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At least 1,081 records · Page 60

A proposed method for electronic feedback compensation of damping in ferromagnetic resonance

Here, we propose an experimental technique for extending feedback compensation of dissipative radiation used in nuclear magnetic resonance (NMR) to encompass ferromagnetic resonance (FMR). This method uses a balanced microwave power detector whose output is phase shifted π/2, amplified, and fed back to drive precession. Using classical control theory, we predict an electronically controllable narrowing of field swept FMR line-widths. This technique is predicted to compensate other sources of spin dissipation in addition to radiative loss.

36 MATERIALS SCIENCE↗

Actuator selection and placement for localized feedback flow control

The selection and placement of actuators and sensors to control compressible viscous flows is addressed by developing a novel methodology based upon the eigensystem structural sensitivity of the linearized evolution operator appropriate for linear feedback control. Forward and adjoint global modes are used to construct a space of possible perturbations to the linearized operator, which yields a small optimization problem for selecting the parameters that best achieve the control objective, including where they should be placed. The method is demonstrated by informing actuation to suppress amplification of the instabilities in boundary layer separation in a high-subsonic diffuser. Complete stabilization is observed in the separated shear layer for short downstream distances at modest Reynolds number. Higher Reynolds numbers and longer distances are expected to be more challenging to stabilize; here the control informed by the procedure still substantively suppresses amplification of instabilities. It is also demonstrated that more complex actuator–sensor selections may not yield superior controllers.

Mechanics↗

Biofilm Feedbacks Alter Hydrological Characteristics of Fractured Rock Impacting Sulfidogenesis and Treatment

Flow-through fractures dominate the movement of fluids in a variety of natural as well as engineered subsurface systems. Microbial activities in fractured rock impact subsurface energy recovery, storage, and waste disposal. It has been recognized that understanding how the contrasting permeability between fracture and matrix interacts with microbial metabolism under thermal and hydrological gradients is key to effective utilization of the subsurface, yet such studies are sparse. Microorganisms mediate the production of hydrogen sulfide (also known as souring) in oil-bearing geological formations. We conducted a comprehensive experimental study of a novel 2D fractured rock system to understand these complex interactions and demonstrated how biofilm development can impact fracture flow, which subsequently feedbacks to moderate sulfidogenesis. Elevated temperature relevant to reservoir conditions interacted with the injection of cold fluid and formed a thermal gradient away from fractures, creating thermal niches for microbial activities in the fractured rock. Finally, results showed that while fracture flows were dominant in the beginning, with time, growth of the biofilm in the fractures reduced permeability, effectively moderating the initial fracture-matrix contrast, and limited microbial accessibility to nutrients and subsequent reactions rates.

59 BASIC BIOLOGICAL SCIENCES↗

Chemical Feedback in the Self-Assembly and Function of Air–Liquid Interfaces: Insight into the Bottlenecks of CO 2 Direct Air Capture

As fossil fuels remain a major source of energy throughout the world, developing efficient negative emission technologies, such as direct air capture (DAC), which remove carbon dioxide (CO 2 ) from the air, becomes critical for mitigating climate change. Although all DAC processes involve CO 2 transport from air into a sorbent/solvent, through an air–solid or air–liquid interface, the fundamental roles the interfaces play in DAC remain poorly understood. In this work, we study the interfacial behavior of amino acid (AA) solvents used in DAC through a combination of vibrational sum frequency generation spectroscopy and molecular dynamics simulations. This study revealed that the absorption of atmospheric CO 2 has antagonistic effects on subsequent capture events that are driven by changes in bulk pH and specific ion effects that feedback on surface organization and interactions. Among the three AAs (leucine, valine, and phenylalanine) studied, we identify and separate behaviors from CO 2 loading, chemical changes, variations in pH, and specific ion effects that tune structural and chemical degrees of freedom at the air–aqueous interface. The fundamental mechanistic findings described here are anticipated to enable new approaches to DAC based on exploiting interfaces as a tool to address climate change.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Self-Amplifying Feedbacks Accelerate Greening and Warming of the Arctic

Increased greening, higher vegetation productivity, and shrubification have been observed in Arctic tundra in response to recent warming. Such changes have affected the near-surface climate through opposing biogeophysical feedbacks (BF) associated with changes to albedo and evapotranspiration. However, the likely spatiotemporal variations of BF to future climate change and the consequences for Arctic vegetation and ecology have not been robustly quantified. In this paper, we apply a regional Earth system model (RCA-GUESS) interactively coupling atmospheric dynamics to land vegetation response in three potential 21st-century radiative forcing simulations for the Arctic. We find that BF, dominated by albedo-mediated warming in early spring and evapotranspiration-mediated cooling in summer, have the potential to amplify or modulate local warming and enhance summer precipitation over land. Finally, the magnitude of these effects depends on radiative forcing and subsequent ecosystem responses. Thus, it is important to account for BF when assessing future Arctic climate change and its ecosystem impacts.

54 ENVIRONMENTAL SCIENCES↗

Microphysical Sensitivity of Superparameterized Precipitation Extremes in the Contiguous United States Due to Feedbacks on Large-Scale Circulation

Superparameterized (SP) global climate models have been shown to better simulate various features of precipitation relative to conventional models, including its diurnal cycle as well as its extremes. While various studies have focused on the effect of differing microphysics parameterizations on precipitation within limited-area cloud-resolving models, we examine here the effect on contiguous U.S. (CONUS) extremes in a global SP model. We vary the number of predicted moments for hydrometeor distributions, the character of the rimed ice species, and the representation of raindrop self-collection and breakup. Using a likelihood ratio test and accounting for the effects of multiple hypothesis testing, we find that there are some regional differences, particularly during spring and summer in the Southwest and the Midwest, in both the current climate and a warmer climate with uniformly increased sea surface temperatures. These differences are most statistically significant and widespread when the number of moments is changed. To determine whether these results are due to (fast) local effects of the different microphysics or the (slower) ensuing feedback on the large-scale atmospheric circulation, we run a series of short, 5-day simulations initialized from reanalysis data. We find that the differences largely disappear in these runs and therefore infer that the different parameterizations impact precipitation extremes indirectly via the large-scale circulation. Finally, we compare the present-day results with hourly rain gauge data and find that SP underestimates extremes relative to observations regardless of which microphysics scheme is used given a fixed model configuration and resolution.

54 ENVIRONMENTAL SCIENCES↗

Power Law Growth and Delayed Feedbacks in Socio-Hydrological Systems

Water infrastructure dynamics result from coupled social and physical hydrological processes embedded in “socio-hydrological systems” (SHSs). Freshwater fuels socioeconomic activity, which in turn exerts pressure on water resources through increased water demand and water quality degradation. Many factors emphasize the need for quantitative tools to predict the future of these systems, including SHS failures due to growing water scarcity from population growth and climate change. However, unfolding the interactions between social and hydrological factors continues to resist theoretical treatment, impeding progress toward a predictive framework. To resolve this issue, we propose and evaluate time delays as surrogates for the social dynamics in SHS models. This approach permits the development of models that describe SHS dynamics in terms of observable, physical, hydrological state variables. We apply this approach to two case studies: (a) reservoir storage capacity growth in the world and the U.S. Water Resources Regions and (b) global water withdrawals. Substantial variability was identified in empirical estimates of growth rates and time delays. Reservoir construction typically follows a saturating, logistic curve with periodic, punctuated equilibria, separated by delays ranging from 5 to 20 years both globally and regionally. In contrast, global water withdrawal data display faster-than-exponential growth, characteristic of a positive feedback through which water use drives further water development. Historical analysis suggests that growth trends in water resources systems are superimposed by recurring periods of innovation and inactivity which are indicative of slow memory dissipation and delayed effects of past water use on current water infrastructure decisions.

54 ENVIRONMENTAL SCIENCES↗

Effects of Low-Carbon Energy Adoption on Airborne Particulate Matter Concentrations With Feedbacks to Future Climate Over California

California plans to reduce emissions of long-lived greenhouse gases (GHGs) through adoption of new energy systems that will also lower concentrations of short-lived absorbing soot contained in airborne particulate matter (PM). Here we examine the direct and indirect effects of reduced PM concentrations under a low-carbon energy (GHG-Step) scenario on radiative forcing in California. Simulations were carried out using the source-oriented WRF/Chem (SOWC) model with 12 km spatial resolution for the year 2054. Furthermore, the avoided aerosol emissions due to technology advances in the GHG-Step scenario reduce ground level PM concentrations by ~8.85% over land compared to the Business-as-Usual (BAU) scenario, but changes to meteorological parameters are more modest. Top-of-atmospheric forcing predicted by the SOWC model increased by 0.15 W m -2 , surface temperature warmed by 0.001 K, and planetary boundary layer height (PBLH) increased by 2.20 cm in the GHG-Step scenario compared to the BAU scenario. PM climate feedbacks are small because the significant changes in ground level PM concentrations associated with the GHG-Step scenario are limited to the first few hundred meters of the atmosphere, with little change for the majority of the vertical column above that level. As an order-of-magnitude comparison, the long-term effects of global reductions in GHG emissions (RCP8.5–RCP4.5) lowered average surface temperature over the California study domain by approximately 0.76 K. The effects of long-lived climate pollutants such as CO 2 are much stronger than the effects of short-lived climate pollutants such as PM soot over California in the year 2054.

54 ENVIRONMENTAL SCIENCES↗

Understanding the eco-geomorphologic feedback of coastal marsh under sea level rise: vegetation dynamic representations, processes interaction, and parametric sensitivity

A growing number of coastal eco-geomorphologic modeling studies have been conducted to understand coastal marsh evolution under sea-level rise (SLR). Although these models quantify marsh topographic change as a function of sedimentation and erosion, their representations of vegetation dynamics that control organic sedimentation differ. How vegetation dynamic schemes contribute to simulation outcomes is not well quantified. Additionally, the sensitivity of modeling outcomes to parameter selection in the available formulations has not been rigorously tested to date, especially under the influence of an accelerating SLR. In this paper, we used a coastal eco-geomorphologic model with different vegetation dynamic schemes to investigate the eco-geomorphologic feedbacks of coastal marshes and parametric sensitivity under SLR scenarios. We found that marsh platform relief increased with sea level rise rate. The simulations with different vegetation schemes exhibited different spatial-temporal variations in elevation and biomass. The nonlinear Spartina scheme presented the most resilient prediction with generally the highest marsh accretion and vegetation biomass, and the least elevation relief under SLR. But the linear Spartina scheme predicts the lowest unvegetated-vegetated ratio. We also found that vegetation-related parameters and sediment diffusivity, which were not well measured or discussed in previous studies, were identified as some of the most critical parameters. Additionally, the model sensitivity to vegetation-related parameters increased with SLR rates. The identified most sensitive parameters may inform how to appropriately choose modeling representations of key processes and parameters for different coastal marsh landscapes under SLR, and demonstrate the importance of future field measurements of these key parameters.

58 GEOSCIENCES↗

On the Importance of Sea Surface Temperature for Aerosol–Induced Brightening of Marine Clouds and Implications for Cloud Feedback in a Future Warmer Climate

Marine low clouds are one of the greatest sources of uncertainty for climate projection. We present an observed climatology of cloud albedo susceptibility to cloud droplet number concentration perturbations (S 0 ) with changing sea surface temperature (SST) and estimated inversion strength for single-layer warm clouds over the North Atlantic Ocean, using eight years of satellite and reanalysis data. The key findings are that SST has a dominant control on S 0 in the presence of co-varying synoptic conditions and aerosol perturbations. Cloud brightening in regions with positive S 0 weakens with increasing local SST. Higher SST significantly hastens cloud-top evaporation with increasing aerosol loading, by accelerating entrainment and facilitating entrainment drying. In a global-warming-like scenario where aerosol loading is reduced, more cloud brightening is expected, mainly as a result of reduced entrainment drying. Furthermore, our results imply a less positive low-cloud liquid water path feedback in a warmer climate with decreasing aerosol loading.

54 ENVIRONMENTAL SCIENCES↗

Rain-Induced Stratification of the Equatorial Indian Ocean and Its Potential Feedback to the Atmosphere

Surface freshening through precipitation can act to stably stratify the upper ocean, forming a rain layer (RL). RLs inhibit subsurface vertical mixing, isolating deeper ocean layers from the atmosphere. This process has been studied using observations and idealized simulations. The present ocean modeling study builds upon this body of work by incorporating spatially resolved and realistic atmospheric forcing. Fine-scale observations of the upper ocean collected during the Dynamics of the Madden-Julian Oscillation field campaign are used to verify the General Ocean Turbulence Model (GOTM). Spatiotemporal characteristics of equatorial Indian Ocean RLs are then investigated by forcing a 2D array of GOTM columns with realistic and well-resolved output from an existing regional atmospheric simulation. RL influence on the ocean-atmosphere system is evaluated through analysis of RL-induced modification to surface fluxes and sea surface temperature (SST). This analysis demonstrates that RLs cool the ocean surface on time scales longer than the associated precipitation event. A second simulation with identical atmospheric forcing to that in the first, but with rainfall set to zero, is performed to investigate the role of rain temperature and salinity stratification in maintaining cold SST anomalies within RLs. Approximately one third, or 0.1°C, of the SST reduction within RLs can be attributed to rain effects, while the remainder is attributed to changes in atmospheric temperature and humidity. The prolonged RL-induced SST anomalies enhance SST gradients that have been shown to favor the initiation of atmospheric convection. These findings encourage continued research of RL feedbacks to the atmosphere.

54 ENVIRONMENTAL SCIENCES↗

The Role of Bjerknes and Shortwave Feedbacks in the Tropical Pacific SST Response to Global Warming

Abstract The evolution of tropical sea surface temperatures (SSTs) in response to greenhouse warming is of great societal and scientific interest. Most state‐of‐the‐art climate models predict a mean “El Niño‐like” warming pattern by century‐end, characterized by greater warming over the Pacific cold tongue compared to the western warm pool. However, it is unclear which proposed mechanism dominates in this response. Here, we present partially coupled abrupt CO 2 doubling experiments in which surface wind stress and shortwave heating are overridden to values from a control simulation. Contrary to previous studies, we find that experiments with overriding of surface wind stress exhibit only 58% of the full reduction in east‐west SST contrast. When both surface wind stress and shortwave flux are overridden, only 34% of the full reduction remains, controlled by spatially‐varying evaporative cooling. These results underscore the importance of Bjerknes and shortwave feedbacks in the tropical Pacific SST response to global warming.

Geology↗

Experimental Whole-Ecosystem Warming Enables Novel Estimation of Snow Cover and Depth Sensitivities to Temperature, and Quantification of the Snow-Albedo Feedback Effect

Climate change is reducing the amount, duration, and extent of snow across high-latitude ecosystems. But, in landscapes where persistent winter snow cover develops, experimental platforms to specifically investigate interactions between warming and changes in snowpack, and impacts on ecosystem processes, have been lacking. We leveraged a whole-ecosystem warming experiment in a boreal peatland forest to quantify how snow duration, depth, and fractional cover vary with warming of up to +9°C. We found that every snow-related quantity we examined declined precipitously as the amount of warming increased. The importance of deep, continuous snow cover for moderating shallow soil temperature is highlighted by an increase in soil temperature variance and the frequency of short-duration freeze-thaw cycles in the warmer plots. We used a paired-plot approach to estimate the magnitude of the snow-albedo feedback effect, and demonstrate that albedo-driven warming linked to reduced snow cover varies between December (+0.4°C increase in maximum air temperature) and March (+1.2°C increase) because of differences in insolation. Overall, results show that even modest future warming will have profound impacts on northern winters and cold-season ecosystem processes. Plot-level data from this warming experiment, and emergent relationships between warming and quantities related to snow cover and duration, could be of enormous value for testing and improving the representation of snow processes in simulation models, especially under future climate scenarios that are outside of the range of historically observed variability.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric Feedbacks Reverse the Sensitivity of Modeled Photosynthesis to Stomatal Function

Stomata mediate fluxes of carbon and water between terrestrial plants and the atmosphere. These fluxes are governed by stomatal function and can be modulated in many Earth system models by an empirical parameter within the calculation of stomatal conductance, the stomatal slope (𝑔 1⁢𝑀 ). Intuitively, 𝑔 1⁢𝑀 represents the marginal water cost of carbon, relating it to the emergent plant property of water use efficiency. Observations show that 𝑔 1⁢𝑀 can range widely across and within plant types in varying environments, and this distribution of 𝑔 1⁢𝑀 is not captured within Earth system models which represent each plant type with a single 𝑔 1⁢𝑀 value. Here we examine how 𝑔 1⁢𝑀 influences photosynthesis using coupled Earth system model simulations by perturbing 𝑔 1⁢𝑀 to observed 5⁢t⁢h and 95⁢t⁢h percentiles for each plant type. We find that high 𝑔 1⁢𝑀 reduces photosynthesis nearly everywhere, while low 𝑔 1⁢𝑀 has regionally dependent responses. Under fixed atmospheric conditions, low 𝑔 1⁢𝑀 increases photosynthesis in the Amazon and central North America but decreases photosynthesis in boreal Canada. These responses reverse when the atmosphere responds interactively due to spatially differing sensitivity to increases in temperature and vapor pressure deficit. Choice of 𝑔 1⁢𝑀 also influences photosynthetic response to changes in atmospheric carbon dioxide (CO 2 ), with lower and higher 𝑔1⁢𝑀 modifying total global response to elevated 2x preindustrial CO 2 by +6.4% and −9.6%, respectively. Our work demonstrates that atmospheric feedbacks are critical for determining the photosynthetic response to 𝑔 1⁢𝑀 assumptions and some regions are particularly sensitive to choice of 𝑔 1⁢𝑀 .

Liu, Amy X. [University of Washington, Seattle, WA↗

Climate change and the permafrost carbon feedback

Large quantities of organic carbon are stored in frozen soils (permafrost) within Arctic and sub-Arctic regions. Awarming climate can induce environmental changes that accelerate the microbial breakdown of organic carbon and the release of the greenhouse gases carbon dioxide and methane. Furthermore, this feedback can accelerate climate change, but the magnitude and timing of greenhouse gas emission from these regions and their impact on climate change remain uncertain. Here we find that current evidence suggests a gradual and prolonged release of greenhouse gas emissions in a warming climate and present a research strategy with which to target poorly understood aspects of permafrost carbon dynamics.

54 ENVIRONMENTAL SCIENCES↗

Alaskan carbon-climate feedbacks will be weaker than inferred from short-term experiments

Climate warming is occurring fastest at high latitudes. Based on short-term field experiments, this warming is projected to stimulate soil organic matter decomposition, and promote a positive feedback to climate change. We show here that the tightly coupled, nonlinear nature of high-latitude ecosystems implies that short-term (<10 year) warming experiments produce emergent ecosystem carbon stock temperature sensitivities inconsistent with emergent multi-decadal responses. We first demonstrate that a well-tested mechanistic ecosystem model accurately represents observed carbon cycle and active layer depth responses to short-term summer warming in four diverse Alaskan sites. We then show that short-term warming manipulations do not capture the non-linear, long-term dynamics of vegetation, and thereby soil organic matter, that occur in response to thermal, hydrological, and nutrient transformations belowground. Our results demonstrate significant spatial heterogeneity in multi-decadal Arctic carbon cycle trajectories and argue for more mechanistic models to improve predictive capabilities.

54 ENVIRONMENTAL SCIENCES↗

Redox-enabled electronic interrogation and feedback control of hierarchical and networked biological systems

Abstract Microelectronic devices can directly communicate with biology, as electronic information can be transmitted via redox reactions within biological systems. By engineering biology’s native redox networks, we enable electronic interrogation and control of biological systems at several hierarchical levels: proteins, cells, and cell consortia. First, electro-biofabrication facilitates on-device biological component assembly. Then, electrode-actuated redox data transmission and redox-linked synthetic biology allows programming of enzyme activity and closed-loop electrogenetic control of cellular function. Specifically, horseradish peroxidase is assembled onto interdigitated electrodes where electrode-generated hydrogen peroxide controls its activity. E. coli ’s stress response regulon, oxyRS , is rewired to enable algorithm-based feedback control of gene expression, including an eCRISPR module that switches cell-cell quorum sensing communication from one autoinducer to another—creating an electronically controlled ‘bilingual’ cell. Then, these disparate redox-guided devices are wirelessly connected, enabling real-time communication and user-based control. We suggest these methodologies will help us to better understand and develop sophisticated control for biology.

59 BASIC BIOLOGICAL SCIENCES↗

Fiber optic computing using distributed feedback

Abstract The widespread adoption of machine learning and other matrix intensive computing algorithms has renewed interest in analog optical computing, which has the potential to perform large-scale matrix multiplications with superior energy scaling and lower latency than digital electronics. However, most optical techniques rely on spatial multiplexing, requiring a large number of modulators and detectors, and are typically restricted to performing a single kernel convolution operation per layer. Here, we introduce a fiber-optic computing architecture based on temporal multiplexing and distributed feedback that performs multiple convolutions on the input data in a single layer. Using Rayleigh backscattering in standard single mode fiber, we show that this technique can efficiently apply a series of random nonlinear projections to the input data, facilitating a variety of computing tasks. The approach enables efficient energy scaling with orders of magnitude lower power consumption than GPUs, while maintaining low latency and high data-throughput.

97 MATHEMATICS AND COMPUTING↗