Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “State Variable”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Effective Electrochemical Charge Storage in the High-Lithium Compound Li8ZrO6

Li8ZrO6 is a pseudolamellar compound with high lithium content. Even though it is intrinsically a poor conductor and does not contain a transition metal with easily variable oxidation states, a new synthetic approach to preparing it in nanocomposite form with intimate contact to a conductive carbon by mechanical delamination enabled galvanostatic cycling of coin half-cells containing Li8ZrO6/C as the cathode and Li-metal as the anode at 221 mAh/g (which corresponds to extracting 2 Li per formula unit) over at least 140 cycles. With a higher capacity limit, a discharge capacity of 331 mAh/g (which corresponds to extracting 3 Li per formula unit) was maintained over 15–20 cycles. Ex-situ and operando X-ray diffraction (XRD) studies of galvanostatically cycled cells showed that at these levels of charge, delithiation follows a reversible, topotactic path with only small distortions around Zr atoms. During this process, crystalline grain sizes decrease continuously, shortening diffusion lengths within grains but increasing the number of grain boundaries and electrode/electrolyte interfaces. Charge storage in Li8ZrO6 appears to involve partial oxidation of oxygen atoms and production of small-polaron holes, as supported by XRD, X-ray photoelectron spectroscopy, and pair-distribution function studies and predicted by quantum mechanical calculations. At higher depths of charge, delithiation results in amorphization of the active electrode material. The charge storage mechanism in Li8ZrO6 is unusual among lithium-ion battery electrode materials and involves a combination of mechanisms that resemble intercalation and conversion reactions. With further refinement, Li8ZrO6/C based materials open up opportunities to develop new cathode materials for lithium-ion batteries that may improve on currently existing capacity barriers.

Li diffusion↗
DOE OSTI2025

Criegee Intermediates Compete Well with OH as a Cleaning Agent for Atmospheric Amides

Elucidating the chemical kinetics of stabilized Criegee intermediates (sCIs) in the atmosphere is critically important for climate modeling. Here, we report a class of very rapid bimolecular reactions of two sCIs, namely, CH 2 OO and syn-CH 3 CHOO, with amides. We used electronic structure calculations and kinetics calculations to elucidate a universal mechanism by which the oxygen atom of the carbonyl group in an amide is added to the carbon atom of the COO group in the sCI with simultaneous transfer of the amide hydrogen to the terminal oxygen atom of the carbonyl oxide of the sCI. The barriers for the mechanism are submerged below reactants by ∼9 kcal/mol, which means that the tight transition state is not the rate-determining step, and the rate constants are determined by loose free energy bottlenecks between the reactants and the precursor complexes. We calculate the rate constants due to these loose and barrierless transition states by variable-reaction-coordinate variational transition-state theory. We find that bimolecular reactions of sCIs with amides are very rapid, with rate constants 1 to 5 × 10 –10 cm 3 molecule –1 s –1 , which is a factor of 2 faster than the rate constants of carboxylic acids with sCIs and 10 2 faster than the rate constants of OH reactions with amides. This has the consequence that, under a wide range of conditions, sCIs are the major sink for atmospheric amides, in contrast to the usual assumption that OH radicals are the dominant sinks.

Amides↗
DOE OSTI2024

Efficient generation and amplification of intense vortex and vector laser pulses via strongly-coupled stimulated Brillouin scattering in plasmas

The past decade has seen tremendous progress in the production and utilization of vortex and vector laser pulses. Although both are considered as structured light beams, the vortex lasers have helical phase fronts and phase singularities, while the vector lasers have spatially variable polarization states and polarization singularities. In contrast to the vortex pulses that carry orbital angular momentum (OAM), the vector laser pulses have a complex spin angular momentum (SAM) and OAM coupling. Despite many potential applications enabled by such pulses, the generation of high-power/-intensity vortex and vector beams remains challenging. Here, we demonstrate using theory and three-dimensional simulations that the strongly-coupled stimulated Brillouin scattering (SC-SBS) process in plasmas can be used as a promising amplification technique with up to 65% energy transfer efficiency from the pump beam to the seed beam for both vortex and vector pulses. We also show that SC-SBS is strongly polarization-dependent in plasmas, enabling an all-optical polarization control of the amplified seed beam. Additionally, the interaction of such structured lasers with plasmas leads to various angular momentum couplings and decouplings that produce intense new light structures with controllable OAM and SAM. This scheme paves the way for novel optical devices such as plasma-based amplifiers and light field manipulators.

Physics↗
DOE OSTI2024

Nonperturbative Zou-Wang-Mandel effect

The Zou-Wang-Mandel (ZWM) effect is a remarkable consequence of photon indistinguishability and continuous-variable entanglement in which an optical phase shift is imprinted on photonic modes associated with optical paths that that do not pass through the phase shift source. By bringing the canonical formalism of continuous-variable Gaussian states to bear on the mode-structure of the ZWM experiment, we show that the physical consequence of implementing optical path identity is a renormalization of quadrature squeezing which governs the entanglement of four effective optical modes. Nonperturbative expressions for the ZWM interference patterns and normalized first-order coherence function are derived. Generalizations to $\mathscr{H}$-graph states with more than four modes directly follow from the general method used to analyze the minimal example. Here, we show that a ZWM interferometer with a laser-seeded signal mode, which estimates an idler phase shift by detecting photons that did not propagate through the phase shift, exhibits an optimal sensitivity comparable to that of a laser-seeded SU(1,1) interferometer if path identity is implemented with high fidelity.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2022

Heralded Multiplexed High-Efficiency Cascaded Source of Dual-Rail Entangled Photon Pairs Using Spontaneous Parametric Down-Conversion

Deterministic sources of high-fidelity entangled qubit pairs encoded in the dual-rail photonic basis, i.e., presence of a single photon in one of two orthogonal modes, are a key enabling technology of many applications of quantum information processing, including high-rate, high-fidelity quantum communications over long distances. The most popular and mature sources of such photonic entanglement, e.g., those that leverage spontaneous parametric down-conversion (SPDC) or spontaneous four-wave mixing, generate an entangled (so-called continuous-variable) quantum state that contains contributions from high-order photon terms that lie outside the span of the dual-rail basis, which is detrimental to most applications. One often uses low pump power to mitigate the effects of those high-order terms. However, that reduces the pair generation rate, and the source becomes inherently probabilistic. We investigate a cascaded source that performs a linear-optical entanglement swap between two SPDC sources, to generate a heralded photonic entangled state that has a higher fidelity (to the ideal Bell state) compared to a free-running SPDC source. Furthermore, with the Bell swap providing a heralding trigger, we show how to build a multiplexed source, which despite reasonable switching losses and detector loss and noise, yields a fidelity versus success probability trade-off of a high-efficiency source of high-fidelity dual-rail photonic entanglement. We find, however, that there is a threshold of 1.5 dB of loss per switch, beyond which multiplexing hurts the fidelity versus success probability trade-off.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

An Energy Efficient Ethernet Strategy Based on Traffic Prediction and Shaping

Recently, different communities in computer science, telecommunication, and control systems have devoted a huge effort towards the design of energy efficient solutions for data transmission and network management. This paper collocates along this research line and presents a novel energy efficient strategy conceived for Ethernet networks. The proposed strategy, which exploits the opportunities offered by the IEEE 802.3az amendment to the Ethernet standard (known as energy efficient Ethernet) is based on the possibility of predicting the future traffic from the analysis of the current data flow. In agreement with the results of such a dynamic prediction, Ethernet links can be forced into a low power consumption state for variable intervals. Theoretical bounds are derived to detail how the performance figures depend on the parameters of the designed strategy and scale with respect to traffic load. Furthermore, simulation results carried out with both real and synthetic traffic traces are presented to prove the effectiveness of the strategy, which leads to considerable energy savings at the cost of only a limited bounded delay in data delivery.

Cenedese, Angelo (ORCID:0000000322495094)↗
DOE OSTI2022

Impact of Tropical Cyclone Wind Forcing on the Global Climate in a Fully Coupled Climate Model

Tropical cyclones (TCs) alter upper-ocean temperature and influence ocean heat content via enhanced turbulent mixing. A better understanding of the role of TCs within the climate system requires a fully coupled modeling framework, where TC-induced ocean responses feed back to the atmosphere and subsequently to the climate mean state and variability. Here, we investigate the impacts of TC wind forcing on the global ocean and the associated feedbacks within the climate system using the fully coupled Community Earth System Model version 1.3 (CESM1.3). Using the low-resolution version of CESM1.3 (1° atmosphere and ocean grid spacing) with no intrinsic TCs, we conduct a suite of sensitivity experiments by inserting TC winds extracted from a high-resolution (0.25° atmosphere grid spacing) TC-permitting simulation into the low-resolution model. Results from the low-resolution TC experiment are compared to a low-resolution control simulation to diagnose TCs’ impact. We found that the added TC winds can increase ocean heat content by affecting ocean vertical mixing, air–sea enthalpy fluxes, and cloud amount. Here, the added TCs can influence mean SST, precipitation, ocean subsurface temperature, and ocean mixed layer depth. We found a strengthening of the wind-driven subtropical cells and a weakening of the Atlantic meridional overturning circulation due to the changes of surface buoyancy fluxes. TCs in the model cause anomalous equatorward ocean heat convergence in the deep tropics and an increase of poleward ocean heat transport out of the subtropics. Our modeling results provide new insights into the multiscale interactions between TCs and the coupled climate system.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Assessment of CMIP5 and CMIP6 AMIP Simulated Clouds and Surface Shortwave Radiation Using ARM Observations over Different Climate Regions

The simulations of clouds and surface radiation from 10 CMIP6 models and their CMIP5 predecessors are compared to the ARM ground-based observations over different climate regions. Compared to the ARM radar-lidar derived total cloud fractions (CFT) and cloud fraction vertical distributions over the six selected sites, both CMIP5 and CMIP6 significantly underestimated CFT and low-level CF over the Northern Hemispheric midlatitude sites (SGPC1 and ENAC1), although the biases are generally smaller in CMIP6. Over the tropical oceanic site (TWPC2), 5 out of 10 CMIP6 models better simulated low-level CF than their CMIP5 predecessors. CMIP6 simulations generally agreed well with the ARM observations in CFT and cloud fraction vertical distributions over the tropical continental (MAOM1) and coastal (TWPC3) sites but missed the transitions between dry and wet seasons, similar to CMIP5 simulations. The improvements in downwelling shortwave fluxes (SWdn) at the surface from the majority of CMIP6 compared to CMIP5 primarily resulted from the improved cloud fraction simulations, especially over the SGPC1, ENAC1, and TWPC3 sites. By contrast, both CMIP5 and CMIP6 models exhibited diverse performances of clouds and shortwave radiation over the Arctic site (NSAC1), where CMIP6 models produced more clouds than CMIP5 models, especially for the low-level clouds. The comparisons between observations and CMIP5 and CMIP6 simulations provide valuable quantitative assessments of the accuracy of mean states and variabilities in the model simulations and shed light on general directions to improve climate models in different regions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

ARM data-oriented metrics and diagnostics package for climate model evaluation (ARM-DIAGS-V3) version 3

A Python-based metrics and diagnostics package is currently being developed by the ARM Infrastructure Team at Lawrence Livermore National Laboratory to facilitate the use of long-term high frequency measurements from the ARM program in evaluating the regional climate simulation of clouds, radiation, precipitation, and aerosols. This metrics and diagnostics package computes climatological means of targeted climate model simulation and generates tables and plots for comparing the model simulation with ARM observational data. The CMIP model data sets are also included in the package to enable model inter-comparison as demonstrated in Zhang et al. (2018) and Zhang et al. (2020). The mean of the CMIP model can be served as a reference for individual models. Basic performance metrics are computed to measure the accuracy of mean state and variability of climate models. The evaluated physical quantities include cloud fraction, temperature, relative humidity, cloud liquid water path, total column water vapor, precipitation, sensible and latent heat fluxes, aerosol optical depth, and radiative fluxes, with plan to extend to more fields, such as the evaluation of model simulated aerosol physicochemical properties and cloud microphysics properties. Process-oriented diagnostics focusing on aerosol, cloud, and precipitation-related phenomena are also being developed for the evaluation and development of specific model physical parameterizations. In addition to the Southern Great Plains (SGP), North Slope of Alaska (NSA) and Tropical Western Pacific (TWP) atmospheric observatories in the ARMDIAGS version 2.0, the version 3.0 package have extended to the data collected at the ARM Eastern North Atlantic (ENA) atmospheric observatory and the Observation and Modeling of the Green Ocean Amazon (GOAMAZON) field campaign. The metrics and diagnostics package are currently built upon standard Python libraries and additional Python packages developed by DOE (CDAT). The ARM metrics and diagnostic package is available publicly with the hope that it can serve as an easy entry point for climate modelers to compare their models with ARM data. In this report, we first provide an overview of major metrics in section 2. The input data, which constitutes the core content of the metrics and diagnostics package, is summarized in section 3. A user's guide documenting the workflow/structure of the version 3.0 codes and including step-by-step instruction for running the package is described in section 4.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Rapid Optimization of Total Variation with Applications in Imaging, Additive Manufacturing, and Qualification

Total Variation optimization penalizes the gradient of a control variable or state. While this work focuses on image processing in particular, it has also found applications in inverse problems and topology optimization. In image processing, the goal is to maintain faithfulness to the original image while denoising and/or deblurring. Additionally, bilevel optimization over the spatially varying regularization weights can illuminate interfaces such as damage regions and other anomalies. We will address two fundamental challenges with TV-optimization: (i) the typical slow convergence of existing TV-optimization methods, and (ii) the selection of spatially varying TV parameters to promote interface detection. Additionally, we will apply such techniques to image data collected in additive manufacturing. In said context, stochasticity in build events induces flaws in the manufactured piece, compromising the integrity of said part. There is a critical need for in-situ monitoring to spot anomalies once they form, and in this setting we apply our total variation and hyperparameter solvers. We will develop a customized algorithm based on for extreme-scale TV-optimization that achieves super-linear or quadratic-convergence, a critical property for real-time, image-by-image analysis. A worst-case outcome is a preprocessing step that enhances image quality in-situ, specifically for out-of-focus and noisy images.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Holographic Space-Time and Quantum Information

The formalism of Holographic Space-time (HST) is a translation of the principles of Lorentzian geometry into the language of quantum information. Intervals along time-like trajectories, and their associated causal diamonds, completely characterize a Lorentzian geometry. The Bekenstein-Hawking-Gibbons-’t Hooft-Jacobson-Fischler-Susskind-Bousso Covariant Entropy Principle, equates the logarithm of the dimension of the Hilbert space associated with a diamond to one quarter of the area of the diamond’s holographic screen, measured in Planck units. The most convincing argument for this principle is Jacobson’s derivation of Einstein’s equations as the hydrodynamic expression of this entropy law. In that context, the null energy condition (NEC) is seen to be the analog of the local law of entropy increase. The quantum version of Einstein’s relativity principle is a set of constraints on the mutual quantum information shared by causal diamonds along different time-like trajectories. The implementation of this constraint for trajectories in relative motion is the greatest unsolved problem in HST. The other key feature of HST is its claim that, for non-negative cosmological constant or causal diamonds much smaller than the asymptotic radius of curvature for negative c.c., the degrees of freedom localized in the bulk of a diamond are constrained states of variables defined on the holographic screen. This principle gives a simple explanation of otherwise puzzling features of BH entropy formulae, and resolves the firewall problem for black holes in Minkowski space. It motivates a covariant version of the CKN [1] bound on the regime of validity of quantum field theory (QFT) and a detailed picture of the way in which QFT emerges as an approximation to the exact theory

tensor network↗
DOE OSTI2021

First-principles Prediction of X-Ray Polarization from Magnetic Reconnection in High-frequency BL Lacertae Objects

Relativistic magnetic reconnection is a potential particle acceleration mechanism for high-frequency BL Lac objects (HBLs). The Imaging X-ray Polarimetry Explorer (IXPE) scheduled to launch in 2021 has the capability to probe the evolution of magnetic field in HBLs, examining the magnetic reconnection scenario for the HBL flares. In this paper, we make the first attempt to self-consistently predict HBL X-ray polarization signatures arising from relativistic magnetic reconnection via combined particle-in-cell and polarized radiation transfer simulations. Here, we find that although the intrinsic optical and X-ray polarization degrees are similar on average, the X-ray polarization is much more variable in both the polarization degree and angle (PD and PA). Given the sensitivity of the IXPE, it may obtain one to a few polarization data points for one flaring event of nearby bright HBLs Mrk 421 and 501. However, it may not fully resolve the highly variable X-ray polarization. Due to temporal depolarization, where the integration of photons with variable polarization states over a finite period of time can lower the detected PD, the measured X-ray PD can be considerably lower than the optical counterpart or even undetectable. The lower X-ray PD than the optical thus can be a characteristic signature of relativistic magnetic reconnection. For very bright flares where the X-ray polarization is well resolved, relativistic magnetic reconnection predicts smooth X-ray PA swings, which originate from large plasmoid mergers in the reconnection region.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Aircraft in-situ measurements from SOCRATES constrain the anthropogenic perturbations of cloud droplet number

Aerosol-cloud interactions (ACI) in warm clouds alter reflected shortwave radiation by influencing cloud microphysical and macrophysical properties. The variable of state controlling ACI is the cloud droplet number concentration (N d ). Here, we examine the perturbations in N d due to anthropogenic aerosols (ΔN d, PD-PI ) using a perturbed parameter ensemble (PPE) hosted in the sixth Community Atmosphere Model (CAM6). Surrogate models are created for the CAM6 PPE outputs and are used to generate 1 million model variants of CAM6 by sampling 45 sources of parameter uncertainty. The range of uncertain physical parameters related to ACI are constrained with observations of aerosol and cloud properties from SOCRATES. The likely range of uncertain parameters and the associated range of ΔN d, PD-PI are more strongly constrained with observations of N d relative to observations of cloud condensation nuclei. We conduct sensitivity tests of how constraints on ΔN d, PD-PI are affected by systematic uncertainties in observations and our limitations in our surrogate models created for CAM6 PPE outputs. Based on this, we provide guidance on the impact of reducing systematic uncertainty in airborne microphysical observations and in surrogate models.

Song, Ci [Univ. of Wyoming, Laramie, WY (United St↗
DOE OSTI2022

An evaluation of the E3SMv1 Arctic ocean and sea-ice regionally refined model

The Energy Exascale Earth System Model (E3SM) is a state-of-the-science Earth system model (ESM) with the ability to focus horizontal resolution of its multiple components in specific areas. Regionally refined global ESMs are motivated by the need to explicitly resolve, rather than parameterize, relevant physics within the regions of refined resolution, while offering significant computational cost savings relative to the respective cost of configurations with high-resolution (HR) everywhere on the globe. In this paper, we document results from the first Arctic regionally refined E3SM configuration for the ocean and sea-ice components (E3SM-Arctic-OSI), while employing data-based atmosphere, land, and hydrology components. Our aim is an improved representation of the Arctic coupled ocean and sea-ice state, its variability and trends, and the exchanges of mass and property fluxes between the Arctic and the sub-Arctic. We find that E3SM-Arctic-OSI increases the realism of simulated Arctic ocean and sea-ice conditions compared to a similar low-resolution E3SM simulation without the Arctic regional refinement in ocean and sea-ice components (E3SM-LR-OSI). In particular, exchanges through the main Arctic gateways are greatly improved with respect to E3SM-LR-OSI. Other aspects, such as the Arctic freshwater content variability and sea-ice trends, are also satisfactorily simulated. Yet, other features, such as the upper-ocean stratification and the sea-ice thickness distribution, need further improvements, involving either more advanced parameterizations, model tuning, or additional grid refinements. Overall, E3SM-Arctic-OSI offers an improved representation of the Arctic system relative to E3SM-LR-OSI, at a fraction (15 %) of the computational cost of comparable global high-resolution configurations, while permitting exchanges with the lower-latitude oceans that cannot be directly accounted for in Arctic regional models.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Controllability of nonlinear systems.

Discussion of the controllability of nonlinear systems described by the equation dx/dt - F(x,u). Concepts formulated by Chow (1939) and Lobry (1970) are applied to establish criteria for F and its derivatives to obtain qualitative information on sets which can be obtained from x which denotes a variable of state in an arbitrary, real, analytical manifold. It is shown that controllability implies strong accessibility for a large class of manifolds including Euclidean spaces.-

Sussmann, H. J.↗
NASA NTRS1974

Time response simulation of the 1975 Viking Orbiter digital tape recorder

The objective of the present study was to verify and understand in depth the performance of the speed control (frequency loop) servo of the 1975 Viking Orbiter (VO75) digital tape recorder (DTR). The time response method employed is written in the continuous system simulation language (CSSL) for the Univac 1108 computer system. In order to demonstrate the power and flexibility of the graphic interactive simulation program, four aspects of system dynamics are interactively adjusted to arrive at a number of stable system configurations that have significantly different tape transport and/or summing amplifier gain, larger static/dynamic Coulomb friction, and different system lag than envisioned in the nominal design by linear methods. Work is currently underway to derive a new higher-order DST transfer function and to simulate the servo using state-space variable techniques.

Mukhopadhyay, A. K.↗
NASA NTRS1982

Estimates of software size from state machine designs

The length, or size (in number of Source Lines of Code) of programs represented as state machines, it is demonstrated, can be reliably estimated in terms of the number of internal state machine variables.

Britcher, R. N.↗