Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “reference site conditions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

Corrosion Atmospheric Exposure Facility PRL #239 SWMU Assessment Report/Confirmation Sampling Work Plan

The National Aeronautics and Space Administration (NASA) Resource Conservation and Recovery Act (RCRA) permit requires identification and evaluation of known Solid Waste Management Units (SWMU) located at the Kennedy Space Center (KSC). The Corrosion Atmospheric Exposure Facility (CAEF), also known as facility number K8-0600, and the Corrosion Test Area (CTA); also known as facility number K8-0237, herein referred to as the site, is designated Potential Release Location (PRL) 239 under the NASA RCRA permit. A SWMU Assessment (SA) was conducted between November 2019 and February 2020 to identify potential environmental impacts related to current and historic operations being conducted at the site. The SA included a site reconnaissance visit in February 2020, interviews with various personnel possessing knowledge of past work practices and operations at the site, and review of available historical documentation, engineering drawings, and facility inspection reports. Current site conditions were documented in photographs. Soil types and wildlife habitat were also evaluated. The objective of the assessment was to identify potential locations of concern (LOC) at the site and to determine whether further evaluation is required.

Kimberly Clower↗
NASA NTRSDate not supplied

Creating A Consistent Historical NASA POWER Solar Radiation Dataset to Support Renewable Energy, Building Energy Efficiency and Agro-Climatology Decisions

Prediction of Worldwide Energy Resources (POWER) project provides irradiance dataset to support renewable energy, building energy efficiency and agricultural needs. These datasets are derived from Global Energy and Water Cycle Experiment Surface Radiation Budget (GEWEX SRB) and Clouds and the Earth’s Radiant Energy System (CERES SYN1Deg). A systematic bias has been reported between these two datasets for the years with overlapping observations. For obtaining a consistent climate data record spanning the entire time record of observations, it is crucial to understand and remove the bias in the irradiance dataset. Inconsistency in solar radiation data can lead to inaccurate conclusions about solar energy potential and obscure real trends in solar radiation patterns that would impact energy availability assessments. In this study, we adapt quantile mapping approach to remove the systematic bias and to improve reliability of shortwave and longwave irradiance data. We present a validation of the bias corrected data against ground truth. For each 1° latitude and 1° longitude grid box across the globe, we match the CDFs of the reference dataset (CERES SYN1Deg) to that of the SRB dataset, thereby, adjusting the irradiance values to match the empirical distribution of two different measurements. The performance of quantile mapping is evaluated by using the metrics such as Mean Absolute Deviation (MAD). The results indicate that the quantile mapping significantly improves the accuracy and reliability of solar irradiance dataset especially for the weather conditions associated with high cloud cover and extreme irradiance values. The initial range of MAD for the studied sites for daily data was 4 to 19 Wm-2. After correction these reduced to 3 to 7 Wm-2. The findings from this study have important implications for solar energy system design, agricultural planning, and climate modeling community. Reducing the inconsistency and biases in solar irradiance dataset can enable better planning and operation of solar energy systems, leading to increased efficiency and cost-effectiveness. Additionally, this work also contributes to the statistical post-processing techniques in the renewable energy domain and highlights the potential of historical and near-real-time NASA POWER dataset as a valuable resource for solar energy research and applications.

POWER↗
NASA NTRS1973

An exploratory simulation study of a head-up display for general aviation lightplanes

The concept of a simplified head-up display referred to as a landing-site indicator (LASI) for use in lightplanes is discussed. Results of a fixed-base simulation study exploring the feasibility of the LASI concept are presented in terms of measurements of pilot performance, control-activity parameters, and subjective comments of four test subjects. These subjects, all of whom had various degrees of piloting experience in this type aircraft, performed a series of simulated landings both with and without the LASI starting from different initial conditions in the final approach leg of the landing maneuver.

Harris, R. L., Sr.↗
NASA NTRS2015

Evaluation of Spaceborne L-band Radiometer Measurements for Terrestrial Freeze/Thaw Retrievals in Canada

The landscape freeze/thaw (FT) state has an important impact on the surface energy balance, carbon fluxes, and hydrologic processes; the timing of spring melt is linked to active layer dynamics in permafrost areas. L-band (1.4 GHz) microwave emission could allow the monitoring of surface state dynamics due to its sensitivity to the pronounced permittivity difference between frozen and thawed soil. The aim of this paper is to evaluate the performance of both Aquarius and Soil Moisture and Ocean Salinity (SMOS) L-band passive microwave measurements using a polarization ratio-based algorithm for landscape FT monitoring. Weekly L-band satellite observations are compared with a large set of reference data at 48 sites across Canada spanning three environments: tundra, boreal forest, and prairies. The reference data include in situ measurements of soil temperature (Tsoil) and air temperature (Tair), and Moderate Resolution Imaging Spectroradiometer (MODIS) land surface temperature (LST) and snow cover area (SCA) products. Results show generally good agreement between Lband FT detection and the surface state estimated from four reference datasets. The best apparent accuracies for all seasons are obtained using Tair as the reference. Aquarius radiometer 2 (incidence angle of 39.6) data gives the best accuracies (90.8), while for SMOS the best results (87.8 of accuracy) are obtained at higher incidence angles (55- 60). The FT algorithm identifies both freeze onset and end with a delay of about one week in tundra and two weeks in forest and prairies, when compared to Tair. The analysis shows a stronger FT signal at tundra sites due to the typically clean transitions between consistently frozen and thawed conditions (and vice versa) and the absence of surface vegetation. Results in the prairies were poorer because of the influence of vegetation growth in summer (which decreases the polarization ratio) and the high frequency of ephemeral thaw events during winter. Freeze onset and end maps created from the same algorithm applied to SMOS and Aquarius measurements characterize similar FT patterns over Canada. This study shows the potential of using L-band spaceborne observations for FT monitoring, but underlines some limitations due to ice crusts in the snowpack, liquid water content in snow cover during the spring freeze to thaw transition, and vegetation growth.

soil freeze/thaw↗
NASA NTRS2019

Evaluation of the Surface Reflectance Long-Term Data Record from AVHRR over Multiple Land Surface Types

In this work, we evaluate the performance of the AVHRR surface reflectance LTDR V4 using Landsat-5 Thematic Mapper (TM5) Collection-1 surface reflectance data over 440 globally distributed sites, which give a representative set of land surface types and climate conditions. Surface reflectance anisotropy effects were normalized using the VJB method, and spectral response differences were accounted for with spectral band adjustment factors (SBAFs) computed as a function of the Normalized Difference Vegetation Index (NDVI) from a set of over 100,000 hyperspectral spectra from Hyperion. The performance of the AVHRR record is reported in terms of the accuracy, precision, and uncertainty, as compared to the specifications of the reference product. Results show that the AVHRR record performance is close to the 0.071ρ+0.0071 specification defined in the original TM5 product evaluation.

LTDR↗
DOE OSTI2026

Reduced-Order CFD Modeling to Support Waste Loading Optimization in Hanford WTP Vitrification

The U.S. DOE Hanford Site stores over 56 million gallons of radioactive liquid tank waste that must be treated and immobilized for long-term disposal The Waste Treatment and Immobilization Plant (WTP) will vitrify this waste by feeding it into Joule-heated melters, where it is incorporated into a stable borosilicate glass Computational fluid dynamics (CFD) simulations of glass melters can provide insight into the maximum achievable waste loading under varying melter operating conditions Fully resolved VOF multiphase simulations were used as the reference model to capture bubble-driven convection in the melter, including bubble formation, rise behavior, and induced glass melt circulation Effective bubble column diameter and rise velocity were extracted from the resolved simulations, compared with empirical correlations, and refit across relevant viscosity and gas flow rate conditions Explicit gas–liquid interface tracking was replaced with a single-phase momentum source term model, enabling faster steady-state CFD simulations while preserving the dominant hydrodynamic effects of bubbling New empirical correlations were developed for effective bubble column diameter and bubble rise velocity by fitting resolved simulation data across expected melter viscosity and gas flow rate ranges, providing improved inputs for the momentum source term model compared with existing literature correlations The momentum source term model reduced fluid-domain mesh size by 89% and achieved an 8.4× computational speedup relative to resolved bubbling simulations The validated momentum source term approach enables prediction of process-relevant heat transfer behavior in the integrated melter model, including heat transfer from the molten glass to the cold cap, plenum, refractory walls, and surrounding structural regions under varying melter operating conditions

12 - MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTE↗
NASA NTRS1999

Analyses of Transistor Punchthrough Failures

The failure of two transistors in the Altitude Switch Assembly for the Solid Rocket Booster followed by two additional failures a year later presented a challenge to failure analysts. These devices had successfully worked for many years on numerous missions. There was no history of failures with this type of device. Extensive checks of the test procedures gave no indication for a source of the cause. The devices were manufactured more than twenty years ago and failure information on this lot date code was not readily available. External visual exam, radiography, PEID, and leak testing were performed with nominal results Electrical testing indicated nearly identical base-emitter and base-collector characteristics (both forward and reverse) with a low resistance short emitter to collector. These characteristics are indicative of a classic failure mechanism called punchthrough. In failure analysis punchthrough refers to an condition where a relatively low voltage pulse causes the device to conduct very hard producing localized areas of thermal runaway or "hot spots". At one or more of these hot spots, the excessive currents melt the silicon. Heavily doped emitter material diffuses through the base region to the collector forming a diffusion pipe shorting the emitter to base to collector. Upon cooling, an alloy junction forms between the pipe and the base region. Generally, the hot spot (punch-through site) is under the bond and no surface artifact is visible. The devices were delidded and the internal structures were examined microscopically. The gold emitter lead was melted on one device, but others had anomalies in the metallization around the in-tact emitter bonds. The SEM examination confirmed some anomalies to be cosmetic defects while other anomalies were artifacts of the punchthrough site. Subsequent to these analyses, the contractor determined that some irregular testing procedures occurred at the time of the failures heretofore unreported. These testing irregularities involved the use of a breakout box and were the likely cause of the failures. There was no evidence to suggest a generic failure mechanism was responsible for the failure of these transistors.

Nicolas, David P.↗
NASA NTRS2000

BOREAS RSS-17 1994 ERS-1 Level-3 Freeze/Thaw Backscatter Change Images

The Boreal Ecosystem-Atmosphere Study (BOREAS) Remote Sensing Science (RSS)-17 team acquired and analyzed imaging radar data from the European Space Agency's (ESA's) European Remote Sensing Satellite (ERS)-1 over a complete annual cycle at the BOREAS sites in Canada in 1994 to detect shifts in radar backscatter related to varying environmental conditions. Two independent transitions corresponding to soil thaw and possible canopy thaw were revealed by the data. The results demonstrated that radar provides an ability to observe thaw transitions at the beginning of the growing season, which in turn helps constrain the length of the growing season. The data set presented here includes change maps derived from radar backscatter images that were mosaicked together to cover the southern BOREAS sites. The image values used for calculating the changes are given relative to the reference mosaic image. The data are stored in binary image format files. The imaging radar data are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).

Rignot, Eric↗
DOE OSTI2023

Compaction of crushed salt for safe containment – a summary of the KOMPASS projects

Abstract. For the underground disposal of high-level nuclear waste in rock salt formations, the safety concept includes the backfilling of open cavities with crushed salt. For the prognosis of the sealing function of the backfill for the safe containment of the radioactive waste, it is crucial to have a comprehensive process understanding of the crushed-salt compaction behavior. The crushed-salt compaction process is influenced by internal properties (e.g., grain size, mineralogy, and moisture content) and boundary conditions (e.g., temperature, stress state, and compaction rate) and, therefore, involves several coupled thermal–hydro–mechanical (THM) processes (Hansen et al., 2014; Kröhn et al., 2017). With the paradigm shift from the limited release of radionuclides to safe containment due to the German Repository Site Selection Act passed in 2017, the importance of crushed salt as geotechnical barrier has increased, with a focus on the evolution of its hydraulic properties. Based on the knowledge gaps in the current process understanding, the “Compaction of crushed salt for safe containment” (KOMPASS) projects were initiated to improve the scientific basis behind using crushed salt for the long-term isolation of high-level nuclear waste within rock salt repositories. The efforts to improve the prediction of crushed-salt compaction begun during the first phase of the KOMPASS projects (Czaikowski et al., 2020) and were followed up in a second phase ending in June 2023. The primary achievements of the projects are as follows (Czaikowski et al., 2020; Friedenberg et al., 2022): specification of the KOMPASS reference material, an easily available and reproducible synthetic crushed-salt material, for generic investigations; development of pre-compaction methods and successful production of samples in the short term and under in situ loading conditions; formulation of an extended laboratory program addressing the isolated investigation of known relevant factors influencing the compaction behavior of crushed salt (Düsterloh et al., 2022); execution of long-term compaction tests addressing isotropic and deviatoric load changes, temperature, and compaction state; construction of a backfill body using the KOMPASS reference material in the Sondershausen mine through collaboration with the SAVER (Entwicklung eines salzgrusbasierten Versatzkonzepts unter der Option Rückholbarkeit) project (Schaarschmidt and Friedenberg, 2022); advancement of the tools for microstructure investigation methods (Svensson and Laurich, 2022); generation (first stages) of a microphysical process list combining literature research with our own findings; benchmarking of long-term compaction test for model development and optimization of various existing models as well as the development of new models; application of a virtual demonstrator (2D model representing a backfilled drift in rock salt) for the visualization of developments and the quantification of the models (Rabbel, 2022). In summary, the KOMPASS projects contributed to the reduction of uncertainties and the strengthening of the safety case for using crushed salt within rock salt repositories.

Friedenberg, Larissa↗
NASA NTRS2000

A New Interferometer for Monitoring Atmospheric Phase Fluctuations

Water vapor in the Earth's troposphere introduces an extra electrical path in the propagation of radio signals through the atmosphere. The distribution of water vapor is irregular and distorts the wavefronts of incoming radio waves, limiting the angular resolution that can be achieved with ground-based telescopes. The level of fluctuations depends both on the location of the site ,and on the prevailing atmospheric conditions. The ability to measure the fluctuations is therefore important when choosing a site for a new instrument, and for scheduling observations of existing telescopes. Existing phase monitors are radio interferometers that monitor monochromatic beacon tones from geostationary communications satellites at a frequency of about 12 GHz. They have a classical heterodyne design based on two satellite receiving antennas; each has a front-end for amplifying and down-converting the incoming signals using a local oscillator that is phase-locked to a common reference frequency. In addition to multiple phase-locked loops these instruments require expensive phase-stable cabling to reduce the effects of thermal drift. The new system uses two consumer 18" digital satellite TV dishes to monitor satellite TV broadcast signals over a bandwidth of 500 MHz (12.2 to 12.7 GHz). The novel design eliminates the need for phase-locked loops and thermally stable components, and uses a pair of Gilbert Cell multipliers to perform the broadband correlation. A phase monitor has been been built and deployed at the site of the Berkeley-Illinois-Maryland Association Millimeter Array in Northern California, and has been operating successfully since June 1998, measuring the difference in electrical path length for parallel lines of sight to the satellite separated by a baseline of 100 m. With a hardware cost of approximately $4000, it is much cheaper than previous instruments, and the low power requirements and high reliability make the system suitable for site testing in remote locations.

Lay, Oliver↗
NASA NTRS1992

Simulations of surface winds at the Viking Lander sites using a one-level model

The one-level model developed by Mass and Dempsey for use in predicting surface flows in regions of complex terrain was adapted to simulate surface flows at the Viking lander sites on Mars. In the one-level model, prediction equations for surface winds and temperatures are formulated and solved. Surface temperatures change with time in response to diabatic heating, horizontal advection, adiabatic heating and cooling effects, and horizontal diffusion. Surface winds can change in response to horizontal advection, pressure gradient forces, Coriolis forces, surface drag, and horizontal diffusion. Surface pressures are determined by integration of the hydrostatic equation from the surface to some reference level. The model has successfully simulated surface flows under a variety of conditions in complex-terrain regions on Earth.

Bridger, Alison F. C.↗
DOE OSTI2026

A total of 19 months of daily weather logging on the US east coast: the WFIP3 event log

The Third Wind Forecast Improvement Project (WFIP3) is a multi-institutional field campaign designed to advance the understanding and prediction of the offshore atmospheric boundary layer along the US east coast. Extending from February 2024 through August 2025, WFIP3 combines long-term coastal and offshore measurements with targeted modeling and forecasting efforts. This data paper presents the WFIP3 event log, a curated record of 578 d of meteorological phenomena and field observations that complements the campaign's extensive high-frequency datasets. The event log provides both manually documented daily weather discussions and automatically derived indicators of atmospheric processes – including low-level jets, wind ramps, extreme wind veer, and weak wind conditions – based on observations from scanning lidars deployed at three coastal and offshore sites. The dataset offers structured metadata, standardized time and site identifiers, and consistent terminology to facilitate its integration with WFIP3's observational and modeling data products. The log supports diverse applications, from model evaluation and forecast verification to the selection of case studies on offshore boundary-layer dynamics. The WFIP3 event log is publicly available through the US Department of Energy's Wind Data Hub, providing the research community with a transparent and enduring contextual reference for the interpretation and use of WFIP3 measurements.

17 WIND ENERGY↗
NASA NTRS1993

Optical characterization of LDEF contaminant film

Dark brown molecular film deposits were found at numerous locations on the Long Duration Exposure Facility (LDEF) and have been documented in great detail by several investigators. The exact deposition mechanism for these deposits is as yet unknown, although direct and scattered atomic oxygen, and solar radiation interacting with materials outgassing products have all been implicated in the formation process. Specimens of the brown molecular film were taken from below the flange of the experimental tray located at position D10 on the LDEF. The tray was one of two, comprising the same experiment, the other being located on the wake facing side of the LDEF satellite at position B4. Having access to both trays, we were able to directly compare the effect that orientation with respect to the atomic oxygen flux vector had on the formation of the brown molecular film deposits. The film is thickest on surfaces facing toward the exterior, i.e. the tray corner, as can be seen by comparing the lee and wake aspects of the rivets. The patterns appear to be aligned not with the velocity vector but with the corner of the tray suggesting that flux to the surface is due to scattered atomic oxygen rather than direct ram impingement. The role of scattered flux is further supported by more faint plume patterns on the sides of the tray. The angle of these plumes is strongly aligned with the ram direction but the outline of the deposit implies that incident atoms are scattered by collisions with the edges of the opening resulting in a directed, but diffuse, flux of atomic oxygen to the surface. Spectral reflectance measurements in the 2 to 10 micron (4000 to 1000 wavenumbers) spectral range are presented for the film in the 'as deposited' condition and for the free standing film. The material was analyzed by FTIR (Fourier Transform Infrared) microspectroscopy using gold as the reference standard. The 'as deposited' specimen was on an aluminum rivet taken from beneath the tray flange while the free film was obtained by chipping some of the material from the rivet. The transmission spectrum over the 2 to 10 micron range for the free film is presented. This spectrum appears to be essentially the same as that presented by Crutcher et.al. for films formed at vent sites which faced into the ram direction and suggested to originate from urethanes and silicones used on the LDEF. Banks et. al. state that silicones, when exposed to atomic oxygen, release polymeric scission fragments which deposit on surfaces and form a glassy, dark contaminant layer upon further atomic oxygen exposure and solar irradiation.

Blakkolb, Brian K.↗
DOE OSTI2023

High-Throughput Directed Evolution of Marine Microalgae and Phototrophic Consortia for Improved Biomass Yields (Final Report)

Primary project achievements include using selective pressures (O 2 , light, temperature) and developing culturing regimes for the diatom Nitzschia inconspicua str. hildebrandi to attain enrichments with an ~90% increase in areal biomass productivity relative to the parental strain under pond-mimicking conditions with high O 2 stress in laboratory bioreactors. The resulting strain (GAI-337) was tested further for dilution time, culture density, CO 2 supplementation, pH, temperature, and dissolved O 2 concentration under outdoor pond-mimicking conditions to improve areal productivities. These experiments yielded an optimum harvest and dilution time just after sunset, ~0.45 g AFDW L -1 initial culture density for maximal productivities, no requirement for CO 2 supplementation or pH control, maximal performance under a diel temperature curve going from 24 °C at night to 36 °C during the day, and benefits from some O 2 removal from the culture by bubbling with air. Using pond-mimicking laboratory bioreactors, N. inconspicua GAI-337 achieved ~42 g AFDW m -2 d -1 . Nutrient limitation experiments resulted in a biomass composition that equated to ~160 Gallons of Gasoline Equivalent energy per ton AFDW, highlighting the potential of GAI-337 as a promising renewable fuel feedstock strain. Genome resequencing has revealed genome alterations potentially contributing to the improved growth of GAI-337 in the laboratory. Based on the comparative analyses of the GAI-337 and GAI-229 (reference) strains, we identified 144 single nucleotide substitutions that resulted in amino acid change, 7 single nucleotide substitutions that resulted in protein truncation; 5 deletions; and 1 frameshift mutation. From the mutations that potentially affect expression of functionally annotated genes, particular interest was noted for an interferon-induced 6-16 family protein that may be involved in the host immune response against microbe invasion; the chaperone protein DnaK, which may function to protect the folding of proteins within the cell; and SPRY domain protein that is found in many eukaryotic proteins important in cell signaling pathways. Transcriptome analysis revealed over 1000 genes with increased transcript levels. Many of these and many of the genes with mutations are not yet functionally annotated and an increased bioinformatics effort is necessary to more completely analyze the Nitzschia inconspicua genome. Adaptive laboratory evolution (ALE) was performed for over 300 days using consecutive 0.5°C temperature increases in a constant temperature incubator to attain greater thermal tolerance in Nitzschia inconspicua. The adapted strain was able to grow at a constant temperature of 37.5°C; whereas this constant temperature was lethal to the parental control, which had an upper temperature boundary of 35.5°C prior to adaptive evolution. Several high-temperature clonal isolates were obtained from the evolved population following ALE, and increased temperature tolerance was observed in clonal adapted cultures. The final temperature adaptation was maintained through cryopreservation and was observed in multiple clonal isolates, including multiple clonal isolates with significantly increased cell size, indicating the potential occurrence of a sexual cycle during the clonal isolation process. A survey of Nannochloropsis strains was conducted for tolerances to high pH and high bicarbonate media. Nannochloropsis granulata showed promising growth in diel bioreactors and was successfully grown at the GAI Kauai farm site in long-term growth campaigns. Co-culturing using Nitzschia inconspicua, Nannochloropsis and a cyanobacterium were assembled in the laboratory to determine if productivity synergies could be attained. Although all strains grew well in the laboratory high-bicarbonate media individually, the cyanobacterium quickly outgrew the other strains in the laboratory consortium pushing the co-culture away from a diverse (and potentially synergistic assemblage) phototroph culture towards a monoculture dominated by the cyanobacterium. Several outdoor growth campaigns were conducted, with productivities ranging between 10-20 g/m 2 /d of biomass. The best performing strain in the laboratory (GAI-337) did not outperform reference strains at the Kauai farm under the conditions used. Addition growth campaigns are necessary under conditions that result in higher biomass (>20 g/m 2 /d) and that attain higher O 2 levels are likely necessary. Initial data indicate that the thermally adapted strain did slightly better than the control strain at higher temperatures; however, additional campaigns are necessary to establish statistical significance. In summary, Nitzschia inconspicua is able to attain exemplary biomass and lipid yields in the laboratory bioreactors. Strain evolution to both O 2 and temperature resulted in targeted strain improvements. Additional outdoor campaigns are necessary to determine if laboratory improvements translate to the field.

09 BIOMASS FUELS↗
NASA NTRS2005

Afterbody Heating Predictions for a Mars Science Laboratory Entry Vehicle

The Mars Science Laboratory mission intends to deliver a large rover to the Martian surface within 10 km of its target site. One candidate entry vehicle aeroshell consists of a 3.75-m diameter, 70-deg sphere-cone forebody and a biconic afterbody similar to that of Viking. This paper presents computational fluid dynamics predictions of laminar afterbody heating rates for this configuration and a 2010 arrival at Mars. Computational solutions at flight conditions used an 8-species Mars gas model in chemical and thermal non-equilibrium. A grid resolution study examined the effects of mesh spacing on afterbody heating rates and resulted in grids used for heating predictions on a reference entry trajectory. Afterbody heating rate reaches its maximum value near 0.6 W/sq cm on the first windward afterbody cone at the time of peak freestream dynamic pressure. Predicted afterbody heating rates generally are below 3% of the forebody laminar nose cap heating rate throughout the design trajectory. The heating rates integrated over time provide total heat load during entry, which drives thermal protection material thickness.

Edquist, Karl T.↗
DOE OSTI2020

Estimating total attenuation using Rayleigh targets at cloud top: applications in multilayer and mixed-phase clouds observed by ground-based multifrequency radars

At millimeter wavelengths, attenuation by hydrometeors, such as liquid droplets or large snowflakes, is generally not negligible. When using multifrequency ground-based radar measurements, it is common practice to use the Rayleigh targets at cloud top as a reference in order to derive attenuation-corrected reflectivities and meaningful dual-frequency ratios (DFRs). By capitalizing on this idea, this study describes a new quality-controlled approach that aims at identifying regions of cloud where particle growth is negligible. The core of the method is the identification of a “Rayleigh plateau”, i.e., a large enough region near cloud top where the vertical gradient of DFR remains small. By analyzing co-located Ka–W band radar and microwave radiometer (MWR) observations taken at two European sites under various meteorological conditions, it is shown how the resulting estimates of differential path-integrated attenuation (ΔPIA) can be used to characterize hydrometeor properties. When the ΔPIA is predominantly produced by cloud liquid droplets, this technique alone can provide accurate estimates of the liquid water path. When combined with MWR observations, this methodology paves the way towards profiling the cloud liquid water, quality-flagging the MWR retrieval for rain and drizzle contamination, and/or estimating the snow differential attenuation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Recent Developments in Revealing the Impact of Complex Metal Oxide Reconstruction on Catalysis

Surface reconstruction of complex metal oxides refers to the alterations of the topmost catalyst surface, relative to the bulk structure, following exposure to pretreatment or reaction conditions during heterogeneous catalysis. (1) This structural and electronic transformation may involve (1) changes of the exposed crystallographic facets, (2) changes in chemical composition, such as the enrichment of specific elements, and, (3) morphological variations, including surface roughness and defects (Scheme 1). Beyond relaxation, surface reconstruction here also encompasses disruptions to the periodicity of the sublayers and changes to its stoichiometry. This change significantly influences the chemical properties of the catalyst surface, such as redox sites, (2) acid/base pairs, hydroxyl groups, (3) and surface defects. Surface reconstruction occurs due to the thermodynamic drive to lower the surface energy of the catalyst under the surrounding environment (e.g., temperature, chemical potential of species present). In addition to the treatment or reaction conditions, the extent of reconstruction also depends on the elements in the metal oxide structure. For instance, annealing ABO 3 perovskites (SrTiO 3 , BaTiO 3 , and BaZrO 3 ) at high temperatures (500 °C) in O 2 has a very different impact on the A/B ratio at the surface (ranging from 0.9 to 2.5), depending on the identity of A and B. (4) Metal oxide surface reconstruction under an electric field and exposure to acidic and alkaline media has recently gained increased attention in electrocatalysis, such as in the oxygen evolution reaction (OER); (5,6) however, in this Viewpoint we focus on the impact of surface reconstruction on thermal catalysis, a critical enduring research theme with ongoing challenges. Here, we start showcasing approaches to characterize surface reconstruction at the topmost surface layer, such as low-energy ion scattering (LEIS), discussing advantages and limitations. Next, we connect characterization of surface reconstruction to site-specific kinetic analysis, enabled via steady-state isotopic transient kinetic analysis (SSITKA), and we express our viewpoint on building structure–performance relationships by deeply understanding reconstructed surfaces. Later, we comment on the potential of tuning surface reconstruction to enhance catalytic performance. Finally, we explore the interplay between surface reconstruction and the “intelligent behavior”.

alcohol conversion↗
DOE OSTI2021

NRAP-Open-IAM Analytical Reservoir Model: Development and Testing

Geological carbon sequestration (GCS) is a key technology for reducing global carbon dioxide (CO 2 ) emissions. Over the last decade, the U.S. Department of Energy has invested in understanding the science base, developing practical implementation methods, and demonstrating secure GCS technologies to mitigate the environmental impacts associated with the atmospheric release of CO 2 . As part of the National Risk Assessment Partnership, a systems-level risk assessment tool, called the NRAP-Open-IAM, has been developed to conduct risk assessment and enable safe operations at a GCS site. The current NRAP-Open-IAM contains a simple reservoir model component that calculates the evolution of CO 2 saturation and fluid pressure in a storage reservoir during CO 2 injection operations. This report presents the development and testing of a new analytical reservoir reduced-order model (ROM), which is extended from an existing semi-analytical model for estimation of CO 2 and brine leakage along legacy wells, and enhances the capability of the NRAP-Open-IAM to simulate more types of reservoir conditions. The developed model is validated against three reference studies, and the results indicate that the new ROM predicts the behavior of the two-phase fluids (brine and injected CO 2 ) well and is applicable to different reservoir simulation boundary conditions (i.e., constant pressure boundary and infinite-acting boundary) without a priori user specification of the boundary type. Sensitivity analysis for a set of model parameters is performed using 4,000 synthetic cases prepared via a fully automated process and using machine-learning-based feature selection. The stochastic analysis identifies gravitational number (i.e., ratio of gravitational forces to viscous force) and distance between the injection well and observation location as the most impactful parameters for matching the pressure and CO 2 saturation, respectively, between the numerical simulations and the ROM. This report details the possible ROM uncertainties and serves as a guide for users to understand the use and limitations of this ROM. The code implementation of the model will be released as a module within the NRAP-Open-IAM.

54 ENVIRONMENTAL SCIENCES↗