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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Enhanced Thermoelectric Properties for PEDOT:PSS/Undoped Ge Thin-Film Bilayered Heterostructures

Modulation doping is one of the strategies to improve thermoelectric power factors of nanocomposites and thin-film bilayered heterostructures by effectively increasing electrical conductivity. Here, it is reported that thin-film heterostructures of heavily doped p-type organic conducting polymer, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and undoped thin-film Ge can enhance thermoelectric power factor by modulation doping. The maximum power factor and Seebeck coefficient of the bilayered heterostructures are 154 µW m -1 K -2 and 398 µV K -1 , respectively, corresponding to 47-fold and 41-fold increases compared to those of bulk PEDOT:PSS and 64-fold increase compared to power factor of undoped Ge. The enhancements in power factor and Seebeck coefficient are quantitatively described by the hole transfer from PEDOT:PSS to Ge, which takes into account the band alignment at the interface detected by Kraut's method. Agreement between the simulation and experiment results also implies predictability of thermoelectric performances of nanoscale bilayered heterostructures in general, when band offset, Fermi level, and individual electronic properties are available. This work can be further extended to predict performance of other nanoscale combinations of thermoelectric and other electronic materials in general.

charge transport↗
DOE OSTI2015

X-Ray Radar Imaging Technique Using a 2 Mev Linear Electron Accelerator

X-ray radar imaging, patented in 2013 by James R. Wood, combines standard radar techniques with the penetration power of x-rays to image scenes. Our project strives to demonstrate the technique using a 2 MeV linear electron accelerator (linac) to generate the S-band–modulated x-ray signals. X-ray detectors such as photodiodes and scintillators are used to detect the signals in backscatter and transmission detection schemes. The S-band microstructure is imposed on the variable-width electron pulse, and this modulation carries over to the bremsstrahlung x-rays after the electron beam is incident upon a copper-tungsten alloy target. Using phase/distance calculations and a low-jitter timing system, we expect to detect different object distances by comparing the measured phase differences. The experimental setup, which meets strict jitter requirements, and preliminary experimental results are presented.

43 PARTICLE ACCELERATORS↗
DOE OSTI2012

Test particle simulation of direct laser acceleration in a density-modulated plasma waveguide

Direct laser acceleration (DLA) of electrons by the use of the intense axial electric field of an ultrafast radially polarized laser pulse is a promising technique for future compact accelerators. Density-modulated plasma waveguides can be implemented for guiding the propagation of the laser pulse to extend the acceleration distance and for the quasi-phase-matching between the accelerated electrons and the laser pulse. A test particle model is developed to study the optimal axial density modulation structure of plasma waveguides for laser pulses to efficiently accelerate co-propagating electrons. A simple analytical approach is also presented, which can be used to estimate the energy gain in DLA. The analytical model is validated by the test particle simulation. The effect of injection phase and acceleration of electrons injected at various radial positions are studied. The results indicate that a positively chirped density modulation of the waveguide structure is required to accelerate electron with low initial energies, and can be effectively optimized. A wider tolerance on the injection phase and radial distance from the waveguide axis exists for electrons injected with a higher initial energy.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1979

ATS-6 satellite radio beacon measurements at Ootacamund, India

ATS-6 radio beacon measurements of modulation phase and Faraday rotation made at Ootacamund, India in 1975-1976 are discussed with emphasis on the measurement and analysis errors. The modulation-phase errors are insensitive to the geomagnetic field and provide an accurate determination of the total columnar electron content. Comparison of modulation-phase measurements at different frequencies shows a minor sensitivity to the ATS-6 pitch angle. For the low geomagnetic latitude and nearly transverse propagation conditions of Ootacamund, the use of a fixed conversion coefficient gives an unreliable Faraday content. However, the Faraday rotation measurements may be used to determine the shape factor F, which provides information about the electron density height profile.

Davies, K.↗
DOE OSTI2021

Beam Profile Measurements Utilizing an Amplitude Modulated Pulsed Fiber Laser at PIP2IT

Fermilab is undertaking the development of a new 800 MeV superconducting RF linac to replace its present normal conducting 400 MeV linac. The PIP-II linac consists of a warm front-end generating 2 mA of 2.1 MeV H⁻ followed immediately by a series of superconducting RF cryomodules to 800 MeV. To limit the potential damage to the superconducting RF cavities, PIP-II will utilize laser-based monitors to obtain beam profiles via photoionization. This paper will present the results of transverse and longitudinal beam profile measurements using a prototype profile monitor that was tested with 2.1 MeV H⁻ beam at the PIP-II Injector Test (PIP2IT) accelerator. This prototype profile monitor utilizes a high repetition rate fiber laser and fiber optic transport into the PIP2IT enclosure. In addition, results will be shown of narrow-band electron detection from amplitude modulated laser pulses.

43 PARTICLE ACCELERATORS↗
DOE OSTI2014

Long-range electronic reconstruction to a d xz,yz -dominated Fermi surface below the LaAlO 3 /SrTiO 3 interface

Low dimensionality, broken symmetry and easily-modulated carrier concentrations provoke novel electronic phase emergence at oxide interfaces. However, the spatial extent of such reconstructions - i.e. the interfacial “depth” - remains unclear. Examining LaAlO 3 /SrTiO 3 heterostructures at previously unexplored carrier densities $n_{2D}$ ≥ 6.9 × 10 14 cm –2 , we observe a Shubnikov-de Haas effect for small in-plane fields, characteristic of an anisotropic 3D Fermi surface with preferential d xz,yz orbital occupancy extending over at least 100 nm perpendicular to the interface. Quantum oscillations from the 3D Fermi surface of bulk doped SrTiO 3 emerge simultaneously at higher $n_{2D}$. We distinguish three areas in doped perovskite heterostructures: narrow (<20 nm) 2D interfaces housing superconductivity and/or other emergent phases, electronically isotropic regions far (>120 nm) from the interface and new intermediate zones where interfacial proximity renormalises the electronic structure relative to the bulk.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Betatron x-ray radiation in the self-modulated laser wakefield acceleration regime: prospects for a novel probe at large scale laser facilities

This paper presents an experimental and theoretical study of betatron x-ray radiation from laser wakefield acceleration in the self-modulated regime. Our experiments use picosecond duration laser pulses up to 150 J, for plasmas with electronic densities on the order of 10 19 cm -3 . In the self-modulated regime, electrons accelerated in the wake of the laser pulse are subject to both the longitudinal plasma and transverse laser electrical fields. As a result, they undergo oscillations and radiate a synchrotron-like spectrum. In our experimental configuration, electrons accelerated up to about 300 MeV, as well as betatron x-ray spectra with energies of 10 s of keV and photon fluxes between 10 8 –10 10 photons/eV/Sr are reported here. Our experiments open the prospect of using betatron x-ray radiation for applications, and the source could be competitive with current x-ray backlighting methods on multi-kilojoule laser systems used for high energy density or fusion sciences.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Novel microbial based enzymatic CO2 fixation mechanisms: Conformational control of enzymatic reactivity

The broad, long-term goal of the research is to provide insight into the mechanism of novel carboxylation and electron bifurcation reactions as paradigms to study how enzyme utilized protein conformational change to protect reactive intermediates and/or control the pathway in a catalytic cycle. catalyzed by enzymes involved in bacterial alkene, ketone, and epoxide metabolism. We are examining two paradigms in which conformational change is a key mechanistic feature of 1) protecting reaction intermediates that are sensitive to breakdown in the presence of water and 2) directing electron flow in reactions that split electron pairs along two pathways in reactions that fine tune metabolic efficiency in microbial metabolism. Both paradigms are of key importance in defining the molecular determinants of reactions relevant to CO 2 capture and fuel upcycling. In the first paradigm the compounds acetone and bicarbonate are activated by the addition of phosphate creating reaction intermediates (phosphoenolacetone and carboxyphosphate) that are very sensitive to breakdown in the presence of water. We are studying the mechanism of how the enzyme protects these reactive intermediates from water by encapsulating them upon their formation within a hydrophobic protein channel leading to an enzyme active site approximately 40 Å away. In the second paradigm, we are examining how the direction of electron transfer reactions can be modulated through protein conformational change that alters either the difference driving force or distance or both between electron transfer pathways in enzymes that catalyze electron bifurcation. We are using a combination of enzyme kinetics, mass spectrometry, spectroscopy, and structural analysis through X-ray diffraction and scattering methods to characterize the mechanism of conformational changes along the catalytic path. Within the context of the mission of the Department of Energy and the core activities of the Energy Biosciences, the results obtained in the study will reveal new insights into the fundamentals of novel carboxylation / CO 2 capture chemical transformations and electron transfer reactions that equate to biological fuel upcycling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

Periodic escape of relativistic electrons from the Jovian magnetosphere

We adopt a model in which the Jovian magnetospheric tail is forced open by plasma that is accelerated out of the ionosphere by the centrifugal force of corotation. Any longitudinal asymmetry that exists in the ionospheric plasma source and/or the planetary magnetic field will cause a diurnal variation in the radial extent of the trapping region for energetic electrons. This diurnal variation in the extent of the particle trapping region can result in a time-dependent loss of relativistic electrons from the Jovian magnetosphere, modulated at the planetary rotation period. The diurnal trapping process may be relevant to the observation of electron pulses in interplanetary space during the Pioneer 10 approach to Jupiter.

Hill, T. W.↗
DOE OSTI2012

The E-lens test bench for RHIC beam-beam compensation

To compensate for the beam-beam effects from the proton-proton interactions at IP6 and IP8 in the Relativistic Heavy Ion Collider (RHIC), we are fabricating two electron lenses that we plan to install at RHIC IR10. Before installing the e-lenses, we are setting-up the e-lens test bench to test the electron gun, collector, GS1 coil, modulator, partial control system, some instrumentation, and the application software. Some e-lens power supplies, the electronics for current measurement will also be qualified on test bench. The test bench also was designed for measuring the properties of the cathode and the profile of the beam. In this paper, we introduce the layout and elements of the e-lens test bench; and we discuss its present status towards the end of this paper.

43 PARTICLE ACCELERATORS↗
DOE OSTI2015

Charge Transport across DNA-Based Three-Way Junctions

DNA-based molecular electronics will require charges to be transported from one site within a 2D or 3D architecture to another. While this has been shown previously in linear, π-stacked DNA sequences, the dynamics and efficiency of charge transport across DNA three-way junction (3WJ) have yet to be determined. Here, we present an investigation of hole transport and trapping across a DNA-based three-way junction systems by a combination of femtosecond transient absorption spectroscopy and molecular dynamics simulations. Hole transport across the junction is proposed to be gated by conformational fluctuations in the ground state which bring the transiently populated hole carrier nucleobases into better aligned geometries on the nanosecond time scale, thus modulating the π–π electronic coupling along the base pair sequence.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

A large area 100-channel PICOSEC Micromegas detector with time resolution at the 20 ps level

Abstract The PICOSEC Micromegas precise timing detector is based on a Cherenkov radiator coupled to a photocathode operating in a semi-transparent mode and a Micromegas amplification structure. The first proof of concept single-channel prototype was able to achieve a time resolution below 25 ps. One of the crucial aspects in the development of precise timing gaseous detectors applicable in high-energy physics experiments is a modular design that enables large area coverage. The first 19-channel multi-pad prototype with an active area of approximately 10 cm 2 suffered from degraded timing resolution due to the non-uniformity of the preamplification gap thickness. A new 100 cm 2 detector module with 100 channels based on a rigid hybrid ceramic/FR4 Micromegas board for improved drift gap uniformity was developed. Initial measurements with 80 GeV/c muons showed improvements in timing response over the measured pads and a time resolution below 25 ps. More recent measurements with a thinner drift gap detector module and newly developed RF pulse amplifiers show that the pad centre resolution can be enhanced to the level of 17 ps. This work will present the development of the detector from structural simulations, design, and beam test commissioning with a focus on the timing performance of a thinner drift gap detector module in combination with new electronics using an automated timing scan method.

Utrobicic, A.↗
DOE OSTI2014

Poster — Thur Eve — 61: A new framework for MPERT plan optimization using MC-DAO

This work combines the inverse planning technique known as Direct Aperture Optimization (DAO) with Intensity Modulated Radiation Therapy (IMRT) and combined electron and photon therapy plans. In particular, determining conditions under which Modulated Photon/Electron Radiation Therapy (MPERT) produces better dose conformality and sparing of organs at risk than traditional IMRT plans is central to the project. Presented here are the materials and methods used to generate and manipulate the DAO procedure. Included is the introduction of a powerful Java-based toolkit, the Aperture-based Monte Carlo (MC) MPERT Optimizer (AMMO), that serves as a framework for optimization and provides streamlined access to underlying particle transport packages. Comparison of the toolkit's dose calculations to those produced by the Eclipse TPS and the demonstration of a preliminary optimization are presented as first benchmarks. Excellent agreement is illustrated between the Eclipse TPS and AMMO for a 6MV photon field. The results of a simple optimization shows the functioning of the optimization framework, while significant research remains to characterize appropriate constraints.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

The electrochemical impact on electrostatic modulation of the metal-insulator transition in nickelates

For physical studies of correlated electron systems and for realizing novel device concepts, electrostatic modulation of metal-insulator transitions (MITs) is desired. The inherently high charge densities needed to modulate MITs make this difficult to achieve. The high capacitance of ionic liquids are attractive but, voltages are needed that can be in excess of the electrochemical stability of the system. Here, we show temperature/resistivity data that suggest electrostatic modulation of the MIT temperature of NdNiO{sub 3} in a wide regime. However, additional voltammetric and x-ray photoelectron spectroscopy measurements demonstrate the electrochemical impact of the electrostatic doping approach with ionic liquids.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Extraordinary Redox Activities in Ladder-Type Conjugated Molecules Enabled by B ← N Coordination-Promoted Delocalization and Hyperconjugation

The introduction of B ← N coordinate bond-isoelectronic to C-C single bond-into π-systems represents a promising strategy to impart exotic redox and electrochromic properties into conjugated organic molecules and macromolecules. To achieve both reductive and oxidative activities using this strategy, a cruciform ladder-type molecular constitution was designed to accommodate oxidation-active, reduction-active, and B ← N coordination units into a compact structure. Two such compounds (BN-F and BN-Ph) were synthesized via highly efficient N-directed borylation. These molecules demonstrated well-separated, two reductive and two oxidative electron-transfer processes, corresponding to five distinct yet stable oxidation states, including a rarely observed boron-containing radical cation. Spectroelectrochemical measurements revealed unique optical characteristics for each of these reduced/oxidized species, demonstrating multicolor electrochromism with excellent recyclability. Distinct color changes were observed between each redox state with clear isosbestic points on the absorption spectra. Here, the underlying redox mechanism was elucidated by a combination of computational and experimental investigations. Single-crystal X-ray diffraction analysis on the neutral state, the oxidized radical cation, and the reduced dianion of BN-Ph revealed structural transformations into two distinct quinonoid constitutions during the oxidation and reduction processes, respectively. B ← N coordination played an important role in rendering the robust and reversible multistage redox properties, by extending the charge and spin delocalization, by modulating the π-electron density, and by a newly established hyperconjugation mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Elucidating the Structural and Electronic Effects of Ni and Mn Cationic Incorporation on CoOOH for Efficient Benzyl Alcohol Electrooxidation

Transition-metal oxyhydroxides such as CoOOH are promising low-cost electrocatalysts for the selective electrooxidation of organic molecules, yet the influence of ubiquitous transition-metal impurities on their performance and durability remains poorly understood. Here, we experimentally probed the individual and synergistic electrochemical and structural effects of Ni and Mn incorporations into model CoOOH electrocatalysts toward an efficient benzyl alcohol oxidation reaction (BAOR). Comprehensive electrochemical, microscopic, and spectroscopic analyses reveal that Ni incorporation enhances charge-transfer kinetics and overall activity through the formation of catalytically active Ni 3+ sites, whereas Mn exhibited a more complex but interesting role. At the early stages of operation, Mn 4+ acts as a stabilizing surface layer that mitigates catalyst degradation but partially blocks Co sites before they undergo gradual leaching. The concurrent incorporation of both Ni and Mn yields a trimetallic 2NMC@NF electrocatalyst that integrates the activity benefits of Ni with the stability conferred by Mn, achieving 92.9% benzyl alcohol conversion and 91.4% Faradaic efficiency after 24 h at 1.5 V vs RHE. These findings elucidate how trace Ni and Mn impurities, often introduced from electrolytes or external sources, can modulate the lattice and electronic structure of CoOOH, offering a design strategy for enhancing both activity and long-term stability in electrocatalytic organic oxidation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Ultrafast vibrational control of organohalide perovskite optoelectronic devices using vibrationally promoted electronic resonance

Vibrational control (VC) of photochemistry through the optical stimulation of structural dynamics is a nascent concept only recently demonstrated for model molecules in solution. Extending VC to state-of-the-art materials may lead to new applications and improved performance for optoelectronic devices. Metal halide perovskites are promising targets for VC due to their mechanical softness and the rich array of vibrational motions of both their inorganic and organic sublattices. Here, we demonstrate the ultrafast VC of FAPbBr 3 perovskite solar cells via intramolecular vibrations of the formamidinium cation using spectroscopic techniques based on vibrationally promoted electronic resonance. The observed short (~300 fs) time window of VC highlights the fast dynamics of coupling between the cation and inorganic sublattice. First-principles modelling reveals that this coupling is mediated by hydrogen bonds that modulate both lead halide lattice and electronic states. Cation dynamics modulating this coupling may suppress non-radiative recombination in perovskites, leading to photovoltaics with reduced voltage losses.

36 MATERIALS SCIENCE↗