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At least 109 records · Page 6

Titanium Alloy Strong Back for IXO Mirror Segments

A titanium-alloy mirror-holding fixture called a strong back allows the temporary and permanent bonding of a 50 degree D263 glass x-ray mirror (IXO here stands for International X-ray Observatory). The strong back is used to hold and position a mirror segment so that mounting tabs may be bonded to the mirror with ultra-low distortion of the optical surface. Ti-15%Mo alloy was the material of choice for the strong back and tabs because the coefficient of thermal expansion closely matches that of the D263 glass and the material is relatively easy to machine. This invention has the ability to transfer bonded mounting points from a temporary location on the strong back to a permanent location on the strong back with minimal distortion. Secondly, it converts a single mirror segment into a rigid body with an acceptable amount of distortion of the mirror, and then maneuvers that rigid body into optical alignment such that the mirror segment can be bonded into a housing simulator or mirror module. Key problems are that the mirrors are 0.4-mm thick and have a very low coefficient of thermal expansion (CTE). Because the mirrors are so thin, they are very flexible and are easily distorted. When permanently bonding the mirror, the goal is to achieve a less than 1-micron distortion. Temperature deviations in the lab, which have been measured to be around 1 C, have caused significant distortions in the mirror segment.

Byron, Glenn P.↗

Environmental protection of titanium alloys at high temperatures

Various concepts were evaluated for protecting titanium alloys from oxygen contamination at 922 K (1200 F) and from hot-salt stress-corrosion at 755 K (900 F). It is indicated that oxygen-contamination resistance can be provided by a number of systems, but for hot-salt stress-corrosion resistance, factors such as coating integrity become very important. Titanium aluminides resist oxygen ingress at 922 K through the formation of alumina (on TiAl3) or modified TiO2 (on Ti3Al, TiAl) scales. TiAl has some resistance to attack by hot salt, but has limited ductility. Ductile Ti-Ni and Ti-Nb-Cr-Al alloys provide limited resistance to oxygen ingress, but are not greatly susceptible to hot-salt stress-corrosion cracking.

Wright, I. G.↗

Relative susceptibility of titanium alloys to hot-salt stress-corrosion

Susceptibility of titanium alloys to hot-salt stress-corrosion cracking increased as follows: Ti-2Al-11Sn-5Zr-0.2Si(679), Ti-6Al-2Sn-4Zr-2Mo(6242), Ti-6Al-4V(64), Ti-6Al-4V-3Co(643), Ti-8Al-1Mo-1V(811), and Ti-13V-11Cr-3A1(13-11-3). The Ti-5Al-6Sn-2Zr-1Mo-0.25Si(5621S) alloy was both the least and most susceptible depending on heat treatment. Such rankings can be drastically altered by heat-to-heat and processing variations. Residual compressive stresses and cyclic exposures also reduce susceptibility to stress-corrosion. Simulated turbine-engine compressor environmental variables such as air velocity, pressure, dewpoint, salt concentration, and salt deposition temperature have only minor effects. Detection of substantial concentrations of hydrogen in all corroded alloys confirmed the existence of a hydrogen embrittlement mechanism.

Gray, H. R.↗

Polyimide weld bonding for titanium alloy joints

Two weld bonding processes were developed for joining titanium alloy; one process utilizes a weld-through technique and the other a capillary-flow technique. The adhesive used for the weld-through process is similar to the P4/A5F system. A new polyimide laminating resin, BFBI/BMPM, was used in the capillary-flow process. Static property information was generated for weld-bonded joints over the temperature range of 219 K (-65 F) to 561 K (+550 F) and fatigue strength information was generated at room temperature. Significant improvement in fatigue strength was demonstrated for weld-bonded joints over spot-welded joints. A demonstration was made of the applicability of the weld-through weld-bonding process for fabricating stringer stiffened skin panels.

Vaughan, R. W.↗

Hot-salt stress-corrosion of titanium alloys as related to turbine operation

In an effort to simulate typical compressor operating conditions of current turbine engines, special test facilities were designed. Air velocity, air pressure, air dewpoint, salt deposition temperature, salt concentration, and specimen surface condition were systematically controlled and their influence on hot-salt stress-corrosion evaluated. The influence of both continuous and cyclic stress-temperature exposures was determined. The relative susceptibility of a variety of titanium alloys in commonly used heat-treated conditions was determined. The effects of both environmental and material variables were used to interpret the behavior of titanium alloys under hot-salt stress-corrosion conditions found in jet engines and to appraise their future potential under such conditions.

Gray, H. R.↗

Lunar-derived titanium alloys for hydrogen storage

Hydrogen gas, which plays an important role in many projected lunar power systems and industrial processes, can be stored in metallic titanium and in certain titanium alloys as an interstitial hydride compound. Storing and retrieving hydrogen with titanium-iron alloy requires substantially less energy investment than storage by liquefaction. Metal hydride storage systems can be designed to operate at a wide range of temperatures and pressures. A few such systems have been developed for terrestrial applications. A drawback of metal hydride storage for lunar applications is the system's large mass per mole of hydrogen stored, which rules out transporting it from earth. The transportation problem can be solved by using native lunar materials, which are rich in titanium and iron.

Love, S.↗