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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Pore-Scale Study on the Positive Feedback Between Stress and Porosity Caused by Pressure Solution in Porous Media

Pressure solution is an important process in the evolution of sedimentary rocks, which provide storage space for most of our petroleum resources. It directly influences the generation, migration, and storage of petroleum fluids in subsurface sedimentary rocks. Here, in this paper, we develop a pore-scale, mechanochemical model to demonstrate a possible positive feedback between the local porosity and pore surface stress, in which a higher local porosity causes a higher local pore surface stress, thus enhancing pressure solution and consequently further increasing the local porosity. Pore surface stress represents stress on a solid grain adjacent to a pore. Specifically, the pore-scale, mechanochemical model directly simulates the stress distribution over solid and pore surfaces using a finite element model. The dissolution of solids at the solid-pore interfaces under a far-from-equilibrium condition is simulated using a first-order kinetics model that accounts for the local stress distribution. The updated pore geometry, caused by pore surface dissolution, is then used in the stress simulation in the next numerical iteration. Two types of porous media, the Oriskany sandstone and an artificial porous medium with spherical pores, were tested in the mechanochemical simulation. The positive stress-porosity feedback during pressure solution was observed in both samples. In addition, the model quantitatively illustrated the distribution of local mineral dissolution rates on all pore surfaces, as well as its relation to the effective mineral dissolution rate of the entire sample. Based on the comparison between the two porous media, the local mineral dissolution was regulated by pore space distribution, geometry, and coalescence during pressure solution. This work is the first that uses direct, pore-scale numerical simulation to demonstrate the positive stress-porosity feedback during pressure solution, which has the potential to advance the understanding of the mechanical-chemical (MC) coupling in many geological processes that are relevant to subsurface energy systems, such as the recovery of petroleum hydrocarbons and geothermal energy.

CT scanning↗
DOE OSTI2023

X-ray diffraction reveals two structural transitions in szomolnokite

Hydrated sulfates have been identified and studied in a wide variety of environments on Earth, Mars, and the icy satellites of the solar system. The subsurface presence of hydrous sulfur-bearing phases to any extent necessitates a better understanding of their thermodynamic and elastic properties at pressure. End-member experimental and computational data are lacking and are needed to accurately model hydrous, sulfur-bearing planetary interiors. In this work, high-pressure X-ray diffraction (XRD) and synchrotron Fourier-transform infrared (FTIR) measurements were conducted on szomolnokite (FeSO 4 ·H 2 O) up to ~83 and 24 GPa, respectively. This study finds a monoclinic-triclinic (C2/c to P1¯) structural phase transition occurring in szomolnokite between 5.0(1) and 6.6(1) GPa and a previously unknown triclinic-monoclinic (P1¯ to P2 1 ) structural transition occurring between 12.7(3) and 16.8(3) GPa. The high-pressure transition was identified by the appearance of distinct reflections in the XRD patterns that cannot be attributed to a second phase related to the dissociation of the P1¯ phase, and it is further characterized by increased H 2 O bonding within the structure. We fit third-order Birch-Murnaghan equations of state for each of the three phases identified in our data and refit published data to compare the elastic parameters of szomolnokite, kieserite (MgSO 4 ·H 2 O), and blödite (Na 2 Mg(SO 4 ) 2 ·4H 2 O). At ambient pressure, szomolnokite is less compressible than blödite and more than kieserite, but by 7 GPa both szomolnokite and kieserite have approximately the same bulk modulus, while blödite’s remains lower than both phases up to 20 GPa. Furthermore, these results indicate the stability of szomolnokite’s high-pressure monoclinic phase and the retention of water within the structure up to pressures found in planetary deep interiors.

58 GEOSCIENCES↗
DOE OSTI2022

Basic Energy Sciences Roundtable: Foundational Science for Carbon Dioxide Removal Technologies (Brochure)

Basic research to identify and understand the fundamental principles governing carbon dioxide removal processes of capture, conversion, and storage is essential for achieving zero carbon emissions by 2050. In March 2022, the Office of Basic Energy Sciences (BES)—in coordination with the US Department of Energy (DOE) technology Offices of Energy Efficiency and Renewable Energy, Fossil Energy and Carbon Management, and Nuclear Energy—held a roundtable titled, “Foundational Science for Carbon Dioxide Removal Technologies,” to discuss the scientific and technical barriers for CO 2 capture, conversion, and storage. Five priority research opportunities were identified to address these scientific and technical challenges and accelerate progress toward the realization of zero carbon emissions. The PROs are as follows: 1) Master Interfacial Processes of CO2 Transport and Reactivity Across Multiple Length and Time Scales; 2) Create Materials that Simultaneously Exhibit Multiple Properties for CO 2 Capture and Release or Conversion; 3) Discover Unconventional Pathways for Energy-Efficient CO 2 Capture, Release, and Conversion; 4) Control Multiphase Interactions Required for CO 2 Conversion into Minerals and Materials; and 5) Achieve Predictive Understanding of Coupled Processes in Complex Subsurface Geologic Systems for Secure Carbon Storage.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Local-Scale Framework for Techno-Economic Analysis of Subsurface Hydrogen Storage

The energy sector is evolving toward increased reliance on renewable energy technologies to meet state, national, and organization decarbonization goals. This trend is creating challenges and opportunities with meeting current and future energy demand under the variable supply conditions that most renewables provide. Hydrogen (H 2 ) is a promising energy carrier that may meet the need for both on-demand and long-duration storage to maintain energy security and resilience. Underground hydrogen storage (UHS) is a method of storing H 2 in subsurface geological systems, such as depleted hydrocarbon reservoirs, salt caverns, saline aquifers, hard rock, and other engineered systems. UHS has the potential to store large quantities of H 2 over time, providing a reliable source of energy while minimizing surface footprints at a lower investment cost compared to surface storage. Earlier work estimated that, if converted and retrofitted, existing underground natural gas storage (UGS) facilities in the U.S. can store approximately 327 TWh, or 9.8 million metric tons, of pure H 2 . However, a shift to pure H 2 would decrease the collective working-gas energy of the UGS facilities by approximately 75% due to physical and chemical differences between natural gas and hydrogen. The same work also suggests that almost 75% of the existing UGS facilities in the U.S. could maintain current energy demand buffering using a blend of only 20% H 2 to 80% natural gas, by volume at surface conditions. If we can take advantage of the suite of mature technologies of existing UGS facilities and natural gas utility systems to accelerate the transition to a hydrogen economy in the U.S., a 20% H 2 blend could lead to a 6-7% reduction of greenhouse gas emissions for energy delivered through natural gas utility systems.

03 NATURAL GAS↗
DOE OSTI2026

Big Data Meets Geothermal Exploration (CRADA Final Report)

As part of the Cyclotron Road program, Zanskar Geothermal & Minerals, Inc. investigated the application of micro-earthquake and ambient noise seismology methods to imaging and characterizing the structural characteristics and hydrothermal flux of subsurface faults. Significant advances in what could be resolved were enabled by two major developments in seismology: 1) the availability of large-n arrays of low-cost seismometers, and 2) the availability of increased computational power and semi-automated data reduction algorithms. In tandem, these advances may improve the signal-to-noise ratio and spatial precision of the data collected and enable higher-resolution characterization of subsurface fracture systems and their spatio-temporal evolution. These tools supported efforts to reduce dry-hole risk and to improve wellfield productivity for geothermal resource development. In particular, two applications of these advances were evaluated: 1) fracture-seismic imaging, which was used to detect ambient emissions from fluid-filled fractures, and 2) reservoir tomography, which used information about travel paths, source locations, and source parameters of micro-earthquakes to identify areas of enhanced permeability. Integration of these methods provided guidance for siting wells and served as prior constraints for reservoir models, informing forecasts of power potential and production and injection strategies aimed at minimizing temperature decline and improving overall resource productivity.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

Editorial: Hydrology, ecology, and nutrient biogeochemistry at the terrestrial-aquatic interface

Terrestrial-aquatic interfaces (TAI) play important roles in mediating the exchange of water and chemicals between land, surface and subsurface water systems, which is tightly coupled with biogeochemical transformations that influence water quality and ecosystem health (Harvey and Gooseff, 2015; Harvey et al., 2019). Understanding and predicting the interactions between the hydrologic, ecologic, and biogeochemical processes at those interfaces is crucial for the sustainable management of water resources and promotion of healthy ecosystems under different environmental stresses and disturbances, including climate change, human activities, and more frequent occurrence of extreme events. Both process-based and data-driven approaches have emerged to address critical challenges at TAIs as integral parts of the Earth system (e.g., Ward and Packman, 2019; Chen et al., 2021; Dwivedi et al., 2022). In this Research Topic, we sought research that advances the understanding of coupled hydrologic, ecologic, and biogeochemical processes along various TAIs from the summit to sea, e.g., river corridors and coastal TAI systems. We invited observational, experimental, theoretical, analytical, numerical, and data-driven research that aims to understand hydro-biogeochemical processes such as the redox dynamics and biogeochemical transformations of carbon, nutrients, and metals occurring at the TAIs and address their heterogeneity and scaling challenges.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Policy-Driven Sustainable Saline Drainage Disposal and Forage Production in the Western San Joaquin Valley of California

Environmental policies to address water quality impairments in the San Joaquin River of California have focused on the reduction of salinity and selenium-contaminated subsurface agricultural drainage loads from westside sources. On 31 December 2019, all of the agricultural drainage from a 44,000 ha subarea on the western side of the San Joaquin River basin was curtailed. This policy requires the on-site disposal of all of the agricultural drainage water in perpetuity, except during flooding events, when emergency drainage to the River is sanctioned. The reuse of this saline agricultural drainage water to irrigate forage crops, such as ‘Jose’ tall wheatgrass and alfalfa, in a 2428 ha reuse facility provides an economic return on this pollutant disposal option. Irrigation with brackish water requires careful management to prevent salt accumulation in the crop root zone, which can impact forage yields. The objective of this study was to optimize the sustainability of this reuse facility by maximizing the evaporation potential while achieving cost recovery. This was achieved by assessing the spatial and temporal distribution of the root zone salinity in selected fields of ‘Jose’ tall wheatgrass and alfalfa in the drainage reuse facility, some of which have been irrigated with brackish subsurface drainage water for over fifteen years. Electromagnetic soil surveys using an EM-38 instrument were used to measure the spatial variability of the salinity in the soil profile. The tall wheatgrass fields were irrigated with higher salinity water (1.2–9.3 dS m -1 ) compared to the fields of alfalfa (0.5–6.5 dS m -1 ). Correspondingly, the soil salinity in the tall wheatgrass fields was higher (12.5 dS m -1 –19.3 dS m -1 ) compared to the alfalfa fields (8.97 dS mm -1 –14.4 dS mm -1 ) for the years 2016 and 2017. Better leaching of salts was observed in the fields with a subsurface drainage system installed (13–1 and 13–2). The depth-averaged root zone salinity data sets are being used for the calibration of the transient hydro-salinity computer model CSUID-ID (a one-dimensional version of the Colorado State University Irrigation Drainage Model). This user-friendly decision support tool currently provides a useful framework for the data collection needed to make credible, field-scale salinity budgets. In time, it will provide guidance for appropriate leaching requirements and potential blending decisions for sustainable forage production. This paper shows the tie between environmental drainage policy and the role of local governance in the development of sustainable irrigation practices, and how well-directed collaborative field research can guide future resource management.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

Permafrost and Subsurface Ice in the Solar System

The properties and behavior of planetary permafrost are discussed with reference to the ability of such surfaces to sustain loads characteristics of spacecraft landing and planetary bases. In most occurrences, water ice is in close proximity to, or in contact with, finely divided silicate mineral matter. When ice contacts silicate mineral surfaces, a liquid-like, transition zone is created. Its thickness ranges from several hundred Angstron units at temperatures near 0 degrees C to about three Angstrom units at -150 degrees C. When soluble substances are present, the resulting brine enlarges the interfacial zone. When clays are involved, although the interfacial zone may be small, its extent is large. The unfrozen, interfacial water may amount to 100% or more weight at a temperature of -5 degrees C. The presence of this interfacial unfrozen water acts to confer plasticity to permafrost, enabling it to exhibit creep at all imposed levels of stress. Nucleation processes and load-bearing capacity are examined.

Anderson, D. M.↗
NASA NTRS1992

Automated in situ observations of upper ocean biogeochemistry, bio-optics, and physics and their potential use for global studies

The processes controlling the flux of carbon in the upper ocean have dynamic ranges in space and time of at least nine orders of magnitude. These processes depend on a broad suite of inter-related biogeochemical, bio-optical, and physical variables. These variables should be sampled on scales matching the relevant phenomena. Traditional ship-based sampling, while critical for detailed and more comprehensive observations, can span only limited portions of these ranges because of logistical and financial constraints. Further, remote observations from satellite platforms enable broad horizontal coverage which is restricted to the upper few meters of the ocean. For these main reasons, automated subsurface measurement systems are important for the fulfillment of research goals related to the regional and global estimation and modeling of time varying biogeochemical fluxes. Within the past few years, new sensors and systems capable of autonomously measuring several of the critical variables have been developed. The platforms for deploying these systems now include moorings and drifters and it is likely that autonomous underwater vehicles (AUV's) will become available for use in the future. Each of these platforms satisfies particular sampling needs and can be used to complement both shipboard and satellite observations. In the present review, (1) sampling considerations will be summarized, (2) examples of data obtained from some of the existing automated in situ sampling systems will be highlighted, (3) future sensors and systems will be discussed, (4) data management issues for present and future automated systems will be considered, and (5) the status of near real-time data telemetry will be outlined. Finally, we wish to make it clear at the outset that the perspectives presented here are those of the authors and are not intended to represent those of the United States JGOFS program, the International JGOFS program, NOAA's C&GC program, or other global ocean programs.

Dickey, Tommy D.↗
NASA NTRS2022

Development of a Loop Antenna Deployment System for TEM-Based Subsurface Mars Water Detection

The subsurface of Mars has the potential to harbor existing deposits of liquid water, which are of great interest both scientifically (in the search for life) and as resources for future astronauts living on the red planet. However, the depth to a potential subsurface aquifer may be kilometers deep, which is well beyond what current surface or orbital approaches can survey while also confirming the unique signature for liquid water. Inspired by critical technology for exploring deep aquifers on Earth, we are developing the Transient H2O Reconnaissance (TH2OR) instrument at NASA’s Jet Propulsion Laboratory (JPL). TH2OR operates on the principle of transient electromagnetics (TEM), which leverages induction and electromotive force to induce a current in a subsurface water body using a loop-shaped antenna that provides both transmit and receive functions when placed on the surface. On Mars, TEM may be even more effective given the relative dryness of the subsurface compared to a more conductive, saline, liquid, water body on Earth. However, to probe deep within the subsurface (below 5 km) a large enclosed antenna is needed – specifically, a 100-m diameter effective loop or a shape with roughly equivalent area that can transmit at low frequencies (kHz-Hz). The deployment of a large-scale structure on the surface is complicated by the fact that the transmit wire must be both lightweight and robust to contact with the surface. Further, TH2OR may be delivered to the surface by a non-mobile vehicle, so it is desired that the deployment can be activated from a static location. This paper provides an overview of the deployment trade study, focusing on our current, favored approach, using a projectile wire launcher. Building on past approaches in the literature, we have developed and fielded an Earth-based, gas-projectile prototype for launching a triangle-shaped antenna onto analogue terrain. Our results compare simulated launch performance to actual field tests conducted under Earth gravity and pressure conditions. We discuss how Earth performance maps to a prospective Mars deployment under reduced gravity and pressure. We also provide lessons learned and next steps towards the development of an integrated TH2OR instrument for finding water on Mars.

Stamenkovic, Vlada↗
DOE OSTI2022

Calcium carbonate minerals as scavengers of metals and radionuclides: Their role in natural attenuation and remediation

Calcium carbonates (CaCO3) are ubiquitous naturally occurring minerals in subsurface sediments. Calcium carbonate coatings are common in many terrestrial environments and are known to coat a variety of reactive mineral surfaces in soils and sediments, altering their reactivity and chemical behavior. For these reasons, contaminant interactions with CaCO3 minerals are relevant to contaminant fate and transport. Significant advancements have been made recently toward identifying relevant contaminant (e.g., U, I, and Cr) attenuation mechanisms, which may also serve as a basis for in situ remediation strategies. Hence, the objective of this review paper is to 1) describe the state-of-knowledge of calcium carbonate minerals as universal scavengers of metals and radionuclides; 2) provide a state of the science of how calcium carbonate interactions affect contaminant fate and transport in the subsurface environmental systems; and 2) provide insights on the use of calcium carbonate natural attenuation mechanisms and their application to the remediation of complex sites. Knowledge gaps are also identified that, when closed, can advance the use of carbonate minerals for in situ remedy applications.

Qafoku, Nikolla↗
NASA NTRS1975

Subsurface sounders

Airborne or spaceborne electromagnetic systems used to detect subsurface features are discussed. Data are given as a function of resistivity of ground material, magnetic permeability of free space, and angular frequency. It was noted that resistivities vary with the water content and temperature.

Source record↗
NASA NTRS2006

Self-propelled instrumented deep drilling system

An autonomous subsurface drilling device has spaced-apart forward and rearward feet sections coupled to an axial thruster mechanism between them to operate using an inchworm method of mobility. In one embodiment, forward and rearward drill sections are carried on forward and rearward feet sections for drilling into material in the borehole in both forward and rearward directions, to allow the device to maneuver in any direction underground. In another embodiment, a front drill section has a drill head for cutting into the borehole and conveying cuttings through a center spine tube to an on-board depository for the cuttings. The feet sections of the device employ a foot scroll drive unit to provide radial thrust and synchronous motion to the feet for gripping the borehole wall. The axial thrust mechanism has a tandem set of thrusters in which the second thruster is used to provide the thrust needed for drilling, but not walking. A steering mechanism composed of concentric inner and outer eccentric rings provided with the rearward feet section allow small corrections in both direction and magnitude to the drilling direction as drilling commences.

Myrick, Thomas M.↗
NASA NTRS2017

Energy in a Planetary Context

The potential present day habitability of solar system bodies beyond Earth is limited to subsurface environments, where the availability of energy in biologically useful form is a paramount consideration. Energy availability is commonly quantified in terms of molar Gibbs energy changes for metabolisms of interest, but this can provide an incomplete and even misleading picture. A second aspect of life's requirement for energy - the rate of delivery, or power - strongly influences habitability, biomass abundance, growth rates, and, ultimately, rates of evolution. We are developing an approach to quantify metabolic power, using a cell-scale reactive transport model in which physical and chemical environmental parameters are varied. Simultaneously, we evaluate cell-specific energy flux requirements and their dependence on environmental "extremes". Comparison of metabolic power supply and demand provides a constraint on how biomass abundance varies across a range of environmental parameters, and thereby a prediction of the relative habitability of different environments. We are evaluating the predictive capability of this approach through comparison to observed distributions of microbial abundance in a range of subsurface (predominantly serpentinizing) systems.

MARINE GEOMICROBIOLOGY↗
DOE OSTI2021

About the Complex Natural and Engineered Systems Pillar

Los Alamos National Laboratory is a world leader in applying multi-disciplinary science to complex systems within the Complex Natural and Engineered Systems (CNES) challenge areas. Our search for solutions requires science and technology innovation, as well as an integrated experiment, theory, and modeling and simulation approach. Our research and development spans from improving engineered systems such as nuclear weapons and the power grid, to understanding the interface of human and engineered systems from the subsurface to space, to studying how complex natural systems such as disease and climate impact humanity.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗