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At least 1,081 records · Page 60

Unraveling the advances of trace doping engineering for potassium ion battery anodes via tomography

Doping have been considered as a prominent strategy to stabilize crystal structure of battery materials during the insertion and removal of alkali ions. The instructive knowledge and experience acquired from doping strategies predominate in cathode materials, but doping principle in anodes remains unclear. Here, we demonstrate that trace element doping enables stable conversion-reaction and ensures structural integrity for potassium ion battery (PIB) anodes. With a synergistic combination of X-ray tomography, structural probes, and charge reconfiguration, we encode the physical origins and structural evolution of electro-chemo-mechanical degradation in PIB anodes. By the multiple ion transport pathways created by the orderly hierarchical pores from “surface to bulk” and the homogeneous charge distribution governed in doped nanodomains, the anisotropic expansion can be significantly relieved with trace isoelectronic element doping into the host lattice, maintaining particle mechanical integrity. Our work presents a close relationship between doping chemistry and mechanical reliability, projecting a new pathway to reengineering electrode materials for next-generation energy storage.

25 ENERGY STORAGE↗

Discovery of a z ∼ 0.8 ultra steep spectrum radio halo in the MeerKAT-South Pole Telescope Survey

Radio haloes are diffuse synchrotron sources that trace the turbulent intracluster medium (ICM) of galaxy clusters. However, their origin remains unknown. Two main formation models have been proposed: the hadronic model, in which relativistic electrons are continuously injected by cosmic-ray protons; and the leptonic turbulent re-acceleration model, where cluster mergers re-energize electrons in situ. A key discriminant between the two models would be the existence of ultra-steep spectrum radio haloes (USSRHs), which can only be produced through turbulent re-acceleration. Here, we report the discovery of an USSRH in the galaxy cluster SPT-CLJ2337–5942 at redshift $z = 0.78$ in the MeerKAT-South Pole Telescope 100 deg$^2$ UHF (0.58–1.09 GHz) survey. This discovery is noteworthy for two primary reasons: it is the highest redshift USSRH system to date; and the close correspondence of the radio emission with the thermal ICM as traced by Chandra X-ray observations, further supporting the leptonic re-acceleration model. The halo is underluminous for its mass, consistent with a minor merger origin, which produces steep-spectrum, lower luminosity haloes. This result demonstrates the power of wide-field, high-fidelity, low-frequency ($\lesssim 1$ GHz) surveys like the MeerKAT-SPT 100 deg$^2$ programme to probe the origin and evolution of radio haloes over cosmic time, ahead of the Square Kilometre Array.

X-rays: galaxies↗

Diffuse X-ray Emission from M101

The total 0.45-2.0 keV luminosity of M101 is 3.1 x 10(exp 39) ergs/s, of which 2.2 x 10(exp 39) ergs/s is due to diffuse emission. Of the diffuse emission, no more than 6% can be due to unresolved point sources such as X-ray binaries, and approx. 11% is due to dwarf stars. The diffuse emission traces the spiral arms and is roughly correlated with the H alpha and FUV (far ultraviolet) emission. The radial distribution closely follows the optical profile. The bulk of the diffuse emission is characterized by a two thermal component spectrum with kT = 0.20,0.75 keV, and the ratios of the emission measures of the two components is roughly constant as a function of both radius and surface brightness. The softer component has a sufficiently large covering factor that the bulk of the emission is likely extra-planar. We find no evidence of an extended axisymmetric X-ray halo, suggesting that any such halo has a strength much smaller than current predictions.

Kuntz, K. D.↗

An X-ray survey of hot white dwarf stars - Evidence for a m(He)/n(H) versus Teff correlation

Observations of 13 white dwarf and subdwarf stars using the Einstein Observatory High Resolution Image are reported. Included are stars of classes DA, DB, DAV, sDO, and sDB, with optically determined effective temperatures in the range 10,000-60,000 K. X-ray emission was detected from two of the 13: the very hot (55,000 K) DA1 star WD 2309 + 105 (= EG 233), with a count rate one-fifth that of HZ 43, and the relatively cool (26,000 K) DA3 star WD 1052 - 273 (=GD 125). The effective temperatures determined from ultraviolet and optical observations were used to place limits on the He content of the white dwarf photospheres, presuming that trace photospheric He is the missing opacity source which quenches the thermal X-rays in these stars. When presently obtained results were combined with those available from the literature evidence was found for a correlation between Teff and n(He)/n(H), in which HZ 43 is a conspicuous exception to the general trend. Both this correlation and the exceptional behavior of HZ 43 are qualitatively accounted for by a radiative acceleration model, in which the rate of upward movement of the He is a function of temperature and surface gravity

Petre, R.↗

Simultaneous observations of the blazar PKS 2155-304 from ultra-violet to TeV energies

Here we report the results of the first ever contemporaneous multi-wavelength observation campaign on the BL Lac object PKS 2155−304 involving Swift , NuSTAR , Fermi -LAT, and H.E.S.S. The use of these instruments allows us to cover a broad energy range, which is important for disentangling the different radiative mechanisms. The source, observed from June 2013 to October 2013, was found in a low flux state with respect to previous observations but exhibited highly significant flux variability in the X-rays. The high-energy end of the synchrotron spectrum can be traced up to 40 keV without significant contamination by high-energy emission. A one-zone synchrotron self-Compton model was used to reproduce the broadband flux of the source for all the observations presented here but failed for previous observations made in April 2013. A lepto-hadronic solution was then explored to explain these earlier observational results.

79 ASTRONOMY AND ASTROPHYSICS↗

In search of stratospheric bromine oxide

The Imaging Spectrometric Observatory (ISO) is capable of recording spectra in the wavelength range of 200 to 12000 Angstroms. Data from a recent Spacelab 1 ATLAS mission has imaged the terrestrial airglow at tangent ray heights of 90 and 150 km. These data contain information about trace atmospheric constituents such as bromine oxide (BrO), hydroxyl (OH), and chlorine dioxide (OClO). The abundances of these species are critical to stratospheric models of catalytic ozone destruction. Heretofore, very few observations were made especially for BrO. Software was developed to purge unwanted solar features from the airglow spectra. The next step is a measure of the strength of the emission features for BrO. The final analysis will yield the scale height of this important compound.

Lestrade, John Patrick↗

Environmental control and life support systems

Viewgraphs on Environmental Control and Life Support Systems (ECLSS) for Space Station Freedom are presented. Topics covered include: crew generated wastes processing and reclamation; water reclamation - pre- and post-treatment; simplified waste water processing; improved trace contaminant removal; and real time microbial analysis.

Ray, Charles D.↗

The cool-star spectral catalog: A uniform collection of IUE SWP-LOs

Over the past decade and a half of its operations, the International Ultraviolet Explorer has recorded low-dispersion spectrograms in the 1150-2000 A interval of more than 800 stars of late spectral type (F-M). The sub-2000 A region contains a number of emission lines that are key diagnostics of physical conditions in the high-excitation chromospheres and subcoronal 'transition zones' of such stars. Many of the sources have been observed a number of times, and the available collection of SWP-LO exposures in the IUE Archives exceeds 4,000. With support from the Astrophysics Data Program, we have assembled the archival material into a catalog of IUE far-UV fluxes of late-type stars. In order to ensure uniform processing of the spectra, we: (1) photometrically corrected the raw vidicon images with a custom version of the 1985 SWP ITF; (2) identified and eliminated, sharp cosmic-ray 'hits' by means of a spatial filter; (3) extracted the spectral traces with the 'optimal' (weighted-slit) strategy; and (4) calibrated them against a well-characterized reference source, the DA white dwarf G191-B2B. Our approach is similar to that adopted by the IUE Project for its 'Final Archive', but our implementation is specialized to the case of chromospheric emission-line sources. We measured the resulting SWP-LO spectra using a semi-autonomous algorithm that establishes a smooth continuum by numerical filtering, and then fits the significant emissions (or absorptions) by means of a constrained Bevington-type multiple-Gaussian procedure. The algorithm assigns errors to the fitted fluxes - or upper limits in the absence of a significant detection - according to a model based on careful measurements of the noise properties of the IUE's intensified SEC cameras. Here, we describe the 'visualization' strategies we adopted to ensure human-review of the semi-autonomous processing and measuring algorithms; the derivation of the noise model and the assignment of errors; and the structure of the final catalog as delivered to the Astrophysics Data System.

Ayres, T.↗

Gradients and anisotropies of high energy cosmic rays in the outer heliosphere

Two cosmic rays which pass through the same point going in opposite directions will, in the absence of scattering and inhomogeneities in the magnetic field, trace helices about adjacent flux tubes, whose centerlines are separated by one gyrodiameter. A directional anisotropy at the point suggests a difference in the number of cosmic rays loading the two flux tubes; that is, a density gradient over the baseline of a gyrodiameter. Previous studies at lower energies have shown that the cosmic ray density gradients vary in time and space. It is suggested that the radial gradient associated with solar cycle modulation is supported largely by narrow barriers which encircle the sun and propagate outward with the solar wind. If so, the anisotropy is a desirable way to detect spatial gradients, because it can be associated with the local solar wind and magnetic field conditions. Anisotropic measurements made by Cerenkov detectors on Pioneers 10 and 11 were studied. It was found that local anisotropy varies greatly, but that the long term average is consistent with the global radial gradient measured between two spacecraft over a baseline of many AU.

Fillius, W.↗

Hinode Observations of the Onset Stage of a Solar Filament Eruption

We used Hinode X-Ray Telescope (XRT) and Solar Optical Telescope (SOT) filtergraph (FG) Stokes-V magnetogram observations, to study the early onset of a solar eruption that includes an erupting filament that we observe in TRACE EUV images. The filament undergoes a slow rise for at least 20min prior to its fast eruption and strong soft X-ray (SXR) flaring; such slow rises have been previously reported, and the new Hinode data elucidate the physical processes occurring during this period. XRT images show that during the slow-rise phase, an SXR sigmoid forms from apparent reconnection low in the sheared core field traced by the filament, and there is a low-level intensity peak in both EUV and SXRs during the slow rise. MDI and SOT FG Stokes-V magnetograms show that the pre-emption filament is along a neutral line between opposing-polarity enhanced network cells, and the SOT magnetograms show that these opposing fields are flowing together and canceling for at least six hours prior to eruption. From the MDI data we measured the canceling network fields to be approx. 40 G, and we estimated that approx. 10(exp 19)Mx of flux canceled during the five hours prior to eruption; this is only approx.5% of the total flux spanned by the eruption and flare, but apparently its tether-cutting cancellation was enough to destabilize the sigmoid field holding the filament and resulted in that field's eruption.

Sterling, Alphonse C.↗

Geochemical studies of the White Breccia Boulders at North Ray Crater, Descartes region of the lunar highlands

The samples of the White Breccia Boulders obtained during the Apollo 16 mission and investigated in the reported study include an anorthositic breccia (67415), a dark matrix breccia (67435), a light matrix breccia (67455), and a large clast of dark matrix breccia (67475) taken from the 67455 boulder. The chemical analyses of bulk samples of the samples are listed in a table. A graph shows the lithophile trace element abundances. Another graph indicates the variation of Sm with Al2O3 content for samples from the White Breccia Boulders. The North Ray Crater breccias are found to be in general slightly more aluminous than breccias from the other stations at the Apollo 16 site. Analyses of eight Apollo 16 breccias cited in the literature range from 25% to 35% Al2O3. However, the North Ray Crater breccias are more clearly distinct from the other Apollo 16 breccias in their contents of lithophile trace elements.

Lindstrom, M. M.↗

Early Hinode Observations of a Solar Filament Eruption

We use Hinode X-Ray Telescope (XRT) and Solar Optical Telescope (SOT) filtergraph (FG) Stokes-V magnetogram observations to study the early onset of a solar eruption that includes an erupting filament that we observe in TRACE EUV images; this is one of the first filament eruptions seen with Hinode. The filament undergoes a slow rise for at least 30 min prior to its fast eruption and strong soft X-ray flaring, and the new Hinode data elucidate the physical processes occurring during the slow-rise period: During the slow-rise phase, a soft X-ray (SXR) sigmoid forms from apparent reconnection low in the sheared core field traced by the filament, and there is a low-level intensity peak in both EUV and SXRs during the slow rise. The SOT data show that magnetic flux cancellation occurs along the neutral line of the filament in the hours before eruption, and this likely caused the low-lying reconnection that produced the microflaring and the slow rise leading up to the eruption.

Sterling, Alphonse C.↗

Electromagnetic cascades in pulsars

The development of pair photon cascades initiated by high energy electrons above a pulsar polar cap is simulated numerically. The calculation uses the energy of the primary electron, the magnetic field strength, and the period of rotation as parameters and follows the curvature radiation emitted by the primary, the conversion of this radiation e(+) - e(-) pairs in the intense fields, and the quantized synchrotron radiation by the secondary pairs. A recursive technique allows the tracing of an indefinite number of generations using a Monte Carlo method. Gamma ray and pair spectra are calculated for cascades in different parts of the polar cap and with different acceleration models. It is found that synchrotron radiation from secondary pairs makes an important contribution to the gamma ray spectrum above 25 MeV, and that the final gamma ray and pair spectra are insensitive to the height of the accelerating region, as long as the acceleration of the primary electrons is not limited by radiation reaction.

Daugherty, J. K.↗

Fine particles in the Soufriere eruption plume

The size distributions of fine particles measured at tropospheric altitudes in the periphery of the eruption plume formed during the April 17, 1979 eruption of Soufriere Volcano and in the low-level effluents on May 15, 1979 were found to be bimodal, having peak concentrations at geometric mean diameters of 1.1 and 0.23 micrometers. Scanning electron microscopy and energy-dispersive X-ray analysis of the samples revealed an abundance of aluminum and silicon and traces of sodium, magnesium, chlorine, potassium, calcium, and iron in the large-particle mode. The submicrometer-sized particles were covered with liquid containing sulfur, assumed to be in the form of liquid sulfuric acid.

Woods, D. C.↗

Origin of Archean anorthosites - Evidence from the Bad Vermilion Lake anorthosite complex, Ontario

Studies of the petrology and geochemistry of the anorthosite complex at Bad Vermillion Lake, Canada, based on 400 samples collected in summer, 1979, are presented. Petrographic, microprobe, X-ray-fluorescence, and instrumental-neutron-activation analyses were performed. Major and trace-element abundances of the anorthositic rocks and surrounding mafic and felsic rocks are reported in tables, chondrite-normalized rare-earth-element patterns are shown, and the anorthositic, intrusive, and metavolcanic formations are characterized in detail. The anothrositic plagioclases are found to have a coarse porphyritic texture and calcic composition (80 normative mol percent An) similar to those of other Archean anorthosite complexes. Chemical similarities indicate that the gabbro and mafic to felsic metavolcanic formations associated with the anorthosite complex may be comagmatic with it, while the absence of ultramafic material and the bulk composition of the comagmatic basalt (about 20 wt percent Al2O3) suggest that much of the original comagmatic material has been separated.

Ashwal, L. D.↗

High-resolution X-ray imaging of M33

The nearby spiral galaxy M33 was observed for 35 ks with the high-resolution imager on ROSAT in 1992 January and August. We find 27 X-ray sources more luminous than 6 x 10(exp 36) ergs/s within 17.5 arcmin of the nucleus, of which 12 were discovered by the Einstein Observatory. Three of the ROSAT sources are coincident with giant H II regions, and seven are coincident or nearly coincident with supernova remnants. There is evidence for long-term variability between the Einstein and ROSAT observations in three sources, one of which was not detected in the ROSAT observations. Aside from an eclipsing binary X-ray source discovered by the Einstein Observatory, there is no evidence for variability within the ROSAT observations. Of the 120 cataloged holes in the H I layer in the field of view, two have significant X-ray emission. One is coincident with the giant H II region IC 133 while the other appears to be due to the chance superposition of a strong X-ray point source. Such holes are thought to be created by energetic stellar winds and supernovae from massive stars in young associations. We detect diffuse X-ray emission with a luminosity of about 10(exp 39) ergs/s, which may trace the spiral arms within 10 arcmin of the nucleus.

Schulman, Eric↗