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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Observation of a phase transition within the domain walls of ferromagnetic Co3Sn2S2

Abstract The ferromagnetic phase of Co 3 Sn 2 S 2 is widely considered to be a topological Weyl semimetal, with evidence for momentum-space monopoles of Berry curvature from transport and spectroscopic probes. As the bandstructure is highly sensitive to the magnetic order, attention has focused on anomalies in magnetization, susceptibility and transport measurements that are seen well below the Curie temperature, leading to speculation that a “hidden” phase coexists with ferromagnetism. Here we report spatially-resolved measurements by Kerr effect microscopy that identify this phase. We find that the anomalies coincide with a deep minimum in domain wall (DW) mobility, indicating a crossover between two regimes of DW propagation. We demonstrate that this crossover is a manifestation of a 2D phase transition that occurs within the DW, in which the magnetization texture changes from continuous rotation to unidirectional variation. We propose that the existence of this 2D transition deep within the ferromagnetic state of the bulk is a consequence of a giant quality factor for magnetocrystalline anisotropy unique to this compound. This work broadens the horizon of the conventional binary classification of DWs into Bloch and Néel walls, and suggests new strategies for manipulation of domain walls and their role in electron and spin transport.

36 MATERIALS SCIENCE↗
DOE OSTI2016

A review of whole cell wall NMR by the direct-dissolution of biomass

To fully realize the potential of lignocellulosic biomass as a renewable resource for the production of fuels, chemicals, and materials, an improved understanding of the chemical and molecular structures within biomass and how those structures are formed during biosynthesis and transformed during (thermochemical and biological) conversion must be developed. This effort will require analytical techniques which are not only in-depth, rapid, and cost-effective, but also leave native cell wall features intact. Whole plant cell wall nuclear magnetic resonance (NMR) analysis facilitates unparalleled structural characterization of lignocellulosic biomass without causing (or with minimal) structural modification. The objective of this review is to summarize research pertaining to solution- or gel-state whole plant cell wall NMR analysis of biomass, demonstrating the capability of NMR to delineate the structural features and transformations of biomass. In particular, this review will focus on the application of a two-dimensional solution-state NMR technique and perdeuterated ionic liquid based organic electrolyte solvents for the direct dissolution and analysis of biomass. Furthermore, we believe this type of analysis will be critical to advancing biofuel research, improving bioprocessing methodology, and enhancing plant bioengineering efforts.

09 BIOMASS FUELS↗
DOE OSTI2017

Oxygen-promoted catalyst sintering influences number density, alignment, and wall number of vertically aligned carbon nanotubes

A lack of synthetic control and reproducibility during vertically aligned carbon nanotube (CNT) synthesis has stifled many promising applications of organic nanomaterials. Oxygen-containing species are particularly precarious in that they have both beneficial and deleterious effects and are notoriously difficult to control. In this paper, we demonstrated diatomic oxygen's ability, independent of water, to tune oxide-supported catalyst thin film dewetting and influence nanoscale (diameter and wall number) and macro-scale (alignment and density) properties for as-grown vertically aligned CNTs. In particular, single- or few-walled CNT forests were achieved at very low oxygen loading, with single-to-multi-walled CNT diameters ranging from 4.8 ± 1.3 nm to 6.4 ± 1.1 nm over 0–800 ppm O 2 , and an expected variation in alignment, where both were related to the annealed catalyst morphology. Morphological differences were not the result of subsurface diffusion, but instead occurred via Ostwald ripening under several hundred ppm O 2 , and this effect was mitigated by high H 2 concentrations and not due to water vapor (as confirmed in O 2 -free water addition experiments), supporting the importance of O 2 specifically. Further characterization of the interface between the Fe catalyst and Al 2 O 3 support revealed that either oxygen-deficit metal oxide or oxygen-adsorption on metals could be functional mechanisms for the observed catalyst nanoparticle evolution. Finally, taken as a whole, our results suggest that the impacts of O 2 and H 2 on the catalyst evolution have been underappreciated and underleveraged in CNT synthesis, and these could present a route toward facile manipulation of CNT forest morphology through control of the reactive gaseous atmosphere alone.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2015

Characterization of carrier transport properties in strained crystalline Si wall-like structures in the quasi-quantum regime

We report the transport characteristics of both electrons and holes through narrow constricted crystalline Si “wall-like” long-channels that were surrounded by a thermally grown SiO{sub 2} layer. The strained buffering depth inside the Si region (due to Si/SiO{sub 2} interfacial lattice mismatch) is where scattering is seen to enhance some modes of the carrier-lattice interaction, while suppressing others, thereby changing the relative value of the effective masses of both electrons and holes, as compared to bulk Si. In the narrowest wall devices, a considerable increase in conductivity was observed as a result of higher carrier mobilities due to lateral constriction and strain. The strain effects, which include the reversal splitting of light- and heavy-hole bands as well as the decrease of conduction-band effective mass by reduced Si bandgap energy, are formulated in our microscopic model for explaining the experimentally observed enhancements in both conduction- and valence-band mobilities with reduced Si wall thickness. Also, the enhancements of the valence-band and conduction-band mobilities are found to be associated with different aspects of theoretical model.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Increased magnetic damping of a single domain wall and adjacent magnetic domains detected by spin torque diode in a nanostripe

Spin torque resonance has been used to simultaneously probe the dynamics of a magnetic domain wall and of magnetic domains in a nanostripe magnetic tunnel junction. Due to the large associated resistance variations, we are able to analyze quantitatively the resonant properties of these single nanoscale magnetic objects. In particular, we find that the magnetic damping of both the domains and the domain wall is doubled compared to the damping value of the host magnetic layer. We estimate the contributions to the damping arising from the dipolar couplings between the different layers in the junction and from the intralayer spin pumping effect, and find that they cannot explain the large damping enhancement that we observe. We conclude that the measured increased damping is intrinsic to large amplitudes excitations of spatially localized modes or solitons such as vibrating or propagating domain walls.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Numerical validation of axial plasma momentum lost to a lateral wall induced by neutral depletion

Momentum imparted to a lateral wall of a compact inductively coupled plasma thruster is numerically investigated for argon and xenon gases by a particle-in-cell simulation with Monte Carlo collisions (PIC-MCC). Axial plasma momentum lost to a lateral wall is clearly shown when axial depletion of the neutrals is enhanced, which is in qualitative agreement with the result in a recent experiment using a helicon plasma source [Takahashi et al., Phys. Rev. Lett. 114, 195001 (2015)]. The PIC-MCC calculations demonstrate that the neutral depletion causes an axially asymmetric profile of the plasma density and potential, leading to axial ion acceleration and the non-negligible net axial force exerted to the lateral wall in the opposite direction of the thrust.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Dynamical effect of confining wall on diffusion of fluid at nanoscale

The dynamical effect of wall-fluid interaction on diffusion in direction perpendicular to confining walls has been studied, theoretically. The properties of fluids which incorporates the effect of static changes in confined fluid has been modified to include, directly, the dynamical effects of wall on the motion of particles. The results obtained for VACF in perpendicular direction of channel of width of two atomic diameters are presented and compared with the molecular dynamic (MD) simulation results as well as the results obtained without including the dynamical effect.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Origin of a Raman scattering peak generated in single-walled carbon nanotubes by X-ray irradiation and subsequent thermal annealing

We have found that a Raman scattering (RS) peak around 1870 cm{sup −1} was produced by the annealing of the X-ray irradiated film of single-walled carbon nanotubes (SWNTs) at 450 {sup o}C. The intensity of 1870-cm{sup −1} peak showed a maximum at the probe energy of 2.3 eV for the RS spectroscopy with various probe lasers. Both the peak position and the probe-energy dependence were almost identical to those of the one-dimensional carbon chains previously reported in multi-walled carbon nanotubes. Consequently, we concluded that the 1870-cm{sup −1} peak found in the present study is attributed to carbon chains. The formation of carbon chains by the annealing at temperature lower than 500 {sup o}C is firstly reported by the present study. The carbon chains would be formed by aggregation of the interstitial carbons, which are formed as a counterpart of carbon vacancies by X-ray irradiation diffused on SWNT walls. The result indicates that the combination of X-ray irradiation and subsequent thermal annealing is a feasible tool for generating new nanostructures in SWNT.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

Role of flexoelectric coupling in polarization rotations at the a-c domain walls in ferroelectric perovskites

Ferroelectric and ferroelastic domain walls play important roles in ferroelectric properties. However, their couplings with flexoelectricity have been less understood. Here, we applied phase-field simulation to investigate the flexoelectric coupling with ferroelectric a/c twin structures in lead ziconate titanate thin films. Local stress gradients were found to exist near twin walls that created both lateral and vertical electric fields through the flexoelectric effect, resulting in polarization inclinations from either horizontal or normal orientation, polarization rotation angles deviated from 90°, and consequently highly asymmetric a/c twin walls. Furthermore, by tuning the flexoelectric strengths in a reasonable range from first-principles calculations, we found that the transverse flexoelectric coefficient has a larger influence on the polarization rotation than longitudinal and shear coefficients. And as polar rotations that commonly occur at compositional morphotropic phase boundaries contribute to the piezoelectric enhancement, this work calls for further exploration of alternative strain-engineered polar rotations via flexoelectricity in ferroelectric thin films.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Electrostatic potential mapping at ferroelectric domain walls by low-temperature photoemission electron microscopy

Low-temperature X-ray photoemission electron microscopy (X-PEEM) is used to measure the electric potential at domain walls in improper ferroelectric Er 0.99 Ca 0.01 MnO 3 . Here, by combining X-PEEM with scanning probe microscopy and theory, we develop a model that relates the detected X-PEEM contrast to the emergence of uncompensated bound charges, explaining the image formation based on intrinsic electronic domain-wall properties. In contrast to previously applied low-temperature electrostatic force microscopy (EFM), X-PEEM readily distinguishes between positive and negative bound charges at domain walls. Finally, our study introduces an X-PEEM-based approach for low-temperature electrostatic potential mapping, facilitating nanoscale spatial resolution and data acquisition times on the order of 0.1-1 s.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Effect of reflections on 2D tomographic reconstructions of filtered cameras and on interpreting spectroscopic measurements in the JET ITER-like wall divertor

Considering reflections from metallic wall surfaces in generation of tomographic reconstructions of the tangentially viewing, visible-range spectroscopic divertor cameras in JET has been observed to yield enhanced spatial accuracy and significant reduction of emission artifacts in experimentally resolved 2D line emission distributions. Neglection of reflections in the tomography process was found to lead to overestimation of the emission near the wall surfaces by up to a factor of 4, as well as to formation of bright emission artifacts between the main emission regions and the wall surfaces, comprising locally up to 50% of the emission. Mimicking divertor spectroscopy measurements by integrating the tomographic reconstructions along vertical lines-of-sight implies that reflections comprise 15%–25% of the observed line-integrated emission peaks. Additionally, the spatial differences in the reflection contribution between the different lines-of-sight are less pronounced than in the 2D reconstructions due to the dominance of the brightest emission regions through which the spectroscopic lines-of-sight pass. However, postprocessing EDGE2D-EIRENE simulations using the CHERAB code and synthetic spectroscopy suggests a decrease of the spectroscopically inferred divertor electron temperature by up to 75%, when redistribution of the observed light due to reflections is considered.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Time-dependent modeling of coupled plasma-wall dynamics

Effects of dynamic wall outgassing on divertor plasma during an ELM-like heat pulse are modelled using newly coupled edge plasma code UEDGE and all reaction-diffusion code FACE. Different divertor regimes are simulated depending on the degree of the plasma detachment. It is shown that hydrogen outgassing from the divertor target plate induced by ELM pulse in the semi-detached regime can trigger deep plasma detachment. The induced detachment does not spontaneously reverse after the pulse due to ineffective implantation of low energy plasma hydrogen in the target material. Furthermore, we demonstrate that plasma neutrals play essential role in heat transport in a detached divertor. The modelled hydrogen dynamics in the wall material demonstrates that the heat pulse leads to enhanced hydrogen transport toward the wall bulk.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Cellulose synthase complexes act in a concerted fashion to synthesize highly aggregated cellulose in secondary cell walls of plants

Significance Plant cell walls are important in plant development and for textiles, wood products, and bioenergy. Cellulose, the microfibrillar component of primary cell walls (PCWs) and secondary cell walls (SCWs), is formed by cellulose synthase complexes (CSCs) at the plasma membrane. Here, we show that CSCs behave differently during PCW and SCW synthesis and form microfibrils with different organization. During PCW synthesis, dispersed CSCs synthesize cellulose microfibrils with low aggregation, whereas during SCW synthesis, densely arranged groups of CSCs move coherently to synthesize highly aggregated microfibrils. Our study suggests that controlled alterations in CSC distribution and orchestrated movements contribute to the high density and bundling of cellulose microfibrils in SCWs.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Simulations of Heat Transfer Using Tight-Fitting Twisted Tape Inserts for First Wall Cooling in Molten Salt Breeder Blankets

One of the major components in fusion energy systems is the fusion blanket, which has a vacuum vessel to contain the plasma. As part of the fusion blanket/vacuum vessel, the first wall and plasma-facing components require sufficient cooling to prevent material degradation during operation from the superheated plasma. Most fusion blanket concepts involve first wall and divertor coolant channels with heat transfer enhancements (HTEs) that are intended to withstand the incident high heat fluxes of 1 to 5 MW/m 2 . Twisted tape inserts are a proposed HTE that have been investigated previously for first wall cooling and monoblock divertor cooling channels and in other nonfusion heat transfer components. By inserting twisted tapes into straight pipes, the amount of turbulence in the system can be increased at lower Reynolds numbers by swirling the flow. This results in better heat transfer characteristics with marginal increases in frictional pressure losses. In particular, simulations of high-Prandtl-number fluids such as the proposed molten salt FLiBe in twisted tapes, which is prototypic to liquid immersion blankets, have not been previously explored. Here, in this study, we simulate various Prandtl numbers in pipes with twisted tape inserts using large eddy simulations to determine the effects of increasing Prandtl numbers on heat transfer performance. The quantities of particular interest are the Nusselt number and the friction factor, which were recovered using data reduction techniques to determine impacts on heat transfer and pressure losses. This work serves as a starting point for determining the feasibility of twisted tape inserts for liquid immersion blanket concepts.

LES↗
DOE OSTI2016

Anomalous feedback and negative domain wall resistance

Magnetic induction can be regarded as a negative feedback effect, where the motive-force opposes the change of magnetic flux that generates the motive-force. In artificial electromagnetics emerging from spintronics, however, this is not necessarily the case. In this paper, by studying the current-induced domain wall dynamics in a cylindrical nanowire, we show that the spin motive-force exerting on electrons can either oppose or support the applied current that drives the domain wall. The switching into the anomalous feedback regime occurs when the strength of the dissipative torque β is about twice the value of the Gilbert damping constant α. Finally, the anomalous feedback manifests as a negative domain wall resistance, which has an analogy with the water turbine.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2019

Dominant two-fluid magnetohydrodynamic instabilities in CFETR upgrade phase-I scenario in presence of perfect conducting wall

Here, the dominant two-fluid magnetohydrodynamic (MHD) stabilities of China Fusion Engineering Test Reactor upgrade phase-I baseline equilibria in presence of perfect conducting wall have been evaluated using the initial value code NIMROD. Our MHD simulations show that for equilibrium with q axis < 1, high-n edge localized modes are slightly stabilized by toroidal shear flow, and n = 1 mode is found to be unstable in the core region with the characteristic of sawtooth instability. For q axis > 2 equilibrium, all modes are found to be unstable but edge localized both in single-fluid and two-fluid MHD models. Specifically for n ≤ 13 modes, the two-fluid MHD model gives a slightly higher growth rate than the single-fluid MHD model, while for n > 13 modes, this trend becomes the opposite, which means the two-fluid MHD model is needed for high-n mode analysis. In addition, n = 1–10 modes are found to be more unstable with increasing wall position and eventually their growth rates approach values in the no-wall limit.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Noninvasive THz-TDS measurements of plasma bounded and optically shielded by Hall thruster wall material

We experimentally demonstrate the capability of terahertz time-domain spectroscopy (THz-TDS) to noninvasively measure the electron density and collision frequency of plasma bounded and optically shielded by Hall thruster wall material. This paper augments the standard THz-TDS plasma diagnostic theory to account for plasma boundaries, presents THz optical property measurements of three different wall materials (grades M, M26, and HP boron nitride composite), and provides electron density and collision frequency measurements of an inductively coupled plasma bounded and optically shielded by each wall material. We find that the electron density measurement capability is weakly impacted by the boundaries, whereas the electron collision frequency measurement capability is strongly reduced by the boundaries. Here, the bounded plasma electron density trends deviate substantially from those of the unbounded plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Domain walls and gravitational waves in the Standard Model

We study domain walls which can be created in the Standard Model under the assumption that it is valid up to very high energy scales. We focus on domain walls interpolating between the physical electroweak vacuum and the global minimum appearing at very high field strengths. The creation of the network which ends up in the electroweak vacuum percolating through the Universe is not as difficult to obtain as one may expect, although it requires certain tuning of initial conditions. Our numerical simulations confirm that such domain walls would swiftly decay and thus cannot dominate the Universe. We discuss the possibility of detection of gravitational waves produced in this scenario. We have found that for the standard cosmology the energy density of these gravitational waves is too small to be observed in present and planned detectors.

79 ASTRONOMY AND ASTROPHYSICS↗