describes present efforts to make the models better suited for engineering design, including improving their computation speed, developing faster processes for model parameter identification including under aging, and predicting the performance of a proposed electrode material recipe a priori using microstructure models.

25 ENERGY STORAGE↗

MAPPING THE CENTRAL REGION OF THE PPN CRL 618 AT SUBARCSECOND RESOLUTION AT 350 GHz

CRL 618 is a well-studied pre-planetary nebula. We have mapped its central region in continuum and molecular lines with the Submillimeter Array at 350 GHz at {approx}0.''3-0.''5 resolutions. Two components are seen in the 350 GHz continuum: (1) a compact emission at the center tracing the dense inner part of the H II region previously detected in a 23 GHz continuum and it may trace a fast ionized wind at the base; and (2) an extended thermal dust emission surrounding the H II region, tracing the dense core previously detected in HC{sub 3}N at the center of the circumstellar envelope. The dense core is dusty and may contain millimeter-sized dust grains. It may have a density enhancement in the equatorial plane. It is also detected in carbon chain molecules HC{sub 3}N and HCN and their isotopologues, with higher excitation lines tracing closer to the central star. It is also detected in CH{sub 2}CHCN toward the innermost part. Most of the emission detected here arises within {approx}630 AU (0.''7) of the central star. A simple radiative transfer model is used to derive the kinematics, physical conditions, and the chemical abundances in the dense core. The dense core is expanding and accelerating, with the velocity increasing roughly linearly from {approx}3 km s{sup -1} in the innermost part to {approx}16 km s{sup -1} at 630 AU. The mass-loss rate in the dense core is extremely high with a value of {approx}1.15 Multiplication-Sign 10{sup -3} M{sub Sun} yr{sup -1}. The dense core has a mass of {approx}0.47 M{sub Sun} and a dynamical age of {approx}400 yr. It could result from a recent enhanced heavy mass-loss episode that ends the asymptotic giant branch phase. The isotopic ratios of {sup 12}C/{sup 13}C and {sup 14}N/{sup 15}N are 9 {+-} 4 and 150 {+-} 50, respectively, both lower than the solar values.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Adaptation of the Skeletal System during Long-duration Spaceflight

This review will highlight evidence from crew members flown on space missions greater than 90 days to suggest that the adaptations of the skeletal system to mechanical unloading may predispose crew members to an accelerated onset of osteoporosis after return to Earth. By definition, osteoporosis is a skeletal disorder - characterized by low bone mineral density and structural deterioration - that reduces the ability of bones to resist fracture under the loading of normal daily activities. Involutional or agerelated osteoporosis is readily recognized as a syndrome afflicting the elderly population because of the insipid and asymptomatic nature of bone loss that does not typically manifest as fractures until after age approximately 60. It is not the thesis of this review to suggest that spaceflight-induced bone loss is similar to bone loss induced by metabolic bone disease; rather this review draws parallels between the rapid and earlier loss in females that occurs with menopause and the rapid bone loss in middle-aged crew members that occurs with spaceflight unloading and how the cumulative effects of spaceflight and ageing could be detrimental, particularly if skeletal effects are totally or partially irreversible. In brief, this report will provide detailed evidence that long-duration crew members, exposed to the weightlessness of space for the typical long-duration (4-6 months) mission on Mir or the International Space Station -- 1. Display bone resorption that is aggressive, that targets normally weight-bearing skeletal sites, that is uncoupled to bone formation and that results in areal BMD deficits that can range between 6-20% of preflight BMD; 2. Display compartment-specific declines in volumetric BMD in the proximal femur (a skeletal site of clinical interest) that significantly reduces its compressive and bending strength and which may account for the loss in hip bone strength (i.e., force to failure); 3. Recover BMD over a post-flight time period that exceeds spaceflight exposure but for which the restoration of whole bone strength remains an open issue and may involve structural alteration; and 4. Display risk factors for bone loss -- such as the negative calcium balance and down-regulated calcium-regulating hormones in response to bone atrophy -- that can be compounded by the constraints of conducting mission operations (inability to provide essential nutrients and vitamins). The full characterization of the skeletal response to mechanical unloading in space is not complete. In particular, countermeasures used to date have been inadequate and it is not yet known whether more appropriate countermeasures can prevent the changes in bone that have been found in previous flights, knowledge gaps related to the effects of prolonged (greater than or equal to 6 months) space exposure and to partial gravity environments are substantial, and longitudinal measurements on crew members after spaceflight are required to assess the full impact on skeletal recovery.

Sibonga, Jean D.↗

The Saturn System Through the Eyes of Cassini

More than 400 years ago, Galileo Galilei trained his homemade telescope on the night sky and observed that Saturn had two objects closely related to the planet extending on either side. At the time, in 1610, Galileo declared them to be moons. A few decades later, Saturn moon science accelerated at a dizzying pace. Christiaan Huygens first observed Saturn's largest moon Titan in 1655 and was the first to describe the extended moon-like features at Saturn as a disk of material sounding the planet. From 1671 to 1674, Giovanni Cassini discovered the moons lapetus, Rhea, Dione and Tethys. In 1675, Cassini discovered the gap in Saturn's rings that we now know as the Cassini Division. In the space age, before the Cassini-Huygens mission, we had only hints of the discoveries awaiting us at Saturn. Pioneer 11 and Voyagers 1 and 2 conducted flybys decades ago. But these quick encounters didn't allow time for more extensive research. NASA and the European Space Agency created a partnership to orbit a Saturn orbiter (Cassini) and a lander (Huygens) on Titan. Like its namesakes, the Cassini-Huygens mission not only discovered previously unknown moons, but it also helped us understand the science behind their formation, their interactions with the rings, and how truly diverse they are. The Cassini-Huygens mission revolutionized what we know about the Saturn system. The rings of Saturn, the moons, and the planet itself offer irresistible and inexhaustible subjects for intense study, and Cassini-Huygens did not disappoint. The Saturnian system proved to be a rich ground for science exploration and discoveries, and Cassini has been nothing short of a discovery machine. At the time Cassini plunged into Saturn at the end of its mission, it had observed the planet for a little less than half of a Saturn year. But it also orbited the gas giant 293 times, forever changing our understanding of the Saturn system and yielding tremendous insight for understanding the entire Solar System.

Green, James↗

Motion Sickness and Concerns for Urban Air Mobility Vehicles: A Literature Review

Motion sickness is a general term for a constellation of signs and symptoms, generally due to exposure to abrupt, periodic, or unnatural accelerations, especially when traveling in a vehicle. Motion sickness results from a mismatch of the visual and nonvisual (vestibular and kinesthetic) information, the observed scene and the motion felt or lack of it. Motion sickness onset is associated with a pattern of physiological changes in heart rate, peripheral blood flow, respiration, and skin conductance and the pattern is repeatable for a particular subject but variable between subjects. Demographic factors such as gender and age that affect motion sickness are well known with children, women, and older adults more likely to be susceptible. Often motion sickness is assessed and quantified using variations of the motion sickness susceptibility questionnaires including the Pensacola Diagnostic Rating Scale and the Simulator Sickness Questionnaire. Even though symptoms are easily identified by such questionnaires, they commonly are subjective. Tools such as these questionnaires for screening individuals susceptible to motion sickness are useful, however, they are only mildly predictive. Moreover, models for predicting motion sickness, which have largely been developed for sea sickness, do not consider task characteristics. Predictions of motion sickness rates and prevalence for Urban Air Mobility (UAM) vehicles are not possible at present because data from actual flight or full-fidelity simulation are simply not yet available. Extrapolation from other modes of transportation (i.e., automobiles, buses, trains, boats, other types of aircraft) is difficult because of differences in the motion stimulus experienced, trip duration, and other factors. How UAM vehicles will change the social dynamics of passenger interaction and vehicle interior design changes (e.g., seat orientations) is unknown. Should motion sickness prove to be an issue, vehicle design modifications such as having passengers face forward, providing additional seat recline, giving each person their own climate control for airflow, perhaps ensuring the horizon is visible to all passengers (reducing visual occlusion by the headrest) and visually stabilizing displays on carry-on devices (smart phones, tablets, etc.) may benefit passengers. Several commercial companies provide wearable devices for physiological monitoring that have been validated and are suitable for use with passengers in UAM vehicles or high-fidelity simulators. Potential countermeasures for motion sickness include user-worn devices, anti-motion sickness medications, and non-pharmacological approaches such as biofeedback and Autogenic Feedback Training Exercise. Both simulator and in-vehicle UAM research is needed to evaluate the effectiveness of any potential countermeasure.

motion sickness↗

Probing Particle Diffusion around Two Nearby Pulsars with TeV Gamma-Ray Observations from HAWC

Nearby cosmic-ray accelerators, especially pulsar wind nebulae, are possible origins of the local multi-GeV positron excess. Pulsar Geminga and B0656+14, less than 300 pc from the Earth, have been postulated as the main sources of the positron excess. With one and half years of data, the HAWC gamma-ray observatory discovered very extended TeV gamma-ray structures produced from high-energy electrons and positrons around these two nearby middle-aged pulsars. Morphology studies suggest that the diffusion in the vicinity of these two pulsars is 100 times slower than the average in our Galaxy. This result provides important constraints on the origin of positron excess, but raises questions like why diffusion is so slow at high energies near these pulsars. With more than twice of data from the previous results, we now explore the possibility of energy-dependent diffusion at these sources.

79 ASTRONOMY AND ASTROPHYSICS↗

The Age of Precision Cosmology

In the past two decades, our understanding of the evolution and fate of the universe has increased dramatically. This "Age of Precision Cosmology" has been ushered in by measurements that have both elucidated the details of the Big Bang cosmology and set the direction for future lines of inquiry. Our universe appears to consist of 5% baryonic matter; 23% of the universe's energy content is dark matter which is responsible for the observed structure in the universe; and 72% of the energy density is so-called "dark energy" that is currently accelerating the expansion of the universe. In addition, our universe has been measured to be geometrically flat to 1 %. These observations and related details of the Big Bang paradigm have hinted that the universe underwent an epoch of accelerated expansion known as Uinflation" early in its history. In this talk, I will review the highlights of modern cosmology, focusing on the contributions made by measurements of the cosmic microwave background, the faint afterglow of the Big Bang. I will also describe new instruments designed to measure the polarization of the cosmic microwave background in order to search for evidence of cosmic inflation.

Chuss, David T.↗

The Early Universe: Searching for Evidence of Cosmic Inflation

In the past two decades, our understanding of the evolution and fate of the universe has increased dramatically. This "Age of Precision Cosmology" has been ushered in by measurements that have both elucidated the details of the Big Bang cosmology and set the direction for future lines of inquiry. Our universe appears to consist of 5% baryonic matter; 23% of the universe's energy content is dark matter which is responsible for the observed structure in the universe; and 72% of the energy density is so-called "dark energy" that is currently accelerating the expansion of the universe. In addition, our universe has been measured to be geometrically flat to 1 %. These observations and related details of the Big Bang paradigm have hinted that the universe underwent an epoch of accelerated expansion known as "inflation" early in its history. In this talk, I will review the highlights of modern cosmology, focusing on the contributions made by measurements of the cosmic microwave background, the faint afterglow of the Big Bang. I will also describe new instruments designed to measure the polarization of the cosmic microwave background in order to search for evidence of cosmic inflation.

Chuss, David T.↗

Patterns of Local Recurrence and Dose Fractionation of Adjuvant Radiation Therapy in 462 Patients With Soft Tissue Sarcoma of Extremity and Trunk Wall

Purpose: To study the impact of dose fractionation of adjuvant radiation therapy (RT) on local recurrence (LR) and the relation of LR to radiation fields. Methods and Materials: LR rates were analyzed in 462 adult patients with soft tissue sarcoma who underwent surgical excision and adjuvant RT at five Scandinavian sarcoma centers from 1998 to 2009. Medical records were reviewed for dose fractionation parameters and to determine the location of the LR relative to the radiation portals. Results: Fifty-five of 462 patients developed a LR (11.9%). Negative prognostic factors included intralesional surgical margin (hazard ratio [HR]: 7.83, 95% confidence interval [CI]: 3.08-20.0), high malignancy grade (HR: 5.82, 95% CI: 1.31-25.8), age at diagnosis (HR per 10 years: 1.27, 95% CI: 1.03-1.56), and malignant peripheral nerve sheath tumor histological subtype (HR: 6.66, 95% CI: 2.56-17.3). RT dose was tailored to margin status. No correlation between RT dose and LR rate was found in multiple Cox regression analysis. The majority (65%) of LRs occurred within the primary RT volume. Conclusions: No significant dose–response effect of adjuvant RT was demonstrated. Interestingly, patients given 45-Gy accelerated RT (1.8 Gy twice daily/2.5 weeks) had the best local outcome. A total dose of 50 Gy in 25 fractions seemed adequate following wide margin surgery. The risk of LR was associated with histopathologic subtype, which should be included in the treatment algorithm of adjuvant RT in soft tissue sarcoma.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

THE DYNAMICAL MASS AND THREE-DIMENSIONAL ORBIT OF HR7672B: A BENCHMARK BROWN DWARF WITH HIGH ECCENTRICITY

The companion to the G0V star HR7672 directly imaged by Liu et al. has moved measurably along its orbit since the discovery epoch, making it possible to determine its dynamical properties. Originally targeted with adaptive optics because it showed a long-term radial velocity (RV) acceleration (trend), we have monitored this star with precise Doppler measurements and have now established a 24 year time baseline. The RV variations show significant curvature (change in the acceleration) including an inflection point. We have also obtained a recent image of HR7672B with NIRC2 at Keck. The astrometry also shows curvature. In this paper, we use jointly fitted Doppler and astrometric models to calculate the three-dimensional orbit and dynamical mass of the companion. The mass of the host star is determined using a direct radius measurement from CHARA interferometry in combination with high-resolution spectroscopic modeling. We find that HR7672B has a highly eccentric, e = 0.50{sup +0.01}{sub -0.01}, near edge-on, i = 97.3{sup +0.4}{sub -0.5} deg, orbit with semimajor axis, a = 18.3{sup +0.4}{sub -0.5} AU. The mass of the companion is m = 68.7{sup +2.4}{sub -3.1} M{sub J} . HR7672B thus resides near the substellar boundary, just below the hydrogen-fusing limit. These measurements of the companion mass are independent of its brightness and spectrum and establish HR7672B as a rare and precious 'benchmark' brown dwarf with a well-determined mass, age, and metallicity essential for testing theoretical evolutionary models and synthetic spectral models. Indeed, we find that such models under-predict its luminosity by a factor of Almost-Equal-To 2. HR 7672B is presently the only L, T, or Y dwarf known to produce an RV trend around a solar-type star.

79 ASTRONOMY AND ASTROPHYSICS↗