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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Multi-functionalized basic immobilized amine sorbents for removal of metal contaminants from wastewater

This disclosure provides polyamine sorbent compositions for the separation of metals from aqueous solutions. The polyamine sorbent compositions comprise a silica support, an aminosilane bound to the silica support, an epoxysilane bound to the silica support, and a polyamine where the polyamine is chemically tethered onto a solid silica support through via the epoxysilane. The polyamine may be further stabilized within the bulk sorbent through hydrogen bonding interactions with the aminosilane. The sorbent compositions resist leaching by H 2 O in an aqueous stream containing heavy oxyanion-based (and other) metals and demonstrate stability over a pH range of 2-14. The sorbent compositions are useful for the separation of metals from aqueous solutions. The cationic heavy metals are captured by the co-existing amine groups (—NH 2 , —NH, —N) from the polymeric network while additional metal capture capacity is derived from the introduction of a secondary silane linker.

Gray, McMahan L.↗
NASA NTRS1993

Thermal control of ice-stream margins

The thermal balance at the base of an ice sheet near an ice-stream margin was investigated theoretically. Specifically, conditions such that the base of the ice sheet would be frozen in the absence of heat generated by the ice motion were investigated. The base of the ice stream is maintained at melting as a result of high dissipation of heat at the base associated with its fast motion over the bed. Heat dissipation in the inter-ice-stream ridge ice is presumed to be too small to maintain melting conditions on the bed there. Two opposing effects can be identified near the shear margin separating the fast and slow motions. Because the velocity of an ice stream falls off toward its margin, there is a near margin heat deficit zone where the heat generated at the bed is not, by itself, sufficient to maintain melting conditions. Without some counteracting process, the base could freeze inward toward the ice stream and cause it to narrow. The marginal shearing generates heat within the ice above the bed. This heat produces a thermal shielding effect that tends to warm the bed on both sides of the boundary between the fast and slow motion. This shielding effect, if strong enough, could produce a thawed zone beyond the fast/slow boundary. If melting at the bed by itself allows fast motion, then the ice stream would be free to widen. A coupled mass and heat flow model is being developed to examine these competing processes. Preliminary calculations using available information for boundary conditions appropriate for Ice Stream B predict that the shielding effect is most important. This tentative result suggests that thermal conditions are such that the ice stream could widen unstably. Other constraints would be required to stabilize the width. Possible factors could be bed morphology beneath ridges that does not allow fast motion even in thawed conditions, or inward advection of cold ice from the ridges across the margin and into the ice stream, which suppresses the shielding effect. The unknown geothermal heat flow beneath ice streams and inter ice-stream ridges is a major uncertainty in doing these calculations.

Raymond, Charles F.↗
NASA NTRS1993

Transition prediction and control in subsonic flow over a hump

The influence of a surface roughness element in the form of a two-dimensional hump on the transition location in a two-dimensional subsonic flow with a free-stream Mach number up to 0.8 is evaluated. Linear stability theory, coupled with the N-factor transition criterion, is used in the evaluation. The mean flow over the hump is calculated by solving the interacting boundary-layer equations; the viscous-inviscid coupling is taken into consideration, and the flow is solved within the separation bubble. The effects of hump height, length, location, and shape; unit Reynolds number; free-stream Mach number, continuous suction level; location of a suction strip; continuous cooling level; and location of a heating strip on the transition location are evaluated. The N-factor criterion predictions agree well with the experimental correlation of Fage; in addition, the N-factor criterion is more general and powerful than experimental correlations. The theoretically predicted effects of the hump's parameters and flow conditions on transition location are consistent and in agreement with both wind-tunnel and flight observations.

Masad, Jamal A.↗
NASA NTRS1991

Simulating boundary layer transition with low-Reynolds-number k-epsilon turbulence models. I - An evaluation of prediction characteristics. II - An approach to improving the predictions

The capability of two k-epsilon low-Reynolds number (LRN) turbulence models, those of Jones and Launder (1972) and Lam and Bremhorst (1981), to predict transition in external boundary-layer flows subject to free-stream turbulence is analyzed. Both models correctly predict the basic qualitative aspects of boundary-layer transition with free stream turbulence, but for calculations started at low values of certain defined Reynolds numbers, the transition is generally predicted at unrealistically early locations. Also, the methods predict transition lengths significantly shorter than those found experimentally. An approach to overcoming these deficiencies without abandoning the basic LRN k-epsilon framework is developed. This approach limits the production term in the turbulent kinetic energy equation and is based on a simple stability criterion. It is correlated to the free-stream turbulence value. The modification is shown to improve the qualitative and quantitative characteristics of the transition predictions.

Schmidt, R. C.↗
DOE OSTI2019

Single-step Conversion of Methyl Ethyl Ketone to Olefins over Zn x Zr y O z Catalysts in Water

In this study we investigated the conversion of aqueous methyl-ethyl-ketone (MEK) to olefin fuel precursors over Zn x Zr y O z mixed oxide catalysts. Experiments were carried out in water as MEK is intended to be produced from the dehydration of 2,3-butanediol in fermentation broth which is highly diluted in water. We demonstrated that Zn x Zr y O z catalysts are highly effective for converting aqueous MEK to C 4 -C 5 olefins. High selectivity to olefins equal to 85% was reached at 92% per pass conversion when under H 2 atmosphere. Catalyst stability was demonstrated for 60 hours' time on stream, highlighting the potential for upgrading 2,3-butanediol contained in fermentation broth without the need for energy-intensive water separation. Increased concentration of MEK in the aqueous feed results in increased activity towards olefin production. However, water inhibits catalyst deactivation from coking. A mechanistic investigation revealed the impact of the reaction environment (inert or reducing atmosphere) on the reaction pathways. In an inert environment, the mechanism involves consecutive aldol condensation of MEK and 3-pentanone intermediate. Under reducing conditions two reaction pathways compete with each other as MEK hydrogenation to butenes occurs concurrently with the aldol condensation/decomposition.

09 BIOMASS FUELS↗
NASA NTRS1973

Research in plasma physics

Three aspects of barium ion cloud dynamics are discussed. First, the effect of the ratio of ion cloud conductivity to background ionospheric conductivity on the motion of barium ion clouds is investigated and compared with observations of barium ion clouds. This study led to the suggestion that the conjugate ionosphere participates in the dynamics of barium ion clouds. Second, analytic work on the deformation of ion clouds is presented. Third, a linearized stability theory was extended to include the effect of the finite extent of an ion cloud, as well as the effect of the ratio of ion cloud to ionospheric conductivities. The stability properties of a plasma with contra-streaming ion beams parallel to a magnetic field are investigated. The results are interpreted in terms of parameters appropriate for collisionless shock waves. It is found that this particular instability can be operative only if the up-stream Alfven Mach number exceeds 5.5.

Source record↗
NASA NTRS1979

A theory of solar type 3 radio bursts

Energetic electrons propagating through the interplanetary medium are shown to excite the one dimensional oscillating two stream instability (OTSI). The OTSI is in turn stabilized by anomalous resistivity which completes the transfer of long wavelength Langmuir waves to short wavelengths, out of resonance with the electrons. The theory explains the small energy losses suffered by the electrons in propagating to 1 AU, the predominance of second harmonic radiation, and the observed correlation between radio and electron fluxes.

Goldstein, M. L.↗
NASA NTRS1979

A theory of solar type III radio bursts

A theory of type III bursts is reviewed. Energetic electrons propagating through the interplanetary medium are shown to excite the one dimensional oscillating two stream instability (OTSI). The OTSI is in turn stabilized by anomalous resistivity which completes the transfer of long wavelength Langmuir waves to short wavelengths, out of resonance with the electrons. The theory explains the small energy losses suffered by the electrons in propagating to 1 AU, the predominance of second harmonic radiation, and the observed correlation between radio and electron fluxes.

Goldstein, M. L.↗
NASA NTRS1978

Interaction of a tethered satellite with the atmosphere and the resultant environment

The calibration of apparatus like mass spectrometers under free molecular conditions and the design and execution of relevant calibration experiments in the transition regime in low density wind tunnels is addressed. Potential access to the tethered satellite for beam instrumentation is discussed and would involve aerodynamic design input on the satellite, both as to preferred shape for the experiments and aerodynamic control for up-stream pointing. Aerodynamic design for the purpose of stabilization and pointing is also discussed.

Deleeuw, J. H.↗
NASA NTRS1991

A comparison of numerical methods for the Rayleigh equation in unbounded domains

A second-order finite difference and two spectral methods, including a Chebyshev tau and a Chebyshev collocation method were implemented to determine the linear hydrodynamic stability of an unbounded shear flow. The velocity profile of the basic flow in the stability analysis mimicks that of a one-stream free mixing layer. Local and global eigenvalue solution methods are used to determine individual eigenvalues and the eigenvalue spectrum, respectively. The calculated eigenvalue spectrum includes a discrete mode, a continuous spectrum associated with the equation singularity and a continuous spectrum associated with the domain unboundedness. The efficiency and the accuracy of these discretization methods in the prediction of the eigensolutions of the discrete mode were evaluated by comparison with a conventional shooting procedure. Their capabilities in mapping out the continuous eigenvalue spectra are also discussed.

Liou, W. W.↗
NASA NTRS1990

On the Goertler vortex instability mechanism at hypersonic speeds

The linear instability of the hypersonic boundary layer on a curved wall is considered. As a starting point real-gas effects are ignored and the viscosity of the fluid is taken to be related to the temperature either by Chapman's Law or by Sutherland's Law. It is shown that the flow is susceptible to Goertler vortices. If Chapman's Law is used the vortices are trapped in the logarithmically thin adjustment layer in which the temperature of the basic flow changes rapidly to its free stream value and the nonuniqueness of the neutral stability curve associated with incompressible Goertler vortices is shown to disappear at high Mach numbers if the appropriate 'fast' streamwise dependence of the instability is built into the disturbance flow structure. If, on the other hand, Sutherland's Law is used, the vortices are found to spread into an O(1) region and the concept of a unique neutral stability curve is not tenable because of the nonparallel effects. For both laws the leading order terms in the expansions of the Goertler number are independent of the wave number and are due to the curvature of the basic state.

Hall, P.↗
DOE OSTI2019

H2@Scale: Economic Potential of Hydrogen as an Energy Intermediate

The H2@Scale concept envisions hydrogen as an energy intermediate across multiple energy sectors. The concept is motivated both by the opportunity to produce hydrogen from low-cost energy resources, and by the many potential applications of hydrogen, including as energy for transportation - used directly in fuel cell electric vehicles (FCEVs), as a feedstock for synthetic fuels, and to upgrade oil and biomass - feedstock for industry (e.g., for ammonia production, metals refining, and other end uses), heat for industry and buildings, and electricity storage. A key hydrogen production opportunity is using variable renewable electricity (i.e., electricity generated by wind turbines or solar photovoltaic panels) during hours when generation exceeds the load on the grid as a source of low-cost, dispatch constrained electricity (LDE). In addition to producing low-cost hydrogen, electrolysis can also serve as a form of responsive load on the electric grid, which can enhance grid stability, reduce curtailment, and create a supplementary revenue stream for generators. The future use and adoption of hydrogen across end-use applications depends both the cost of hydrogen production and on each application's threshold price (i.e., the maximum price each application will pay for hydrogen - above that price, the application has an alternative that is more economic). We estimate economic potential of the hydrogen market - the quantity of hydrogen at an equilibrium price at which suppliers are willing to produce and consumers are willing to buy the same quantity of hydrogen - by developing supply and demand curves for hydrogen production and use. The demand curves are based on the threshold price for various quantities of hydrogen in each market, which is affected by projected prices for alternatives that could provide the same service (e.g., fuel for vehicles, feedstock for metals refining). The supply curves include hydrogen produced via natural gas steam methane reforming, high-temperature electrolysis coupled with nuclear power plants, biomass gasification, and low-temperature electrolysis using LDE. We use a range of market and technology-advancement assumptions to estimate the economic potential for five scenarios in the mid 21st century timeframe, and the corresponding impacts on energy use and emissions. We estimate hydrogen's economic potential to be 14-48 MMT/yr in the contiguous United States - corresponding to 1.5-5 times current annual consumption - depending on key assumptions about the future market conditions and the success of hydrogen production research and development (R&D) in our five scenarios. As a result of the estimated economic potential markets, we also approximate that grid-integrated electrolysis can increase the penetration of wind generation in the electricity market by providing a value stream for LDE, and that total U.S. fossil fuel use could decline below a scenario with high renewable penetration on the grid. We find that hydrogen has potential to provide technical and economic synergies when integrated across multiple sectors of the U.S. energy system, but continued R&D, infrastructure, and market development for LDE are required.

08 HYDROGEN↗
NASA NTRS1978

High performance, high density hydrocarbon fuels

The fuels were selected from 77 original candidates on the basis of estimated merit index and cost effectiveness. The ten candidates consisted of 3 pure compounds, 4 chemical plant streams and 3 refinery streams. Critical physical and chemical properties of the candidate fuels were measured including heat of combustion, density, and viscosity as a function of temperature, freezing points, vapor pressure, boiling point, thermal stability. The best all around candidate was found to be a chemical plant olefin stream rich in dicyclopentadiene. This material has a high merit index and is available at low cost. Possible problem areas were identified as low temperature flow properties and thermal stability. An economic analysis was carried out to determine the production costs of top candidates. The chemical plant and refinery streams were all less than 44 cent/kg while the pure compounds were greater than 44 cent/kg. A literature survey was conducted on the state of the art of advanced hydrocarbon fuel technology as applied to high energy propellents. Several areas for additional research were identified.

Frankenfeld, J. W.↗
NASA NTRS1990

The effect of small streamwise velocity distortion on the boundary layer flow over a thin flat plate with application to boundary layer stability theory

Researchers show how an initially linear spanwise disturbance in the free stream velocity field is amplified by leading edge bluntness effects and ultimately leads to a small amplitude but linear spanwise motion far downstream from the edge. This spanwise motion is imposed on the boundary layer flow and ultimately causes an order-one change in its profile shape. The modified profiles are highly unstable and can support Tollmein-Schlichting wave growth well upstream of the theoretical lower branch of the neutral stability curve for a Blasius boundary layer.

Goldstein, M. E.↗
DOE OSTI2020

Raspberry colloid-templated approach for the synthesis of palladium-based oxidation catalysts with enhanced hydrothermal stability and low-temperature activity

It is becoming increasingly urgent to develop and utilize novel, more efficient and stable materials for mobile and stationary emission control applications as the deleterious consequences of anthropogenic air pollution are becoming more evident and pressing. Tightening regulations, particularly related to automotive exhaust treatment, together with continued improvements in engine design, that result in lowering the engine operating temperatures and inadvertently lead to the release of an overwhelming proportion of pollutants during the cold start, present new challenges for materials design, specifically for oxidation catalysts. In particular, improvements in the low-temperature activity while maintaining catalyst stability at high temperatures are required from the next-generation catalyst. Typical catalysts for removal of pollutants from automotive exhaust streams incorporate platinum group metals (PGMs). They tend to be inefficient at low temperatures (below 250 °C), thus accounting for the cold start problem, yet sinter and lose their activity at high temperatures that are frequently encountered during catalyst operation. High PGM loadings are often employed to compensate for catalyst inefficiencies and fast degradation, ultimately resulting in high-cost catalytic converters. Here, we have developed a new approach for the design and formation of catalytic materials that allows for both significantly more efficient PGM incorporation and improved overall catalyst performance at reduced PGM loadings. The method provides control over the composition and geometry of the support through self-assembly of sacrificial composite template — “raspberry” polymeric colloids decorated with catalytic particles — accompanied by infiltration with metal-oxide precursor and subsequent removal of the colloids. This method simultaneously structures the porous network and organizes the catalytic particles within it. Uniquely, the resulting catalytic particles are partially embedded in the support matrix and partially exposed to the pore interior, producing catalytic sites that are both stable and accessible. Herein, the feasibility of this novel and versatile approach for automotive catalytic conversion is demonstrated: the studies include testing alumina-based raspberry-colloid-templated (RCT) catalysts containing Pd nanoparticles (RCT Pd/Al2O3) for oxidation of propane and carbon monoxide under simulated diesel exhaust conditions and hydrothermal aging at 800 °C for 50 h in the simulated stream. The RCT Pd/Al2O3 catalysts exhibit exceptional activity toward CO oxidation, reduced reaction onset temperature, and high stability to elevated temperatures (demonstrated through prolonged exposure to temperatures up to 950 °C) and reactive gas streams, without migration, sintering or loss of the precious metal NPs. Notably, the novel catalyst shows the same or slightly better performance than the commercial catalysts even when the PGM load is reduced by ~80 % compared to the commercial counterparts. These results provide confidence for the utilization of the RCT approach for the fabrication of robust nanostructured catalysts for next-generation, energy-efficient catalytic converters with improved performance at low and high temperatures and reduced costs. The RCT methodology is, in addition, highly generalizable, and can thus be applied for the design of a wide range of catalytic systems in the automotive sector and beyond.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Evolutionary NAS in Light of Model Stability for Accurate Continual Learning

Continual learning, the capability to learn new knowledge from streaming data without forgetting the previous knowledge, is a critical requirement for dynamic learning systems, especially for emerging edge devices such as self-driving cars and drones. However, continual learning is still facing the catastrophic forgetting problem. Previous work illustrate that model performance on continual learning is not only related to the learning algorithms but also strongly dependent on the inherited model, i.e., the model where continual learning starts. The better stability of the inherited model, the less catastrophic forgetting and thus, the inherited model should be elaborately selected. Inspired by this finding, we develop an evolutionary neural architecture search (ENAS) algorithm that emphasizes the Stability of the inherited model, namely ENAS-S. ENAS-S aims to find optimal architectures for accurate continual learning on edge devices. On CIFAR-10 and CIFAR-100, we present that ENAS-S achieves competitive architectures with lower catastrophic forgetting and smaller model size when learning from a data stream, as compared with handcrafted DNNs.

Du, Xiaocong↗
NASA NTRS1994

Triple flame structure and diffusion flame stabilization

The stabilization of diffusion flames is studied using asymptotic techniques and numerical tools. The configuration studied corresponds to parallel streams of cold oxidizer and fuel initially separated by a splitter plate. It is shown that stabilization of a diffusion flame may only occur in this situation by two processes. First, the flame may be stabilized behind the flame holder in the wake of the splitter plate. For this case, numerical simulations confirm scalings previously predicted by asymptotic analysis. Second, the flame may be lifted. In this case a triple flame is found at longer distances downstream of the flame holder. The structure and propagation speed of this flame are studied by using an actively controlled numerical technique in which the triple flame is tracked in its own reference frame. It is then possible to investigate the triple flame structure and velocity. It is shown, as suggested from asymptotic analysis, that heat release may induce displacement speeds of the triple flame larger than the laminar flame speed corresponding to the stoichiometric conditions prevailing in the mixture approaching the triple flame. In addition to studying the characteristics of triple flames in a uniform flow, their resistance to turbulence is investigated by subjecting triple flames to different vortical configurations.

Veynante, D.↗
NASA NTRS1988

Analysis of 5 KHz combustion instabilities in 40K methane/LOX combustion chambers

In 40K methane/LOX 5 KHz engine tests, (first transverse mode) combustion instabilities observed by Rocketdyne are analyzed using Heidmann and Wieber's vaporization model to include LOX flow oscillations. The LOX flow oscillations are determined by including acoustic waves in the feed system analysis. The major parameter controlling stability is the distance (or time delay) associated with atomizing the LOX stream in the coaxial injection system. Results of the analysis that show the influence of mixture ratio, oxidizer and fuel injection velocities, burning time and combustion chamber/injector dimensions on stability are used to explain the existing data. Calculated results to predict the influence of design changes being made for the next set of experiments are also presented.

Breisacher, Kevin J.↗