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At least 1,081 records · Page 60

A Framework for Quantitative Assessment of Impacts Related to Energy and Mineral Resource Development

Natural resource planning at all scales demands methods for assessing the impacts of resource development and use, and in particular it requires standardized methods that yield robust and unbiased results. Building from existing probabilistic methods for assessing the volumes of energy and mineral resources, we provide an algorithm for consistent, reproducible, quantitative assessment of resource development impacts. The approach combines probabilistic input data with Monte Carlo statistical methods to determine probabilistic outputs that convey the uncertainties inherent in the data. For example, one can utilize our algorithm to combine data from a natural gas resource assessment with maps of sage grouse leks and pinon-juniper woodlands in the same area to estimate possible future habitat impacts due to possible future gas development. As another example: one could combine geochemical data and maps of lynx habitat with data from a mineral deposit assessment in the same area to determine possible future mining impacts on water resources and lynx habitat. The approach can be applied to a broad range of positive and negative resource development impacts, such as water quantity or quality, economic benefits, or air quality, limited only by the availability of necessary input data and quantified relationships among geologic resources, development alternatives, and impacts. In conclusion, the framework enables quantitative evaluation of the trade-offs inherent in resource management decision-making, including cumulative impacts, to address societal concerns and policy aspects of resource development.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Formation of Lamellar Carbides in Alloy 617-HAZ and Their Role in the Impact Toughness of Alloy 617/9%Cr Dissimilar Welded Joint

The relationship between the microstructure and impact toughness, especially the formation of the lamellar carbides and its effect on the impact toughness of the heat-affected zone of Alloy 617 (Alloy 617-HAZ), was systematically investigated. Impact test was performed on Alloy 617/9%Cr dissimilar welded joints aged for different time at 620 °C. The results showed that the characteristic zones of the whole welded joint revealed decreased impact toughness with increasing the aging time. The impact energies in weld metal showed high stability despite the aging process, while the Alloy 617-HAZ for all testing specimens presented the lowest impact toughness with various aging time. Meanwhile, the mixed grains were found in the base metal (BM) and heat-affected zone of Alloy 617, together with the twins with different widths located in the interior of the large grains. The columnar and equiaxed grain zones appear alternately due to the multilayer and multi-pass welding technique. In particular, compared with Alloy 617-BM, coarsened and even lamellar carbides were observed in Alloy 617-HAZ. These special carbides can separate the grains and therefore result in the formation of intergranular fracture morphology in Alloy 617-HAZ. Besides, the microhardness distribution was tested with a proper load, and the results exhibited that the weld possessed the highest hardness for all specimens with various aging time. The higher microhardness in Alloy 617-HAZ compared with that in Alloy 617-BM was attributed to the high density of the dislocations, which could be detected by transmission electron microscope. As a result, the coarsened carbides aggregated in the grain boundaries to form the lamellar layer are deemed as the main factor to reduce the impact toughness in Alloy 617-HAZ.

36 MATERIALS SCIENCE↗

Impact Behavior of Polyester GFRP for Naval Applications: Influence of the Clamping Device and Fluid–Material Interaction

The low-velocity impact behavior of polyester glass fiber composite laminates has been investigated under different clamping conditions, by wetting the specimens surface with fluids having different densities. Unidirectional composite laminates, based on polymer resin and fibers of naval interest, with different thicknesses have been manufactured by resin transfer molding process in order to have a high control of the final properties and a high fiber volume fraction. Impact tests in air have been, first, performed up to penetration on all manufactured composites having four different thicknesses to get information on the material impact behavior. The effect of the clamping conditions and the interaction of the laminates with two fluids different in density, i.e., water and paraffin oil, have been investigated, then, only on the thickest laminates that showed a lower tendency to impact damage. In particular, the impact tests have been performed by impacting the front surface of the sample and by wetting the back surface of the composite samples under unclamped and clamped conditions, replicating the boundary constraints suggested by ASTM D7136 Standard for the conventional impact tests. Experimental results showed a lower initial rigidity, higher absorbed energy and deflection for specimens exposed to liquids with respect to those exposed to air, confirming the need of taking into account the fluid interaction in the case of marine composite applications.

36 MATERIALS SCIENCE↗

Impact Damage Investigation on Glass Fiber-Reinforced Plate Laminates at Room and Lower Temperatures through Ultrasound Testing and Electronic Speckle Pattern Interferometry

In this work, the evaluation of damage area due to low-velocity impact tests at different impact energy values and different temperatures on glass fiber-reinforced plate laminates was investigated by two nondestructive evaluation (NDE) techniques, electronic speckle pattern interferometry (ESPI) and ultrasound testing (UT). Composites are characterized by several interacting failure modes such as matrix breakage, fiber failure and delaminations, which can be simultaneously induced by low-velocity impacts and can be different depending on the temperature. It can be complicated to detect by visual inspections of the structures for such phenomena. This paper aims to investigate the dependence of the damaged area with respect to temperature variation on glass fiber composite laminates. GF composite laminates were impacted with three energy levels (5, 10, 20 J) and at different temperatures (room temperature, − 25, − 50 °C) by a drop weight impact machine. The results show that at decreasing temperature, a decrease in the damage extension was observed, which is more evident at increasing impact energy. Moreover, as expected, the results confirm UT and ESPI techniques are able to identify the barely visible low-velocity impact damage. However, some limitations for detection were found in ESPI. Nonetheless, the ESPI technique can be considered as one of the useful NDE methods if the calibration and the post-processing methods are improved.

36 MATERIALS SCIENCE↗

A heuristic tool to assess regional impacts of renewable energy infrastructure on conservation areas

Wind and hydropower are important renewable components of national energy portfolios, but their infrastructure negatively affects biodiversity. Regional development requires identification of scenarios that minimize the cumulative impacts of multiple facilities. We introduce the cumulative impact plot (CIP) to quantify cumulative impacts of renewable energy development within a region. Summed impacts of facilities are plotted as a function of the number of facilities, with facilities ranked by increasing (the best-case scenario) or decreasing (worst-case scenario) individual impact. These curves represent lower and upper bounds to which alternative development scenarios (e.g., facilities ranked by generating capacity) can be compared. We used CIPs to assess overlap of potential wind and hydropower facilities with two types of conservation area in the United States: (1) federally protected lands and (2) critical habitats of federally threatened and endangered species. Here, we evaluated two alternative scenarios: facilities ranked by (A) decreasing generating capacity and (B) increasing distance from urban centers. Differences between the best-case and worst-case scenarios were large, thus revealing opportunities to develop facilities with limited impact on conservation areas. Alternative scenarios maximizing energy density generally resulted in conservation area overlap intermediate to best-case and worst-case scenarios. CIPs can also identify the proportion of wind versus hydropower favored under alternative scenarios. Build-out scenarios aimed at minimizing conservation area overlap favor hydropower, whereas alternative scenarios favor wind power. We conclude that CIPs can (1) complement—but should not replace—project-level environmental impact assessment, (2) integrate strategic, cumulative, and scenario-based assessments, and (3) harness rapidly growing geospatial data.

54 ENVIRONMENTAL SCIENCES↗

Transverse impact by RCCs on S-glass and Kevlar® FRC strips

This study aims to isolate interactions between plies and tows and reveal fundamental physics involved in transverse impact on fiber-reinforced composite (FRC) structures. Composite strips were sectioned from large panels and characterized by optical photography, three-dimensional synchrotron X-ray computed tomography, and scanning electron microscopy (SEM). Each strip was impacted perpendicularly by a right circular cylinder (RCC) projectile at a velocity ranging from ~ 150 to 600 m/s. The global strip behavior, as well as localized deformation and failure of the strip near the projectile corner, were both captured by high-speed optical imaging. S-Glass FRC strips were observed to fail in tension ahead of the RCC projectiles’ flat surfaces while Kevlar® FRC strips fractured at the projectile corners. The concept of critical velocity region previously used for impact on yarns was introduced to define different failure modes of each composite strip type. The strip damage extent was found to increase with the impact velocity and reach the maximum at the upper limit of the critical velocity region. Above the critical velocity region, the damage extent decreased with impact velocity. Wave propagations and load histories in the composite strips during impact were quantified and compared with Smith’s theory. Finally, critical velocities of single fibers, yarns, and composite strips and ballistic limits of single-ply and multi-ply composite panels were compared to provide insight into the design of impact-resistant fabrics and composites.

42 ENGINEERING↗

Life cycle thinking in impact assessment—Current practice and LCA gains

It has been advocated that life cycle thinking (LCT) should be applied in impact assessment (IA) to a greater extent, since some development proposals pose a risk of significant impacts throughout the interconnected activities of product systems. Multiple authors have proposed the usage of life cycle assessment (LCA) for such analytical advancement, but little to no research on this tool application has been founded in IA practice so far. The aim of this article is to elaborate further on the gains assigned to application of LCA. The research builds on a review of 85 Danish IA reports, which were analysed for analytical appropriateness and application of LCT. Through a focus on the non-technical summary, the conclusion and the use of specific search words, passages containing LCT were searched for in each IA report. These passages were then analysed with a generic framework. The results reveal that LCT is appropriate for most of the IAs, but that LCA is rarely applied to provide such a perspective. Without LCA, the IAs show mixed performance in regard to LCT. Most IAs do consider the product provision of development proposals, but they rarely relate impacts to this function explicitly. Many IAs do consider downstream impacts, but assessments of upstream, distant impacts are generally absent. It is concluded that multiple analytical gains can be attributed to greater application of LCA in IA practice, though some level of LCT already exists. - Highlights: • Life cycle thinking is appropriate across the types and topics of impact assessment. • Yet, life cycle assessment is rarely used for adding such perspective. • Impact assessment practice does apply some degree of life cycle thinking. • However, application of life cycle assessment could bring analytical gains.

54 ENVIRONMENTAL SCIENCES↗

Risk analysis within environmental impact assessment of proposed construction activity

Environmental impact assessment is an important process, prior to approval of the investment plan, providing a detailed examination of the likely and foreseeable impacts of proposed construction activity on the environment. The objective of this paper is to develop a specific methodology for the analysis and evaluation of environmental impacts of selected constructions – flood protection structures using risk analysis methods. The application of methodology designed for the process of environmental impact assessment will develop assumptions for further improvements or more effective implementation and performance of this process. The main objective of the paper is to improve the implementation of the environmental impact assessment process. Through the use of risk analysis methods in environmental impact assessment process, the set objective has been achieved. - Highlights: This paper is informed by an effort to develop research with the aim of: • Improving existing qualitative and quantitative methods for assessing the impacts • A better understanding of relations between probabilities and consequences • Methodology for the EIA of flood protection constructions based on risk analysis • Creative approaches in the search for environmentally friendly proposed activities.

54 ENVIRONMENTAL SCIENCES↗

An integrated modelling framework to assess long-term impacts of water management strategies steering soil subsidence in peatlands

Around the world many peatlands are managed unsustainably. Drainage of the peat causes soil subsidence and a range of negative societal impacts. Integrated strategies are required to ensure more sustainable long-term settings, based on impact assessment models that simulate the interrelated dynamics of water management and soil subsidence, and determine the spatial and temporal range of societal impacts. This paper presents an integrated modelling framework that meets these requirements. We used the framework to assess the impacts of a range of water management strategies in Dutch peatlands. Average soil subsidence rates were shown to range from 0.6 to 4.5 mm·y{sup −1}, resulting in marked differences in societal impacts that affect stakeholders unequally. Moreover, the impacts on real estate damage and water system maintenance revealed inverse trends that result in increasingly unbalanced cost-benefit ratios. The generated insights led the regional water authority to change their current water management strategy, preventing unsustainable future developments. We find the results relevant for improving stakeholders' awareness of long-term impacts of management strategies, and making negotiation processes on goals, means, and possible future pathways more transparent. - Highlights: •We developed an integrated modelling framework to support peatland management. •We used the case of Dutch peatlands to illustrate the added value of the framework. •Spatial patterns and temporal trends show how stakeholders are affected unequally. •The results were used to improve water management strategies.

02 PETROLEUM↗

The ecosystem approach in ecological impact assessment: Lessons learned from windfarm developments on peatlands in Scotland

Highlights: • Recent wind energy projects in Scotland mostly fail to consider ecosystem-level impacts on peatland. • Projects on peatland illustrate the usefulness of an ecosystem approach to Environmental Impact Assessment. • Defining more meaningful functional management units can improve Environmental Impact Assessment outcomes. • VAn ecosystem approach could also improve ecosystem services assessments. - Abstract: The Ecosystem Approach introduced in 1994 through the Convention on Biological Diversity, together with related Ecosystem-based Management and Landscape Approaches, are frequently called upon to improve ecological impact assessment. Current practice typically does not have such a systems focus and we explore the potential for explicitly adopting an Ecosystem Approach in the Environmental Impact Assessment process using wind energy development on peatland, in Scotland, as a case study. Based on a review of 21 windfarm projects (>50 MW) approved by the Scottish Government we provide an overview of current practice and identify and discuss how the 12 principles of the Ecosystem Approach can help identify options for more appropriate impact assessment. These include defining functional units of analysis that reflect the spatial and temporal linkages of peatland elements through hydrological connections, rather than a focus on individual vegetation types and simple distance buffers. Our conclusions are not limited to peatland and are relevant wherever meaningful functional management units can be defined, including in marine environments. Our results also show that environmental statements for wind energy development in Scotland largely ignore ecosystem services and the people that benefit from them. As for threatened species and other biodiversity features, an Ecosystem Approach is a prerequisite to the meaningful inclusion of ecosystem services in impact assessment.

54 ENVIRONMENTAL SCIENCES↗

Projecting Life-Cycle Environmental Impacts of Corn Production in the U.S. Midwest under Future Climate Scenarios using machine learning approach

Emission factors and process-based mechanism models are popular approaches used to estimate life-cycle environmental impacts. However, emission factors are often incapable of describing spatial and temporal heterogeneity of agricultural emissions, whereas process-based mechanism models, capable of capturing the heterogeneity, tend to be very complicated, and time-consuming. Efficient predictions of life-cycle environmental impacts from agricultural production are lacking. This study develops a rapid predictive model to quantify life-cycle global warming (GW), eutrophication (EU) and acidification (AD) impacts of corn production using a novel machine learning approach. We used the boosted regression tree (BRT) model to estimate current and future life-cycle environmental impacts of corn production in 12 U.S. Midwest at county scale under four Intergovernmental Panel on Climate Change (IPCC)’s climate scenarios (RCP2.6. 4.5, 6.0, and 8.5) for years 2009-2100. Results show that future life-cycle GW, EU and AD impacts of corn production will increase under all four scenarios, with the worst environmental impacts shown under the RCP 8.5 scenario. Significant spatial variation were estimated to be 3.6, 29.9 and 1.8-folds under the RCP4.5 scenario, and 6.6, 152.9 and 1.6-folds under the RCP8.5 scenario, respectively. Findings from this study demonstrate the importance of considering county-level life-cycle environmental impacts and the influences of climate change in future years to aid in developing potential adaptation and mitigation programs and policies.

Machine learning, climate change, projections, env↗

Influence of construction and demolition waste management on the environmental impact of buildings

Highlights: Black-Right-Pointing-Pointer Environmental impacts of different demolition practices. Black-Right-Pointing-Pointer 'Top-down' approach to the Life Cycle Analysis methodology. Black-Right-Pointing-Pointer Results based on real buildings measurements and demolition contractor activities. Black-Right-Pointing-Pointer Not every type of selective demolition brings about environmental benefits. - Abstract: The purpose of this study is to quantify comparable environmental impacts within a Life Cycle Analysis (LCA) perspective, for buildings in which the first (Materials) and last (End of Life) life cycle stages are adjusted to several waste/material management options. Unlike most LCAs, the approach is 'top-down' rather than 'bottom-up', which usually involves large amounts of data and the use of specific software applications. This approach is considered appropriate for a limited but expedient LCA designed to compare the environmental impacts of different life cycle options. Present results, based on real buildings measurements and demolition contractor activities, show that shallow, superficial, selective demolition may not result in reduced environmental impacts. Calculations actually show an increase (generally less than 5%) in most impact categories for the Materials and End of Life stages because of extra transportation needs. However, core material separation in demolition operations and its recycling and/or reuse does bring environmental benefits. A reduction of around 77% has been estimated in the climate change impact category, 57% in acidification potential and 81% in the summer smog impact (for the life cycle stages referred).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A New Crater Near InSight: Implications for Seismic Impact Detectability on Mars

A new 1.5 m diameter impact crater was discovered on Mars only ~40 km from the InSight lander. Context camera images constrained its formation between 21 February and 6 April 2019; follow-up High Resolution Imaging Science Experiment images resolved the crater. During this time period, three seismic events were identified in InSight data. In this paper, we derive expected seismic signal characteristics and use them to evaluate each of the seismic events. However, none of them can definitively be associated with this source. Atmospheric perturbations are generally expected to be generated during impacts; however, in this case, no signal could be identified as related to the known impact. Using scaling relationships based on the terrestrial and lunar analogs and numerical modeling, we predict the amplitude, peak frequency, and duration of the seismic signal that would have emanated from this impact. The predicted amplitude falls near the lowest levels of the measured seismometer noise for the predicted frequency. Hence, it is not surprising this impact event was not positively identified in the seismic data. Finding this crater was a lucky event as its formation this close to InSight has a probability of only ~0.2, and the odds of capturing it in before and after images are extremely low. We revisit impact-seismic discriminators in light of real experience with a seismometer on the Martian surface. Using measured noise of the instrument, we revise our previous prediction of seismic impact detections downward, from ~a few to tens, to just ~2 per Earth year, still with an order of magnitude uncertainty.

58 GEOSCIENCES↗

Implications of climate change impacts for emission and land use scenario development

Scenarios of future emissions and land use produced by integrated assessment models have traditionally been developed without accounting for how climate change impacts could affect the emissions and land use trajectories themselves. This omission risks skewing our assessments of the plausible range of future emission pathways and associated Earth system changes. Beyond the salience for emission scenario development, a better integrated representation of human and Earth system changes and feedbacks would enable better anticipation of the implications of alternative socio-economic development pathways. We use the Global Change Analysis Model to investigate whether endogenizing several impacts when generating its baseline emission scenario is warranted. We do so by comparing the emissions and land use change that result from the baseline scenario with and without impacts, where impacts are implemented as exogenous changes to water availability, crop and labor productivity, and energy demand and supply. Our results indicate that the effect on global emissions leads to less than 0.1 °C increase in warming by 2100 and therefore do not support endogenizing impacts. This conclusion is conditional on our modeling framework and the specific impact channels represented but is consistent with other studies that have addressed the magnitude of feedbacks by implementing a two-way coupling. However, we do find regional impacts indicating that local economies and well-being measures may be affected significantly.

climate impacts↗

A Method to Estimate the Chronic Health Impact of Air Pollutants in U.S. Residences

Background: Indoor air pollutants (IAPs) cause multiple health impacts. Prioritizing mitigation options that differentially affect individual pollutants and comparing IAPs with other environmental health hazards require a common metric of harm. Objectives: Our objective was to demonstrate a methodology to quantify and compare health impacts from IAPs. The methodology is needed to assess population health impacts of large-scale initiatives—including energy efficiency upgrades and ventilation standards—that affect indoor air quality (IAQ). Methods: Available disease incidence and disease impact models for specific pollutant–disease combinations were synthesized with data on measured concentrations to estimate the chronic heath impact, in disability-adjusted life-years (DALYs) lost, due to inhalation of a subset of IAPs in U.S. residences. Model results were compared with independent estimates of DALYs lost due to disease. Results: Particulate matter ≤ 2.5 μm in aerodynamic diameter (PM2.5), acrolein, and formaldehyde accounted for the vast majority of DALY losses caused by IAPs considered in this analysis, with impacts on par or greater than estimates for secondhand tobacco smoke and radon. Confidence intervals of DALYs lost derived from epidemiology-based response functions are tighter than those derived from toxicology-based, interspecies extrapolations. Statistics on disease incidence in the United States indicate that the upper-bound confidence interval for aggregate IAP harm is implausibly high. Conclusions: The approach demonstrated in this study may be used to assess regional and national initiatives that affect IAQ at the population level. Cumulative health impacts from inhalation in U.S. residences of the IAPs assessed in this study are estimated at 400–1,100 DALYs lost annually per 100,000 persons.

60 APPLIED LIFE SCIENCES↗

Analysis of Drought Impacts on Electricity Production in the Western and Texas Interconnections of the United States

Electricity generation relies heavily on water resources and their availability. To examine the interdependence of energy and water in the electricity context, the impacts of a severe drought to assess the risk posed by drought to electricity generation within the western and Texas interconnections has been examined. The historical drought patterns in the western United States were analyzed, and the risk posed by drought to electricity generation within the region was evaluated. The results of this effort will be used to develop scenarios for medium- and long-term transmission modeling and planning efforts by the Western Electricity Coordination Council (WECC) and the Electric Reliability Council of Texas (ERCOT). The study was performed in response to a request developed by the Western Governors Association in conjunction with the transmission modeling teams at the participating interconnections. It is part of a U.S. Department of Energy-sponsored, national laboratory-led research effort to develop tools related to the interdependency of energy and water as part of a larger interconnection-wide transmission planning project funded under the American Recovery and Reinvestment Act. This study accomplished three main objectives. It provided a thorough literature review of recent studies of drought and the potential implications for electricity generation. It analyzed historical drought patterns in the western United States and used the results to develop three design drought scenarios. Finally, it quantified the risk to electricity generation for each of eight basins for each of the three drought scenarios and considered the implications for transmission planning. Literature on drought impacts on electricity generation describes a number of examples where hydroelectric generation capacity has been limited because of drought but only a few examples of impact on thermoelectric generation. In all documented cases, shortfalls of generation were met by purchasing power from the market, albeit at higher prices. However, sufficient excess generation and transmission must be available for this strategy to work. Although power purchase was the most commonly discussed drought mitigation strategy, a total of 12 response strategies were identified in the literature, falling into four main categories: electricity supply, electricity demand response, alternative water supplies, and water demand response. Three hydrological drought scenarios were developed based on a literature review and historical data analysis. The literature review helped to identify key drought parameters and data on drought frequency and severity. Historical hydrological drought data were analyzed for the western United States to identify potential drought correlations and estimate drought parameters. The first scenario was a West-wide drought occurring in 1977; it represented a severe drought in five of the eight basins in the study area. A second drought scenario was artificially defined by selecting the conditions from the 10th-percentile drought year for each individual basin; this drought was defined in this way to allow more consistent analysis of risk to electricity generation in each basin. The final scenario was based upon the current low-flow hydro modeling scenario defined by WECC, which uses conditions from the year 2001. These scenarios were then used to quantify the risk to electricity generation in each basin. The risk calculations represent a first-order estimate of the maximum amount of electricity generation that might be lost from both hydroelectric and thermoelectric sources under a worst-case scenario. Even with the conservative methodology used, the majority of basins showed a limited amount of risk under most scenarios. The level of risk in these basins is likely to be amenable to mitigation by known strategies, combined with existing reserve generation and transmission capacity. However, the risks to the Pacific Northwest and Texas Basins require further study. The Pacific Northwest is vulnerable because of its heavy reliance on hydroelectric generation. Texas, conversely, is vulnerable because of its heavy dependence on thermoelectric generation, which relies on surface water for cooling, along with the fact that this basin seems to experience more severe drought events on average. Further modeling analysis will be performed in conjunction with the modeling teams at the participating interconnections (WECC and ERCOT) to explore the transmission implications of the drought scenarios in more detail. Given the first-order nature of this analysis, more detailed study of the potential impacts of drought on electricity generation is recommended. Future analyses should attempt to model the potential impacts of drought at the power-plant level, including potential mitigation strategies; include the effects of drought duration; understand the impacts of climate change; and consider economic impacts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

User Guide for the International Jobs and Economic Development Impacts Model

The International Jobs and Economic Development Impacts (I-JEDI) model is a freely available economic model that estimates gross economic impacts from wind, solar, and geothermal energy projects for several different countries. Building on the original JEDI model, which was developed for the United States, I-JEDI was developed under the USAID Enhancing Capacity for Low Emission Development Strategies (EC-LEDS) program to support countries in assessing economic impacts of LEDS actions in the energy sector. I-JEDI estimates economic impacts by characterizing the construction and operation of energy projects in terms of expenditures and the portion of these expenditures made within the country of analysis. These data are then used in a country-specific input-output (I-O) model to estimate employment, earnings, gross domestic product (GDP), and gross output impacts. Total economic impacts are presented as well as impacts by industry. This user guide presents general information about how to use I-JEDI and interpret results as well as detailed information about methodology and model limitations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey

High performance polymers with bio-based modifiers are promising materials in terms of applications and environmental impact. In this work, raw acacia honey was used as a bio-modifier for epoxy resin, as a rich source of functional groups. The addition of honey resulted in the formation of highly stable structures that were observed in scanning electron microscopy images as separate phases at the fracture surface, which were involved in the toughening of the resin. Structural changes were investigated, revealing the formation of a new aldehyde carbonyl group. Thermal analysis confirmed the formation of products that were stable up to 600 °C, with a glass transition temperature of 228 °C. An energy-controlled impact test was performed to compare the absorbed impact energy of bio-modified epoxy containing different amounts of honey with unmodified epoxy resin. The results showed that bio-modified epoxy resin with 3 wt% of acacia honey could withstand several impacts with full recovery, while unmodified epoxy resin broke at first impact. The absorbed energy at first impact was 2.5 times higher for bio-modified epoxy resin than it was for unmodified epoxy resin. In this manner, by using simple preparation and a raw material that is abundant in nature, a novel epoxy with high thermal and impact resistance was obtained, opening a path for further research in this field.

36 MATERIALS SCIENCE↗