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Progress Report on the Nevada Play Fairway Project: Integrated Geological, Geochemical, and Geophysical Analyses of Possible New Geothermal Systems in the Great Basin Region

The Great Basin region of the western USA is capable of producing much greater amounts of geothermal energy than the current ~670 MW from ~25 power plants. Most geothermal resources in this region are blind, and thus the favorable characteristics for geothermal activity must be synthesized and methodologies need to be developed to discover new commercial-grade systems. In the Nevada play fairway project, nine geologic, geochemical, and geophysical parameters were synthesized to produce a new detailed geothermal potential map of 96,000 km2 from west-central to eastern Nevada. These parameters were grouped into subsets and individually weighted to delineate rankings for local permeability, regional permeability, and heat, which collectively defined geothermal play fairways (i.e., most likely locations for significant geothermal fluid flow). This work is aimed at reducing the risks in geothermal exploration and therefore facilitating discovery of new commercial-grade systems in blind settings, as well as in areas with surface expressions of geothermal activity. Twenty-four highly prospective areas, including both known undeveloped systems and previously undiscovered potential blind systems, were identified across the region for further analysis. Five of the most promising sites have been selected for detailed studies: Granite Springs Valley, Sou Hills, southern Gabbs Valley, Crescent Valley, and Steptoe Valley. Multiple techniques, including detailed geologic mapping, shallow temperature surveys, detailed gravity surveys, LiDAR, geochemical studies, seismic reflection analysis, and 3D modeling, are now being employed in these areas. The ultimate goal of these detailed studies is to determine the most likely areas for high permeability thermal fluids such that potential drill sites can be targeted. Potential new blind systems discovered in this project include southern Gabbs Valley and Granite Springs Valley currently undergoing detailed study, as well as step-overs in the Dun Glen area and along the west flank of the Humboldt Range.

15 GEOTHERMAL ENERGY↗

Discovering Geothermal Systems in the Great Basin Region: An Integrated Geologic, Geochemical, and Geophysical Approach for Establishing Geothermal Play Fairways

The Great Basin currently hosts ~24 geothermal power plants with more than 600 MW of capacity, but estimates suggest that the region is capable of producing much greater amounts of geothermal energy. Recent studies indicate that a combination of geological, geochemical, and geophysical features characterize the most robust geothermal systems. Considering that most of the geothermal resources in this region are blind, it is imperative that the favorable characteristics for geothermal activity be synthesized and techniques perfected for the discovery of new viable systems. We therefore utilized a multi-disciplinary approach and synthesized 9 geologic, geochemical, and geophysical parameters to produce a new detailed geothermal play fairway map of a large transect across the Great Basin region (96,000 km2) from west-central to eastern Nevada, with the primary objective of facilitating discovery of commercial-grade, blind geothermal fields (i.e. systems with no surface hot springs or fumaroles). Our analysis included: 1) structural settings (i.e., patterns of faulting), 2) age of recent faulting, 3) slip rates on recent faults, 4) regional-scale strain rates, 5) the tendency of faults to slip or dilate based on their orientation in the regional stress field, 6) earthquake density, 7) gravity data, 8) temperature at 3 km depth, and 9) geochemistry from springs and wells. These parameters were grouped into subsets to delineate rankings for local permeability, regional permeability, and heat, which collectively defined the geothermal play fairways (i.e., most likely locations for significant geothermal fluid flow). A major challenge was developing appropriate weightings of individual data types to best predict permeability and overall geothermal potential. Rigorous statistical methods, utilizing 34 benchmarks of known relatively high-temperature (>130°C) geothermal systems in the region, were employed to determine the hierarchal weights of each parameter. The new geothermal potential maps will help to reduce the risks in prospecting for new geothermal systems throughout the region.

15 GEOTHERMAL ENERGY↗

Discovery of a Blind Geothermal System in Southern Gabbs Valley, Western Nevada, through Application of the Play Fairway Analysis at Multiple Scales

The Great Basin region is capable of generating much greater amounts of geothermal energy than currently produced. Most geothermal resources in this region are blind, and thus favorable characteristics for geothermal activity must be synthesized and methodologies developed to discover new commercial-grade systems. The geothermal play fairway concept involves integration of multiple parameters indicative of geothermal activity to identify promising areas for new development. In the Nevada play fairway project, geologic, geochemical, and geophysical parameters were initially synthesized to produce a new geothermal potential map of 96,000 km2. Southern Gabbs Valley in western Nevada is a particularly promising site selected for detailed study. It contains favorable structural settings, including Quaternary fault intersections and a displacement transfer zone. Geologic, geophysical, and geochemical techniques were employed to define the most likely sites for high permeability and select targets for temperature-gradient holes. Permeability models were revised to reflect results of detailed analyses and generate new detailed play fairway maps. The most promising site lies in an area of multiple fault intersections in a broader displacement transfer zone directly north of the Petrified Springs dextral fault, as revealed by gravity, magnetic, and MT data. A 2-m temperature anomaly and warm temperature gradient wells (~120oC at ~150 m depth) confirm the presence of a geothermal system and provide initial validation of the play fairway methodology. The system is blind, with no surface hot springs, fumaroles, or paleo-geothermal deposits. Lessons learned in the detailed studies include: 1) initially identified sites commonly include multiple favorable settings at a finer scale; 2) promising sites in Cenozoic basins cannot be recognized without detailed geophysical surveys; and 3) play fairway analysis is critical at multiple scales.

15 GEOTHERMAL ENERGY↗

Regional quantitative play fairway analysis: methodology global examples and application for the East African Rift system

Most volcanic arcs and active rifts around the world host producing geothermal systems. Many undiscovered and/or undeveloped systems remain in each of these areas, including magmatic-heated systems, amagmatic extension-related systems, and blind resources lacking active surface manifestations in both types of settings. However, not all volcanic centers or extensional terranes have the same geothermal potential. For example, even when high heat flow is present, permeability is commonly a limiting factor to resource development. A tool recently adapted for the geothermal industry is play fairway analysis, which calculates the regional probability of power-capable resources based on the spatial coincidence of key geologic conditions. In a geothermal setting, these key geologic conditions are heat, permeability, and fluids. Higher enthalpy systems also benefit from suitable cap rock. These parameters can be assessed through multiple geologic, geochemical, and geophysical data sets and integrated quantitatively to produce a single geothermal play fairway map. Potential input data sets include but are not limited to: 1) tectonic setting; 2) structural setting; 3) faults attributed by recency of rupture and slip rate; 3) geodetic crustal stain models; 5) gravity; 6) earthquake distribution; 7) thermal models; 8) geochemistry from springs, wells, and fumaroles; 9) temperature from springs, wells, and fumaroles; 10) fumarole size and type; and 11) age of volcanism. Recent play fairway studies have been completed for volcanic arcs and the dominantly amagmatic, extensional Great Basin region, USA, but have yet to be applied to the East African Rift System (EARS). Previous estimates of total geothermal resource capacity in the EARS is ~20 GWe, but only three areas are currently in production as of 2015: Olkaria and Eburru in Kenya, and Aluto-Langano in Ethiopia for a total installed capacity of <0.7 GWe. Many more volcanic centers host potential resources. In addition, amagmatic and/or blind systems also have potential in the EARS. Play fairway analysis can highlight regions most prospective for geothermal resource development, help identify locations prospective for undiscovered resources, prioritize overall exploration and development efforts, and refine estimates for total undeveloped resource potential.

15 GEOTHERMAL ENERGY↗

A play fairway approach to geothermal exploration in Crescent Valley, Nevada

Crescent Valley received one of the highest favorability scores in phase I of the DOE-sponsored Nevada play fairway analysis project and was therefore selected for detailed study in phase II. As part of the detailed study, geological, geochemical, and geophysical data were collected, synthesized, and analyzed to identify favorable structural settings for geothermal fluids in the basin. A total of eight favorable structural settings were identified. Two host known geothermal systems, and six could potentially host blind geothermal systems. In phase II a predictive geothermal potential model was conducted for each favorable structural setting. The highest-ranking areas in Crescent Valley are in the Dann Hot Springs step-over (relay ramp), followed by the two northern step-overs along the Cortez Mountains front, as well as a fault intersection at Hot Springs Point.

15 GEOTHERMAL ENERGY↗

Nonlinear controller for nonlinear wave energy converters

The present invention is directed to a nonlinear controller for nonlinear wave energy converters (WECs). As an example of the invention, a nonlinear dynamic model is developed for a geometrically right-circular cylinder WEC design for the heave-only motion, or a single degree-of-freedom (DOF). The linear stiffness term is replaced by a nonlinear cubic hardening spring term to demonstrate the performance of a nonlinear WEC as compared to an optimized linear WEC. By exploiting the nonlinear physics in the nonlinear controller, equivalent power and energy capture, as well as simplified operational performance is observed for the nonlinear cubic hardening spring controller when compared to an optimized linear controller.

Wilson, David G.↗

A Viable Path Forward to Carbon Capture and Storage in Wyoming, USA

The State of Wyoming, USA, benefits from favorable geologic, regulatory, and infrastructure attributes that promote efficient and sustainable carbon capture and storage (CCS). Two research sites in Wyoming exhibit high potential for the underground geologic storage of greater than 50 million metric tons of carbon dioxide (CO 2 ) over 25 years. Funded by the U.S. Department of Energy’s (DOE) Carbon Storage Assurance and Facility Enterprise (DOE CarbonSAFE) Phase I prefeasibility initiative, studies of both sites indicate promising capture, transport, utilization, and storage characteristics. The Dry Fork site is located near Gillette, in northeast Wyoming. Four storage reservoir/seal pairs have been identified at the Dry Fork site that provide excellent prospects for stacked storage of CO 2 . All four reservoirs lie at sufficient depths to maintain supercritical CO 2 and all four seals exhibit favorable characteristics for stratigraphic confinement. The reservoir with the highest expected significance is the Pennsylvanian/Permian Minnelusa Formation, which consists of near-shore dunes and shoreline sands, as well as shale and carbonate layers. The Minnelusa resides at a depth of ~2,900 m below the land surface and is ~45 m thick in the study area. Average porosity for samples from core within 10 km of the study area is 9%, with permeability values as high as 169 mD (n=6). The Permian Opeche Formation seals the Minnelusa and consists of redbed shales with minor fine-grained siltstones and evaporite deposits. Entry pressures as high as ~4700 psia were measured by mercury injection capillary pressure (MICP) analysis on core samples from the Opeche. A CarbonSAFE Phase II feasibility proposal at the Dry Fork site has recently been selected by DOE for negotiation leading to award. The second proposed site is located at the Rock Springs Uplift (RSU) in southwest Wyoming. Four reservoir/seal pairs have been studied at the RSU, all of which present promising geologic attributes for the stacked storage of CO 2 . The two deepest reservoirs (Mississippian Madison Limestone and Pennsylvanian/Permian Weber Formation) and their seals were studied previously under the auspices of the Wyoming Carbon Underground Storage Project (WY-CUSP), which was funded by DOE and the State of Wyoming. For the more recent CarbonSAFE initiative, two shallower reservoir/seal pairs were studied in detail. The highest priority of these reservoirs is the Triassic/Jurassic Nugget Formation, which consists of eolian sands and minor fluvial and interdune deposits. The Nugget lies at a depth of ~2,800 m and is ~140 m thick in the study area. Average measured porosity for samples from core within 40 km of the study site is 9%, with permeability values as high as 91 mD (n=10). The Nugget is sealed by the overlying Jurassic Gypsum Spring and Morrison Formations, as well as a thick (~1,700 m) regional Upper Cretaceous seal that includes shales from multiple geologic units. Entry pressures as high as 1120 psia were measured by MICP for shales within this regional confining unit. Overall, the State of Wyoming provides an advantageous climate to develop sustainable integrated CCS projects based on the following considerations: (1) well-characterized and favorable geology; (2) some of the largest deposits of economically recoverable coal in the USA; (3) an existing CO 2 -enhanced oil recovery industry, including CO 2 pipeline infrastructure; (4) supportive commercial enterprises, including utilities and the oil and gas industry; (5) supportive policymakers; (6) a favorable legal and regulatory environment; (7) proximity to carbon-constrained markets such as the State of California; (8) large CO 2 emission sources, including coal-fired power plants; and (9) backing for carbon capture, storage, and management related research and development, specifically implementation of the Integrated Test Center at Dry Fork Station, which is hosting the coal-track of the NRG/COSIA Carbon XPrize® competition.

Phillips, Erin↗

Geothermal play-fairway analysis of Washington State prospects

Herein, analysis of existing geologic, geophysical, and geochemical data revealed areas with elevated heat and permeability, defining three promising plays along the central axis of the magmatic arc of Washington State: Mount St. Helens, Wind River valley, and the southeast flank of Mount Baker. These areas are geothermal ‘fairways’, or locations with high geothermal resource potential based on modeling. This project applies innovative data analyses (Poly3D) in conjunction with methods proven in previous geothermal favorability studies (ArcGIS and MATLAB) to extract new value from existing public data. Heat and permeability potential models for each play are weighted using the Analytical Hierarchy Process, and combined to map geothermal resource potential and locations for further data collection at each site. Heat potential is based on: (1) temperature gradients, (2) volcanic vents, (3) Quaternary intrusive rocks, (4) spring temperature, and (5) spring geothermometry. Permeability potential is based on: (1) slip and (2) dilation tendency on mapped and seismic faults (3) maximum shear strain rate, and (4) dilatational strain rate at the surface, (5) modeled fault displacement distribution, and (6) displacement gradient, (7) shear, and (8) tensile fracture density, and (9) local geology and geophysical data. This information is vital for revealing the small scale heat and permeability potential of each study area, locating areas of undiscovered or untapped resources, and reducing the risk and cost involved in greenfield exploration and development. Preliminary analysis of the three play areas shows promise for geothermal development. Uncertainty modeling is underway and the results will guide future exploration plans.

15 GEOTHERMAL ENERGY↗

Self-governing bearing assembly

A self-governing bearing assembly is disclosed. The self-governing bearing assembly includes a stator and a rotor. The stator includes a brake contacting surface. The stator is one of an outer ring and an inner ring. The rotor includes the other of the outer ring and the inner ring, brake pads, and a circular spring. The brake pads are positioned radially from the brake contacting surface and adapted to rotate with the other of the outer ring and the inner ring. Each of the brake pads includes a pad retention slot. The circular spring is positioned within the pad retention slot of each of the brake pads. The bearing elements are axially aligned with a first bearing portion of the stator and a second bearing portion of the rotor. The bearing elements are adapted to rotationally support the rotor relative to the stator.

Bolton, Justin T.↗

Remediation of Uranium Impacted Sediments in a Watercourse - 12486

In 2009, remediation was initiated for a non-operational fuel cycle facility previously used for government contract work. Between 2009 and the spring of 2011, remediation efforts were focused on demolition of contaminated buildings and removal of contaminated soil. In the late spring of 2011, the last phase of remediation commenced involving the removal of contaminated sediments from portions of a 1,200 meter long gaining stream. Planning and preparation for remediation of the stream began in 2009 with submittal of permit applications to undertake construction activities in a wetland area. The permitting process was lengthy and involved securing permits from multiple agencies. However, early and frequent communication with stakeholders played an integral role in efficiently obtaining the permit approvals. Frequent communication with stakeholders throughout the planning and remediation process also proved to be a key factor in timely completion of the project. The remediation of the stream involved the use of temporary bladder berms to divert surface water flow, water diversion piping, a sediment vacuum removal system, excavation of sediments using small front-end loaders, sediment dewatering, and waste packaging, transportation and disposal. Many safeguards were employed to protect several species of concern in the work area, water management during project activities, challenges encountered during the project, methods of Final Status Survey, and stream restoration. The planning and permitting effort for the Site Brook remediation began in May 2009 and permits were approved and in place by February 2011. The remediation and restoration of the Site Brook began in April 2011 and was completed in November 2011. The remediation of the Site Brook involved the use of temporary bladder berms to divert surface water flow, water diversion piping, a sediment vacuum removal system, excavation of sediments using small front-end loaders, sediment dewatering, and waste packaging, transportation, disposal, FSS, and restoration. Early and frequent communications with stakeholders proved to be a key factor in timely completion of the project. Challenges encountered during the remediation effort were overcome by proper planning and having preparedness procedures in place prior to executing the work. With the remediation and restoration successfully completed, the only remaining task is to monitor/maintain the restoration for 10 years. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Groundwater Remediation in a Flood plain Aquifer at Shiprock, New Mexico - 16097

The Shiprock, New Mexico, Disposal Site is the location of a former uranium and vanadium ore-processing mill that operated from 1954 to 1968. During milling years, tailings leachate and other mill-related liquids migrated into underlying sediments, resulting in the contamination of groundwater beneath the river terrace containing the mill and a nearby flood plain alluvial aquifer adjacent to the San Juan River. The US DOE Office of Legacy Management manages the site and is implementing the current groundwater remedy for the flood plain area, consisting of natural flushing supplemented by extraction of alluvial groundwater to accelerate reduction in contaminant concentrations. The alluvial aquifer contains elevated concentrations of sulfate, uranium, and nitrate derived largely from the historical eastward migration of groundwater through terrace alluvium and underlying bedrock to the flood plain. The bedrock formation beneath the entire Shiprock site is Mancos shale, which forms an escarpment that separates the terrace from the flood plain. Contamination in the flood plain alluvial aquifer is influenced by a dynamic flow system that changes seasonally and from year to year. Simulations with a flood plain flow model based on monitored groundwater levels and coincident river-surface elevations show that background groundwater flow, unaffected by remediation pumping, is characterized by distinct hydraulic conditions for three separate periods each year. During months of low river flow in winter and early spring, river losses to the aquifer create a large hypo-rheic zone in the south half of the flood plain. Simultaneously, recharge of continually flowing surface water emptying onto the north half of the flood plain from Bob Lee Wash creates divergent, radial flow from the wash outlet and diverts northwestward-migrating contaminant plumes to the northeast where they discharge to the river. Subsequent bank storage processes in May and June from high snow melt runoff change background flow directions, increasing the spread of contamination in the alluvium. From mid-summer through fall, river flows are typically similar in value to those observed prior to the onset of snow melt, but groundwater elevations in the aquifer are noticeably lower than water levels observed in winter and early spring and may induce river losses to the aquifer. Several different contaminant sources have impacted the alluvial aquifer. Much of the contamination originated as tailings leachate and raffinate wastewater that infiltrated the terrace subsurface and eventually reached the flood plain at the escarpment. Additional sources of contamination in the aquifer included discharge of mill effluent to Bob Lee Wash and a pond at the base of the escarpment, and aqueous mobilization of solid-phase contamination in the form of windblown deposits and contaminants adsorbed to alluvial sediments. The degree to which remnant, secondary-source processes, such as leaching of solid-phase deposits and discharge of terrace groundwater across the escarpment, contribute to existing contaminant plumes is uncertain. The flood plain remediation system consists of two groundwater extraction wells, pumping from two horizontal wells placed in trenches near the base of the escarpment, a sump collecting discharges from seeps in the escarpment wall, and discharge of collected water to an evaporation pond on the terrace. Flow-model simulations indicate that most contaminated areas are captured by remediation pumping, resulting in several zones of freshwater between the river and the escarpment. Despite the highly transient nature of groundwater flow beneath the flood plain and the varied contaminant sources, initiation of remediation pumping in 2003 and coordinated operation of the system's various components have successfully removed large amounts of contaminant mass and helped prevent discharge of contaminated groundwater to the river. The percentage reductions of dissolved sulfate, uranium, and nitrate mass in the aquifer estimated for the first 9 years of remediation range from 40% to 72%. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Robotic Underwater Decontamination Services for Nuclear Applications-18464

Successful Underwater Robotic Decontamination Demonstrates Dose-Saving And Outage-Shortening Technology Diakont successfully provided underwater robotic decontamination services on a North American nuclear power plant's refueling cavity and dryer-separator pool in Spring 2017 using a new tool system. Historically, nuclear plant operators have conducted cleaning and decontamination of these surfaces manually, after draining water from the space. However manual decontamination is slow, and can result in excessive personnel dose exposure. The underwater robotic decontamination services present a vast improvement over manual decontamination because it reduces personnel dose exposure, reduces radwaste, doesn't impact plant chemistry, and doesn't risk inadvertently spreading contamination. Also the new decontamination method avoids the risk of personnel injury and component damage associated with hydrolasing. And by performing the decontamination robotically while the cavities are flooded, in many cases the critical path outage schedule can be shortened. Able to decontaminate horizontal, vertical, and curved surfaces, the decontamination tools easily navigate to areas within flooded cavities that are inaccessible to previous solutions, performing decontamination in parallel to other activities including fuel movement. Also, unlike other legacy solutions, the new tools do not require continuous use of an overhead crane or other method of suspension while performing the decontamination activities. The ROV-type decontamination tool attaches and drives along the cavity and component surfaces using a high-force, no-flow vortex generator, even in the presence of Residual Heat Removal (RHR) or shutdown cooling flow. Efficient, effective cleaning is performed using a rugged brushing action to detach the crud, while vacuuming it away at high flow rates to a submerged filter. At the Spring 2017 refueling outage, the decontamination services with the new methodology were so effective that no additional manual cavity decontamination was required after drain-down. Using the tool's ability to swim, attach, and crawl, field technicians decontaminated the majority of the surfaces designated by the plant operator. Preliminary surveys indicated that all contamination levels were reduced to <50 K dpm/100 cm{sup 2}, helping the utility meet their INPO/Industry collective radiation exposure goals. The new cleaning and decontamination services are ideal for servicing various underwater areas within nuclear power plants such as refueling cavities, BWR-6 drywell heads, spent fuel pools, cask loading pools and fuel transfer canals. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Occurrence of Radiological Contamination in Urban Parks Established over Former Landfill Sites - 19433

In 2005, the National Park Service was notified that elevated radiation levels were detected at Great Kills Park during a baseline radiological mapping effort conducted by the Counter Terrorism Bureau of the New York City Police Department and the United States Department of Energy. Great Kills Park is in the Staten Island Unit of Gateway National Recreation Area. A records search determined that approximately 1.1 x 10{sup 6} square meters (280 acres) of the park was established over an area in which the New York City Department of Sanitation placed approximately 1.2 x 10{sup 7} cubic meters (15.1 million cubic yards) of waste fill from 1944 to 1948. Since 2005, a series of response actions and investigations were conducted on behalf of the National Park Service to mitigate risk to human health and the environment and to determine the nature of radiological contamination at Great Kills Park. The findings support that radiological contamination is related to certain components of waste fill, including incinerator residue from both on and offsite incinerators, coal ash from the historical use of coal-fired boilers for heating, and incidental radiological artifacts in the waste fill due to their historical use and subsequent disposal. A majority of the radiological artifacts were determined to contain Ra-226 and included radioluminescent markers, radium buttons, radium paint containers, and brachytherapy devices. The National Park Service is currently performing a Remedial Investigation for the waste-filled area of Great Kills Park under the Comprehensive Environmental Response, Compensation and Liability Act. Several other Parks in Gateway National Recreation Area were established in areas with a similar history to Great Kills Park, and overlie waste fill historically placed during landfilling operations. Recently, radiological surveys were performed over limited portions of Spring Creek Park in the Jamaica Bay Unit of Gateway National Recreation Area. These surveys identified several locations with gamma radiation levels above the ambient level, several of which were attributable to radiological artifacts similar in nature to those recovered at Great Kills Park. Ongoing investigations at Great Kills Park and the recent findings at Spring Creek Park suggest that radiological contamination may be associated with historical landfilling practices that were common prior to the regulation and control of radioactive materials. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Investigation of Radiological Contamination at Parks in the Gateway National Recreation Area - 20350

In 2005, the National Park Service was notified that elevated radiation levels were detected at Great Kills Park during a baseline radiological mapping effort conducted by the Counter Terrorism Bureau of the New York City Police Department and the United States Department of Energy. Great Kills Park is in the Staten Island Unit of the Gateway National Recreation Area. A records search determined that approximately 280 acres of the park was established over an area in which the New York City Department of Sanitation placed approximately 15.1 million cubic yards of waste fill from 1944 to 1948. Since 2005, a series of response actions and investigations were conducted on behalf of the National Park Service to mitigate risk to human health and the environment and to determine the nature of radiological contamination at Great Kills Park. The findings support that radiological contamination is related to certain components of waste fill, including incinerator residue from both on and offsite incinerators, coal ash from the historical use of coal-fired boilers for heating, and incidental radiological artifacts in the waste fill due to their historical use and subsequent disposal. A majority of the radiological artifacts were determined to contain radium-226 and included radioluminescent markers, radium impregnated switch board buttons, radium paint containers, and brachytherapy devices. The National Park Service has several other Parks in the Gateway National Recreation Area that were established in areas with a similar history to Great Kills Park, and overlie waste fill historically placed during landfilling operations, including Spring Creek Park and Dead Horse Bay. Over the last year, the National Park Service has performed additional radiological investigations at Great Kills Park as part of the ongoing Remedial Investigation under the Comprehensive Environmental Response, Compensation, and Liability Act. In addition, preliminary radiological investigations were performed at Spring Creek Park and Dead Horse Bay Park in the Jamaica Bay Unit of Gateway National Recreation Area. These investigation activities identified gamma radiation levels above the ambient level, several of which were attributable to radiological artifacts similar in nature to those recovered at Great Kills Park. Ongoing investigations at Parks in the Gateway National Recreation Area support an association between radiological contamination and historical landfilling practices that were common prior to the regulation and control of radioactive materials. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Circumvention of safety related equipment at nuclear fuel services, Inc. - 14570

On June 17, 2014, at Nuclear Fuel Services, Inc. (NFS), an employee was observed improperly operating two (2) spring return (i.e., spring closed) valves identified as Safety Related Equipment (SRE). These valves were also identified as Items Relied on for Safety (IROFS). The valves were important for both Nuclear Criticality Safety (NCS) and Chemical Safety purposes. The valves were observed to be 'propped' in the open position, thereby circumventing the intended safety function of the valves. The event was reported to the NRC Operations Center on June 18, 2014 (Event no. 50208); and, NFS' investigation concluded that the cause (of the event) was due to a willful act by a Nuclear Process Operator. In addition, when reviewing the event for NRC reportability, there was an organizational focus on NCS accident sequences with limited consideration of other aspects of the Integrated Safety Analysis (ISA). In other words, when determining reportability, the performance requirements for NCS accident sequences were reviewed and determined to be satisfied; however, the chemical safety accident sequences had not been considered during this review. The initial event and the reportability issues were entered into NFS' Corrective Action Program (CAP) and investigated. The investigation also included human performance and safety culture implications. This paper summarizes the circumstances surrounding the event and discusses the lessons learned as a result of the event investigation and review. (authors)

42 ENGINEERING↗

Experimental and Computational Insights into the Structural Dynamics of the Fc Fragment of IgG1 Subtype from Biosimilar VEGF‐Trap

The constant fragment (Fc) of the immunoglobulin G1 (IgG1) subtype is increasingly recognized as a crucial scaffold in the development of advanced therapeutics due to its enhanced specificity, efficacy, and extended half‐life. A prime example is VEGF‐Trap (Aflibercept), a recombinant fusion protein that merges the Fc region of the IgG1 subtype with the binding domains of vascular endothelial growth factor receptors (VEGFR)‐1 and VEGFR‐2. The Fc region's role in N‐glycosylation is particularly important, as it significantly influences protein stability. Herein, the first near‐physiological temperature structures of the N‐glycan‐bound Fc fragment of IgG1 subtype from a biosimilar VEGF‐Trap are presented, determined using the SPring‐8 Angstrom Compact free electron LAser (SACLA) and the Turkish Light Source (Turkish DeLight). Comparative analysis with cryogenic structures, including existing data, reveals alternate conformations within the glycan‐binding pocket. Furthermore, molecular dynamics simulations indicate the presence of a high degree of structural plasticity, explaining how the protein adapts its structure through conformational changes. The observed structural fluctuations/conformational changes demonstrate the effect of N‐glycans on protein stability. These findings offer new insights into the molecular basis of Fc‐mediated functions and provide valuable information for the design of next‐generation therapeutics.

60 APPLIED LIFE SCIENCES↗

PoroTomo: BRAD and BRDY GPS Station RINEX Files - March 26, 2015

This dataset provides links to daily RINEX files for two GPS stations at Brady's Hot Springs as of March 26, 2014. The data is formatted as compressed GNSS RINEX observation files, accessible through formatted CSV files, as well as in links to the complete daily time series data. The CSV files serve as a directory for navigating to the correct FTP locations to access the desired data. Users are advised to cross-reference the filenames and station identifiers (BRAD or BRDY) when downloading files. The files were generated by the UNAVCO GSAC Repository, and all data-related timestamps and units are specified within the CSV structure. Additional Resources, including the original database for direct downloads and links to the previous and following set of RINEX data (as of 12-2-14 and 9-17-2015, respectively), are also provided.

15 GEOTHERMAL ENERGY↗

An experimental study of the role of subsurface plumbing on geothermal discharge

In order to better understand the diverse discharge styles and eruption intervals observed at geothermal features, we performed here three series of laboratory experiments with differing plumbing geometries. A single, straight conduit that connects a hot water bath (flask) to a vent (funnel) can originate geyser-like periodic eruptions, continuous discharge like a boiling spring, and fumarole-like steam discharge, depending on the conduit length and radius. The balance between the heat loss from the conduit walls and the heat supplied from the bottom determines whether and where water can condense which in turn controls discharge style. Next, we connected the conduit to a cold water reservoir through a branch, simulating the inflow from an external water source. Colder water located at a higher elevation than a branching point can flow into the conduit to stop the boiling in the flask, controlling the periodicity of the eruption. When an additional branch is connected to a second cold water reservoir, the two cold reservoirs can interact. Our experiments show that branching allows new processes to occur, such as recharge of colder water and escape of steam from side channels, leading to greater variation in discharge styles and eruption intervals. This model is consistent with the fact that eruption duration is not controlled by emptying reservoirs. We show how differences in plumbing geometries can explain various discharge styles and eruption intervals observed in El Tatio, Chile, and Yellowstone, USA.

58 GEOSCIENCES↗