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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Chemical changes in thirdhand smoke associated with remediation using an ozone generator

Ozonation is a common remediation approach to eliminate odors from mold, tobacco and fire damage in buildings. Little information exists to: 1) assess its effectiveness; 2) provide guidance on operation conditions; and 3) identify potential risks associated with the presence of indoor ozone and ozonation byproducts. The goal of this study is to evaluate chemical changes in thirdhand smoke (THS) aerosols induced by high levels of ozone, in comparison with THS aerosols aged under similar conditions in the absence of ozone. Samples representing different stages of smoke aging in the absence of ozone, including freshly emitted secondhand smoke (SHS) and THS, were collected inside an 18-m 3 room-sized chamber over a period of 42 h after six cigarettes were consumed. The experiments involved collection and analysis of gas phase species including volatile organic compounds (VOCs), volatile carbonyls, semivolatile organic compounds (SVOCs), and particulate matter. VOC analysis was carried out by gas chromatography/mass spectrometry with a thermal desorption inlet (TD-GC/MS), and volatile carbonyls were analyzed by on-line derivatization with dinitrophenylhydrazine (DNPH), followed by liquid chromatography with UV/VIS detection. SVOCs were extracted from XAD-coated denuders and Teflon-coated fiberglass filters in the absence of ozone. In those extracts, tobacco-specific nitrosamines (TSNAs) and other SVOCs were analyzed by gas chromatography with positive chemical ionization-triple quadrupole mass spectrometric detection (GC/PCI-QQQ-MS), and polycyclic aromatic hydrocarbons (PAHs) were quantified by gas chromatography with ion trap mass spectrometric detection (GC/IT-MS) in selected ion monitoring mode. Particulate matter concentration was determined gravimetrically. In a second experiment, a 300 mg h -1 commercial ozone generator was operated during 1 h, one day after smoke was generated, to evaluate the remediation of THS by ozonation. VOCs and volatile carbonyls were analyzed before and after ozonation. Extracts from fabrics that were exposed in the chamber before and after ozonation as surrogates for indoor furnishings were analyzed by GC/IT-MS, and aerosol size distribution was studied with a scanning mobility particle sizer. Ozone concentration was measured with a photometric detector. An estimated 175 mg ozone reacted with THS after 1 h of treatment, corresponding to 58% of the total O 3 released during that period. Fabric-bound nicotine was depleted after ozonation, and the surface concentration of PAHs adsorbed to fabric specimens decreased by an order of magnitude due to reaction with ozone, reaching pre-smoking levels. These results suggest that ozonation has the potential to remove harmful THS chemicals from indoor surfaces. However, gas phase concentrations of volatile carbonyls, including formaldehyde, acetaldehyde and acetone were higher immediately after ozonation. Ultrafine particles (UFP, in most cases with size <60 nm) were a major ozonation byproduct. UFP number concentrations peaked shortly after ozonation ended, and remained at higher-than background levels for several hours. Based on these results, minimum re-entry times after ozone treatment were predicted for different indoor scenarios. Clearly defining re-entry times can serve as a practical measure to prevent acute exposures to ozone and harmful ozonation byproducts after treatment. This study evaluated potential benefits and risks associated with THS remediation using ozone, providing insights into this technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1991

Geography of cretaceous extinctions: Data base development

Data bases built from the source literature are plagued by problems of data quality. Unless the data acquisition is done by experts, working slowly, the data base may contain so much garbage that true signals and patterns cannot be detected. On the other hand, high quality data bases develop so slowly that satisfactory statistical analysis may never be possible due to the small sample sizes. Results of a test are presented of the opposite strategy: rapid data acquisition by non-experts with minimal control on data quality. A published list of 186 species and genera of fossil invertibrates of the latest Cretaceous Age (Maestrichtian) were located through a random search of the paleobiological and geological literature. The geographic location for each faunal list was then transformed electronically to Maestrichtian latitude and longitude and the lists were further digested to identify the genera occurring in each ten-degree, latitude-longitude block. The geographical lists were clustered using the Otsuka similarity coefficient and a standard unweight-pair-group method. The resulting clusters are remarkably consistent geographically, indicating that a strong biogeographic signal is visible despite low-quality data. A further test evaluated the geographic pattern of end-Cretaceaous extinctions. All genera in the data base were compared with Sepkoski's compendium of time ranges of genera to determine which of the reported genera survived the Cretaceous mass extinction. In turn, extinction rates for the ten-degree, latitude-longitude blocks were mapped. The resulting distribution is readily interpretable as a robust pattern of the geography of the mass extinction. The study demonstrates that a low-quality data base, built rapidly, can provide a basis for meaningful analysis of past biotic events.

Raup, D. M.↗
NASA NTRS1978

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Various surface preparations for titanium 6-4 alloy were studied. An anodizing method was investigated, and compared with the results of other chemical treatments, namely, phosphate/fluoride, Pasa-Jell and Turco. The relative durability of the different surface treatments was assessed by monitoring changes in surface chemistry and morphology occasioned by aging at 505 K (450 F). Basic electron spectroscopic data were collected for polyimide and polyphenylquinoxaline adhesives and synthetic precursors. Fractographic studies were completed for several combinations of adherend, adhesive, and testing conditions.

Chen, W.↗
DOE OSTI2022

Cosmic ray spectrum of protons plus helium nuclei between 6 and 158 TeV from HAWC data

Here, a measurement with high statistics of the differential energy spectrum of light elements in cosmic rays, in particular, of primary H plus He nuclei, is reported. The spectrum is presented in the energy range from 6 to 158 TeV per nucleus. Data was collected with the High Altitude Water Cherenkov (HAWC) Observatory between June 2015 and June 2019. The analysis was based on a Bayesian unfolding procedure, which was applied on a subsample of vertical HAWC data that was enriched to 82% of events induced by light nuclei. To achieve the mass separation, a cut on the lateral age of air shower data was set guided by predictions of CORSIKA/QGSJET-II-04 simulations. The measured spectrum is consistent with a broken power-law spectrum and shows a kneelike feature at around E = 24.0$^{+3.6}_{-3.1}$ TeV , with a spectral index γ = -2.51 ± 0.02 before the break and with γ = -2.83 ± 0.02 above it. The feature has a statistical significance of 4.1σ. Within systematic uncertainties, the significance of the spectral break is 0.8σ.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Factors associated with treatment limitations in two Swedish intensive care units: Prevalence and patient involvement

Abstract The aim was to study the prevalence, documentation, and patient involvement in treatment limitations (TLs) in two Swedish intensive care units (ICUs). All patients admitted to the ICUs of two Swedish regional hospitals in 2019 were screened for inclusion. Exclusion criteria included postanesthesia care <24 h. Patients were identified using the Swedish Intensive Care Registry (SIR) and data were extracted from SIR and hospital charts. Uni‐ and multivariable logistic analysis was performed to investigate associations with the presence of TLs. A total of 3090 patients were admitted to the two ICUs in 2019. After exclusion, 1019 patients were included in the study. 45.5% were women and the mean age was 62.9 years. 26.5% of the patients had one or several TLs. Age (OR 1.04 per one year increase 95% confidence interval (CI) 1.02–1.05), SAPS3‐score (OR 1.08 per one unit increase 95% CI 1.06–1.09) and ICU length of stay (OR 1.11 per one day increase 95% CI 1.05–1.17) were independently associated with an increased likelihood of receiving a TL. 17% of the patients were involved in the decision‐making process and in >30% of cases neither the patient nor next‐of‐kin were informed. Women were to a larger extent involved in the decision process than men (24.5 vs. 12.5% p < .05). When the intensivist documented why a TL was established, patient autonomy was four times more commonly stated as the motivation for the TL among women compared to men (15.5% vs. 3.8% p < .05). TLs were common in two Swedish ICUs but a substantial number of patients and next‐of‐kin were not involved in the decision‐making process or informed of the decision. Women were more often than men engaged in the decision to establish a TL.

Jönsson, Nino↗
NASA NTRS1975

Timber type separability in Southeastern United States on LANDSAT-1 MSS data

A quantitative, computer-aided study was made on the spectral separability of timber types and condition classes in the Southeastern United States, using LANDSAT-1 multispectral scanner data. It was concluded that LANDSAT-1 could be used effectively to discriminate the gross forest features of softwood, hardwood, and regeneration. The only significant detectable age difference would be between an established forest versus a young (or denuded) forest. The red or near infrared bands would be better for discrimination; phenological early and late spring data would be better than winter. And a temporal analysis would be superior to single-season analysis. Lastly, two spectral bands would be most cost effective for computer analysis. The study site was Sam Houston National Forest of East Texas, a typical forest in the Flatwoods Zone, Southern Region, U. S. Forest Service.

Kan, E. P.↗
NASA NTRS1976

Amino acids in modern and fossil woods

The amino acid composition and the extent of racemization in several modern and fossil woods are reported. The method of analysis is described, and data are presented on the total amino acid concentration, the amino acid ratios, and the enantiomeric ratios in each sample. It is found that the amino acid concentration per gram of dry wood decreases with age of the sample, that the extent of racemization increases with increasing age, and that the amounts of aspartic acid, threonine, and serine decrease relative to valine with increasing age. The relative racemization rates of amino acids in wood, bone, and aqueous solution are compared, and it is shown that racemization in wood is much slower than in bone or aqueous solution. Racemization results for woods from the Kalambo Falls area of Zambia are used to calculate a minimum age of 110,000 years for the transition between the Sangoan and Acheulian industries at that site. This result is shown to be consistent with numerous radiometric dates for older Acheulian sites in Africa and to compare well with geologically inferred dates for the beginning of the Eemian and the end of the Acheulian industry in southern Africa.

Lee, C.↗
NASA NTRS1983

Cosmogenic records in Antarctic meteorites

Aliquot samples of 29 Antarctic L and H chondrites are analyzed for their nuclear track records and Mn-53 activities. The track density in the analyzed samples ranges from 10 to the 4th to approximately 6 x 10 to the 6th per sq cm. A significant finding is the observation of track-rich grains in a set of four L3 chondrites (ALHA 77215, 77216, 77217, and 77252), suspected of belonging to the same fall based on petrographic observations. An additional sample, ALHA 78105, an L6 chondrite, also has track-rich grains. Mn-53 activity is at near saturation level in approximately 65 percent of the analyzed samples, suggesting exposure ages of greater than 10 m.y. in these cases. Very few H chondrites from the 7-m.y. exposure age peak are apparently sampled among the ones investigated in this study. Approximately 6 percent and 4 percent, respectively, of the Antarctic H and L chondrites analyzed thus far for their cosmogenic records have precompaction irradiation features. A combined analysis of Mn-53 and nuclear track data makes it possible to confirm or rule out the proposed pairing of several sets of Antarctic meteorites and to estimate the preatmospheric sizes of some of these meteorites. The results suggest that most of the small Antarctic meteorites (less than 1 kg) have suffered high (greater than 95 percent) ablation mass-loss.

Goswami, J. N.↗
NASA NTRS1985

Effect of reduction of strategic Columbium addition in 718 Alloy on the structure and properties

A series of alloys was developed having a base composition similar to Inconel 718, with reduced Cb levels of 3.00 and 1.10 wt% Cb. Substitutions of 3.0% W, 3.0W + 0.9V or Mo increased from 3.0% to 5.8% were made for the Cb in these alloys. Two additional alloys, one containing 3.49% Cb and 1.10% Ti and another containing 3.89% Cb and 1.29% Ti were also studied. Tensile properties at rooom and elevated temperatures, stress-rupture tests, and an analysis of extracted phases were carried out for each of the alloys. Additions of solid solution elements to a reduced Cb alloy had no significant effect on the properties of the alloys under either process condition. The solution and age alloys with substitutions of 1.27% i at 3.89% Cb had tensile properties similar top hose of the original alloy and stress-rupture properties superior to the original alloy. The improved stress-rupture properties were the result of significant precipitation of Ni3Ti-gamma prime in the alloy, which is more stable than gamma' at the elevated temperatures. At lower temperatures, the new alloy benefits from gamma' strengthening. With more precise control and proper processing, the reduced Cb direct-age alloy could substitute for Alloy 718 in high strength applications.

Ziegler, K. R.↗
NASA NTRS1988

Collisional evolution in the Eos and Koronis asteroid families - Observational and numerical results

The origin and evolution of the Eos and Koronis families are addressed by an analysis of Binzel's (1987) observational results. The Maxwellian distribution of the Eos family's rotation rates implies a collisionally-evolved population; these rates are also faster than those of the Koronis family and nonfamily asteroids. While the age of the Eos family may be comparable to the solar system's, that of the Koronis family could be considerably younger. Greater shape irregularity may account for the Koronis family's higher mean lightcurve amplitude.

Binzel, Richard P.↗
NASA NTRS1994

Atmospheric parameters of field subdwarf B stars

High signal-to-noise ratio optical spectrophotometry of a sample of field subluminous B stars drawn largely from the Palomar Green ultraviolet-excess survey is analyzed with a new grid of model atmospheres and synthetic spectra. The stellar effective temperatures, surface gravities, and photospheric helium abundances are determined simultaneously from a detailed analysis of hydrogen and helium absorption line profiles. The derived temperatures and gravities place the subluminous B stars in the theoroetical Hertzsprung-Russell (H-R) diagram along and bounded below by theoretical sequences of the zero-age extended horizontal branch, lending strong support to the hypothesis that these stars are composed of helium-burning cores of approximately 0.5 solar mass overlain by very thin layers of hydrogen (approximately less than 0.02 solar mass). Various scenarios for their past evolutionary history are examined in the context of their probable future evolution into white dwarfs of lower than average mass.

Saffer, Rex A.↗
NASA NTRS2002

Autonomic neural control of dynamic cerebral autoregulation in humans

BACKGROUND: The purpose of the present study was to determine the role of autonomic neural control of dynamic cerebral autoregulation in humans. METHODS AND RESULTS: We measured arterial pressure and cerebral blood flow (CBF) velocity in 12 healthy subjects (aged 29+/-6 years) before and after ganglion blockade with trimethaphan. CBF velocity was measured in the middle cerebral artery using transcranial Doppler. The magnitude of spontaneous changes in mean blood pressure and CBF velocity were quantified by spectral analysis. The transfer function gain, phase, and coherence between these variables were estimated to quantify dynamic cerebral autoregulation. After ganglion blockade, systolic and pulse pressure decreased significantly by 13% and 26%, respectively. CBF velocity decreased by 6% (P<0.05). In the very low frequency range (0.02 to 0.07 Hz), mean blood pressure variability decreased significantly (by 82%), while CBF velocity variability persisted. Thus, transfer function gain increased by 81%. In addition, the phase lead of CBF velocity to arterial pressure diminished. These changes in transfer function gain and phase persisted despite restoration of arterial pressure by infusion of phenylephrine and normalization of mean blood pressure variability by oscillatory lower body negative pressure. CONCLUSIONS: These data suggest that dynamic cerebral autoregulation is altered by ganglion blockade. We speculate that autonomic neural control of the cerebral circulation is tonically active and likely plays a significant role in the regulation of beat-to-beat CBF in humans.

Non-NASA Center↗
NASA NTRS1996

Influence of spaceflight on succinate dehydrogenase activity and soma size of rat ventral horn neurons

Succinate dehydrogenase (SDH) activities and soma cross-sectional areas (CSA) of neurons in the dorsolateral region of the ventral horn at the L5 segmental level of the spinal cord in the rat were determined after 14 days of spaceflight and after 9 days of recovery on earth. The results were compared to those in age-matched ground-based control rats. Spinal cords were quick-frozen, and the SDH activity and CSA of a sample of neurons with a visible nucleus were determined using a digitizer and a computer-assisted image analysis system. An inverse relationship between CSA and SDH activity of neurons was observed in all groups of rats. No change in mean CSA or mean SDH activity or in the size distribution of neurons was observed following spaceflight or recovery. However, there was a selective decrease in the SDH activity of neurons with soma CSA between 500 and 800 microns2 in the flight rats, and this effect persisted for at least 9 days following return to 1 g. It remains to be determined whether the selected population of motoneurons or the specific motor pools affected by spaceflight may be restricted to specific muscles.

short duration↗
NASA NTRS2013

A Upgrade of the Aeroheating Software "MINIVER"

Many software packages assist engineers with performing flight vehicle analysis, but some of these packages have gone many years without updates or significant improvements to their workflows. One such software package, known as MINIVER, is a powerful yet lightweight tool used for aeroheating analyses. However, it is an aging program that has not seen major improvements within the past decade. As part of a collaborative effort with the Florida Institute of Technology, MINIVER has received a major user interface overhaul, a change in program language, and will be continually receiving updates to improve its capabilities. The user interface update includes a migration from a command-line interface to that of a graphical user interface supported in the Windows operating system. The organizational structure of the pre-processor has been transformed to clearly defined categories to provide ease of data entry. Helpful tools have been incorporated, including the ability to copy sections of cases as well as a generalized importer which aids in bulk data entry. A visual trajectory editor has been included, as well as a CAD Editor which allows the user to input simplified geometries in order to generate MINIVER cases in bulk. To demonstrate its continued effectiveness, a case involving the JAXA OREX flight vehicle will be included, providing comparisons to captured flight data as well as other computational solutions. The most recent upgrade effort incorporated the use of the CAD Editor, and current efforts are investigating methods to link MINIVER projects with SINDA/Fluint and Thermal Desktop.

Louderback, Pierce↗
NASA NTRS2016

Transgenic Mouse Model for Reducing Oxidative Damage in Bone

Bone loss can occur due to many challenges such age, radiation, microgravity, and Reactive Oxygen Species (ROS) play a critical role in bone resorption by osteoclasts (Bartell et al. 2014). We hypothesize that suppression of excess ROS in skeletal cells, both osteoblasts and osteoclasts, regulates skeletal growth and remodeling. To test our hypothesis, we used transgenic mCAT mice which overexpress the human anti-oxidant catalase gene targeted to the mitochondria, the main site for endogenous ROS production. mCAT mice have a longer life-span than wildtype controls and have been used to study various age-related disorders. To stimulate remodeling, 16 week old mCAT mice or wildtype mice were exposed to treatment (hindlimb-unloading and total body-irradiation) or sham treatment conditions (control). Tissues were harvested 2 weeks later for skeletal analysis (microcomputed tomography), biochemical analysis (gene expression and oxidative damage measurements), and ex vivo bone marrow derived cell culture (osteoblastogenesis and osteoclastogenesis). mCAT mice expressed the transgene and displayed elevated catalase activity in skeletal tissue and marrow-derived osteoblasts and osteoclasts grown ex vivo. In addition, when challenged with treatment, bone tissues from wildtype mice showed elevated levels of malondialdehyde (MDA), indicating oxidative damage) whereas mCAT mice did not. Correlation analysis revealed that increased catalase activity significantly correlated with decreased MDA levels and that increased oxidative damage correlated with decreased percent bone volume (BVTV). In addition, ex-vivo cultured osteoblast colony growth correlated with catalase activity in the osteoblasts. Thus, we showed that these transgenic mice can be used as a model to study the relationship between markers of oxidative damage and skeletal properties. mCAT mice displayed reduced BVTV and trabecular number relative to wildtype mice, as well as increased structural model index in the cancellous tibia. Treatment caused bone loss in wildtype mice, as expected. Treatment also caused deficits in microarchitecture of mCAT mice, although less severe than wildtype mice in some parameters (percent bone volume, structural model index and cortical area). In conclusion, our results indicate that endogenous ROS signaling in both osteoblast and osteoclast lineage cells contributes to skeletal growth and remodeling, and quenching oxidative damage could play a role in bone loss prevention.

transgenic mice↗
NASA NTRS2020

Snow Property Inversion from Remote Sensing (SPIReS): A Generalized Multispectral Unmixing Approach with Examples from MODIS and Landsat 8 OLI

Spectral mixture analysis has a history in mappingsnow, especially where mixed pixels prevail. Using multiplespectral bands rather than band ratios or band indices, retrievalsof snow properties that affect its albedo lead to more accu-rate estimates than widely used age-based models of albedoevolution. Nevertheless, there is substantial room for improve-ment. We present the Snow Property Inversion from RemoteSensing (SPIReS) approach, offering the following improve-ments: 1) Solutions for grain size and concentrations of lightabsorbing particles are computed simultaneously; 2) Only snowand snow-free endmembers are employed; 3) Cloud-maskingand smoothing are integrated; 4) Similar spectra are groupedtogether and interpolants are used to reduce computation time.The source codes are available in an open repository. Com-putation is fast enough that users can process imagery ondemand. Validation of retrievals from Landsat 8 operational landimager (OLI) and moderate-resolution imaging spectroradiome-ter (MODIS) against WorldView-2/3 and the Airborne SnowObservatory shows accurate detection of snow and estimatesof fractional snow cover. Validation of albedo shows low errorsusing terrain-correctedin situmeasurements. We conclude bydiscussing the applicability of this approach to any airborne orspaceborne multispectral sensor and options to further improve retrievals.

Edward H Blair↗
NASA NTRS2021

Formaldehyde evolution in U.S. wildfire plumes during FIREX-AQ

Formaldehyde (HCHO) is one of the most abundant non-methane volatile organic compounds (VOCs) emitted by fires. HCHO also undergoes chemical production and loss as a fire plume ages, and it can be an important oxidant precursor. In this study, we disentangle the processes controlling HCHO by examining its evolution in wildfire plumes sampled by the NASA DC-8 during the FIREX-AQ field campaign. In nine of the twelve analyzed plumes, dilution-normalized HCHO increases with physical age (range 1 – 6 h). The balance of HCHO loss (mainly via photolysis) and production (via OH-initiated VOC oxidation) seems to control the sign and magnitude of this trend. Plume-average OH concentrations, calculated from VOC decays, range from –0.5 (± 0.5) × 10 6 to 5.3 (±0.7) × 10 6 cm -3 . The production and loss rates of dilution-normalized HCHO seem to decrease with plume age. Plume-to-plume variability in dilution-normalized secondary HCHO production correlates with OH abundance rather than normalized OH reactivity, suggesting that OH is the main driver of fire-to-fire variability in HCHO secondary production. Analysis suggests an effective HCHO yield of 0.33 (± 0.05) per VOC molecule oxidized for the 12 wildfire plumes. This finding can help connect space-based HCHO observations to the oxidizing capacity of the atmosphere and to VOC emissions.

Air quality↗
NASA NTRS2001

Damage Assessment of Creep Tested and Thermally Aged Udimet 520 Using Acousto-Ultrasonics

Due to elevated temperatures and excessive stresses, turbine components may experience creep behavior. As a result, it is desirable to monitor and assess the current condition of such components. This study employed the Acousto-Ultrasonics (AU) method in an effort to monitor the state of the material at various percentages of used up creep life in the nickel base alloy, Udimet 520. A stepped specimen (i.e., varying cross sectional area) was employed which allowed for a postmortem nondestructive evaluation (NDE) analysis of the various levels of used up life. The overall objectives here were two fold: First, a user friendly, graphical interface AU system was developed, and second the new AU system was applied as an NDE tool to assess distributed damage resulting from creep. The experimental results demonstrated that the AU method shows promise as an NDE tool capable of detecting material changes as a function of used up creep life. Furthermore, the changes in the AU parameters were mainly attributed to the case of combined load and elevated temperature (i.e., creep) and not simply because of a timed exposure at elevated temperature (i.e., heat treatment or thermal aging).

Gyekenyesi, Andrew L.↗