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At least 1,081 records · Page 60

Phosphors for near UV-Emitting LED's for Efficacious Generation of White Light

1) We studied phosphors for near-UV (nUV) LED application as an alternative to blue LEDs currently being used in SSL systems. We have shown that nUV light sources could be very efficient at high current and will have significantly less binning at both the chip and phosphor levels. We identified phosphor blends that could yield 4100K lamps with a CRI of approximately 80 and LPWnUV,opt equal to 179 for the best performing phosphor blend. Considering the fact that the lamps were not optimized for light coupling, the results are quite impressive. The main bottleneck is an optimum blue phosphor with a peak near 440 nm with a full width half maximum of about 25 nm and a quantum efficiency of >95%. Unfortunately, that may be a very difficult task when we want to excite a phosphor at ~400 nm with a very small margin for Stokes shift. Another way is to have all the phosphors in the blend having the excitation peak at 400 nm or slightly shorter wavelength. This could lead to a white light source with no body color and optimum efficacy due to no self-absorption effects by phosphors in the blend. This is even harder than finding an ideal blue phosphor, but not necessarily impossible. 2) With the phosphor blends identified, light sources using nUV LEDs at high current could be designed with comparable efficacy to those using blue LEDs. It will allow us to design light sources with multiple wattages using the same chips and phosphor blends simply by varying the input current. In the case of blue LEDs, this is not currently possible because varying the current will lower the efficacy at high current and alter the color point. With improvement of phosphor blends, control over CRI could improve. Less binning at the chip level and also at the phosphor blend level could reduce the cost of SSL light sources. 3) This study provided a deeper understanding of phosphor characteristics needed for LEDs in general and nUV LEDs in particular. Two students received Ph.D. degrees and three undergraduates participated in this work. Two of the undergraduate students are now in graduate school. The results were widely disseminated – 20 archival journal publications (published, accepted or in preparation) and three conference proceedings resulted. The students presented their work at 11 different national/international conferences (32 oral or poster presentations) and the PI’s delivered 12 invited, keynote or plenary lectures.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

White Paper on the Use of Team Calendars with the JIRA Issue Tracking System and Confluence Collaboration Tools for the xLPR Project

ORNL was tasked by xLPR project management to propose a team calendar for use within the xLPR consortium. Among various options that were considered, the approach judged by ORNL to best fit the needs of the xLPR project is presented in this document. The Atlassian Team Calendars plug-in used with the Confluence collaboration tool was recommended for several reasons, including the advantage that it provides for a tight integration between Confluence (found at https://xlpr.ornl.gov/wiki ) and xLPR s JIRA issue tracking system (found at https://xlpr.ornl.gov/jira ). This document is divided into two parts. The first part (Sections 1-6) consists of the white paper, which highlights some of the ways that Team Calendars can improve com mun ication between xLPR project managers, group leads, and team members when JIRA is applied for both issue tracking and change-management activities. Specific points emphasized herein are as follows: The Team Calendar application greatly enhances the added value that the JIRA and Confluence tools bring to the xLPR Project. The Team Calendar can improve com mun ication between xLPR project managers, group leads, and team members when JIRA is applied for both issue tracking and change-management activities. The Team Calendar works across different email tools such as Outlook 2011, Outlook 2010, Outlook 2007, Google Calendars and Mac s iCalendar to name a few. xLPR users can now access the wiki Confluence (with embedded Team Calendars) directly from JIRA without having to re-validate their login. The second part consists of an Annex (Section 7), which describes how users can subscribe to Team Calendars from different calendar applications. Specific instructions are given in the Annex that describe how to Import xLPR Team Calendar to Outlook Version Office 2010 Import xLPR Team Calendar to Outlook Version Office 2007 Subscribe to Team Calendar from Google Calendar The reader is directed to Section 4 for instructions on adding events to the Team Calendar or accessing ORNL staff for assistance with such additions. To seek help with your questions and problems regarding the content of this document, please contact Hilda Klasky at klaskyhb@ornl.gov

97 MATHEMATICS AND COMPUTING↗

Feral Cattle in the White Rock Canyon Reserve at Los Alamos National Laboratory

At the request of the Los Alamos Field Office (the Field Office), Los Alamos National Security (LANS) biologists placed remote-triggered wildlife cameras in and around the mouth of Ancho Canyon in the White Rock Canyon Reserve (the Reserve) to monitor use by feral cattle. The cameras were placed in October 2012 and retrieved in January 2013. Two cameras were placed upstream in Ancho Canyon away from the Rio Grande along the perennial flows from Ancho Springs, two cameras were placed at the north side of the mouth to Ancho Canyon along the Rio Grande, and two cameras were placed at the south side of the mouth to Ancho Canyon along the Rio Grande. The cameras recorded three different individual feral cows using this area as well as a variety of local native wildlife. This report details our results and issues associated with feral cattle in the Reserve. Feral cattle pose significant risks to human safety, impact cultural and biological resources, and affect the environmental integrity of the Reserve. Regional stakeholders have communicated to the Field Office that they support feral cattle removal.

54 ENVIRONMENTAL SCIENCES↗

Development and Utilization of Host Materials for White Phosphorescent Organic Light-Emitting Diodes

Our project was primarily focused on the MYPP 2015 goal for white phosphorescent organic devices (PhOLEDs or phosphorescent organic light-emitting diodes) for solid-state lighting with long lifetimes and high efficiencies. Our central activity was to synthesize and evaluate a new class of host materials for blue phosphors in the PhOLEDs, known to be a weak link in the device operating lifetime. The work was a collaborative effort between three groups, one primarily responsible for chemical design and characterization (Chen), one primarily responsible for device development (Tang) and one primarily responsible for mechanistic studies and degradation analysis (Rothberg). The host materials were designed with a novel architecture that chemically links groups with good ability to move electrons with those having good ability to move “holes” (positive charges), the main premise being that we could suppress the instability associated with physical separation and crystallization of the electron conducting and hole conducting materials that might cause the devices to fail. We found that these materials do prevent crystallization and that this will increase device lifetimes but that efficiencies were reduced substantially due to interactions between the materials creating new low energy “charge transfer” states that are non-luminescent. Therefore, while our proposed strategy could in principle improve device lifetimes, we were unable to find a materials combination where the efficiency was not substantially compromised.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

AVTA Federal Fleet PEV Readiness Data Logging and Characterization Study for NASA White Sands Test Facility

This report focuses on the NASA White Sands Test Facility (WSTF) fleet to identify daily operational characteristics of select vehicles and report findings on vehicle and mission characterizations to support the successful introduction of plug-in electric vehicles (PEVs) into the agencies’ fleets. Individual observations of these selected vehicles provide the basis for recommendations related to electric vehicle adoption and whether a battery electric vehicle (BEV) or plug-in hybrid electric vehicle (PHEV) (collectively plug-in electric vehicles, or PEVs) can fulfill the mission requirements.

33 ADVANCED PROPULSION SYSTEMS↗

Integrated Modeling and Decision-Support System for Water Management in the Puget Sound Basin: Snow Caps to White Caps

Final Report for the EPA-sponsored project Snow Caps to White Caps that provides data products and insight for water resource managers to support their predictions and management actions to address future changes in water resources (fresh and marine) in the Puget Sound basin. This report details the efforts of a team of scientists and engineers from Pacific Northwest National Laboratory (PNNL) and the University of Washington (UW) to examine the movement of water in the Snohomish Basin, within the watershed and the estuary, under present and future conditions, using a set of linked numerical models.

54 ENVIRONMENTAL SCIENCES↗

White Paper Summary of 2nd ASTM International Workshop on Hydrides in Zirconium Alloy Cladding

This white paper recommends that ASTM International develop standards to address the potential impact of hydrides on the long term performance of irradiated zirconium alloys. The need for such standards was apparent during the 2nd ASTM International Workshop on Hydrides in Zirconium Alloy Cladding and Assembly Components, sponsored by ASTM International Committee C26.13 and held on June 10-12, 2014, in Jackson, Wyoming. The potentially adverse impacts of hydrogen and hydrides on the long term performance of irradiated zirconium-alloy cladding on used fuel were shown to depend on multiple factors such as alloy chemistry and processing, irradiation and post irradiation history, residual and applied stresses and stress states, and the service environment. These factors determine the hydrogen content and hydride morphology in the alloy, which, in turn, influence the response of the alloy to the thermo-mechanical conditions imposed (and anticipated) during storage, transport and disposal of used nuclear fuel. Workshop presentations and discussions showed that although hydrogen/hydride induced degradation of zirconium alloys may be of concern, the potential for occurrence and the extent of anticipated degradation vary throughout the nuclear industry because of the variations in hydrogen content, hydride morphology, alloy chemistry and irradiation conditions. The tools and techniques used to characterize hydrides and hydride morphologies and their impacts on material performance also vary. Such variations make site-to-site comparisons of test results and observations difficult. There is no consensus that a single material or system characteristic (e.g., reactor type, burnup, hydrogen content, end-of life stress, alloy type, drying temperature, etc.) is an effective predictor of material response during long term storage or of performance after long term storage. Multi-variable correlations made for one alloy may not represent the behavior of another alloy exposed to identical conditions and the material responses to thermo-mechanical exposures will be different depending on the materials and systems used. The discussions at the workshop showed several gaps in the standardization of processes and techniques necessary to assess the long term performance of irradiated zirconium alloy cladding during dry storage and transport. The development of, and adherence to, standards to help bridge these gaps will strengthen the technical basis for long term storage and post-storage operations, provide consistency across the nuclear industry, maximize the value of most observations, and enhance the understanding of behavioral differences among alloys. The need for, and potential benefits of, developing the recommended standards are illustrated in the various sections of this report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Clean Cities Strategic Planning White Paper: Light Duty Vehicle Fuel Economy

Increasing the energy efficiency of motor vehicles is critical to achieving national energy goals of reduced petroleum dependence, protecting the global climate, and promoting continued economic prosperity. Even with fuel economy and greenhouse gas emissions standards and various economic incentives for clean and efficient vehicles, providing reliable and accurate fuel economy information to the public is important to achieving these goals. This white paper reviews the current status of light-duty vehicle fuel economy in the United States and the role of the Department of Energy (DOE) Clean Cities Program in disseminating fuel economy information to the public.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

White Paper on Potential Hazards Associated with Contaminated Cheesecloth Exposed to Nitric Acid Solutions

This white paper addresses the potential hazards associated with waste cheesecloth that has been exposed to nitric acid solutions. This issue was highlighted by the cleanup of a 100 ml leak of aqueous nitric acid solution containing Heat Source (HS) plutonium on 21 June 2016. Nitration of cellulosic material is a well-understood process due to industrial/military applications of the resulting material. Within the Department of Energy complex, nitric acids have been used extensively, as have cellulosic wipes. If cellulosic materials are nitrated, the cellulosic material can become ignitable and in extreme cases, reactive. We have chemistry knowledge and operating experience to support the conclusion that all current wastes are safe and compliant. There are technical questions worthy of further experimental evaluation. An extent of condition evaluation has been conducted back to 2004. During this time period there have been interruptions in the authorization to use cellulosic wipes in PF-4. Limited use has been authorized since 2007 (for purposes other than spill cleanup), so our extent of condition includes the entire current span of use. Our evaluation shows that there is no indication that process spills involving high molarity nitric acid were cleaned up with cheesecloth since 2007. The materials generated in the 21 June leak will be managed in a safe manner compliant with all applicable requirements.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Benefits Analysis of Smart Grid Projects. White paper, 2014-2016

Smart grids are rolling out internationally, with the United States (U.S.) nearing completion of a significant USD4-plus-billion federal program funded under the American Recovery and Reinvestment Act (ARRA-2009). The emergence of smart grids is widespread across developed countries. Multiple approaches to analyzing the benefits of smart grids have emerged. The goals of this white paper are to review these approaches and analyze examples of each to highlight their differences, advantages, and disadvantages. This work was conducted under the auspices of a joint U.S.-China research effort, the Climate Change Working Group (CCWG) Implementation Plan, Smart Grid. We present comparative benefits assessments (BAs) of smart grid demonstrations in the U.S. and China along with a BA of a pilot project in Europe. In the U.S., we assess projects at two sites: (1) the University of California, Irvine campus (UCI), which consists of two distinct demonstrations: Southern California Edison’s (SCE) Irvine Smart Grid Demonstration Project (ISGD) and the UCI campus itself; and (2) the Navy Yard (TNY) area in Philadelphia, which has been repurposed as a mixed commercial-industrial, and possibly residential, development. In China, we cover several smart-grid aspects of the Sino-Singapore Tianjin Eco-city (TEC) and the Shenzhen Bay Technology and Ecology City (B-TEC). In Europe, we look at a BA of a pilot smart grid project in the Malagrotta area west of Rome, Italy, contributed by the Joint Research Centre (JRC) of the European Commission. The Irvine sub-project BAs use the U.S. Department of Energy (U.S. DOE) Smart Grid Computational Tool (SGCT), which is built on methods developed by the Electric Power Research Institute (EPRI). The TEC sub-project BAs apply Smart Grid Multi-Criteria Analysis (SG-MCA) developed by the State Grid Corporation of China (SGCC) based on the analytic hierarchy process (AHP) with fuzzy logic. The B-TEC and TNY sub-project BAs are evaluated using new approaches developed by those project teams. JRC has adopted an approach similar to EPRI’s but tailored to the Malagrotta distribution grid.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Hybrid Storage Market Assessment: A JISEA White Paper

This white paper evaluates which markets are best suited for battery storage and storage hybrids and reviews regulations and incentives that support or impede the implementation of standalone storage and battery hybrids. The costs of battery storage technologies have dropped in recent years, resulting in a seven-fold increase in installed capacity over the last decade (1). These technologies offer an attractive rate of return in some locations; however, cost and regulatory barriers still limit the market for storage. Hybridizing a battery (combining the battery with a generator) can in some instances reduce total system costs and increase value compared to separate installations. The fast ramping and dispatchability of a battery can complement the generator to provide services that neither battery nor generator could provide alone. Battery hybrids also benefit from some policy incentives and may be better able to meet market and regulatory requirements.

25 ENERGY STORAGE↗

Integrated simulations for fusion research in the 2030's time frame (white paper outline)

This white paper presents the rationale for developing a community-wide capability for whole-device modeling, and advocates for an effort with the expectation of persistence: a long-term programmatic commitment, and support for community efforts. Statement of 2030 goal (two suggestions): (a) Robust integrated simulation tools to aid real-time experimental discharges and reactor designs by employing a hierarchy in fidelity of physics models. (b) To produce by the early 2030s a capability for validated, predictive simulation via integration of a suite of physics models from moderate through high fidelity, to understand and plan full plasma discharges, aid in data interpretation, carry out discovery science, and optimize future machine designs. We can achieve this goal via a focused effort to extend current scientific capabilities and rigorously integrate simulations of disparate physics into a comprehensive set of workflows.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A white paper: The Cornell-BNL FFAG-ERL Test Accelerator

This white paper describes a project that promises to propel high-power, high-brightness electron beam science and applications to an exciting new level. The collaborative effort between Brookhaven and Cornell will be a model for future projects between universities and national lab, taking advantage of the expertise and resources of both to investigate new topics in a timely and cost-effective manner.

43 PARTICLE ACCELERATORS↗

HEP Software Foundation Community White Paper Working Group - Data Analysis and Interpretation

At the heart of experimental high energy physics (HEP) is the development of facilities and instrumentation that provide sensitivity to new phenomena. Our understanding of nature at its most fundamental level is advanced through the analysis and interpretation of data from sophisticated detectors in HEP experiments. The goal of data analysis systems is to realize the maximum possible scientific potential of the data within the constraints of computing and human resources in the least time. To achieve this goal, future analysis systems should empower physicists to access the data with a high level of interactivity, reproducibility and throughput capability. As part of the HEP Software Foundation Community White Paper process, a working group on Data Analysis and Interpretation was formed to assess the challenges and opportunities in HEP data analysis and develop a roadmap for activities in this area over the next decade. In this report, the key findings and recommendations of the Data Analysis and Interpretation Working Group are presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

HEP Software Foundation Community White Paper Working Group - Detector Simulation

A working group on detector simulation was formed as part of the high-energy physics (HEP) Software Foundation's initiative to prepare a Community White Paper that describes the main software challenges and opportunities to be faced in the HEP field over the next decade. The working group met over a period of several months in order to review the current status of the Full and Fast simulation applications of HEP experiments and the improvements that will need to be made in order to meet the goals of future HEP experimental programmes. The scope of the topics covered includes the main components of a HEP simulation application, such as MC truth handling, geometry modeling, particle propagation in materials and fields, physics modeling of the interactions of particles with matter, the treatment of pileup and other backgrounds, as well as signal processing and digitisation. The resulting work programme described in this document focuses on the need to improve both the software performance and the physics of detector simulation. The goals are to increase the accuracy of the physics models and expand their applicability to future physics programmes, while achieving large factors in computing performance gains consistent with projections on available computing resources.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Lake Roosevelt White Sturgeon Modeling Support

This report contains summarized progress on the construction, validation, and calibration of a hydrodynamic and water temperature model, and individual-based sturgeon model, for the Transboundary Reach of the Columbia River and Lake Roosevelt. A 1-dimensional hydrodynamic and water temperature model, the Modular Aquatic Simulation System in 1-dimension (MASS1), was constructed using existing bathymetry data from the U.S.-Canada international border to Grand Coulee Dam, and validated using velocity, temperature, and water elevation data collected by staff of the CTCR during three distinct hydrodynamic periods occurring in early spring, late spring, and summer in the study area. Parameters of MASS1 were then calibrated so that model simulations matched empirical data of water surface elevations collected in 2016. Several years of MASS1 data were archived and are available for use with the sturgeon IBM: 1975–2001, 2004, 2005, 2007–2015, and April–August 2016. An individual-based simulation model was concomitantly constructed to simulate four of the early life stages of white sturgeon: spawning, embryo incubation, free embryos, and early larvae. Submodels for each of the four life stages contain mathematical algorithms that primarily describe the growth, development, and movement of individuals based on outputs from MASS1. Sturgeon simulations were then run for two historical years where limited recruitment may have occurred (1997 and 2011) and two years in which recruitment likely did not occur (2004 and 2005).

54 ENVIRONMENTAL SCIENCES↗

White Paper on New Opportunities at the Next-Generation Neutrino Experiments (Part 1: BSM Neutrino Physics and Dark Matter)

With the advent of a new generation of neutrino experiments which leverage high-intensity neutrino beams for precision measurements, it is timely to explore physics topics beyond the standard neutrino-related physics. Given that the realm of beyond the standard model (BSM) physics has been mostly sought at high-energy regimes at colliders, such as the LHC at CERN, the exploration of BSM physics in neutrino experiments will enable complementary measurements at the energy regimes that balance that of the LHC. This is in concert with new ideas for high-intensity beams for fixed target and beam-dump experiments world-wide, e.g., those at CERN. The combination of the high intensity proton beam facilities and massive detectors for precision neutrino oscillation parameter measurements and for CP violation phase measurements will help make BSM physics reachable even in low energy regimes in accelerator based experiments. Large mass detectors with highly precise tracking and energy measurements, excellent timing resolution, and low energy thresholds will enable searches for BSM phenomena from cosmogenic origin, as well. Therefore, it is conceivable that BSM topics in the next generation neutrino experiments could be the dominant physics topics in the foreseeable future, as the precision of the neutrino oscillation parameter and CPV measurements continues to improve. In this spirit, this white paper provides a review of the current landscape of BSM theory in neutrino experiments in two selected areas of the BSM topics - dark matter and neutrino related BSM - and summarizes the current results from existing neutrino experiments to set benchmarks for both theory and experiment. This paper then provides a review of upcoming neutrino experiments throughout the next 10 - 15 year time scale and their capabilities to set the foundation for potential reach in BSM physics in the two aforementioned themes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Astro2020 APC White Paper: Elevating the Role of Software as a Product of the Research Enterprise

Software is a critical part of modern research, and yet there are insufficient mechanisms in the scholarly ecosystem to acknowledge, cite, and measure the impact of research software. The majority of academic fields rely on a one-dimensional credit model whereby academic articles (and their associated citations) are the dominant factor in the success of a researcher's career. In the petabyte era of astronomical science, citing software and measuring its impact enables academia to retain and reward researchers that make significant software contributions. These highly skilled researchers must be retained to maximize the scientific return from petabyte-scale datasets. Evolving beyond the one-dimensional credit model requires overcoming several key challenges, including the current scholarly ecosystem and scientific culture issues. This white paper will present these challenges and suggest practical solutions for elevating the role of software as a product of the research enterprise.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗