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DOE OSTI2024

Concrete Testing Case for Closure of Handford’s 241-C Underground Storage Tanks

Sixty percent of the nation's highly toxic and radioactive mixed wastes are stored at Hanford in 177 deteriorating underground storage tanks. To close or remove these storage tanks from service and place them in a condition that is protective of human health and the environment, the tanks must be physically stabilized to prevent subsidence once wastes have been retrieved. Remaining residual liquid waste in the tanks that cannot be removed must be solidified and the solid wastes encapsulated to meet the Nuclear Regulatory Commission, Department of Energy, Environmental Protection Agency, and the State of Washington requirements. The Department of Energy has developed cementitious flowable concretes to restrict access and provide chemical stabilization for radionuclides. Formulation, laboratory, and field testing for application at Hanford began with flowable, self-leveling structural and non-structural fills. A slump flow equal to or greater than 610 mm, 0% bleed water, and 0.1% (by volume) shrinkage measurements were key parameters guiding reformulation efforts that resulted in highly flowable, self-consolidating concretes that met Hanford 241-C Tank closure short- and long-term regulatory and engineering performance requirements.

formula development↗

DOE OSTI2024

Meteorological Conditions and Atmospheric Components Concentration in Urban Sites in Knoxville, USA. 2024

This dataset, which contains five csv files, reports several meteorological conditions such as temperature, wind speed, solar radiation, and net radiation measured in Cumberland Estates Park (CEP) and Socially Equal Energy Efficient Development (SEEED) sites in Knoxville, Tennessee, USA. Also, hourly concentration of particulate matter (PM) with different aerodynamic diameter and inorganic gases such as ozone and nitrogen dioxide measured in the two are included in this dataset. The concentrations of PM and inorganic gases were monitored using the MODULAIR, a low-cost sensor equipped with a solar power module. The measurement of the concentration of biogenic and anthropogenic volatile organic compounds (VOCs) of the two sites was determined using a High-Resolution Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-ToF-MS). The VOCs were collected using miniature canister (400 mL) equipped with female RAVEqc valve to 1/4” male compression fitting and an integrated passive air sampling kit. This work is a part of a larger study which investigates the impact of soil moisture and plant evapotranspiration on ambient temperature and relative humidity in several city parks in Knoxville, Tennessee.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Atmospheric and Soil Parameters in Five Urban Sites in Knoxville, Tennessee. 2024

This dataset, which contains ten csv files, reports several meteorological conditions such as temperature, wind speed, solar radiation, and net radiation measured in several urban parks in Knoxville, Tennessee, USA: Cumberland Estates Park (CEP), Socially Equal Energy Efficient Development (SEEED), West View Park (WVP), Victor Ashe Park (VAP), and West Hills Park (WHP). Also, hourly average of soil parameters such soil temperature, moisture, and matric potential measured in the five sites are included in this dataset. Air temperature, wind speed and direction, and solar radiation data were obtained from a METER ATMOS 41 All-in-One Weather Station (Pullman, Washington, USA). Soil moisture and temperature parameters were measured the METER Teros 12 probes embedded to a depth of 5 cm into the soil, while soil matric potential was measured with a METER Teros 21 probe. Incident and emitted radiation (shortwave and longwave) measurements were made using an Apogee (Logan, Utah, USA) net radiometer (Model SN-500-SS). This work is a part of a larger study which investigates the impact of soil moisture and plant evapotranspiration on ambient temperature and relative humidity in several city parks in Knoxville, Tennessee.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2026

Soil Temperature Sensor Data, May - December 2024, Five sites in Knoxville, Tennessee

This dataset contains surface soil temperature measurements from five urban parks in Knoxville: Cumberland Estates Park (CE), Socially Equal Energy Efficient Development (SD), West View Park (WV), Victor Ashe Park (VA), and West Hills Park (WH). The dataset comprises 29 Excel (.xlsx) and Comma-Separated Values (.csv) files documenting soil temperature recorded by six HOBO Pendant MX Water Temperature Data Loggers at each site, except for CE, which has five sensors. Each logger was installed at a depth of 10 inches and positioned approximately 3 to 6 feet from the weather station at each site. To open both csv and xlsx files, users can utilize spreadsheet applications such as Microsoft Excel, Google Sheets, LibreOffice Calc, and Apple Numbers. This dataset is part of a broader study examining the effects of soil moisture and plant evapotranspiration on ambient temperature and relative humidity across multiple urban parks in Knoxville, Tennessee.

EARTH SCIENCE > LAND SURFACE > SOILS↗

DOE OSTI2022

Detecting Passing Valves at Scale Across Different Buildings and Systems: A Brick Enabled and Mortar Tested Application

Heating hot water distribution systems are typically used in commercial buildings to condition spaces to provide occupant thermal comfort. However, recent research shows significant distribution losses within these systems that drive down the overall hot water plant efficiency. This research focuses on detecting passing valves in reheat coils found in variable air volume (VAV) terminal units to reduce distribution losses. A passing valve allows hot water flow when the actuator on the valve is commanded to be closed. The fluid causes unintentional heating or cooling to occur, causing comfort and control issues, and wasting energy. We developed the passing valve detection algorithm using a framework based on the Brick schema and Mortar platform to ensure that the application is portable and can scale to many buildings. We applied the same application to analyze 1,335 VAV reheat terminal units in 20 buildings. The diversity found in these large datasets increases confidence that any building with VAV reheat terminal units with the required sensors and Brick data model can run our open-source algorithm with little or no modification. In aggregate, 5% of VAV units analyzed were categorized as having a sensor fault, 14% with potential passing valve fault, and 81% with no faults detected. However, there is a significant variation in the proportion of VAV units with a passing valve detected (1% to 83%) of each building’s analyzed units.

Roa, Carlos Duarte↗

DOE OSTI2020

Nuclear Structure Studies. Final Report

This is the final progress report resulting from 55 consecutive years of support as a Principle Investigator supported by the Atomic Energy Commission, the Energy Research and Development Administration and the Department of Energy. Included in various accomplishments are publications issued and experiments conducted.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2020

Summary of Preliminary Concepts for a Port of Alaska Resilient Microgrid

The Port of Alaska in Anchorage enables the economic vitality of the Municipality of Anchorage and State of Alaska. It also provides significant support to defense activities across Alaska, especially to the Joint Base Elmendorf-Richardson (JBER) that is immediately adjacent to the Port. For this reason, stakeholders are interested in the resilience of the Ports operations. This report documents a preliminary feasibility analysis for developing an energy system that increases electric supply resilience for the Port and for a specific location inside JBER. The project concept emerged from prior work led by the Municipality of Anchorage and consultation with Port stakeholders. The project consists of a microgrid with PV, storage and diesel generation, capable of supplying electricity to loads at the Port a specific JBER location during utility outages, while also delivering economic value during blue-sky conditions. The study aims to estimate the size, configuration and concept of operations based on existing infrastructure and limited demand data. It also explores potential project benefits and challenges. The report goal is to inform further stakeholder consultation and next steps.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2020

Overview of Preliminary Concepts for a Port of Alaska Resilient Microgrid

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2020

Development of a High-Energy Neutron Sniffer and Subsequent Dose Quantification for High-Energy Particle Accelerator Shielding Surveys

The objective of this research is to design a portable neutron detector that is lightweight and responds to neutrons with energies of 20 MeV and greater. The instrument will be used as a ‘sniffer’ probe for identifying shielding weaknesses at high-energy particle accelerators and be paired with a plastic scintillator to quantify the high-energy neutron dose equivalent. The sniffer probes are two different sizes and comprised of either cesium iodide or sodium iodide, all doped with thallium, making a total of four detectors. The probes were calibrated to respond only to radiations with 8 MeV electron equivalent energy or higher, vastly reducing detector response from background and lower energy radiations. The sniffer probes were tested using californium- 252 and americium-beryllium sources, followed by high-energy (up to 800 MeV) neutron exposures at the Los Alamos Neutron Science Center Weapons Neutron Research (WNR) facility. The sniffer probes were then used to identify areas around the accelerator facility where elevated levels of high-energy radiation was present and the plastic scintillators were placed in these locations to determine the high-energy neutron dose equivalent. The dose equivalent is calculated by measuring the 12 C(n,2n) 11 C reaction, which has a 20.4 MeV neutron threshold. Two locations behind the WNR facility were identified with the probes and the dose equivalent rates from neutron energies above 20 MeV were calculated to be 1.24 mrem/h behind flightpath 30-left and 1.53 behind flightpath 30-right. Of the four sniffer probes, the 2-inch x 2-inch cesium iodide is the recommended probe for performing high-energy shielding surveys. The larger crystal size yields higher sensitivity at lower count rates and the more dense material increases the likelihood of interaction within the crystal.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2020

Studies of surface adsorbate electronic structure and femtochemistry at the fundamental length and time scales. Final report

The electronic structure and ultrafast (10-15 s-femtosecond timescale) electron dynamics were investigated for clean and atom/molecule covered metal surfaces. The studies were performed by scanning tunneling microscopy (STM) to measure the structure of adsorbed atoms and molecules on metal surfaces, and to investigate their electronic properties. The electronic structure of the observed molecular networks was calculated by electronic structure theory in collaboration with Prof. Jin Zhao, who is a long-time collaborator, a Professor at the University of Science and Technology of China, and holds an Adjunct Professorship at the University of Pittsburgh. We also investigated the electronic properties of C60 molecules when they are templated by corrugated black phosphorous surfaces. We found unexpected charge delocalization that is enabled by the templating. This research was done in collaboration with Professor Min Feng at the Wuhan University, and who also holds an Adjunct Professorship at the University of Pittsburgh. Moreover, the electronic structure and electron dynamics in metal surfaces were investigated by time-resolved photoemission electron spectroscopy. The focus of ultrafast spectroscopy has been on the plasmonic response of silver surfaces. One direction has been to develop multidimensional (energy, momentum, and time) photoelectron spectroscopy of the coherent response of solid surfaces. This method was applied to study the collective electron excitations known generally as plasmons, which screen optical fields from penetration into metals. Although this collective response has been known for more than 60 years and is used extensively to deposit optical energy into metals, how this happens is poorly known. We investigated the plasmonic response of silver at the point where the dielectric response passes through zero and bulk plasmon is excited by light. We discovered that the plasmon excitation decays by exciting electrons from the Fermi level of a metal, which is contrary to what is believed in the plasmonic science community. This research has been performed in collaboration with Dr. Marcel Reutzel, who was a postdoctoral fellow working on this research at the University of Pittsburgh, and now has a faculty position at the University of Göttingen in Germany. Prof. Branko Gumhalter from the Institute of Physics in Zagreb contributed on the theory of plasmonic decay processes. Furthermore, we investigated the Floquet engineering of electronic bands in metals leading to multiphoton photoemission and above threshold photoemission. Finally, we demonstrated that it is possible to change the electronic structure of metals by application of optical fields. Our studies indicated that this happens on subfemtosecond time scale and could potentially be used in ultrafast information processing and quantum computation. Related document information

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2020

Development of a High-Energy Neutron Sniffer and Subsequent Dose Quantification for High-Energy Particle Accelerator Shielding Surveys [Slides]

Abstract not provided.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2021

Development of an Advanced Hydrogen Energy Storage System using Aerogel in a Cryogenic Flux Capacitor (CFC)

The Cryogenic Flux Capacitor (CFC) is a cold, dense fluid storage core with integrated design features that afford the designer flexibility and provide new possibilities for the storage and discharge of energy. The stored energy, in this case, is represented by hydrogen physically bonded within the nanoscale pores within the aerogel composite blanket material, and the process of bonding or debonding is governed by principles of physical adsorption (physisorption) and thermodynamics. The large surface area afforded by the nanoporous aerogel (~1,000 m2/g) allows for storage densities close to, or in some cases exceeding, that of normal boiling point liquids. Its performance easily exceeds what can be achieved via ambient temperature, high-pressure gas storage for an equivalent volume. CFC storage is predicted to be easily scalable, is constructed from readily available commercial materials, lends itself to a range of pressure applications, and is geometry insensitive. They can also be used in modular designs, affording even more flexibility for potential deployment. In addition to the aerogel adsorbent within the blanket material, a CFC includes thermally-conductive membrane layered with the aerogel, which acts as a large-area, quick-response thermal management system. The system conducts heat throughout the volume to discharge the unit quickly. This same thermal management system can also be connected to a refrigeration system, or cold fluid such as liquid nitrogen (LN2), to facilitate the charging up of the CFC. The charging and discharging can be performed as fast or as slow as desired by controlling the cooling or heating supplied to the CFC.

08 HYDROGEN↗

DOE OSTI2022

Introducing Small Scale Waste-to-Energy Technology in Microgrids (Cooperative Research and Development Final Report, CRADA Number CRD-17-00703)

Cogent has developed an innovative, proprietary waste-to-energy (WTE) system, the HelioStorm(TM) Gasifier, capable of efficiently operating on small amounts of heterogeneous municipal solid waste feedstocks, converting them into a clean syngas that can be used to fuel an electricity generator, all with rapid on/off cycle times. NREL will work with Cogent to complete a computer simulation of an integrated HelioStorm(TM) plasma gasifier system and dual fuel diesel generator. Cogent will test the performance of an actual HelioStorm(TM) WTE system and dual fuel diesel generator at their test facility using steady state electrical loads and provide a report describing the performance of the integrated system.

09 BIOMASS FUELS↗

DOE OSTI2022

Regional Feedstock Partnership Biomass Quality Assessment Final Report

The United States (U.S.) Department of Energy (DOE) developed the Billion-Ton Vision to enable production of one-billion tons of sustainable, reliable biomass for the bioenergy industry by 2030 (Perlack et al., 2005). The Sun Grant Regional Feedstock Partnership (RFP) was organized to fill information gaps and validate biomass yield assumptions related to the Billion-Ton Study (Owens, 2018; Owens, Karlen, and Lacey, 2016). Along with the more than 130 scientific publications generated from these studies, yield and sustainability data from the RFP field trials not only validated the Billion-Ton estimates, but were critical in developing both the U.S. Billion-Ton Update report in 2011 and the 2016 Billion-Ton Report (DOE, 2011; 2016). The intention of this biomass quality assessment report is to build on these initial successes from the RFP field trials by focusing on variability in biomass quality data necessary to evaluate conversion performance. This report contains a summary of chemical quality results from samples collected as part of the RFP field trials. This report focuses on assessment of the impact of experimental agronomic designs on biomass properties followed by analyses of the impact of environmental and production variables on biomass properties. Datasets include species and other genetic variables, fertilizer treatments, harvest information, and yield, as well as other publicly available data such as precipitation, temperature, soil properties, and drought. The key outcomes from this chemical quality focused assessment have included: • Complete evaluation of the impacts of agronomic designs, genetics, and environmental conditions on chemical properties for Miscanthus, switchgrass, sorghum, energycane, mixed perennial grasses, and shrub willow short-rotation feedstocks • Over 30 peer review publications and technical reports focused on variability in quality data • Development of spatial and temporal environmental quality prediction maps for Miscanthus and switchgrass feedstocks allowing for comprehensive evaluation of variability in feedstock chemical quality across U.S. regions and over multiple harvest years

09 BIOMASS FUELS↗

DOE OSTI2022

AI@DOE Interim Executive Report

Interim executive report for DOE’s Office of Science, NNSA, and Applied Energy Offices, in collaboration with the Artificial Intelligence and Technology Office, DOE AI roundtable workshops (December 2021 through February 2022) (“AI@DOE”). These workshops were used to help identify AI research requirements and priorities for the next decade for Department of Energy in developing machine-learning-based prediction and decision-support capabilities that address and anticipate DOE mission challenges. These missions’ challenges for AI include: AI to advance scientific discovery and technological innovation AI to support high consequence decisions while managing risk AI to improve DOE’s responsiveness to national & global issues AI to assist stewardship of the environment and national critical infrastructure These will be addressed in large part through the development and application of new and powerful artificial intelligence and/or machine learning algorithms and strategies. https://web.cvent.com/event/fc3922f8-fc75-4041-a317-f13a1da44f7c/summary?locale=en-US&i=2Wx2tjbStkydRFq_N2whPw

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2022

Exceedance Response Action (ERA) Level 2 (Technical Report)

The Sandia National Laboratories, California (SNL/CA) site comprises approximately 410 acres and is located in the eastern portion of Livermore, Alameda County, California. The property is owned by the United States Department of Energy/National Nuclear Security Administration (DOE/NNSA) and is being managed and operated by National Technology & Engineering Solutions of Sandia, LLC (NTESS). Operations at the SNL/CA facility consist of DOE statutory responsibilities for nuclear weapon research and design, development of energy technologies, and basic scientific research. Specific industrial activities occur in discrete buildings and include electroplating or anodizing, machine shop, permitted hazardous waste treatment, storage and disposal facility (TSDF), and a scrap yard.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Systems Packages for Washington State Building Performance Standard Incentive Program: Phase 1 Analysis

Starting in 2026 Washington State building performance standards will come into effect that require commercial buildings larger than 50,000 sf to meet site energy use intensity targets. To support a state incentive program designed to encourage building owners to start complying early, we characterized the building stock energy use of 11 building types, analyzed 43 energy upgrade measures, and developed seven packages of energy upgrade measures using the ComStock energy analysis tool. Each energy upgrade package included from 4 to 17 energy measures consisting of lighting, HVAC, and envelope upgrades. Package savings were calculated for four priority building types using a sample of 35,000 buildings characterized by four building area bins, three climate zones, and two county types (urban and rural). Of the 28 package and building type combinations analyzed, 17 (61%) met or exceeded program energy savings targets and two packages met targets for all four building types.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2021

Powering the Blue Economy Foundational Research & Development Topics Reliability for Marine Energy Power Systems

Ocean observing platforms are deployed across the world’s oceans to collect meteorological and oceanographic data. Current technology makes use of solar panels and battery banks to provide power to these platforms, which can be challenging at high latitudes due to lack of solar insolation and cold temperatures. Marine renewable energy (MRE) generation offers a potential improvement in consistent power generation throughout the year for this use on ocean observation buoys. This report analyzes existing reliability of high latitude coastal weather buoys and tsunami detection buoys to determine performance standards that MRE generation sources must meet to become viable power sources for these remote systems. Using measurements recorded from the U.S. National Data Buoy Center’s coastal weather buoys and tsunami detection buoys, the analysis calculated the historic data availability – or the percentage of time a measurement is recorded – to evaluate the reliability of ocean observation buoys. The results show that coastal weather buoys operate at 74% data availability and the tsunami detection systems operate at an average 72% data availability. The results describe the total reliability of the system, including many different types of failures not associated with the power system such as mooring failures or equipment failures caused by extreme weather. Power system outages may only account for a small portion of the system failures. Reliability is an important design criterion for the power system of ocean observation platforms. Future power systems that would be designed for these buoys, such as an MRE generator, need to have a minimum reliability of 72% and 74% to meet the overall performance of the weather buoys and tsunami buoys, respectively. However, power system reliability likely needs to be much higher than overall system reliability, so that power system outages do not negatively impact the overall performance of the buoy.

42 ENGINEERING↗