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At least 1,081 records · Page 60

Space processing of chalcogenide glasses

Manufacture of chalcogenide glasses in space will eliminate many of the causes of optical non-homogeneity and contamination that are inherent in earth-bound manufacture. A program is outlined to demonstrate the feasibility of various techniques and processes that will be utilized to manufacture chalcogenide glasses in space. Amorphous character, purity, and homogeneity parameters are being investigated at various stages of the glass forming process. These parameters in merit index form will serve to provide guidelines for the design of the actual melting experiment in space, and for the optimization of the exact chalcogenide composition to be included in the space experiments.

Larsen, D. C.↗

Further studies of the new component of cosmic rays at low energies

Recent observations with cosmic ray telescopes aboard the Pioneer 10 space probe have revealed an anomalous spectrum of nitrogen and oxygen nuclei relative to other nuclei such as carbon in the quiet time cosmic radiation below about 40 MeV/nuc. These observations are extended with additional data from Pioneer 10 and considerable new data from an identical telescope aboard Pioneer 11. In addition to the enhancement of nitrogen and oxygen nuclei observed earlier, the intensity of neon is enhanced as well. The spectra of boron, magnesium, and silicon appear to be similar to that of carbon. Data on the isotopic composition, solar modulation, and radial gradient of these nuclei are presented.

Webber, W. R.↗

Fibrous refractory composite insulation

Family of high-temperature, low-density refractory composite insulations made from aluminoborosilicate and silica fibers has insulating material with improved mechanical and thermal properties. Composition is useful for reusable heat-shield materials.

Goldstein, H. E.↗

Geochemical anomalies on the eastern limb and farside of the moon

A variety of orbital geochemistry and photogeologic data was used to investigate major geochemical anomalies on the east limb and farside of the moon and to determine the processes responsible for their formation. These anomalies are located in the following regions: (1) near Langemak crater, (2) Mare Marginis, (3) Balmer crater, (4) terrain north of Taruntius crater, and (5) Van de Graaff. It was concluded that these anomalies are related to episodes of extrusive igneous activity which produced deposits with a variety of ages and compositions. Some of the associated volcanic deposits exhibit albedos and surface morphologies similar to those of the nearside maria, while others are now thinly covered by highland debris and are commonly represented by light plains units which exhibit clusters of dark-haloed craters. Little evidence was found for a genuine episode of highland volcanism (e.g., Apollo 15 KREEP basalt, highland basalt, etc.). The existence of intermediate basalts on the eastern limb and farside supports previous suggestions that KREEP-like volcanism was not limited to a small area of the lunar nearside. Eastern limb and farside volcanic activity has been more extensive in both space and time and has produced a greater variety of compositions than has previously been thought. Since thinly covered basaltic units can exert a strong influence on regional surface chemistry as determined from orbit, caution is urged in interpreting the surface compositions of highland terrains which exhibit a high density of dark-haloed impact craters.

Hawke, B. R.↗

Generic waste management requirements for a controlled ecological life support system /CELSS/

Regenerative life support systems for future space missions will require closure of the waste-food loop. Each mission application will generate specific requirements for the waste management system. However, there are generic input and output requirements that can be identified when a probable scenario is chosen. This paper discusses the generic requirements when higher plants are chosen as the primary food source. Attention is focused on the quality and quantity of nutrients necessary for culturing higher plants. The types of wastes to be processed are also discussed. In addition, requirements generated by growing plants on three different substrates are presented. This work suggests that the mineral composition of waste materials may require minimal adjustment to satisfy the plant requirements.

Hoshizaki, T.↗

Low cost silicon-on-ceramic photovoltaic solar cells

A technique has been developed for coating low-cost mullite-based refractory substrates with thin layers of solar cell quality silicon. The technique involves first carbonizing one surface of the ceramic and then contacting it with molten silicon. The silicon wets the carbonized surface and, under the proper thermal conditions, solidifies as a large-grained sheet. Solar cells produced from this composite silicon-on-ceramic material have exhibited total area conversion efficiencies of ten percent.

Koepke, B. G.↗

Review of alternative fuels data bases

Based on an analysis of the interaction of fuel physical and chemical properties with combustion characteristics and indicators, a ranking of the importance of various fuel properties with respect to the combustion process was established. This ranking was used to define a suite of specific experiments whose objective is the development of an alternative fuels design data base. Combustion characteristics and indicators examined include droplet and spray formation, droplet vaporization and burning, ignition and flame stabilization, flame temperature, laminar flame speed, combustion completion, soot emissions, NOx and SOx emissions, and the fuels' thermal and oxidative stability and fouling and corrosion characteristics. Key fuel property data is found to include composition, thermochemical data, chemical kinetic rate information, and certain physical properties.

Harsha, P. T.↗

Non-catalytic surfaces for metallic heat shields

The magnitude of the atom recombination coefficients needed for metal heat shield surfaces on Shuttle-type vehicles is analyzed and discussed. Prior work which identifies surfaces having low catalytic activity is reviewed. Arc tunnel tests to evaluate catalytic activity are described and the difficulties of such tests are discussed. Results are presented which show major differences between atom recombination and atom exchange from molecules. Results of surface analysis show that bulk and surface composition of a coating are different.

Swann, R. T.↗

Spectral reflectance study of the Hadley-Appenine (Apollo 15) region

Twenty-three near infrared spectra were obtained from the Mauna Kea Observatory 2.2 m telescope. Results of an analysis of near infrared spectra obtained for surface units in the Hadley-Apennine region were presented. Compositional trends from the interior to exterior of the Imbrium are discussed.

Lucey, P. G.↗

Selective weathering of shocked minerals and chondritic enrichment of the Martian fines

In a recent paper, Boslough and Cygan reported the observation of shock-enhanced chemical weathering kinetics of three silicate minerals. Based on the experimental data and on those of Tyburczy and Ahrens for enhanced dehydration kinetics of shocked serpentine, a mechnaism is proposed by which shock-activated minerals are selectively weathered on the surface of Mars. The purpose of the present abstract is to argue on the basis of relative volumes of shocked materials that, as a direct consequence of selective weathering, the composition of the weathered surface units on Mars should be enriched in meteoritic material.

Boslough, M. B.↗

Theories of the origin and evolution of the giant planets

Following the accretion of solids and gases in the solar nebula, the giant planets contracted to their present sizes over the age of the solar system. It is presently hypothesized that this contraction was rapid, but not hydrodynamic; at a later stage, a nebular disk out of which the regular satellites formed may have been spun out of the outer envelope of the contracting giant planets due to a combination of total angular momentum conservation and the outward transfer of specific angular momentum in the envelope. If these hypotheses are true, the composition of the irregular satellites directly reflects the composition of planetesimals from which the giant planets formed, while the composition of the regular satellites is indicative of the composition of the less volatile components of the outer envelopes of the giant planets.

Pollack, J. B.↗

Electrically conducting polymers for aerospace applications

Current research on electrically conducting polymers from 1974 to the present is reviewed focusing on the development of materials for aeronautic and space applications. Problems discussed include extended pi-systems, pyrolytic polymers, charge-transfer systems, conductive matrix resins for composite materials, and prospects for the use of conducting polymers in space photovoltaics.

Meador, Mary Ann B.↗

A new composite electrode architecture for energy storage devices

The research objective is to determine how the electrode microstructure (architecture) affect the performance of the nickel hydroxide electrochemical system. It was found that microstructure and additional surface area makes a difference. The best architectures are the FIBREX/nickel and nickel fiber composite electrodes. The conditioning time for full utilization was greatly reduced. The accelerated increase in capacity vs. cycling appears to be a good indicator of the condition of the electrode/active material microstructure and morphology. Conformal deposition of the active material may be indicated and important. Also higher utilizations were obtained; greater than 80 pct. after less than 5 cycles and greater than 300 pct. after more than 5 cycles using nickel fiber composite electrode assuming a 1 electron transfer per equivalent.

Ferro, Richard E.↗

Computing Thermodynamic And Transport Properties

CET89 calculates compositions in chemical equilibrium and properties of mixtures of any chemical system for which thermodynamic data available. Provides following options: obtains chemical-equilibrium compositions and corresponding thermodynamic mixture properties for assigned thermodynamic states; calculates dilute-gas transport properties of complex chemical mixtures; obtains Chapman-Jouguet detonation properties for gaseous mixtures; calculates properties of incident and reflected shocks in terms of assigned velocities; and calculates theoretical performance of rocket for both equilibrium and frozen compositions during expansion. Rocket performance based on optional models of finite or infinite area combustor.

Mcbride, B.↗

Integration of optical and microwave images for geologic mapping and resource explorations

Multispectral images in the visible, near-IR, short-wave IR, thermal IR, and microwave regions, obtained during the Geologic Remote Sensing Field Experiment were combined with data from Landsat TM, laboratory, and field spectral measurements, as well as traditional geologic mapping and were used to produce thematic image maps showing details of the surface geology for an area at the north end of Death Valley (California/Nevada). The integrated multispectral images provide new geologic information which can be used in mineral deposit models to provide exploration targets. The data demonstrated the relationship between the surface composition of materials and remote sensing in the visible and infrared.

Kruse, Fred A.↗

Composition of transient events in the solar wind: Ulysses/SWICS observations

The Ulysses mission covers an extensive data base which includes an in-ecliptic phase (Oct 1990 - Feb 1992), a southern hemisphere polar pass (with a southernmost point of 80 deg S heliographic latitude reached in Sept 1994). and a south to north transit passing through the ecliptic plane (March 1995). The Solar Wind Ion Composition Spectrometer measures solar wind ion composition, including charge state composition. for all types of solar wind flows. In-ecliptic measurements of the charge states of solar wind heavy ions in transient-related solar wind. such as solar wind associated with coronal mass c ejections (CMEs), typically indicate hotter than normal coronal temperatures. This distinction is not as prevalent for higher latitude observations. In this paper, we present temporal and latitudinal variations in the charge state composition of Oxygen, Silicon, and Iron for several transient-related solar wind events.

Galvin, A. B.↗

Studies of the Surface Treatment and Sizing of Carbon Fiber Surfaces on the Mechanical Properties of Composites Containing Carbon Fibers

Carbon fiber reinforced composites are materials where carbon fibers are used to reinforce a matrix to produce a light and strong material with important applications in the aerospace industry. There are many aspects of the preparation of these materials that would benefit from a study which combines the research of groups involved in the production, testing and analysis of these materials, and studies of the basic surface chemistry involved. This final reports presents the results of a project that has developed a collaboration between groups in all three of the major research universities in the State of Kansas, and promises to lead to a collaborative program that covers the major aspects of composite development and application. Sherwood has provided initial fiber surface treatment and sizing together with fiber and composite surface analysis; Lease, Tomblin and Wang have worked together toward the goal of preparing pre-preg and fabrication of laminated panels; Locke has developed computational models to evaluate the effect of surface treatment (and chemistry) on mechanical properties; Lease, Tomblin and Wang have worked together to perform all necessary mechanical testing. The research has been focused on materials that would benefit the High Speed Civil Transport (HSCT) program. The group has visited Dr. Howard Maars and his colleagues at NASA Langley, and has focused their studies on the NASA requirements discussed in this meeting. An important development, requested by NASA scientists, has been the acquisition and study of K3B as a matrix material for the composites. The project has led to the successful acquisition and surface analysis of K3B, together with the successful deposition of this material onto surface oxidized carbon fibers. Mechanical testing, modelling and the construction of composite preparation equipment has been achieved during the grant period.

Sherwood, Peter M. A.↗