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NASA NTRS2005

Loki Patera: A Magma Sea Story

We consider Loki Patera on Io as the surface expression of a large uniform body of magma. Our model of the Loki magma sea is some 200 km across; larger than a lake but smaller than an ocean. The depth of the magma sea is unknown, but assumed to be deep enough that bottom effects can be ignored. Edge effects at the shore line can be ignored to first order for most of the interior area. In particular, we take the dark material within Loki Patera as a thin solidified lava crust whose hydrostatic shape follows Io's isostatic surface (approx. 1815 km radius of curvature). The dark surface of Loki appears to be very smooth on both regional and local (subresolution) scales. The thermal contrast between the low and high albedo areas within Loki is consistent with the observed global correlation. The composition of the model magma sea is basaltic and saturated with dissolved SO2 at depth. Its average, almost isothermal, temperature is at the liquidus for basalt. Additional information is included in the original extended abstract.

Veeder, G. J.↗
NASA NTRS2005

Pervasive Layering in the Lunar Highland Crust: Evidence from Apollos 15, 16,and 17

This paper presents results of a photogeologic reconnaissance of 70 mm photographs taken on the lunar surface during the Apollo 15, 16, and 17 missions, whose primary objective was to investigate the lunar highland crust. Photographs at all three sites, notably the Apennine Front, show pervasive layered structure. These layers are easily distinguished from lighting artifacts, and are considered genuine crustal structures. Their number, thickness, and extent implies that they are lava flows, not ejecta blankets or intrusive features. They appear to be the upper part of the earliest lunar crust, possibly forming a layer tens of kilometers thick. Remote sensing studies (X-ray fluorescence and reflectance spectroscopy), indicate that the highland crust is dominantly a feldspathic basalt. It is concluded that the highland layers represent a global crust formed by eruptions of high-alumina basalt in the first few hundred million years of the Moon's history.

Lowman, Paul D., Jr.↗
NASA NTRS2004

Teleoperation from Mars Orbit: A proposal for Human Exploration

For a human expedition to Mars, a case can be made that the best strategy for initial exploration is not to actually land the humans on Mars, but to put the humans into Mars orbit and operate on the surface by the technology of teleoperation. This will provide the results of human exploration, but at greatly reduced risk and cost. Teleoperation of Mars surface robots from a Mars-orbital habitat will operation near real time operation with minimum time delay, giving a virtual presence on the surface. By use of teleoperation, it is possible to vastly simplify the surface exploration mission. We now have no need to develop a human-rated Mars Lander and Mars Ascent Vehicle, and we can send geologists & biologists on the mission; not VTOL pilots. It is a cheaper, simpler, and safer way to explore, and hence it will be a faster way to explore. It has the excitement of being there, at a fraction of the price. Tele-exploration from Mars orbit also allows human (virtual) presence at a wide variety of locations. With an orbital base controlling surface telerobotics, human explorers are not stuck with one base location, but can explore all over Mars. They can explore the polar caps and also near-equatorial canyon regions, from the same orbiting base. This frees the mission from landing site constraints. With no need to select a "grab bag" site that contains a large number of geologically diverse features at or near a single location; it is now possible go to all the best sites-- paleolake sites, river beds, volcanic calderas, lava tube sites, layered terrain, canyons, possible shoreline features, the North and South poles. A near-polar inclination 24-hr 39-minute period Mars orbit, for example, will put the orbital station in line-of-sight of a given region for about 8 hours per day-- one teleoperation shift. Since present day life could exist on Mars, planetary protection is also needed to preserve the (possible) fragile Mars biosphere from competition from ferocious Earth life. Isolated biospheres on Earth have been devastated when they have been exposed to alien life forms introduced-accidentally or deliberately-- from another continent. If there is life on Mars, we will wish to protect it from having to compete with introduced Earth biota. Reverse planetary protection-protecting the Earth biosphere from exposure to Mars microorganisms-is also an important consideration. Exploring from orbit will reduce biological risk by keeping humans from exposure to possible Mars microbes. A telerobotic mission will need no quarantine on return to Earth, and avoids the difficult human question of how to isolate Mars mission astronauts infected by Martian microorganisms.

Landis, Geoffrey A.↗
NASA NTRS2005

On Structural Design of a Mobile Lunar Habitat with Multi-Layered Environmental Shielding

The future human lunar missions are expected to undertake far more ambitious activities than those of the Apollo program with the possibility of some missions lasting up to several months. Such extended missions require the use of large-size lunar outposts to accommodate living quarters for the astronauts as well as indoor laboratory facilities. The greatest obstacle to the prolonged human presence on the Moon is the threat posed by the harsh lunar environment that is plagued with multi-source high-energy radiation exposure as well as frequent barrage of meteoroids. Hence, for such extended missions to succeed, it is vital that the future lunar outposts be designed to provide a safe habitat for the astronauts. Over the past few years, a variety of ideas and concepts for future lunar outposts and bases have been proposed. With shielding as the primary concern, some have suggested the use of natural structures such as lava tubes while others have taken a more industrial approach and suggested the construction of fixed structures in the form of inflatable, inflatable with rigid elements, and tent-style membrane. For evaluation of these structural design concepts, Drake and Richter1 have proposed a rating system based on such factors as effectiveness, importance, and timing. While all of these designs, in general, benefit from in-situ resource utilization (i.e., lunar regolith) for shielding, they share a common disadvantage of being fixed to one particular location that would limit exploration to the region in close proximity of the outpost.

Rais-Rohani, Masoud↗
NASA NTRS2004

Superficial Deposits at Gusev Crater Along Spirit Rover Traverses

The Mars Exploration Rover Spirit has traversed a fairly flat, rock-strewn terrain whose surface is shaped primarily by impact events, although some of the landscape has been altered by eolian processes.Impacts ejected basaltic rocks that probably were part of locally formed lava flows from at least 10 meters depth.Some rocks have been textured and/or partially buried by windblown sediments less than 2 millimeters in diameter that concentrate within shallow, partially filled, circular impact depressions referred to as hollows.The terrain traversed during the 90-sol (martian solar day) nominal mission shows no evidence for an ancient lake in Gusev crater.

Grant, J. A.↗
NASA NTRS2005

The nakhlite meteorites: Augite-rich igneous rocks from Mars

The seven nakhlite meteorites are augite-rich igneous rocks that formed in flows or shallow intrusions of basaltic magma on Mars. They consist of euhedral to subhedral crystals of augite and olivine (to 1 cm long) in fine-grained mesostases. The augite crystals have homogeneous cores of Mg' = 63% and rims that are normally zoned to iron enrichment. The core-rim zoning is cut by iron-enriched zones along fractures and is replaced locally by ferroan low-Ca pyroxene. The core compositions of the olivines vary inversely with the steepness of their rim zoning - sharp rim zoning goes with the most magnesian cores (Mg' = 42%), homogeneous olivines are the most ferroan. The olivine and augite crystals contain multiphase inclusions representing trapped magma. Among the olivine and augite crystals is mesostasis, composed principally of plagioclase and/or glass, with euhedra of titanomagnetite and many minor minerals. Olivine and mesostasis glass are partially replaced by veinlets and patches of iddingsite, a mixture of smectite clays, iron oxy-hydroxides and carbonate minerals. In the mesostasis are rare patches of a salt alteration assemblage: halite, siderite, and anhydrite/ gypsum. The nakhlites are little shocked, but have been affected chemically and biologically by their residence on Earth. Differences among the chemical compositions of the nakhlites can be ascribed mostly to different proportions of augite, olivine, and mesostasis. Compared to common basalts, they are rich in Ca, strongly depleted in Al, and enriched in magmaphile (incompatible) elements, including the LREE. Nakhlites contain little pre-terrestrial organic matter. Oxygen isotope ratios are not terrestrial, and are different in anhydrous silicates and in iddingsite. The alteration assemblages all have heavy oxygen and heavy carbon, while D/H values are extreme and scattered. Igneous sulfur had a solar-system isotopic ratio, but in most minerals was altered to higher and lower values. High precision analyses show mass-independent fractionations of S isotopes. Nitrogen and noble gases are complex and represent three components: two mantle sources (Chas-E and Chas-S), and fractionated Martian atmosphere. The nakhlites are igneous cumulate rocks, formed from basaltic magma at approx.1.3 Ga, containing excess crystals over what would form from pure magma. After accumulation of their augite and olivine crystals, they were affected (to various degrees) by crystallization of the magma, element diffusion among minerals and magma, chemical reactions among minerals and magma, magma movement among the crystals, and post-igneous chemical equilibration. The extent of these modifications varies, from least to greatest, in the order: MIL03346, NWA817, Y000593, Nakhla = Governador Valadares, Lafayette, and NWA998. Chemical, isotopic, and chronologic data confirm that the nakhlites formed on Mars, most likely in thick lava flows or shallow intrusions. Their crystallization ages, referenced to crater count chronologies for Mars, suggest that the nakhlites formed on the large volcanic constructs of Tharsis, Elysium, or Syrtis Major. The nakhlites were suffused with liquid water, probably at approx.620 ma. This water dissolved olivine and mesostasis glass, and deposited iddingsite and salt minerals in their places. The nakhlites were ejected from Mars at approx.10.75Ma by an asteroid impact and fell to Earth within the last 10,000 years. Although the nakhlites are enriched in incompatible elements, their source mantle was strongly depleted. This depletion event was ancient, as the nakhlites source mantle was fractionated while short-lived radionuclides (e.g., t(sub 1/2 = 9 my) were still active. This differentiation event may have been core formation coupled with a magma ocean, as is inferred for the moon.

Treiman, Allan H.↗
NASA NTRS1993

Implication of the January 1990 Volcanic Eruption on Io for Resurfacing Rates and Energetics

The high temperature event observed by ground based infrared radiometry of Io in January of 1990 can be modeled as an extremely active silicate lava flow which increased its area and cooled over a period of three hours. The best model at the start of the observations is a thermal source at 1200 K with an area equal to that of a circle of 5.6 km radius, while at the end of the observation sequence a source with a temperature of 700 K and a 13 km radium provides the best match. Given a flow thickness of 10 m, this implies an eruption rate of 300,000 cubic meters per second. This is large by terrestrial standards but consistent with estimates of lunar eruption rates (Head and Wilson 1981) and some terrestrial eruptions such as the 1800-1801 Hualalai flow in Hawaii (Baloga and Spudis 1992)...

Johnson, T. V.↗
NASA NTRS1995

Long-wavelength Radar Studies of the Lunar Maria

Radar measurements at 70 cm and 7.5 m wavelengths provide insight into the structure and chemical properties of the upper 5-100 m of the lunar regolith and crust. Past work has identified a number of anomalous regions and changes in echo strength, some attributed to differences in titanium content. There has been little opportunity, however, to compare calibrated long-wavelength backscatter among different units or to theoretical model results. We combine recent high-resolution (3-5 km) 70-cm radar data for the nearside with earlier calibrated full-disk observations to provide a reasonable estimate of the true lunar backscatter coefficient. These data are tested against models for quasi-specular scattering from the surface, echoes from a buried substrate, and Mie scattering from surface and buried rocks. We find that 70 cm echoes likely arise from Mie scattering by distributed rocks within the soil, consistent with earlier hypotheses. Returns from a buried substrate would provide a plausible fit to the observations only if the regolith depth were ~3 m or less and varied little across the maria. Depolarized echoes are due to some combination of single and multiple scattering events, but it appears that single scattering alone could account for the observed echo power, based on comparisons with terrestrial rocky surfaces. Backscatter strength from the regolith is most strongly affected by the loss tangent, whose variation with mineral content is still poorly defined. We compared the backscatter values for the mare deposits to the oxide contents inferred from spectral ratio methods, and found that in general the unit boundaries evident in radar images closely follow those seen in color difference images. The 70-cm data are not well correlated with TiO2 values found using the Charette relationship nor with Fe abundances derived from Clementine observations. The lack of a relationship between radar echo and Fe content is reasonable given the distribution of iron among various mineral phases, but ilmenite content (FeTiO3) has typically been cited as the dominant cause of changes in loss tangent (and thus the radar absorption). The lack of correlation between the radar data and TiO2 estimates may arise from uncertainties in the Charette technique, subtle differences in the upper surface and bulk properties of the regolith, mineralogic effects on the radar not linked to titanium content, or to some combination of these factors. Dark crater haloes in the mare and highlands, and low radar returns from apparent cryptomare regions, are used to illustrate the role radar data can play in identifying changes in regolith composition; low-return haloes around craters such as Petavius may indicate 5-25% contamination of the highlands soil by excavated mare material or a layer of rock-poor ejecta at least several meters deep. The 7.5-m data were shown to correlate to a reasonable degree with estimates of Fe abundance, suggesting that this component of the mare basalts is primarily responsible for attenuation losses at very long wavelengths. The different sensitivities of the two radar wavelengths and multispectral data offers the potential for future deep mapping of the mare lava flows and regolith.

Lunar MariaRadarLunar Studies↗
NASA NTRS1995

Long-wavelength Radar Studies of the Lunar Maria

Radar measurements at 70 cm and 7.5 m wavelengths provide insight into the structure and chemical properties of the upper 5-100 m of the lunar regolith and crust. Past work has identified a number of anomalous regions and changes in echo strength, some attributed to differences in titanium content. There has been little opportunity, however, to compare calibrated long-wavelength backscatter among different units or to theoretical model results. We combine recent high-resolution (3-5 km) 70-cm radar data for the nearside with earlier calibrated full-disk observations to provide a reasonable estimate of the true lunar backscatter coefficient. These data are tested against models for quasi-specular scattering from the surface, echoes from a buried substrate, and Mie scattering from surface and buried rocks. We find that 70 cm echoes likely arise from Mie scattering by distributed rocks within the soil, consistent with earlier hypotheses. Returns from a buried substrate would provide a plausible fit to the observations only if the regolith depth were approx.3 m or less and varied little across the maria. Depolarized echoes are due to some combination of single and multiple scattering events, but it appears that single scattering alone could account for the observed echo power, based on comparisons with terrestrial rocky surfaces. Backscatter strength from the regolith is most strongly affected by the loss tangent, whose variation with mineral content is still poorly defined. We compared the backscatter values for the mare deposits to the oxide contents inferred from spectral ratio methods, and found that in general the unit boundaries evident in radar images closely follow those seen in color difference images. The 70-cm data are not well correlated with TiO2 values found using the Charette relationship nor with Fe abundances derived from Clementine observations. The lack of a relationship between radar echo and Fe content is reasonable given the distribution of iron among various mineral phases, but ilmenite content (FeTiO3) has typically been cited as the dominant cause of changes in loss tangent (and thus the radar absorption). The lack of correlation between the radar data and TiO2 estimates may arise from uncertainties in the Charette technique, subtle differences in the upper surface and bulk properties of the regolith, mineralogic effects on the radar not linked to titanium content, or to some combination of these factors. Dark crater haloes in the mare and highlands, and low radar returns from apparent cryptomare regions, are used to illustrate the role radar data can play in identifying changes in regolith composition; low-return haloes around craters such as Petavius may indicate 5-25% contamination of the highlands soil by excavated mare material or a layer of rock-poor ejecta at least several meters deep. The 7.5-m data were shown to correlate to a reasonable degree with estimates of Fe abundance, suggesting that this component of the mare basalts is primarily responsible for attenuation losses at very long wavelengths. The different sensitivities of the two radar wavelengths and multispectral data offers the potential for future deep mapping of the mare lava flows and regolith.

Lunar Studies↗
NASA NTRS2007

High-Precision Nd Isotopes in Picrites from Hawaii and Iceland - No Evidence for an Early-Formed Enriched Reservoir

New high-precision Nd isotope measurements have shown that the present-day Nd-142/Nd-144 for average chondrites is approximately 20 ppm lower than that for the terrestrial standard and all recent mantle-derived samples measured to date. One explanation for these differences is that an enriched missing reservoir with lower Nd-142/Nd-144 resides in the mantle to balance the bulk Earth to chondritic. Data from Archean Greenland rocks show anomalies in Nd-142/Nd-144 of up to 40 ppm higher than the proposed average for chondrites. This difference between the Archean Greenland rocks and present-day mantle-derived samples has been interpreted to result from remixing of an early-formed enriched reservoir into the convecting mantle during the Archean. If so, the implication from this is that remixing of the enriched reservoir largely shut down some time in the past such that it must at present reside in a region in the mantle that infrequently participates dynamically and leading to volcanism at the surface. Several studies have suggested that the missing reservoir may be present just above the coremantle boundary (CMB). Depending on the size of this reservoir it could potentially make up all of D or exist as distinct domains within it. If such a reservoir does exist, then mantle-derived samples from plume systems that are thought to come from the CMB may be the best opportunity to identify this component using high-precision Nd isotope measurements. To test this, picrites from Hawaii with coupled enrichments in Os-186-Os-187 that has been proposed to be a signature of core-mantle interaction were measured on the JSC Triton for high-precision Nd-142/Nd-144. For comparison, picrites from Hawaii and Iceland that do not show coupled enrichments in Os-186-Os-187 were measured. We have established an external precision for Nd-142/Nd-144 of 3.6 ppm (2 sigma) during the analytical campaign. The Iceland (n=5) and Hawaiian data (n=9) have Nd-142 ranging from -0.01 plus or minus 0.03 to +0.03 plus or minus 0.03 (2 sigma) and there is no resolvable difference between samples with Os isotope enrichments versus those without. The average epsilon Nd-142 of +0.011 plus or minus 0.034 (2 sigma ) for all of the samples (n=14) is not resolvable from the Ames and La Jolla standards with epsilon Nd-142 of +0.000 plus or minus 0.036 (n=16, 2 sigma). These data confirm recent measurements on lavas for the absence of an ancient enriched Nd-142 isotopic signature in plume systems likely derived from D and indicates that such a reservoir, if existing, must now reside in areas of the deep mantle that plumes do not sample.

Brandon, A. D.↗
NASA NTRS2006

Io: Loki Patera as a Magma Sea

We develop a physical model for Loki Patera as a magma sea. We calculate the total volume of magma moving through the Loki Patera volcanic system every resurfacing cycle (approx.540 days) and the resulting variation in thermal emission. The rate of magma solidification at times reaches 3 x 10(exp 6) kg per second, with a total solidified volume averaging 100 cu km per year. A simulation of gas physical chemistry evolution yields the crust porosity profile and the timescale when it will become dense enough to founder in a manner consistent with observations. The Loki Patera surface temperature distribution shows that different areas are at different life cycle stages. On a regional scale, however, there can be coordinated activity, indicated by the wave of thermal change which progresses from Loki Patera's SW quadrant toward the NE at a rate of approx.1 km per day. Using the observed surface temperature distribution, we test several mechanisms for resurfacing Loki Patera, finding that resurfacing with lava flows is not realistic. Only the crustal foundering process is consistent with observations. These tests also discovered that sinking crust has a 'heat deficit' which promotes the solidification of additional magma onto the sinking plate ("bulking up"). In the limiting case, the mass of sinking material can increase to a mass of approx.3 times that of the foundering plate. With all this solid matter sinking, there is a compensating upward motion in the liquid magma. This can be in excess of 2 m per year. In this manner, solid-liquid convection is occurring in the sea.

heat flow↗
NASA NTRS2006

Widespread Layers in Arabia Terra: Implications for Martian Geologic History

Layered rocks in Arabia Terra have been the focus of several recent papers. Studies have focused on the layers found in crater basins located in the southwest portion of the region. However, Mars Orbiter Camera (MOC) images have identified layered deposits across the region. Terrestrial layered rocks are usually sedimentary, and often deposited in water. Thus extensive layered sequences in Arabia Terra may indicate locations of past, major depositional basins on Mars. Other mechanisms can also create layered rocks, or the appearance of layered rocks, including volcanism (both lava flows and ash falls), wind-blown deposits, and wave-cut terraces at shorelines. By identifying where in the region layers occur, and classifying the layers according to morphology and albedo, past depositional environments may be identified. Arabia Terra is characterized by heavily cratered Noachian plains, as well as a rise from -4000 m in the northwest to 4000 m in the southeast (Mars Orbital Laser Altimeter [MOLA] datum). This slope may have provided a constraint on sediment deposition and thus layer formation. While most of the region is Noachian in age, a significant percentage of the area is identified as Hesperian. Although the history of the Arabia Terra initially seems to be straightforward cratered plains with several younger units atop them analysis of high-resolution imagery may reveal a more complex history.

Venechuk, Elizabeth M.↗
NASA NTRS2006

The Rocks of the Columbia Hills

The Mars Exploration Rover Spirit has identified five distinct rock types in the Columbia Hills of Gusev crater. Clovis Class rock is a poorly-sorted clastic rock that has undergone substantial aqueous alteration. We interpret it to be aqueously-altered ejecta deposits formed by impacts into basaltic materials. Wishstone Class rock is also a poorly-sorted clastic rock that has a distinctive chemical composition that is high in Ti and P and low in Cr. Wishstone Class rock may be pyroclastic in origin. Peace Class rock is a sedimentary material composed of ultramafic sand grains cemented by significant quantities of Mg- and Ca-sulfates. Peace Class rock may have formed when water briefly saturated the ultramafic sands, and evaporated to allow precipitation of the sulfates. Watchtower Class rocks are similar chemically to Wishstone Class rocks, and have undergone widely varying degrees of near-isochemical aqueous alteration. They may also be ejecta deposits, formed by impacts into Wishstone-rich materials and altered by small amounts of water. Backstay Class rocks are basalt/trachybasalt lavas that were emplaced in the Columbia Hills after the other rock classes were, either as impact ejecta or by localized volcanic activity. The geologic record preserved in the rocks of the Columbia Hills reveals a period very early in martian history in which volcanic materials were widespread, impact was a dominant process, and water was commonly present.

Squyres, Steven W.↗
NASA NTRS2006

Concordant Rb-Sr and Sm-Nd Ages for NWA 1460: A 340 Ma Old Basaltic Shergottite Related to Lherzolitic Shergottites

Preliminary Rb-Sr and Sm-Nd ages reported by [1] for the NWA 1460 basaltic shergottite are refined to 336+/-14 Ma and 345+/-21 Ma, respectively. These concordant ages are interpreted as dating a lava flow on the Martian surface. The initial Sr and Nd isotopic compositions of NWA 1460 suggest it is an earlier melting product of a Martian mantle source region similar to those of the lherzolitic shergottites and basaltic shergottite EETA79001, lithology B. We also examine the suggestion that generally "young" ages for other Martian meteorites should be reinterpreted in light of Pb-207/Pb-206 - Pb-204/Pb-206 isotopic systematics [2]. Published U-Pb isotopic data for nakhlites are consistent with ages of approx.1.36 Ga. The UPb isotopic systematics of some Martian shergottites and lherzolites that have been suggested to be approx.4 Ga old [2] are complex. We nevertheless suggest the data are consistent with crystallization ages of approx.173 Ma when variations in the composition of in situ initial Pb as well as extraneous Pb components are considered.

Nyquist, L. E.↗
NASA NTRS2006

Constraints on the Formation of the Moon from High-Precision ND-Isotopic Measurements of Lunar Basalts

The most widely accepted theory for the formation of the Earth-Moon system proposes a giant impact model, where Earth collided in its later stages of accretion with a body of the approximate size of Mars [1, 2]. In this model, the Moon ultimately formed from hot debris generated during this giant impact. Short-lived radioisotopes such as Sm-146 (t(sub 1/2) = 103 Ma) may be useful in determining the chronology of the events that formed the Earth-Moon system and for how these terrestrial bodies evolved following accretion. New high-precision samarium-neodymium data showed that chondritic meteorites are on average 20 ppm lower in 142Nd/144Nd than terrestrial samples [3]. These data suggest that if the bulk silicate Earth (BSE) has a Sm/Nd ratio within the range measured for chondrites, the higher-than-chondritic Nd-142/Nd-144 ratio of terrestrial materials requires that the silicate Earth experienced a global chemical differentiation during the lifetime of Sm-146. If the Moon has super-chondritic Nd-142/Nd-144 identical to the Earth, as suggested by available data [4], then the giant impact must have occurred into an already differentiated Earth, predominantly sampling the Nd-depleted reservoir. In order to test this hypothesis, high-precision Nd-isotope ratios were obtained on a Thermo-Finnigan Triton TIMS for six lunar basalts that span the compositional range of lavas from the Moon: Samples 15555 and LAP 02205 represent low-Ti basalts; 70017 and 74275 are high-Ti basalts; 15386 and SAU 169 are KREEP basalts.

Rankenburg, K.↗
NASA NTRS2006

On the Discovery of CO Nighttime Emissions on Titan by Cassini/VIMS: Derived Stratospheric Abundances and Geological Implications

We present a quantitative analysis of CO thermal emissions discovered on the nightside of Titan by Baines et al. [2005. The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/VIMS. Earth, Moon, and Planets, 96, 119-147] in Cassini/VIMS spectral imagery. We identify these emission features as the P and R branches of the 1-0 vibrational band of carbon monoxide (CO) near 4.65 microns. For CH3D, the prominent Q branch of the nu(2) fundamental band of CH3D near 4.55 microns is apparent. CO2 emissions from the strong nu(3) vibrational band are virtually absent, indicating a CO2 abundance several orders of magnitude less than CO, in agreement with previous investigations. Analysis of CO emission spectra obtained over a variety of altitudes on Titan's nightside limb indicates that the stratospheric abundance of CO is 32 +/- 15 ppm, and together with other recent determinations, suggests a vertical distribution of CO nearly constant at this value from the surface throughout the troposphere to at least the stratopause near 300 km altitude. The corresponding total atmospheric content of CO in Titan is similar to 2.9 +/- 1.5 x 10(exp 14) kg. Given the long lifetime of CO in the oxygen-poor Titan atmosphere (similar to 0.5-1.0 Gyr), we find a mean CO atmospheric production rate of 6 +/- 3 x 10(exp 5) kg yr(exp -1). Given the lack of primordial heavy noble gases observed by Huygens [Niemann et al., 2005. The abundances of constituents of Titan's atmosphere from the GCMS on the Huygens probe. Nature, 438, 779-784], the primary source of atmospheric CO is likely surface emissions. The implied CO/CH4 mixing ratio of near-surface material is 1.8 +/- 0.9 x 10(exp -4), based on an average methane surface emission rate over the past 0.5 Gyr of 1.3 x 10(exp -13) gm cm(exp -2) s(exp -1) as required to balance hydrocarbon haze production via methane photolysis [Wilson and Atreya, 2004. Current state of modeling the photochemistry of Titan's mutually dependent atmosphere and ionosphere. J. Geophys. Res. 109, E06002 Doi: 10.1029/2003JE002181]. This low CO/CH4 ratio is much lower than expected for the sub-nebular formation region of Titan and supports the hypothesis [e.g., Atreya et al., 2005. Methane on Titan: photochemical-meteorological-hydrogeochemical cycle. Bull. Am. Astron. Soc. 37, 735] that the conversion of primordial CO and other carbon-bearing materials into CH4-enriched clathrate-hydrates occurs within the deep interior of Titan via the release of hydrogen through the serpentinization process followed by Fischer-Tropsch catalysis. The time-averaged predicted emission rate of methane-rich surface materials is approximately 0.02 km(exp 3) yr (exp -1), a value significantly lower than the rate of silicate lava production for the Earth and Venus, but nonetheless indicative of significant geological processes reshaping the surface of Titan.

carbon compounds↗
NASA NTRS2005

Monitoring Eruptive Activity at Mount St. Helens with TIR Image Data

Thermal infrared (TIR) data from the MASTER airborne imaging spectrometer were acquired over Mount St. Helens in Sept and Oct, 2004, before and after the onset of recent eruptive activity. Pre-eruption data showed no measurable increase in surface temperatures before the first phreatic eruption on Oct 1. MASTER data acquired during the initial eruptive episode on Oct 14 showed maximum temperatures of similar to approximately 330 C and TIR data acquired concurrently from a Forward Looking Infrared (FLIR) camera showed maximum temperatures similar to approximately 675 C, in narrow (approximately 1-m) fractures of molten rock on a new resurgent dome. MASTER and FLIR thermal flux calculations indicated a radiative cooling rate of approximately 714 J/m(exp 2)/s over the new dome, corresponding to a radiant power of approximately 24 MW. MASTER data indicated the new dome was dacitic in composition, and digital elevation data derived from LIDAR acquired concurrently with MASTER showed that the dome growth correlated with the areas of elevated temperatures. Low SO2 concentrations in the plume combined with sub-optimal viewing conditions prohibited quantitative measurement of plume SO2. The results demonstrate that airborne TIR data can provide information on the temperature of both the surface and plume and the composition of new lava during eruptive episodes. Given sufficient resources, the airborne instrumentation could be deployed rapidly to a newly-awakening volcano and provide a means for remote volcano monitoring.

thermal emissions↗
NASA NTRS2008

Mapping the Sedna-Lavinia Region of Venus

Geologic mapping of Venus at 1:5 M scale has shown in great detail the flow complexes of volcanoes, coronae, and shield fields, and the varying structural patterns that differentiate tesserae from corona rims and isolated patches of densely lineated terrain. In most cases, however, the lower-elevation plains between the higher-standing landforms are discriminated only on the basis of potentially secondary features such as late-stage lava flooding or tectonic overprinting. This result, in which volcanoes and tesserae appear as "islands in the sea," places weak constraints on the relative age of large upland regions and the nature of the basement terrain. In this work, we focus on the spatial distribution and topography of densely lineated and tessera units over a large region of Venus, and their relationship to apparently later corona and shield flow complexes. The goal is to identify likely connections between patches of deformed terrain that suggest earlier features of regional extent, and to compare the topography of linked patches with other such clusters as a guide to whether they form larger tracts beneath the plains. Mapping Approach. We are mapping the region from 57S to 57N, 300E-60E. Since the 1:5 M quadrangles emphasize detail of tessera structure and corona/edifice flows, we simply adopt the outlines of these features as they relate to the outcrops of either "densely lineated terrain" or tessera (Fig. 1). The densely lineated material is mapped in many quadrangles based on pervasive structural deformation, typically with a single major axis (in contrast to the overlapping orthogonal patterns on tesserae). This unit definition is often extended to include material of corona rims. We do not at present differentiate between plains units, since earlier efforts show that their most defining attributes may be secondary to the original emplacement (e.g., lobate or sheet-like flooding by thin flow units, tectonic patterns related to regional and localized stress regimes) [1].

Campbell, Bruce A.↗